• Title/Summary/Keyword: 상온혼합

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Microwave Dielectric Properties of Anatase and Rutile $TiO_2$ Thin Films ($TiO_2$ 유전체 박막의 마이크로파 유전특성)

  • 오정민;김태석;박병우;홍국선;이상영
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.105-105
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    • 2000
  • 현재 급격히발전하는 이동통신기술로 미루어 보아 앞으로는 모든 정보통신이 무선통신으로 이루어질 것이다. 그런데 무선통신은 이동성과 대용량의 정보전송에 초점을 맞추어 발전하고 있다. 많은 정보량을 전달하기 위해서 현재 사용되는 주파수 대역보다 고주파의 전파가 사용되어야 한다. 또한 이동성을 향상시키기 위해서는 통신기기의 소형화를 이루어야 하고 그러기 위해서 궁극적으로 모든 소자를 하나의 칩(chip)으로 집적화하는 것이 필요하다. 따라서 벌크상태로 사용되고 있는 유전체 공진기를 소형화, 즉 박막화해야만 한다. 결국 유전체 박막의 마이크로파 대역에서의 유전특성을 연구하고 그 특성을 향상시켜야만 한다. 통신기기에서 사용되는 유전체 공진기는 소형화를 위해 높은 유전율과 낮은 유전손실(tan$\delta$), 즉 높은 품질계수 (Q)를 가져야 한다. 마이크로파 대역에서 사용되고 있는 유전체 중에서 TiO2는 벌크 상태의 rutile 상에서 100정도의 높은 유전율과, 4 GHz에서 10,000 정도의 높은 품질계수를 나타낸다고 보고되어 있다. 따라서 본 연궁서는 TiO2 박막의 마이크로파 유전특성을 연구하였고 anatase 박막의 유전특성도 측정하였다. TiO2 박막을 RF magnetron reactive sputtering 방법으로 Ar (15 sccm)과 O2 (1.5 sccm) 기체를 사용하여 상온에서 증착하였다. 4mTorr의 증착압력에서 안정한 rutile 박막을 얻었고, 15 mTorrdo서 준안정한 anatase 박막을 얻을 수 있었다. 그리고 그 중간의 압력에서 두 상이 혼합된 박막이 증착되었다. 위와 같은 방법으로 형성한 TiO2 박막의 마이크로파 유전특성을 측정하기 위해 마이크로스트립 링공진기 (microstrip ring resonator)를 제작하였다. 마이크로스트립 링 공진기는 링의 원주길이가 전자기파 파장길이의 정수배가 되면 공진이 일어나는 구조이다. Fused quartz를 기판으로 하여 증착압력을 변수로 하여 TiO2 박막을 증착하였다. 그리고 그 위에 은 (silver)을 사용하여 링 패턴을 형성하였다. 이와 같이 공진기를 제작하여 network analyzer (HP 8510C)로 마이크로파 대역에서의 공진특서을 측정하였다. 공진특성으로부터 전체 품질계수와 유효유전율, 그리고 TiO2 박막의 품질계수를 얻어내었다. 측정결과 rutile에서 anatase로 박막의 상이 변할수록 유전율은 감소하고 유전손실은 증가하는 결과를 나타내었다.

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적외선 센서용 VOx/ZnO/VOx 박막 증착 및 특성 연구

  • Han, Myeong-Su;Mun, Su-Bin;Han, Seok-Man;Sin, Jae-Cheol;Kim, Hyo-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.236-236
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    • 2013
  • 비냉각 적외선 검출기는 산업용 군사용으로 최근 각광을 받고 있다. 이는 주야간 빛이 없는 곳에서도 사물의 열을 감지할 수 있어 인체감지 및 보안감시, 에너지 절감 등에 응용될 수 있는 핵심부품이다. 비냉각 적외선 검출기로는 재료의 저항의 변화를 감지하는 마이크로볼로미터형이 가장 많이 사용된다. 감지재료로는 비정질 실리콘(a-Si)과 산화바나듐(VOx)이 가장 많이 사용된다. VOx 박막은 일반적으로 RF sputtering 방법으로 증착이 되며, 저항이 낮고, 저항의 온도변화 계수(TCR)가 크며 신호 대 잡음 특성이 우수한 반면 산소(oxygen) phase가 다양하여 갓 증착된 상태의 박막은 재현성이 떨어지는 단점이 있다. 본 연구에서는 기존의 V 타겟을 사용한 VOx 박막을 증착하는 방법을 개선하여 ZnO 나노박막을 중간에 삽입하여 저항 특성을 조절할 뿐만 아니라 열처리에 의해 TCR 값을 향상시키고, VO2 phase 가 주로 나타나는 박막 증착 및 공정 방법을 소개한다. RF sputtering 장비를 이용하여 산소와 아르곤 가스의 혼합비를 4.5로 하였으며, VOx 증착 시 플라즈마 Power는 150 W 로 하여 상온에서 증착하였다. 갓 증착된 VOx 다층박막의 XRD 스펙트럼은 V2O5 피크가 주된 상을 이루고 있었으며, 산소열처리에 의해 VO2 상이 주로 나타남을 알 수 있었다. TCR 값은 갓 증착된 샘플에서 -0.13%/K의 값을 얻었으며, $300^{\circ}C$에서 50분간 열처리 후 -3.37%/K 으로 급격히 향상됨을 알 수 있었다. 저항은 열처리 후 약 100 kohm으로 낮아져 검출소자를 위한 조건에 적합한 특성을 얻을 수 있었다. 또한 산소열처리의 온도 및 시간에 따라 TCR 및 표면 거칠기 특성을 조사하였으며, 최적의 열처리 조건을 얻고자 하였다.

