• Economic and Environmental Geology
• /
• v.38 no.1
• /
• pp.23-31
• /
• 2005

This study was performed to investigate the effect of humic acid on the adsorption of arsenic onto hematite and its binding mechanism through the chemical speciation modeling in the binary system and the adsorption modeling in the ternary system. The complexation modeling of arsenic and humic acid was suitable for the binding model with the basis of the electrostatic repulsion and the effect of bridging metal. In comparison with the experimental adsorption data in the ternary system, the competitive adsorption model from the binary intrinsic equilibrium constants was consistent with the amount of arsenic adsorption. However, the additive rule showed the deviation of model in the opposite way of cationic heavy metals, because the reduced organic complexation of arsenic and the enhanced oxyanionic competition diminished the adsorption of arsenic. In terms of the reaction mechanism, the organic complex of arsenic, neutral As(III) and oxyanionic As(V) species were transported and adsorbed competitively to the hematite surface forming the inner-sphere complex in the presence of humic acid.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.18 no.3
• /
• pp.356-363
• /
• 2017

Blast furnace slag(BFS) is a by-product generated during the manufacture of pig ion, and is divided into water-cooled slag(WS) and air-cooled slag(AS) by the coking method of BFS. In this study, concrete specimens with ternary binders were produced at the various replacement levels of cement by AS. Various mechanical properties of concrete, such as compressive and split tensile strengths, absorption and water permeable pore, were measured. In addition, the chloride ions penetration resistance and carbonation resistance were tested to evaluate the durability of concrete incorporating AS. The experimental data indicated that the use of AS up to a maximum of 10% replacement level enhanced the concrete performance. However, a higher replacement of AS exhibited poor mechanical properties and concrete durability.

• Korean Chemical Engineering Research
• /
• v.48 no.4
• /
• pp.534-539
• /
• 2010

The adsorptive removal of organic sulfur compounds including tert-butylmercaptane(TBM), tetrahydrothiophene(THT) and dimethylsulfide(DMS) in methane was investigated over NaY and copper-exchanged NaY(CuNaY) zeolites at 303 K and atmospheric pressure. In the ternary adsorption system, the preferential adsorption of THT over other sulfur compounds on NaY and the concurrent adsorption of all sulfur compounds on CuNaY were achieved, which could be explained by the breakthrough curve, the temperature-programmed desorption, and the apparent activation energy for desorption. The sulfur uptake capacity of CuNaY(2.90~3.20 mmol/g) was much higher than that of NaY(0.70~0.90 mmol/g). A comparative study indicated that the $Cu^{1+}$ sites and acidity of CuNaY were probably responsible for the strong interaction with sulfur atom and high sulfur uptake abilities.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2007.04a
• /
• pp.25-28
• /
• 2007

In this study we measured the changes according to time respectively on the basis of 0, 30, 60 and 90 minutes, taking into consideration the decline in fluidity of concrete according to elapsed time to analyze manufacturing capability of batcher plant according to elapsed time of ready-mixed concrete manufactured in batcher plant, and offer basic data for mixture design of ultra-high strength concrete. The proportion of water-binder was 23.55, water content was 160kg/m3, proportion of replacement of crushed sand was 0, 20 and 40% at 3 level, and we applied to the same condition of triaxial component using blast furnace slag powder and silica fume as admixture. And to meet the demand of certain fluidity, we measured respectively on property before and after hardening of ultra-high strength concrete using superplasticizer. As a result of experiment, before hardening of ultra-high strength concrete showed the best fluidity in conditions of crushed sand replacement rates of 20% and superplasticizer composition of 1.95%, but it appeared that fluidity drops as time goes by in the same composition condition. And it appeared that when it comes to hardened, the changes of compression strength according to elapsed time by crushed sand replacement rates were within 1MPa. Therefore, it turned out that the difference of strength according to elapsed time was low and compression strength of 280dys in composition mentioned above appeared highly as 88MPa.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2008.04a
• /
• pp.537-540
• /
• 2008

Up to now, the RC structures have been recognized as being socially semi-permanent. But in recent years there were reports about the cases of early deterioration of RC structures. Most of all pore structure effects on the durability of concrete as well as mechanical properties of concrete. Therefore, in this study, mixing design was proportioned with the water-binder ratio 0.55 binder compositions corresponding to cement without any supplementary materials(OPC), cement with 50% blast-furnace slag replacement (BFS50), cement with 15% fly ash replacement (FA15), and ternary cement with cement, 15% fly ash, and 35% slag replacement (BFS35+FA15). And this study is to compare pore structure property of concrete by carbonation to investigate the effect of the permeation of deterioration factors such as $CO_2$ and chloride ion under the combined deterioration environments. The results showed that pore volume effects on the diffusibility of chloride ion.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2008.04a
• /
• pp.677-680
• /
• 2008

