• Title/Summary/Keyword: 상 변화물질

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Preparation of Monodispersed Silica-Rubitherm®Microparticles Using Membrane Emulsification and Their Latent Heat Properties (막유화법을 이용한 단분산성 실리카-루비덤® 마이크로 입자의 제조 및 잠열 특성)

  • Kim, Soo-Yeon;Jung, Yeon-Seok;Lee, Sun-Ho;You, Jin-Oh;Youm, Kyung-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.2
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    • pp.215-225
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    • 2015
  • Recently, the importance of energy saving and alternative energy is significantly increasing due to energy depletion and the phase change material (PCM) research for saving energy is also actively investigating. In this research, the membrane emulsification using SPG membrane was used to make various microencapsulated phase change material (MPCM) particles which were comprised of $Rubitherms^{(R)}$ (RT-21 and RT-24) core and silica coating. We investigated the pressure of the dispersion phase, the concentration of surfactant, and the ratio of $Rubitherm^{(R)}$ and silica to prepare various MPCM particles. The DSC and TGA were used to examine the heat stability and latent heat properties. Also, PSA, SEM, and optical microscopy were used to confirm the size of $Rubitherm^{(R)}$ particles and the thickness of silica shell. The average of particle size was $7-8{\mu}m$. And, FT-IR was also used to enforce the qualitative analysis. Finally, the MPCM particles obtained from membrane emulsification showed monodispersed size distribution and the heat stability and latent heat were kept up to 80% compared to pure $Rubitherm^{(R)}$. So, it can be effectively used for wallpaper, buildings and interior products for energy saving as PCMs.

Chemical Characteristic and seasonal trends of airbone particles at Kunsan (군산지역 부유분진의 계절적 농도변화와 화학특성)

  • 오진만;김득수
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.261-262
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    • 2001
  • 도서지역의 경제산업 활동으로 인한 에너지 소비와 교통량의 지속적인 증가는 공해방지와 환경개선 등을 위한 노력에도 불구하고 도시 대기질을 보다 심각한 상태로 오염시키고 있다. 이러한 대기오염물질 중 입자상 오염물질의 경우 그 입자의 크기는 100$\mu\textrm{m}$보다 큰 것에서부터 0.01$\mu\textrm{m}$ 정도까지 다양한 크기로서 대기내에 존재하며, 2.5~10 $\mu\textrm{m}$이하의 미세분진은 태양광의 산란 등을 통해 시정을 감소시키고, 태양복사에도 영향을 주어 지구와 대기간의 복사평형에도 변화를 초래한다(김필수 등, 1991; 문길주 등, 1994). (중략)

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Study on the Regional Deposition of Smoke Particles in Human Respiratory Tract under the Variation of Fire and Breathing Conditions (화재 및 호흡조건 변화에 따른 연기입자의 인체 호흡기 내 영역별 침착량 분석)

  • Goo, Jaehark
    • Fire Science and Engineering
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    • v.33 no.6
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    • pp.95-104
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    • 2019
  • Smoke generated in a fire consists of gaseous substances and particulate matter, such as unburned carbon that adsorbed the gases. Human injury caused by inhalation of gaseous substances present in smoke is mostly short-term, whereas damage caused by inhalation of particulate matter is relatively a long-term phenomenon depending on the state of the gas-phase adsorption. The amount and location of the deposited smoke particles are important factors in estimating the damage caused to humans, which are affected by the breathing conditions as well as particle conditions, such as the size and concentration affected by the combustion conditions. In this study, in order to understand the characteristics of the deposition of smoke particles in the respiratory tract related to the study of human smoke inhalation injury, the number and mass concentration of smoke particles deposited in different areas of the respiratory tract for different fuel types, combustion conditions and breathing conditions were calculated. In addition, the amount of mass deposition of smoke in the respiratory tract for a certain period of inhalation was compared with the atmospheric standard of fine dust.