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In-site Processing and Mechanical Properties of Ti/TiB Composites (반응생성에 의한 Ti/TiB 복합재료의 제조와 기계적 성질)

  • Jeong, Hui-Won;Lee, Yong-Tae
    • Korean Journal of Materials Research
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    • v.9 no.3
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    • pp.307-314
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    • 1999
  • The effect of manufacturing variables, such as reactant powder$(TiB_2, B_4C)$, sintering temperature, and sintering time has been investigated on the microstructure and the mechanical properties of in-situ processed Ti/TiB composites. The mechanical properties were evaluated by measuring the compressive yield strength. The compressive yield strength of the in-situ processed composites was higher than that of the Ti-6AI-4V. The compressive yield strength of the composite made with TiE, reactant powder was higher than that of $B_4C$, mixed at the same volume fraction of reinforcement. It is because bonding nature between the matrix and the $TiB_2$, reactant powder was more strong than that of the other materials. It was proven by the examining the crack propagation path.

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Electrical and Mechanical Properties of Carbon Particle Reinforced Rubber for Electro-Active Polymer Electrode (전기활성 고분자 전극용 탄소입자 강화고무의 전기적 및 기계적 특성)

  • Lee, Jun Man;Ryu, Sang Ryeoul;Lee, Dong Joo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.12
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    • pp.1465-1471
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    • 2013
  • The electrical and mechanical properties of room temperature vulcanized (RTV) silicone rubber composites are investigated as functions of multi-walled carbon nanotube (CNT), carbon black (CB), and thinner content. The thinner is used to improve the CNT and CB dispersion in the matrix. The electrical and mechanical properties of the composite with CNT are improved when compared to the composite with CB at the same content. As the thinner content is 80 phr, the electric resistance of the composite decreases significantly with the CNT content and shows contact point saturation of CNT at 2.5 phr. As the thinner content increases, the dispersion of conductive particles improves; however, the critical CB content increases because of the reduction in the CB weight ratio. It is believed that an electrode that needs good flexibility and excellent electrical properties can be manufactured when the amount of CNT and CB are increased with the thinner content.

Bread-making Properties of Rice Flours Produced by Dry, Wet and Semi-wet Milling (건식, 습식 및 반습식 쌀가루에 의한 쌀빵의 특성 비교)

  • Lee, Myung-Hee;Lee, Young-Tack
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.7
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    • pp.886-890
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    • 2006
  • Rice flours produced by dry, wet, and semi-wet milling methods were used to investigate bread-making properties. Wet milled rice flours were produced by two different steeping temperatures of $25^{\circ}C$ and $55^{\circ}C$, properties of composite flour containing 70% rice flour and 30% wheat flour with the addition of vital wheat gluten were tested. Among rice flours, wet milled rice flour showed increased mixing time and dough stability determined by a mixograph. Wet milled rice flours produced higher loaf volume compared with dry of semi-wet milled rice flours. Wet-milled rice flour steeped at $55^{\circ}C$ appeared to produce good rice breads with relatively high loaf volume. Crumb hardness of bread prepared with wet milled rice flour was lower than the other breads and increased slowly during 3-day storage at $25^{\circ}C$.

Fabrication of High Density BZN-PVDF Composite Film by Aerosol Deposition for High Energy Storage Properties (상온분말분사공정을 이용한 고밀도 폴리머-세라믹 혼합 코팅층 제조 및 에너지 저장 특성 향상)

  • Lim, Ji-Ho;Kim, Jin-Woo;Lee, Seung Hee;Park, Chun-kil;Ryu, Jungho;Choi, Doo hyun;Jeong, Dae-Yong
    • Korean Journal of Materials Research
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    • v.29 no.3
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    • pp.175-182
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    • 2019
  • This study examines paraelectric $Bi_{1.5}Zn_{1.0}Nb_{1.5}O_7$ (BZN), which has no hysteresis and high dielectric strength, for energy density capacitor applications. To increase the breakdown dielectric strength of the BZN film further, poly(vinylidene fluoride) BZN-PVDF composite film is fabricated by aerosol deposition. The volume ratio of each composition is calculated using dielectric constant of each composition, and we find that it was 12:88 vol% (BZN:PVDF). To modulate the structure and dielectric properties of the ferroelectric polymer PVDF, the composite film is heat-treated at $200^{\circ}C$ for 5 and 30 minutes following quenching. The amount of ${\alpha}-phase$ in the PVDF increases with an increasing annealing time, which in turn decreases the dielectric constant and dielectric loss. The breakdown dielectric strength of the BZN film increases by mixing PVDF. However, the breakdown field decreases with an increasing annealing time. The BZN-PVDF composite film has the energy density of $4.9J/cm^3$, which is larger than that of the pure BZN film of $3.6J/cm^3$.

