• 제목/요약/키워드: 상온혼합

검색결과 290건 처리시간 0.039초

A Comparative Study on the Characteristics of Carbon Nanofluids for Efficiency Enhancement of Low Temperature Heat Exchanger (저온열교환기 효율 향상을 위한 탄소나노유체의 특성 비교 연구)

  • Park, Sung-Seek;An, Eoung-Jin;Lee, Kyoung-Soo;Park, Youn-Cheol;Kim, Nam-Jin
    • Journal of Energy Engineering
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    • 제20권3호
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    • pp.209-215
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    • 2011
  • In this study, for efficiency enhancement of low temperature heat exchanger, the thermal conductivity and the viscosity of carbon nanofluids and oxidized carbon nanofluids were measured at $10^{\circ}C$ and $25^{\circ}C$, respectively. Carbon nanofluids were made by ultrasonic-dispersing ones in distilled water after Multi-Walled Carbon Nanotubes (MWCNTs) mixed Sodium Dodecyl Sulfate (SDS, 100 wt%), Polyvinyl pyrrolidone (PVP, 300 wt%) each. Oxidized carbon nanofluids were made by ultrasonic-dispersing Oxidized Carbon Nanotubes (OMWCNTs) in distilled water. The thermal conductivity of carbon nanofluids was measured by using a transient hot-wire method. The viscosity was measured by using a digital viscometer. As a result, the thermal conductivity of oxidized carbon nanofluids was the highest of those compared and the other carbon nanofluids at the same mixture ratio and temperature, and the viscosity was measured the lowest of those compared and the other carbon nanofluids.

Adsorption of Ni(II), Co(II), and Mg(II) from Sulfuric Acid Solution by Diphonix Resin for the Utilization of Laterite Ore (라테라이트광 활용을 위한 황산용액에서 Diphonix 수지의 니켈, 코발트, 마그네슘 흡착)

  • Lee, Man-Seung;Kim, Sang-Bae;Chae, Jong-Gwee
    • Journal of the Mineralogical Society of Korea
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    • 제23권3호
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    • pp.183-189
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    • 2010
  • It is of importance to separate Ni(II) and Co(II) from Mg(II) in solution which was leached from nickel laterite ore. In order to investigate the possibility of separating Ni(II) and Co(II) from Mg(II), adsorption behavior of the three metals from individual and mixed sulfate solutions was investigated by using Diphonix resin. The concentration of each metal in solution was fixed at 100 ppm and the pH of the sulfuric acid solution was changed from 5 to 7. At ambient temperature, the adsorption behavior of the three metal ions followed Langmuir adsorption isotherm. The loading capacity of Diphonix resin for the three metal ions was obtained from the Langmuir isotherm. Since adsorption behavior of the three metal ions from the mixed solution was similar to each other, it was found to be difficult to separate Ni(II) and Co(II) from Mg(II) by using Diphonix resin.

Miscibility and Properties of Ethyl-Branched Polyethylene/Ethylene-Propylene Rubber Blends( I ) (에틸 가지화된 폴리에틸렌과 에틸렌-프로필렌 고무 블렌드의 혼화성와 물성( I ))

  • Cho, Ur-Ryong
    • Elastomers and Composites
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    • 제36권3호
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    • pp.169-176
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    • 2001
  • Ethyl-branched polyethylene[PE(2)] containing 2mole% ethyl branch and three ethylene-propylene rubbers(EPR's) haying the same ethylene(E)-propylene(P) molar ratio(E/P=50/50) with different stereoregularity, that is, random EPR(r-EPR), alternating-EPR(alt-FPR) and isotactic-alternating-EPR(iso-alt-EPR) were mixed for the investigation of their properties depending on the stereoregurarity. The three blends were immiscible at room temperature, and showed the simple additivity effect in density behavior. The melting point depression with blend composition increased in order of PE(2)/r-EPR>PE(2)/alt-EPR>PE(2)/iso-alt-EPR. In the tensile test, this blend systems have the lowest value or the breaking strength at FE(2) fraction of 0.5. This phenomenon results from the greastest separated phase morphology at this blend composition.

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Study of Plasma Polymerization on Wood Powder/PP Composites Interface (플라즈마 처리가 목분/폴리프로필렌 복합재의 계면에 미치는 영향 연구)

  • Ha, Jong-Rok;Kim, Byung Sun;Yi, Jin Woo
    • Composites Research
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    • 제26권3호
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    • pp.170-174
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    • 2013
  • Atmospheric glow plasma polymerization was applied to wood powder before fabricating polypropylene (PP) matrix composites. Seven different types of monomers (Oxygen, Benzene, CH4, Acrylic-acid, Hexafluoroethane, Trifluorotolune, Hexamethyl-disiloxane) were analyzed to determine the most suitable precursor for plasma polymerization. The surface energy was calculated from measured contact angle about each monomer on PP. Hexamethyl-disiloxane (HMDSO) had a highest surface energy and is selected as the most suitable monomer. Wood powder and polypropylene were mixed as pellets by twin screw extruder and then 50 wt% wood powder/PP composites were produced by an injection machine. Tensile strength and Flexural strength have improved by 7.59% and 12.43% at the maximum respectively. SEM (Scanning Electron Microscope) observation on the fracture surface revealed that the plasma polymerization have improved the interfacial bonding and the mechanical properties of the composites.