The Characterization of Floc Formation Under Various Pre-coagulation Conditions (응집-막분리 공정 적용시 전처리 응집조건에 따른 용존성 유기물 상(相)변화 특성)

  • Jung, Chul-Woo;Son, Hee-Jong
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.11
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    • pp.1139-1145
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    • 2008
  • The objectives of this research are to investigate the mechanism of coagulation affecting UF and find out the optimum conditions of the combined of coagulation with UF membrane filtration for NOM removal. During the mixing period, substantial changes in particle size distribution occurred under rapid and slow mixing condition due to the simultaneous formation of microflocs and NOM precipitates. Therefore, combined pretreatment using coagulation (both rapid mixing and slow mixing) improved dissolved removal efficiency. Also, for combined coagulation to membrane process, flux reduction rate showed lower than only UF process. The rate of flux decline for the hydrophobic membrane was considerably greater than for the hydrophilic membrane. Applying coagulation process before membrane filtration showed not only reducing membrane fouling, but also improving the removal of dissolved organic materials that might otherwise not be removed by the membrane.

Effects of pH and Potassium Chloride in Solvent System of High-Speed Countercurrent Chromatography (pH 및 염화칼륨 첨가가 고속역류크로마토그래피의 용매시스템에 미치는 영향)

  • Lee, Chang-Ho;Lee, Boo-Yong;Lee, Hyun-Yu;Lee, Cherl-Ho
    • Korean Journal of Food Science and Technology
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    • v.29 no.6
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    • pp.1222-1227
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    • 1997
  • Effects of the physical properties of solvent system such as pH and polarity change by salt addition in solvent system were investigated by using high speed countercurrent chromatography apparatus (Model CCC-1000, Pharm-Tech Research Corp. USA). The changes of pH and interfacial tension in solvent system of high speed countercurrent chromatography did not significantly affect on retention of stationary phase, but induced remarkable changes in the partition coefficient of ginkgo flavonoids, kaempferol, quercetin and isorhamnetin. The partition coefficients of ginkgo flavonoid standard increase with an increased pH of solvent system and quercetin sharply increased at pH 10.0. Retention of stationary phase decreases with an increased concentration of KCl in butanol of solvent system. Interfacial tension between two phase in solvent system of hexane increases with an increased concentration of KCl. The polarity of solvent system significantly changes the partition coefficients of ginkgo flavonoid.

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Development of Phase Change Thermal Energy Storage System (상변화 물질을 이용한 고효율 축열시스템 개발)

  • 장진택;유영선;윤진하;김영중;장유섭;강금춘
    • Proceedings of the Korean Society for Bio-Environment Control Conference
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    • 1998.05a
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    • pp.77-82
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    • 1998
  • 현재 온실 난방에 주로 이용되고 있는 난방기는 대부분이 화석에너지를 연료로 사용하고 있다. 따라서 생산비의 가중이 불가피하며, 또한 연소 과정에서 발생하는 배기 가스로 인하여 환경 오염이 문제시되고 있다. 따라서 태양에너지를 보다 더 적극적으로 활용할 수 있는 기술의 개발이 요구된다. 태양에너지를 시설 농업에 적극적으로 이용하기 위해서는 주간에 밀도가 낮은 태양에너지를 고밀도로 축열하여 기온이 급강하하는 야간의 보온에 활용하여야 한다. 주간의 온실내 잉여 태양에너지를 축열할수 있는 상변화 온도 3$0^{\circ}C$ 수준의 잠열축열재를 개발하기 위하여 수행한 본 연구의 결과를 요약하면 다음과 같다. 1. SCD에 Borax를 0.0~5.0wt% 첨가하여 과냉도를 25.$0^{\circ}C$에서 $1.5^{\circ}C$ 이하로 조절하였으며, Borax의 적정 함량은 3.0wt%였다. 2. SCD에 Carbopol을 0.0~3.0wt% 첨가하여 상분리량을 70.0%에서 0.0%로 조절하였으며, Carbopol의 적정 함량은 1.5wt%였다.3. 축열재 내구성 검증을 위하여 0~1,500회의 상변화 사이클을 수행하였다. 이때 상변화 온도의 변화량이 $\pm$1.$0^{\circ}C$ 이하, 잠열량 변화가 $\pm$2.0 kacl/kg 이하로서 안정된 값을 보였다. 이상의 결과로 볼 때 축열재의 수명을 10년까지는 보장할 수 있는 것으로 판단되었다.

