• Title/Summary/Keyword: 상변화재료

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프로그래머블 스위치에 이용 가능한 GeTe 박막의 특성 연구

  • Bang, Gi-Su;Lee, Seung-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.378-378
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    • 2013
  • 칼코겐화물의 일부는 전류 등의 에너지 입력에 따라 결정구조가 비정질 및 결정 사이에서 가역적으로 변화하며 상변화에 따라 전기 저항이 바뀌는 특성을 가지고 있다. 이와 같은 칼코겐화물 상변화 재료의 장점을 이용하여 프로그래머블 스위치를 구현할 수 있다. 그러나 상변화 재료만을 이용하는 프로그래머블 스위치는 전기신호 누설의 문제점이 발생한다. 이러한 문제점을 해결하기 위해서 지난 연구에서는 문턱 스위칭 칼코겐화물을 포함하는 다층구조 스위치를 제안하였다. 본 연구에서는 프로그래머블 스위치의 구성물질로서 문턱 스위칭 특성을 보이는 GeTe 박막의 특성을 보고한다. RF magnetron sputtering 방식을 이용하여 GeTe 박막을 증착하고 온도에 따른 결정화 양상 및 표면 형상 변화를 관찰하였다. GeSbTe 박막의 경우 $100^{\circ}C$ 근방에서 결정화가 시작되었고, 온도가 증가할수록 결정화가 급격히 진행되었다. 반면 GeTe 박막에서는 온도 증가에 따른 결정화가 거의 일어나지 않았다. 이러한 결과로부터 GeTe 합금 박막은 프로그래머블 스위치의 구성요소로서 문턱 스위칭에 적합한 물질임을 확인할 수 있었다.

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Phase-Change Properties of the Sb-doped $Ge_1Se_1Te_2$ thin films application for Phase-Change Random Access Memory (상변화 메모리 응용을 위한 Sb을 첨가한 $Ge_1Se_1Te_2$ 박막의 상변화 특성)

  • Nam, Ki-Hyeon;Choi, Hyuk;Ju, Long-Yun;Chung, Hong-Bay
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.156-157
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    • 2007
  • For tens of years many advantages of Phase-Change Random Access Memory(PRAM) were introduced. Although the performance improved gradually, there are some portions which must be improved. So, we studied new constitution of $Ge_1Se_1Te_2$ chalcogenide material to improve phase transition characteristic. Actually, the performance properties have been improved surprisingly. However, crystallization time was as long as ever for amorphization time. We conducted this experiment in order to solve that problem by doping-Sb.

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Compressive Strength and Tensile Properties of High Volume Slag Cement Composite Incorporating Phase Change Material (상변화 물질을 함유한 하이볼륨 슬래그 시멘트 복합재료의 압축강도와 인장특성)

  • Kang, Su-Tae;Choi, Jeong-Il;Lee, Bang Yeon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.2
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    • pp.183-189
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    • 2020
  • The purpose of this study is to investigate the compressive and tensile properties of high volume slag cement-based fiber-reinforced composite incorporating phase change material. Four mixtures were determined according to calcium hydroxide and expansive admixture, and the compressive strength and tension tests were performed. Test results showed that four mixtures showed a compressive strength over 51MPa and a tensile ductility over 3.2%. It was observed that calcium hydroxide and expansive admixture influenced the compressive and tensile performance, and the strength, ductility, and cracking patterns of composite could be improved by including proper amount of calcium hydroxide and expansive admixture.

Nano-scale Observation of Nanomaterials and Nano-devices

  • An, Chi-Won
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.86.1-86.1
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    • 2012
  • 나노재료와 나노기술의 연구개발 지원을 위하여 국가나노인프라인 나노종합팹센터에서 개발되고 있는 나노재료/나노현상의 실시간 관찰을 위한 SiN membrane chip 기술 및 나노그래핀 기반구축에 대한 최근 결과와 향후계획을 소개하고자 한다. 나노재료의 합성, 배열, 구조 등의 실시간 관찰을 가능하게 하기 위하여 제작된SiN membrane chip은 투과전자현미경(transmission electron microscope, TEM)에서 투명한 기판으로, 그 위에 나노재료를 합성, 배열하고 원하는 모양의 전극을 형성하여 나노재료 및 나노소자의 온도변화 및 전기적 특성 측정 등이 가능하다. 이러한 기술은 Ag, Sn, Cu 등 nano-cluster의 percolation 소자, SiN 및 Graphene 나노기공 소자, SiGe, BiTe, Si, ZnO 나노선 및 CNT의 내부구조변화, 상변화 등 다양한 나노재료/나노소자의 나노현상 관찰 및 해석에 적용되었다.