Growth of GaN epilayer on the Si(001) substrate by hot wall epitaxy (Si(001) 기판 위에 HWE 방법으로 성장한 GaN 박막 성장)

  • Lee, H.;Youn, C.J.;Yang, J.W.;Shin, Y.J.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • 제9권3호
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    • pp.273-279
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    • 1999
  • The home-made hot wall epitaxy (HWE) system was utilized for GaN epitaxial layer growth on the Si(001) substrate. It was appeared that GaN epilayer grow with mixed phase of Zinc blende and Wurtzite structure from photoluminescence (PL) and x-ray diffraction (XRD) analysis at the room temperature. We found that intial growth layer has Wurtzite structure from photoluminescence (PL) and x-ray diffractio (XRD) analyses at the room temperature. Wefound that initial growth layer has Wurtzite structure when initial deposition time, the temperature of substrate and source are 4 min, $720^{\circ}C$ and $860^{\circ}C$ respectively, and at the epi growth process GaN, epilayer was grown with relatively stable Wurtzite structure when the temperature of substrate and source are $1020^{\circ}C$ and $910^{\circ}C$ respectively.

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The Experimental Study on Preparation Characteristics of Self-healing Microcapsules for Mixing Cement Composites Utilizing Liquid Inorganic Materials (액상 무기재료를 활용한 시멘트 복합재료 혼합용 자기치유 마이크로 캡슐의 제조 특성에 관한 실험적 연구)

  • Choi, Yun-Wang;Oh, Sung-Rok;Kim, Cheol-Gyu;Lim, Hak-Sang
    • Journal of the Korean Recycled Construction Resources Institute
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    • 제6권4호
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    • pp.236-244
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    • 2018
  • In this study, we tried to fabricate self - healing microcapsules using liquid inorganic materials which can be mixed directly with cement composites. The basic properties of the liquid inorganic material were evaluated and microencapsulation was performed. The focus of this paper is on the quality and manufacturing characteristics of cement composites rather than the healing effects of self - healing microcapsules according to mixed capsules. Test results, the self-healing microcapsules encapsulate liquid inorganic material which is stable at room temperature and has high crack followability, and the yield is over 90%. The size of self - healing microcapsule was able to change according to the synthetic agitation speed and it was able to secure more than 70% of target size. In addition, the loss of less than 10% was found to occur through the membrane strengthening of self - healing microcapsules, and it could be reduced by 50% compared with the case without membrane strengthening.

1-Ethyl-1-Methyl Piperidinium Bis(Trifluoromethanesulfonyl)Imide as a Co-Solvent for Li-ion Battery Electrodes (혼합 용매로서의 1-Ethyl-1-Methyl Piperidinium Bis(Trifluoromethanesulfonyl)Imide의 리튬 이차 전지용 전극별 거동)

  • Koh, Ah Reum;Kim, Ketack
    • Journal of the Korean Electrochemical Society
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    • 제17권2호
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    • pp.103-110
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    • 2014
  • In the study, a room temperature ionic liquids as a co-solvent was used to evaluate the feasibility with various electrodes in Li-ion batteries. 1-Ethyl-1-methyl piperidinium bis(trifluoromethanesulfonyl) imide(PP12 TFSI) is an ionic liquid that melts at $85^{\circ}C$. Pure PP12 TFSI is not able to be used as an electrolyte because it is a solid salt at room temperature. PP12 TFSI is mixed with EC/DEC(1/1 vol.%) to prepare mixed solvents. The electrolyte 1.5M $LiPF_6$ in a mixed solvent having 44 wt.% PP12 TFSI is prepared to evaluated the various electrodes. The electrolytes provides good cycles life of cells with $LiNi_{0.5}Mn_{1.5}O_4(LNMO)$, $LiFePO_4(LFP)$, $Li_4Ti_5O_{12}(LTO)$ and artificial graphite. Further improvement of the cell performances can be accomplished by enhancing wettability of electrolytes to electrodes.

