• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.11
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• pp.18-23
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• 2018

FPSO consists of topside modularized plants for production of crude oil, and hullside structures that serve as support for the topside and storage of produced crude oil. The structural behavior of the FPSO topside module and its supporting hull depends on the interface structure that connects them, and the interface structure consists of a combination of individual unit support structures called Module Support Seat (MSS). Types of interface structures are various and, accordingly, the basic design of the FPSO topside module structure is greatly influenced, so various design methods should be considered from the initial design phase. Structural design of FPSO topside module requires consideration of the number of MSSs, connection type, and structural analysis options such as the range of finite element models, load conditions, and boundary conditions for verification of structural strength. In this study, the comparison combination cases for the above considerations were derived and the strength evaluation was performed, and the structural behavior characteristics of the topside module were compared and analyzed through a detailed review of the analysis results. The results of this study are considered to be a good reference for designing a more reliable topside module structure.

• Journal of the Mineralogical Society of Korea
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• v.18 no.4 s.46
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• pp.289-299
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• 2005

Annealing experiments on albite powders, thin sections, and TEM specimens have been performed utilizing an optical microscope heating stage. Sample orientations were determined by optical microscope and XRD, and then confirmed by TEM diffraction patterns. Partial melting of samples occurred at $1030^{\circ}C$-l2 hr for powder, but at $1060^{\circ}C$-12 hr for TEM specimen. It is difficult to get TEM images of albite microstructures above this temperature due to thickening and the amorphous phase of the melted part. Correlative studies between optical microscopy and TEM indicated that the $1050^{\circ}C$-12 hr annealing in ambient condition was most adequate to observe tweed microstructures in albite through TEM. In situ TEM heating experiments for direct observation of tweed microstructures in albite may require annealing at slightly higher temperatures than $1050^{\circ}C$ considering the high vacuum condition inside TEM.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.45 no.12
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• pp.1048-1058
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• 2017

One of the failure mechanism of spaceborne electronics is a fatigue fracture on solder joint under launch random vibration. Thus, a necessity of early diagnosis through the fatigue life evaluation on solder joint arises to prevent such potential risk of failure. The conventional life prediction methods cannot assure the accuracy of life estimation results if the packaging type changes, and also requires much time and effort to construct the analysis model of highly integrated PCB with various packaging types. In this study, we performed life prediction of PCB based on a reliability and life prediction tool of sherlock as a new approach for evaluating the structural reliability on solder joint, and those prediction results were validated by fatigue tests. In addition, we also investigated an influence of solder height on the fatigue life of solder joint. These results indicated that the Sherlock is applicable tool for evaluating the structural reliability of spaceborne electronic.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2005.11a
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• pp.437-444
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• 2005

Experiments were carried out in an atmospheric pressure, lab-scale gas turbine combustor to see the effect of partial premixing on unstable flame structure and Nox emission characteristics. The swirl angle is 45 deg., fuel-air mixing degrees were varied 0, 50 and 100% respectively at equivalence ratio ranging from 0.53 to 0.79. The evolution of phased-locked OH chemiluminescence images were acquired with an ICCD. NOx emission characteristics were also investigated at each experimental condition. The effect of the fuel-air mixing degree on the flame structure was obtained from phase-locked $OH^*$ images. And it was obtained from local heat release characteristics that the information about the region which the combustion instability was amplified or damped. It also could be confirmed that $\sigma$ has greatly influence on NOx emission characteristics at lean regimes. It would be expected that it could provide invaluable data for understanding the mechanism of combustion instability.