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Characteristics of Cosmetic with Whitening Compounds from Phellodendron amurense (Phellodendron amurense의 미백물질을 이용한 화장품 특성)

  • Cho, Young-Je
    • Journal of Applied Biological Chemistry
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    • v.54 no.2
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    • pp.108-113
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    • 2011
  • The tyrosinase inhibitory activity of extracts from Phellodendron amurense was examined. Tyrosinase inhibitory activity of 60% ethanol extracts was determined as 25% and the inhibitory activity of 60% ethanol extracts against melanin biosynthesis in melanoma cell (B16F10) was 31.2%. The purified inhibitory compounds against tyrosinase by Sephadex LH-20, MCI-gel CHP-20 column chromatography from P. amurense was confirmed as obacunone by $^1H$-NMR, $^{13}C$-NMR and Fast atom bombardment (FAB)-Mass spectrum. The tyrosinase inhibitory activities of purified obacunone was respectively as 35.1%. The safety of essence with tyrosinase inhibitory compounds from P. amurense was also assayed by various safety profiles. First, pH and viscosity change of essence for 60 days were not detected. The essence also showed the stability against temperature and light for 60 days. All these findings suggest that extracts from P. amurense has a great potential as a cosmeceutical ingredient, which has a potent whitening effect.

Photonic Crystals Based on Colloid Self-Assembly (콜로이드 자기 조립체를 이용한 광결정)

  • 박정호;구혜영;김동유
    • Polymer Science and Technology
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    • v.15 no.3
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    • pp.274-285
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    • 2004
  • 콜로이드 결정 (Colloid crystal)이란 용액 상에서 부유 하는 작은 입자들의 자기 조립 (self-assembly)에 의해 형성된 주기적인 2차원 혹은 3차원 구조를 말한다. 이러한 결정 구조는 광학 필터나 스위치, 광 밴드 갭 재료, 바이오 센서 등의 과학 기술적인 응용을 비롯하여 액화 물질의 상 변화 등과 같은 물리적 현상을 규명함에 있어서 중요한 모델을 제시한다. 특히 최근에 콜로이드의 자기 조립체는 자연적으로 갖게 되는 주기적인 유전율 변화 때문에 빛의 진행 방향이나 특성을 조절할 수 있는 광자 결정 (Photonic Crystal) 구조 제작의 경쟁력 있는 접근 방법으로 각광 받고 있다. (중략)

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Thermal Storage/Release Properties of Thermostatic Fabrics Treated with Octadecane-Containing Microcapsules (옥타데칸 함유 마이크로캡슐을 이용한 자동온도조절 직물의 축열.방열성)

  • 김정혜;조길수;조창기
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.285-288
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    • 2002
  • 옥타데칸[$CH_3$[C $H_2$]$_{l6}$$CH_3$]은 상전이 물질(phase change material)이며, 상전이 물질은 상변화를 통해 주변의 온도가 상승하면 녹으면서 열을 흡수하고, 주변의 온도가 낮아지면 결정화(crystallization)하면서 열을 방출하는 축열ㆍ방열성을 반복적으로 나타내는 에너지 물질(enthalpic substance)이다[1, 2]. 옥타데칸은 메탄계열 탄화수소로서 파라핀류(paraffins)에 해당된다. (중략)략)

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Ions Characteristics of Fine Particle in Seoul Area (서울시 미세입자의 이온성분 특성)

  • 이혁수;강충민;이현지;이승일;김희강
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.04a
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    • pp.141-142
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    • 2000
  • 대기 중 입자상 물질은 대기오염물질 중의 하나로 대기질을 평가하는데 매우 중요한 변수로 작용하며 다양한 특성을 가지고 있다. 이 중 미세입자(2.5 $\mu\textrm{m}$이하)는 태양광을 산란, 흡수시켜 시정감소의 주요 원인물질로 작용하고, 구름속에 혼입되어 구름의 반사율을 변화시키며, 호흡을 통하여 인체의 기관지 및 폐내에 흡입되어 천식과 폐암을 유발시키기도 한다. 또한 장거리 이동하면서 물리.화학적 반응을 하고 광역적 시정감소, 산성비와 같은 대기오염현상을 일으킬 뿐만 아니라 인체 각종 질환을 야기할 수 있다. (중략)

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