The surface of particles was energetically modified by inter-grinding OPC and BFS in vibration mill for improvement of the early strength and low-heat evolution of concretes. BFS was pre-grinding in ball-mill to 2535(BS2) and 3245 $cm^2/g$(BS3), in blaine surface area. The inter-grinding time in vibration mill was changed from 10 minutes to 30 minutes. And Mixing ration of BFS to OPC was changed in 60, 70, 80%. After inter-grinding, the change of specific surface area, particle size distribution, hydration heat of cement and compressive strength of mortar were measured. As the result of comparison test with LHC, it was found that the mixture and inter-grinding time satisfying the value of over 100% of compressive strength for 7 days and under 170J/g of heat of hydration for 72 hours. and it was confirmed that the possibility of low heat slag cement utilizing blast furnace slag(BS2, BS3) with the low fineness in high volumes.

• Journal of the Korean Electrochemical Society
• /
• v.22 no.2
• /
• pp.60-68
• /
• 2019

High-voltage operation of the lithium ion battery is one of the advantageous approaches to obtain high energy capacity without changing the conventional cell components and structure. However, operating at harsh condition inevitably results in severe side reactions at the electrode surface and structural disintegration of active material particles. Herein we coated layers composed of $Al_2O_3$ and ZnO on the electrode based on NCM using atomic layer deposition (ALD). Thicker layers of novel Al-doped ZnO (AZO) coating compared to conventional ALD coated layers are prepared. Cathode based on NCM with the varying AZO coating thickness are fabricated and used for coin cell assembly. Effect of ALD coating thickness on the charge-discharge cycle behavior obtained at high-voltage operation was investigated.

• Journal of the Korean Electrochemical Society
• /
• v.20 no.2
• /
• pp.27-33
• /
• 2017

Conventional lithium ion batteries suffer from notorious safety issues caused by inevitable lithium dendrite formation and proliferation during over/fast charging processes. The lithium dendrites or mechanical damage on the separator induce internal short circuit in LiB that generates extensive amount of heat within contacted electrode surfaces through the separator. During this heat generation, conventional polyolefin separators shrinks dramatically, and increasing short circuit pathway, that causes the battery to explode. To overcome this serious issue, ceramic coated separators are developed in commercial LiB to enhance thermal and mechanical stability. In this paper, various size(IL = 488.5 nm, I = 538.7 nm, S = 810.3 nm, D = 1533.3 nm) of $Al_2O_3$ particles are coated using styrene-butadiene rubber(SBR) / carboxymethyl cellulose(CMC) binder on PE separator to investigate its thermal stability and electrochemical effect on LiB coin cell with NCM cathode and Li metal anode.

• Korean Journal of Materials Research
• /
• v.2 no.4
• /
• pp.248-256
• /
• 1992

This paper has reviewed some of the basic principles that underlie the field of defect chemistry in simple ATi$O_3$(A=Ca, Sr, Ba) perovskites. Frenkel defects in perovskite structure is very much unlikely, and Schottky defects and intrinsic electronic defects in undoped materials are negligibly small compared with background acceptor impurities. The electrical properties of perovskite ceramics are dependent on the aliovalent impurities. Since perovskite structure is a ternary system, the stoiohiometry between cations as well as cation-anion ratio will affect defect structure and electrical properties. BaTi$O_3$and SrTi$O_3$show a limited deviation from the cation stoichiometry while CaTi$O_3$has significant excess CaO and Ti$O_2$solubility.

• Journal of the Korean Ceramic Society
• /
• v.33 no.4
• /
• pp.405-410
• /
• 1996

The partial substitution of LiTaO3 with Al2O3 caused the variation of dielectric properties and a lower melting temperature yielding an easier growth of single crystal. The lattice constants and Raman band broadening were measured for the LiTaO3 solid solution in which the cations of Li+ and Ta5+ were partially substituted by Al3+ cation. The LiTaO3 type limit phases were obtained. ; Li1.15Al0.45Ta0.7O3 for cationic excess Li1.15Al0.45Ta0.7O3 for stoichiometry Li0.85Al0.05TaO3 for cationic deficit. The second phase was formed beyond the solubility limit. The limit phase (Li0.85Al0.05TaO3) in the region of cationic deficit showed the lowest Cuire temperature of 61$0^{\circ}C$ and melting point of 152$0^{\circ}C$ compared to the solid solutions in other regions (TMp=1$650^{\circ}C$, Tc=69$0^{\circ}C$ for LiTaO3)