• Title/Summary/Keyword: 석유화학산업

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Magnetic Properties of NiZn-ferrite Synthesized from The Refined Waste Iron Oxide Catalyst (정제된 산화철 폐촉매로부터 합성된 NiZn-페라이트의 자기적 특성)

  • Park, Sang-Il;Lee, Hyo-Sook;Choi, Hyun-Seok;Hwang, Yeon
    • Korean Journal of Crystallography
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    • v.14 no.1
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    • pp.1-6
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    • 2003
  • NiZn-ferrites were synthesized from the waste catalysts. which were by product of styrene monomer process and buried underground as an industrial wastes, and their magnetic properties were investigated. Nickel oxide and zinc oxide powders were mixed with finely ground waste catalysts, and spinel type ferrite was obtained by calcination at 900℃ and sintering at 1325℃ for 5 hours. The initial permeabilities were measured and reflection losses were calculated from S-parameters for the composition of Ni/sub x/Zn/sub 1-x/Fe₂O₄(x=0.36, 0.50, 0.66) and (Ni/sub 0.5/Zn/sub 0.5)/sub 1-y/Fe/sub 2+y/O₄(y=-0.02, 0, 0.02).

Magnetic Properties of NiZn-ferrite Synthesized from Waste Iron Oxide Catalyst (산화철 폐촉매로부터 합성된 NiZn- 페라이트의 자기적 특성)

  • Hwang, Yeon;Kwon, Soon-Kil;Lee, Hyo-Sook;Je, Hae-June;Park, Sang-Il
    • Journal of the Korean Ceramic Society
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    • v.38 no.12
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    • pp.1162-1166
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    • 2001
  • NiZn-ferrite was synthesized from waste catalysts, which were produced from styrene monomer process and buried underground as an industrial wastes, and its magnetic properties were investigated. Nickel oxide and zinc oxide powders were mixed with finely ground waste catalysts, and spinel type ferrite was obtained by calcination at 900$\^{C}$ and sintering at 1230$\^{C}$ for 5 hours. The intial permeability was measured and reflection loss was calculated from S-parameters for the composition of Ni$\_$x/Zn$\_$1-x/Fe$_2$O$_4$(x=0.36, 0.50, 0.66). NiZn-ferrite synthesized from waste iron oxide catalyst showed a feasibility for the use as electromagnetic wave absorber in X-band.

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Introduction to Thermal Insulating Materials and Silica Aerogels (열 차단 소재와 실리카 에어로젤 개요)

  • Hong, Jin-Ho;Kim, Il;Yun, Ju-Ho;Shim, Sang-Eun
    • Elastomers and Composites
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    • v.46 no.1
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    • pp.29-36
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    • 2011
  • The term 'thermal insulating materials' describes a class of materials which can improve the thermal efficiency by reducing the thermal conduction, convention and radiation between the inside and outside of the system. As a thermal insulating material, numerous industrial applications are possible including the automobile, aerospace, aviation, and petrochemical. Especially, the silica aerogel, with their superior thermal insulating behavior, has been widely used as thermal insulating materials. Because the mechanical properties of the silica aerogel cannot meet the industrial demand, use of the silica aerogel is limited. This article aims to review the thermal insulating materials and silica aerogel, and to introduce the silica aerogel/polymer composites.

Implementation of fluid flow measuring and warning alarm system using an WeMos and an fluid flow sensor (WeMos와 유량 센서를 이용한 유속 모니터링 및 경보 알림 시스템 구현)

  • Yoo, Moonsung
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.19 no.1
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    • pp.139-143
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    • 2019
  • Measurement of flow rate is required in various fields. Water meters are often used at home, and flow meters are used in water and sewage plants, petrochemical industries and so on.. A system is needed to monitor the flow rate in real time and notify immediately when flow rate is abnormal. Recently, with the development of the IoT it is possible to construct such devices at low cost. WeMos can be programmed with Arduino IDE as a mini wifii IoT module. The flow sensor can output a digital pulse proportional to the flow rate. In this paper, we developed the flow monitoring and warning system using WeMos and IoT technology. When the system operates, it calculates the flow rate, sends the value as JSON format to the server, monitors the flow rate as graph from the remote with the smartphone. We also implement the system to promptly send alert message to the smart phone using Pushbullet when the flow rate is abnormal.