• Journal of the Society of Naval Architects of Korea
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• v.36 no.3
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• pp.83-92
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• 1999

In this paper, the fluid-structure interaction of large floating structures has been rigorously analyzed and the shear effect on the structural deformation has been investigated in oblique waves. A constant panel method(CPM) based on the Green function method is implemented for computing the hydrodynamic pressure, while a finite element method(FEM) is applied for the structural response based on the Mindlin plate theory with including shear deformation. In order to validate the method, we compared numerical results with experimental ones of Mega Float carried out by Yago & Endo in head waves. General behavior shows good agreement but the local displacement at the ends is slightly different. The numerical results show that the radiation pressure due to the fluid-structure interaction is locally larger than that of wave excitation and mooring devices greatly reduce the response. It is observed that the shear effects among the total deformation constitutes about 4% in the case of Mega Float in oblique waves.

• Journal of the Korea Institute of Building Construction
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• v.10 no.3
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• pp.129-136
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• 2010

This study is an evaluation of the water-tightness properties of rain-block systems in the sliding-roof joint of large-span membrane structures. In this study, we suggested a method of evaluating the water-tightness performance of the joint part of a sliding door in the roof of a large-span membrane structure (for a pilot project), in an environment of rain and wind. The shape of the rainwater blocking systems of the joint part in a sliding door verifies the defects and the effects of water leakage prevention when there is precipitation with wind conditions. To secure the water-tightness of large span membrane structures, it is necessary to have a guideline on the evaluation of the design for rain-block system of the joint part, and the quality of the membrane material, both of a retractable roof and a closed roof.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.368-368
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• 2011

최근에 보고된 양질의 고효율Cu(In,Ga)Se2 (CIGS) 태양전지는 CIGS광흡수층이 강한 (220:204) 우선배향성을 갖는 것으로 알려져 있다 [1]. 이러한 CIGS우선배향성은 Se 증착압력, Na농도, 기판온도 및 Mo후면전극의 표면상태에 영향을 받는 것으로 알려져 있지만 정확한 상호관계는 아직 명확히 알려져 있지 않으며, 특히 Mo후면전극의 영향에 대해서는 체계적인 연구결과조차 극히 드문 상황이다 [2]. 본 연구에서는 CIGS 박막의 우선배향성에 대해 Mo후면전극의 미세구조가 미치는 영향 및 이에 따른 cell특성의 변화에 대해서 연구하였다. Mo후면전극의 미세구조는 2 mTorr~16 mTorr까지 증착압력을 변화시켜 제어되었고, CIGS광흡수층은 이렇게 준비된 Mo후면전극상에 3단계 동시증밥법(3-stage process)을 사용하여 형성하였다. XRD를 통한 박막의 우선배향성 평가에서, Mo 증착압력에 대한 IGS I(300)/I(006) 및 CIGS I(220:204)/I(112)의 거동은 Mo 미세구조와 밀접한 관련이 있는 잔류응력(residual stress)의 변화 거동과 상당히 일치함을 보였다. 이에 반해, 높은 압력의 Mo위에 형성된 강한 (220:204) 우선배향성의 CIGS와 bare-glass위에서 형성된 강한 (112) 우선배향성의 CIGS내 Na농도는 서로 유사하였다. 상기의 결과는 Mo미세구조 그 자체가 CIGS 박막 우선배향성의 원인이 됨을 나타낸다. Selenized Mo시편의 XRD분석 및 IGS/Mo 시편의 TEM분석결과을 통해 MoSe2의 반응성이 잔류응력과 비례하는 Mo in-gain 밀도에 의존하는 함을 알 수 있었고, 이러한 MoSe2반응성(reactivity)과 IGS우선배향성 사이에 상당히 밀접한 관련이 있으며 이에 CIGS의 우선배향성이 결정됨을 확인하였다. 마지막으로, Mo변수에 의해 제작된 cell의 특성분석으로부터 cell의 효율이 주로 VOC의 증가에 기인하여 CIGS (220:204) 우선배향성의 정도에 비례하였다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.28-28
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• 2018