Optoelectronic properties of the Metal-dielectric complex thin films for applying high sensitivity IR image sensors (고감도 적외선 이미지 센서 적용을 위한 금속-유전체 복합 박막의 광전자 특성)

  • Kim, Ye-Na;Kwon, Soon-Woo;Park, Seung-Jun;Kim, Woo-Kyug;Lee, Han-Young;Yoon, Dae-Ho;Yang, Woo-Seok
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • 제21권2호
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    • pp.60-64
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    • 2011
  • High sensitivity IR image sensors require materials characteristics with temperature coefficient of resistance (TCR) and IR range absorption. In this study, the metal-dielectric thermo sensitive films (MDTF) based on $(SiO_2)_x-(Ti)_y$ composition were deposited on substrates of germanium and glass by thermal evaporator. The $SiO_2$ : Ti mixture was made from the ratio of 9 : 1, 8 : 2, 7 : 3, 6 : 4, respectively. $(SiO_2)_x-(Ti)_y$ mixture powder was loaded on tungsten boat in evaporator and was 15.5 cm from the substrate. Resistance of $(SiO_2)_x-(Ti)_y$ in the range of 273~333K were measured as a function of temperature. Temperature coefficient of resistance (TCR) was calculated by the resistance variation. Under the various mixture ratios condition, it is possible to obtain $SiO_2$-Ti layers with resistance from units kilo-ohm to hundreds kilo-ohm. Finally, our results showed that Temperature coefficient of resistance (TCR) of these films varies from -1.4 to $-2.6%K^{-1}$.

Phase Equilibria and $^{13}C$ NMR Analysis of the Double Semi-Clathrates Containing TBAB (TBAB를 포함하는 혼합 하이드레이트의 상평형 및 $^{13}C$ NMR 분석)

  • Lee, Seung-Min;Park, Sung-Min;Lee, Young-Jun;Lee, Sung-Won;Seo, Yong-Won
    • Korean Chemical Engineering Research
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    • 제49권3호
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    • pp.367-371
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    • 2011
  • TBAB (tetra-n-butyl ammonium bromide) forms a semi-clathrate with water under atmospheric pressure conditions and recently has attracted great attention due to its usage as a thermodynamic promoter in gas storage and separation process using gas hydrate formation. In this study, we measured the three-phase (hydrate (H) - liquid water ($L_{w}$)-vapor (V)) equilibria of the ternary $CH_{4}$+TBAB+water and $CO_{2}$+TBAB+water mixtures at the TBAB concentrations of 5 and 32 wt% to investigate promoting characteristics of TBAB. The greater promotion effect of TBAB was observed at 32 wt% than at 5 wt%. This result was in good agreement with that from pure TBAB semi-clathrate phase diagram under atmospheric pressure conditions. Through $^{13}C$ NMR analysis of the $CH_{4}$+TBAB semi-clathrate, it was found that $CH_{4}$ molecules are enclathrated in the cages of the double semi-clathrate and the position of resonance peak from encaged $CH_{4}$ molocules in the double semi-clathrate is the same as that from encaged $CH_{4}$ molocules in the pure $CH_{4}$ hydrate of structure I.

Effect of Garlic and Onion Juice on Fatty Acid Compositions and Lipid Oxidation in Gulbi (salted and semi-dried Yellow croaker) (굴비의 지방산 조성과 지방산화에 마늘과 양파즙이 미치는 영향)

  • Shin, Mee-Jin;Kim, Jeong-Mok
    • Journal of the Korean Society of Food Science and Nutrition
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    • 제33권8호
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    • pp.1337-1342
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    • 2004
  • To improve the quality of Gulbi, 10% garlic juice (GJ), 10% onion juice (OJ), and 10% garlic and onion juice mixture (GOJ) were added to the brine solution as a wet-salting method. The changes of total volatile basic nitrogen (TVB-N) and trimethyl amine (TMA) production, thiobarbituric acid reactive substance (TBARS) value, and total microbial numbers in Gulbi were analyzed during storage at room temperature for 12 days. The group treated with 10% GOJ showed the lowest values of 88.2 mg/l00 g in TVB-N, 14.13 mg/l00 g in TMA, and 3.1 $\mu$mol/kg in TBARS. The fatty acid profile of Gulbi was analyzed on 5, 15, and 30 days to investigate the effect of GOJ treatment. The group treated with GOJ showed higher C22:6 (9.91%) and C20:5 (4.25%) contents than control (7.37% and 3.71%, respectively), but had lower C18:1 (24.44%) content. The saturated fatty acid content in Gulbi was 32∼35% and the C16:0 (21∼23%) was predominant in it. Oleic acid was major unsaturated fatty acid in Gulbi. The contents of polyunsaturated fatty acids (C18:3, C20:5, C22:6) were decreased after 30 days but increased the saturated fatty acid (C16:0) and monoenes (C16:1 and C18:1). The Gulbi treated with GOJ by brine salting method showed higher DHA and EPA (9.91% and 4.25%, respectively) contents than the control group.