A Study of The reference value of the CUSUM control chart that can detect small average changes in the process

  • Jun, Sang-Pyo
    • Journal of the Korea Society of Computer and Information
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    • v.25 no.12
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    • pp.73-82
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    • 2020
  • Most process date such as semiconductor and petrochemical processes, autocorrelation often exists between observed data, but when the existing SPC(Statistical process control) is applied to these processes, it is not possible to effectively detect the average change of the process. In this paper, when the average change of a certain size occurs in the process data following a specific time series model, the average of the residuals changes according to the passage of time, and the change pattern of the average is introduced around the ARMA(1,1) process. Based on this result, the reference value required in the design process of the CUSUM (Cumulative sum) control chart is appropriately considered by considering the type of the time series model of the process data of the CUSUM control chart that can detect small mean changes in the process and the width of the process mean change of interest. It was confirmed through simulation that it should be selected and used.

Prediction of Inhalation Exposure to Benzene by Activity Stage Using a Caltox Model at the Daesan Petrochemical Complex in South Korea (CalTOX 모델을 이용한 대산 석유화학단지의 활동단계에 따른 벤젠 흡입 노출평가)

  • Lee, Jinheon;Lee, Minwoo;Park, Changyong;Park, Sanghyun;Song, Youngho;Kim, Ok;Shin, Jihun
    • Journal of Environmental Health Sciences
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    • v.48 no.3
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    • pp.151-158
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    • 2022
  • Background: Chemical emissions in the environment have rapidly increased with the accelerated industrialization taking place in recent decades. Residents of industrial complexes are concerned about the health risks posed by chemical exposure. Objectives: This study was performed to suggest modeling methods that take into account multimedia and multi-pathways in human exposure and risk assessment. Methods: The concentration of benzene emitted at industrial complexes in Daesan, South Korea and the exposure of local residents was estimated using the Caltox model. The amount of human exposure based on inhalation rate was stochastically predicted for various activity stages such as resting, normal walking, and fast walking. Results: The coefficient of determination (R2) for the CalTOX model efficiency was 0.9676 and the root-mean-square error (RMSE) was 0.0035, indicating good agreement between predictions and measurements. However, the efficiency index (EI) appeared to be a negative value at -1094.4997. This can be explained as the atmospheric concentration being calculated only from the emissions from industrial facilities in the study area. In the human exposure assessment, the higher the inhalation rate percentile value, the higher the inhalation rate and lifetime average daily dose (LADD) at each activity step. Conclusions: Prediction using the Caltox model might be appropriate for comparing with actual measurements. The LADD of females was higher ratio with an increase in inhalation rate than those of males. This finding would imply that females may be more susceptible to benzene as their inhalation rate increases.

The Flow-rate Measurements in a Multi-phase Flow Pipeline by Using a Clamp-on Sealed Radioisotope Cross Correlation Flowmeter (투과 감마선 계측신호의 Cross correlation 기법 적용에 의한 다중상 유체의 유량측정)