수전해(electrochemical water splitting)는 연료전지의 가역적 역반응을 이용하여 물로부터 수소와 산소를 발생시키는 기술이다. 산소는 음극에서 발생하는데, 이 때 음극 표면은 고농도의 산소 음이온 및 라디칼에 장시간 노출된다. 때문에 기계적, 화학적 내구성이 우수한 전극재를 사용할 필요가 있다. 불용성 전극 (dimensionally stable anode, DSA)은 이러한 기술적 요구사항을 잘 만족하는 상용화 된 전극이다. 티타늄이나 티타늄 합금 표면에 촉매를 미량 반복 살포하여 산화물 형태의 매우 견고한 표면을 형성함으로서 내구성을 확보한다. 그러나, 보통 DSA 제조 기법의 특징에 따라 다공성 표면 구조를 사용하지는 않기 때문에 생산 과정이 복잡하고 비용이 많이 발생하는 문제를 여전히 나타내고 있다. 본 연구는 상기 문제를 개선하기 위한 수전해용 음극 제조 기술에 관한 연구이다. 티타늄과 티타늄 합금은 동일한 양극산화 기술 적용이 가능하다는 점을 이용하여 티타늄 기판으로부터 다공성 구조를 형성함으로써 바인더의 사용을 배제하였다. 단일공정양극산화기법 (single-step anodization)을 이용하여 $IrO_2$와 $RuO_2$를 도핑함으로써 TiO2에 촉매능을 부여하였다. 제조된 나노튜브들의 구조적 특징을 HR-TEM (High-resolution transmission electron microscope)과 FE-SEM (Field-emission scanning electron microscope)으로 분석하고 SAED (selective area electron diffraction) 패턴을 분석하여 전극재의 결정성을 확인하였다. 알칼라인 분위기에서 일으킨 산소발생반응 (oxygen evolution reaction, OER)의 LSV (linear sweep voltammetry) 결과를 XPS (X-ray photoelectron microscoscopy) 결과와 연관지어 촉매 표면 구조와 과전압의 관계를 해석하였다. LSV 결과로부터 Tafel 분석을 연달아 수행함으로써 전극의 속도결정단계를 정의하였다. 최종적으로 사이클 테스트 통하여 DSA로써의 성능을 평가하였다.

• Journal of Korean Society of Forest Science
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• v.43 no.1
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• pp.14-19
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• 1979

On treatment with sodium hydroxide at $165^{\circ}$ for 1.5~3hr followed by air oxidation. vanillyl alcohol afforded colored materials. $^{13}C$-NMR spectrum of the material did not show any absorptions assigned to the carbons of chromophoric structures, but gave the valuable information on the chemical structures of the condensation products. On the other hand, the colored material specifically labelled by $^{13}C$ at the benzylic position was prepared by alkali treatment of vanillyl alcohol-[carbinol-$^{13}C$] followed by air oxidation, and $^{13}C$-NMR spectra of the material exhibited absorptions at 101.7 and 104.6 ppm due to the carbons of a quinonemethide structure, indicating that the quinomethide unit would be one of the important types of chromophores in which benzylic carbon of vanillyl alcohol was included.

• Journal of the Korean Electrochemical Society
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• v.22 no.1
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• pp.13-21
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• 2019

Prussian blue analogues(PBAs) are comprised of cyano-bridged transition metal ions. The wide and unique open-framework structures of the PBAs enable reversible intercalation and deintercalation of various ions such as $Na^+$, $K^+$, $Mg^{2+}$, $Zn^{2+}$, etc. In addition, since PBAs are synthesized through coprecipitation reaction in aqueous solution at room temperature, they are produced economically and environmentally friendly. However, the formation of crystals proceeds rapidly, and defects such as vacancy and crystal water tend to be present in the crystals, thereby affecting key battery performance. Therefore, significant efforts to inhibit defects in PBAs have been made. In the case of vacancy, the reaction rate was controlled at the synthesis stage to reduce the formation of vacancy, and the crystal water was removed by heat treatment under vacuum. In addition, by adding transition metals that do not react within the structure of PBA, the structural instability during the electrochemical reaction was largely alleviated.