Interpretation of Ammonia Absorption Behavior in Water Turbulent Flow (물 난류에서의 암모니아 흡수 거동 해석)

  • Lee, Sang-Ryong;Park, Jin-Won
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.3
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    • pp.75-80
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    • 2019
  • The article is devoted to the interpretation of ammonia, one of the fine dust precursors, absorption behavior in water turbulent flow. The water flow was considered as a turbulent flow with Reynolds number more than $10^4$, because ammonia gas penetration depth was deeper at turbulent flow compared to laminar flow. For the interpretation, the dimensionless mass transfer governing-equation and the constant physical-properties at room temperature were used. The diffusivity of ammonia in water and the kinematic viscosity of water were $2{\times}10^{-9}m^2/s$ and $1{\times}10^{-6}m^2/s$, respectively. The concentration distribution of ammonia in water was estimated with respect to the position from the point where the water started to be exposed to ammonia. The quantitative distribution as a function of the mixing length was also acquired. The quantitative interpretation may provide the insight how much the turbulent flow was more efficient to remove ammonia rather than the laminar flow.

Simulation of Ammonia Reduction Effect by Hydroxylamine-oxidoreductase Enzyme Immobilized on the Surface of Water Pipe (수로관 표면 고정 히드록실아민-산화환원효소에 의한 암모니아 저감 효과 모사)

  • Lee, Sang-Ryong;Park, Jin-Won
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.4
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    • pp.35-41
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    • 2020
  • The immobilization of the hydroxylamine-oxidoreductase on the water channel surface was performed to investigate the efficacy of ammonia removal in turbulent flow. The reaction by this enzyme proceeds rapidly by converting hydroxylamine into nitrous acid. For the analysis of the effect, a dimensionless mass transfer governing equation was established with the physical properties based on room temperature. The ammonia diffusion coefficient in water and the kinematic viscosity coefficient of water were 2.45×10-9 ㎡/s and 1×10-6 ㎡/s, respectively. The distribution of ammonia concentration in the water was calculated with respect to the distance from the point at which exposure to ammonia began. The quantitative distribution with respect to the mixing depth was also found. Such a quantitative analysis can provide insight into whether the enzyme immobilized on the water channel surface can be effectively used for ammonia removal.

Microbial Reduction in Kimchi Cabbage Leaves by Washing with Citric Acid and Ethanol (구연산과 에탄올 세척에 의한 배춧잎의 미생물 저감화)

  • Han, Eung Soo;Yang, Ji Hee
    • Food Engineering Progress
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    • v.23 no.2
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    • pp.112-117
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    • 2019
  • The purpose of this study is to develop a method to cultivate lactic acid bacteria (LAB) as a by-product in the fermentation of kimchi through the use of Chinese cabbage leaves. A method to reduce the initial number of microorganisms using citric acid and ethanol to wash cabbage leaves was investigated. In this experiment, Chinese cabbage leaves were washed using a mixture of 3% citric acid and 7% ethanol and the washed cabbage leaves were juiced and used as a sample. The total microorganisms of kimchi cabbage juice (KCJ) was reduced from log 6.53 CFU/g to log 3.69 CFU/g by washing with citric acid and ethanol, and lactic acid bacteria from log 4.40 CFU/g to log 2.01 CFU/g. The salinity of KCJ was appropriate for the growth of lactic acid bacteria but the pH was too low. The yield of washing, juice extraction, and total were 80.82%, 79.32%, and 64.11%, respectively. KCJ made by washing with citric acid and ethanol was good for the culture broth of lactic acid bacteria.

A Study on the Development of Special Materials for Liquidity Improvement Refill Applicable to Poor Ground Conditions in Low Temperature Environment (저온환경 불량한 지반조건에 적용 가능한 유동성 개량 되메움을 위한 특수재료 개발에 관한 연구)

  • Jin Chun Kim;Byung Sun Yoo;Hee Jin Kang;Seok Hyun Kim
    • Journal of Korean Society of Disaster and Security
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    • v.17 no.3
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    • pp.1-11
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    • 2024
  • The purpose of this study is to develop a fluidity-improved refilling material that satisfies smooth construction and long-term durability in a low-temperature environment using special materials and field soil as a refilling material to develop technology for high-speed installation of long-term non-traditional pipelines on poor ground containing a large amount of organic soil in a low-temperature environment. To this end, a special cement material was developed, and an indoor test was conducted to determine the construction performance and durability of the fluidity improved refilling material mixed with the developed special material and field soil to meet the quality standards for field construction. The construction quality standard items of fluidity improved refill materials were set to meet the CLSM (ACI 229R-13) standard suggested by the American ACI (America Concrete Institute). In addition, in order to understand the applicability in a low-temperature environment, the test was performed with the same items at low temperature and compared with the indoor test results at room temperature.