  • Kim, Jin-Seop;Kim, Jong-Bum;Kim, Jae-Ho;Lee, Na-Young;Jung, Sung-Hee
    • Journal of Radiation Protection and Research
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    • v.33 no.1
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    • pp.13-20
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    • 2008
  • The flow rate measurements in a multi-phase flow pipeline were evaluated quantitatively by means of a clamp-on sealed radioisotope based on a cross correlation signal processing technique. The flow rates were calculated by a determination of the transit time between two sealed gamma sources by using a cross correlation function following FFT filtering, then corrected with vapor fraction in the pipeline which was measured by the ${\gamma}$-ray attenuation method. The pipeline model was manufactured by acrylic resin(ID. 8 cm, L=3.5 m, t=10 mm), and the multi-phase flow patterns were realized by an injection of compressed $N_2$ gas. Two sealed gamma sources of $^{137}Cs$ (E=0.662 MeV, ${\Gamma}$ $factor=0.326\;R{\cdot}h^{-1}{\cdot}m^2{\cdot}Ci^{-1}$) of 20 mCi and 17 mCi, and radiation detectors of $2"{\times}2"$ NaI(Tl) scintillation counter (Eberline, SP-3) were used for this study. Under the given conditions(the distance between two sources: 4D(D; inner diameter), N/S ratio: $0.12{\sim}0.15$, sampling time ${\Delta}t$: 4msec), the measured flow rates showed the maximum. relative error of 1.7 % when compared to the real ones through the vapor content corrections($6.1\;%{\sim}9.2\;%$). From a subsequent experiment, it was proven that the closer the distance between the two sealed sources is, the more precise the measured flow rates are. Provided additional studies related to the selection of radioisotopes their activity, and an optimization of the experimental geometry are carried out, it is anticipated that a radioisotope application for flow rate measurements can be used as an important tool for monitoring multi-phase facilities belonging to petrochemical and refinery industries and contributes economically in the light of maintenance and control of them.

Inviting Strategies of Foreign Capital in Regional Governments Focused on Chungnam Province (지방정부의 해외투자유치전략 -충청남도를 중심으로-)

  • Kim, Byeong-Youn
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.4 no.3
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    • pp.39-54
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    • 2009
  • As of July, 2009, Chungnam Province get DI (Direct Investment) of 2,502 corporations as the amount of 31 billion US dollars only for 3 years. Especially, Chungnam provincial governor make a excessive performance of 2.5 times comparing to the target number, 1,000 of inviting capital, that is public promise in the election. Now, the amount of inviting foreign capital is 1.2 billion dollars, at the end of this year it might be 1.4 billion dollars just in case of making a success on going negotiations. This outstanding performance comes from governor's leadership and aggressive strategies of well-trained subordinates. Chungnam Province has nation-wide multiple targets focused on interdisciplinary industries including strategic industries of display, auto-parts, steel, and oil-chemistry. Also, it has organic network system based on the very descriptive and accurate informations managing the task force team consisted of 35 competent members. In conclusion, the core competence of inviting foreign capital in a regional government is governor's strong leadership, activated organization consisted of specially well trained subordinates, and predominant differentiated strategies in details.