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The study for phase change properties of Se added $Ge_2Sb_2Te_5$ thin films ($Ge_2Sb_2Te_5$ 박막의 Se 증가에 따른 상변화 특성 연구)

  • Lim, Woo-Sik;Kim, Sung-Won;Lee, Hyun-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.166-166
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    • 2007
  • PRAM (phase-change random access memory)은 전류 펄스 인가에 따른 기록매질의 비정질-결정질 간 상변화와 그에 동반되는 저항변화를 이용하는 차세대 비휘발성 메모리 소자로서 연구되어지고 있다. 본 논문에서는 $(Ge_2Sb_2Te_5)_{1-x}Se_x$ (x=0,0.05,0.1,0.15) 조성에 대한 벌크 및 박막시료를 제작하고 각 조성에 대한 상변화 특성을 분석하였다. XRD를 통해 열처리 온도에 따른 구조적 분석을 실시하였고 UV-Vis-IR spectrophotometer를 사용하여 박막의 광학적 특성을 분석하였다. 또한 각 조성의 결정화 속도를 비교하기 위해 static tester를 사용하여 레이저 펄스 시간에 대한 반사도 변화를 측정하였고 DSC를 통해 결정화 온도를 측정하였다.

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Developing the Electrode Board for Bio Phase Change Template (바이오 상변화 Template 위한 전극기판 개발)

  • Li, Xue Zhe;Yoon, Junglim;Lee, Dongbok;Kim, Sookyung;Kim, Ki-Bum;Park, Young June
    • Korean Chemical Engineering Research
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    • v.47 no.6
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    • pp.715-719
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    • 2009
  • The phase change electrode board for the bio-information detection through electrical property response of phase change material was developed in this study. We manufactured the electrode board using Aluminum first that is widely used in conventional semiconductor device process. Without further treatment, these aluminum electrodes tend to contain voids in PETEOS(plasma enhanced tetraethyoxysilane) material that are easily detected by cross-sectional SEM(Scanning Electron Microscope). The voids can be easily attacked and transformed into holes in between PETEOS and electrodes after etch back and washing process. In order to resolve this issue of Al electrode board, we developed a electrode board manufacturing method using low resistivity TiN, which has advantages in terms of the step-coverage of phase change($Ge_2Sb_2Te_5$, GST) thin film as well as thermodynamic stability, without etch back and washing process. This TiN material serves as the top and bottom electrode in PRAM(Phase-change Random Access Memory). The good connection between the TiN electrode and GST thin film was confirmed by observing the cross-section of TiN electrode board using SEM. The resistances of amorphous and crystalline GST thin film on TiN electrodes were also measured, and 1000 times difference between the amorphous and crystalline resistance of GST thin film was obtained, which is well enough for the signal detection.

Study of Li-Ion Diffusion and Phase Transition in Cathode of Li-Ion Battery (리튬 이차전지의 양극 내부 이온 확산 및 상변화 특성 연구)

  • Kim, Sooil;Kim, Dongchoul
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.7
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    • pp.665-667
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    • 2013
  • Metal ions show various transitions in the cathode of a lithium-ion battery. The diffusion process of lithiumions and the phase transition in the cathode need to be thoroughly understood for the advanced design of an improved lithium-ion battery. Here, we employ a phase field model to simulate the diffusion of lithiumions and to study the phase transition in the cathode.

Electromagnetic and Thermal Analysis of PRAM cell with phase change material (상변화 재료의 물질상수에 따른 PRAM cell의 전자장 및 열 해석)

  • Jang, Nak-Won;Kim, Hong-Seung;Lee, Seong-Hwan;Mah, Suk-Bum
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.144-145
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    • 2007
  • Phase change random access memory is one of the most promising candidates for next generation non-volatile memories. However, the high reset current is one major obstacle to develop a high density PRAM. One way of the reset current reduction is to develop the new phase change material. In this paper, to reduce the reset current for phase transition, we have investigated the effect of phase change material parameters using finite element analysis.

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Real-time Transformation of FePt Nanoparticles to L10 Phase by the Gas Phase Synthesis (기상합성공정을 이용한 FePt 나노입자의 실시간 L10 상변화)

  • Lee, Ki-Woo;Lee, Chang-Woo;Kim, Soon-Gil;Lee, Jai-Sung
    • Korean Journal of Metals and Materials
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    • v.49 no.1
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    • pp.46-51
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    • 2011
  • Real-time formation of $L1_0$ phase of FePt nanoparticles in the gas phase during ultrasonic-spray pyrolysis is first discussed in the present study. Without any post heat treatment, $L1_0$ phase of FePt nanoparticles appeared at the temperature above $900^{\circ}C$ in the gas phase synthesis. X-ray diffractometry (XRD) and transmission electron microscopy (TEM) studies revealed that FePt nanoparticles less than 10 nm in size contained small volume of $L1_0$ fct phase. However, in other samples obtained at the temperature below $900^{\circ}C$, iron oxide phase co-existed and no evidence of phase transformation was found. Thus, it is anticipated that the time of flight of particles required for crystallization and phase transformation was extended according to the increase of the collision rate. Finally, magnetic properties represented by coercivity and saturation magnetization and functional groups on the particle surface were discussed based on VSM and FT-IR results.