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자성유체 윤활제의 개발 동향

  • 김영규;심우전;김청균
    • Tribology and Lubricants
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    • v.12 no.1
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    • pp.1-5
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    • 1996
  • 자성유체는 자연에서 추출한 것이 아니라 자화성(Magnetizability)과 유도성(Flowability)을 동시에 갖도록 합성한 특수액체이다. 자성유체는 1960년대 중반에 미국의 NASA에서 처음 개발된 이후로 윤활, 밀봉, 감쇄, 의료 등의 분야에서 응용연구가 많이 진행되었기 때문에 고도의 정밀도를 요하는 항공, 우주산업, 컴퓨터와 반도체 분야 등에서 실용화가 크게 진전되고 있다. 특수물질일 자성유체는 전기적으로 도체인 10nm 정도의 미세한 자기입자(Magnetic particles)에 코팅을 한 후, 이것을 물, 탄화수소, 플루오르카본, 에스터 등의 매개유체(Carrier Fluids)에 혼합시켜서 콜로이드 상태로 사용하게 된다. 자성유체는 미세한 자기입자들이 매개유체내에서 서로 충돌하면서 반발력을 발생시켜서 상호간에 늘 콜로이드 상태를 유지하고 있으며, 이 특수유체가 자기장의 영향을 받게 되면 점도가 증가하면서 특이한 성질을 갖게 된다. 상대 접촉 운동면에 경계마찰이나 혼합마찰을 하게 되면 윤활상태는 비교적 나쁘다. 이러한 마찰지역에 콜로이드상의 자성유체 윤활제를 공급하면 기존의 윤활제에 비하여 대단히 효과적으로 윤활을 할 수 있게 된다. 그러나 자성유체 윤활제가 마찰부위에 원활하게 공급하기 위해서는 미끄럼 마찰부에서 자기장을 잘 형성시킬 수 있는 도체이어야 하기 때문에 특별한 윤활 시스템 설계가 제시되어야 한다. 자성유체 윤활제는 합성으로 제조된 특수물질로 여러가지 장점을 갖고는 있으나 기존 윤활유와의 적합성, 마찰열, 밀봉압력 등의 조건에서 제한적으로 사용될 수 밖에 없으므로 항공, 우주 산업이나 석유 화학분야와 같이 특수 환경에서만 사용되고, 또한 기존의 광유계 윤활제에 비하여 대단히 고가하는 문제점을 갖고 있다. 그러나 윤활 마찰면의 다양화와 가혹한 사용조건은 자성유체 윤활제의 연구개발 필요성을 크게 증대시키고 있다.xed Effects Model)을 결정하고, 각각에 해당하는 통계모형을 구축하였다. 이 결과 (1) 업종 및 기업규모별로 그룹간에 유의한 특성이 발견되었으며, (2) R&D 및 광고투자는 기업의 시장성과를 설명하는 중요한 변수이나, (3) R&D 투자의 경우는 광고에 비해 불확실성이 존재하는 것으로 나타났고, (4) 수리모형에서 도출된 한계원리가 통계모형에서도 유효한 것으로 드러났다.등을 토대로 한 10대 산업을 육성하기 위하여 과학기술부는 기술수요조사를 바탕으로 49개 주요기술을 도출하여, 과학기술 일류 국가 실현, 국민소득 2만불 달성이라는 국가적 슬로건을 내걸고 “차세대 성장동력” 창출을 위한 범정부차원의 기획과 연구비의 집중투자를 추진하고 있다.달성하기 위해서는 종합류류 전산망의 시급한 구축과 함께 화물차의 적재율을 높이고 공차율을 낮출 수 있는 운송체계의 수립이 필요한 것으로 판단된다. 그라나 이러한 화물전용차선의 효과는 단기적인 치유책일 수밖에 없기 때문에 물류유통 시설의 확충을 위한 사회간접자본의 구축을 서둘러 시행하여야 할 것이다.으로 처리한 Machine oil, Phenthoate EC 및 Trichlorfon WP는 비교적 약효가 낮았다.>$^{\circ}$E/$\leq$30$^{\circ}$NW 단열군이 연구지역 내에서 지하수 유동성이 가장 높은 단열군으로 추정된다. 이러한 사실은 3개 시추공을 대상으로 실시한 시추공 내 물리검층과 정압주입시험에서도 확인된다.. It was resulted from increase of weight of single cocoon. "Manta"2.5ppm produced 22.2kg of cocoon. It is equal to 9% increase in index, as compared to that of control. In case

Determination of chlorophenols from the industrial wastewater by GC/MS (GC/MS를 이용한 산업폐수중의 염화페놀류 분석)

  • Myung, Seung-Woon
    • Analytical Science and Technology
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    • v.18 no.4
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    • pp.320-328
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    • 2005
  • The most common five chlorophenols (4-chloro-3-methylphenol, 2,4,5-trichlorophenol, 2,4,6-trichlorophenol, 2,3,4,6-tetrachlorophenol, pentachlorophenol) were determined from the industrial wastewater by GC/MS. The samples were collected from the petrochemical company, textile company and leather making company. The developed analytical method was modified by USEPA Method 3510. The samples were extracted with dichloromethane under pH 2 and pH 5-6, and determined by the GC/MS with SIM mode. There were good linearities (above $R^2=0.9943$) on e ranges of the 0.1 ng/mL~10 ng/mL and 0.5 ng/mL~10 ng/mL, and the limit of detection were between 0.1 ng/mL and 0.5 ng/mL. The absolute recoveries were measured at the concentration of 1, 5, and 10 ng/mL, and the recovery was 71.6~98.9% except for PCP. The relative standard deviation (RSD) was 1.2~14.3% and it gave a good reproducibility for the assay. The bias, which shows the accuracy, was a good although it was a little high values (11.3~22.1%) at the low concentration (1 ng/mL).