• 대한치과보철학회:학술대회논문집
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• 2004.11a
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• pp.82-82
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• 2004

• 대한치과보철학회:학술대회논문집
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• 2004.11a
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• pp.56-56
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• 2004

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2014.11a
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• pp.266-267
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• 2014

$TiO_2$ 기반의 DSA 전극에 촉매제를 동시에 도핑할 수 있는 양극산화 단일 공정을 연구하였다. 에틸렌 글리콜 용매하에 $KRuO_4$와 $NH_4F$를 전해질로 사용하여 타이타늄을 양극산화 할 때 도핑과 나노구조 제어를 동시에 수행할 수 있었다. TEM과 XPS 분석 결과, 균일한 Ru 산화물이 $TiO_2$ 구조 내에 분포함을 확인할 수 있었다.

• Applied Chemistry for Engineering
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• v.19 no.3
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• pp.249-258
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• 2008

Nanoporous alumina with highly ordered pore arrays, which is prepared based on electrochemical anodization under the controlled conditions, has attracted great attention due to the variety of its applications. In case of porous alumina, the manipulation of nanoporous structures under different electrochemical conditions and their formation mechanisms have been studied for a long time. Recently, its principles have been applied to other valve metals. Especially, there have been a big success in the preparation of titania nanotubes via the anodization of titanium. In this paper, we review the anodization of aluminum and recent trends in anodization of Ti and other valve metals based on the principles of aluminum anodization.

• Korean Journal of Dental Materials
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• v.45 no.4
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• pp.243-256
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• 2018

The purpose of this study was to investigate the effects of the anodization and cyclic calcification treatment on the surface characteristic and bioactivity of the titanium thin sheet in order to obtain basic data for the production of bioactive titanium membrane. A $30{\times}20{\times}0.08mm$ titanium sheets were prepared, and then they were pickled for 10 seconds in the solution which was mixed with $HNO_3:HF:H_2O$ in a ratio of 12: 7: 81. The $TiO_2$ nanotube layer was formed to increase the specific surface area of the titanium, and then the cyclic calcification treatment was performed to induce precipitation of hydroxiapatite by improvement of the bioactivity. The corrosion resistance test, wettability test and immersion test in simulated body solution were conducted to investigate the effect of these surface treatments. The nanotubes formed by the anodization treatment have a dense structure in which small diameter tubes are formed between relatively large diameter tubes, and their inside was hollow and the outer walls were coupled to each other. The hydroxyapatite precipitates were well combined on the nanotubes by the penetration into the nanotube layer by successive cyclic calcification treatment, and the precipitation of hydroxyapatite tended to increase proportionally after immersion in simulated body solution as the number of cycles increased. In conclusion, it was confirmed that induction of precipitation of hydroxyapatite by cyclic calcification treatment after forming the nanotube $TiO_2$ nanotube layer on the surface of the titanium membrane can contribute to improvement of bioactivity.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2015.05a
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• pp.109-110
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• 2015

알루미늄 합금의 종류중 하나인 ADC12는 가공성이 좋고 가격이 저렴하기 때문에 산업의 많은 분야에 이용할 수 있지만 양극산화를 진행할 시 합금의 주요 구성성분인 실리콘(Si)으로 인해 균열(Crack)이 생기는 문제가 발생하여 이에 따라 균일한 산화막이 생성되지 않다는 단점을 가지고 있다. 이 단점을 극복하기 위해 양극산화를 진행할 때 금속 음이온 성분이 첨가된 전해질을 이용하면 실리콘이 떨어져 나간 부분을 자가치료(Self-healing)할 수 있어 피막의 경도를 포함한 각종 특성이 증가하는 결과를 확인할 수 있다. 본 연구에서는 ADC12를 양극산화할 때 황산 수용액을 기본 전해질로 하여 전해질에 타이타늄(Ti), 마그네슘(Mg), 몰리브덴(Mo)이 포함되어 있는 금속 음이온 물질을 첨가하였고, 금속 음이온 전해질의 농도와 양극산화 진행 시간을 변수로 하여 제조한 산화막의 전기화학적 특성을 SEM(Scanning Electron Microscope), Tafel plot, 그리고 Microvickers hardness tester를 통해 평가하였다.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.200.1-200.1
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• 2014

$TiO_2$에 니켈과 질소가 도입된 촉매를 합성하여 광촉매 활성을 연구하였다. degussa는 methylene blue 분자에 대하여 흡착능력을 거의 나타내지 않았으나, 니켈과 질소의 양이 최적화된 촉매에서는 최대 흡착량이 13.01 mg/g에 달하였다. Zeta potential 측정 결과 최대 -25.46 mV의 음전하를 나타내었으며, 각각의 촉매흡착성은 이와 비례하는 것으로 나타났다. 특히 니켈이 도입된 $TiO_2$는 흡착능력뿐만 아니라 가시광선을 이용한 MB분해 실험에서 우수한 광촉매 특성을 나타내었다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2006.04a
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• pp.147-147
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• 2006

• Resources Recycling
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• v.25 no.5
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• pp.64-74
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• 2016

Titanium and iron are closely related in nature, although titanium is the ninth most abundant element in the Earth's crust. Iron in titanium ores must be removed for use as feedstocks in the manufacture of titanium dioxide pigments and pure $TiCl_4$ for metal titanium. In this study, various beneficiation processes of ilmenite for production of $TiO_2$ have been reviewed and compared. Most of these processes involve a combination of pyrometallurgy and hydrometallurgy. These beneficiation processes of ilmenite generate considerable quantities of wastes primarily in the form of iron salt, iron oxide and acidic effluents. Therefore, it is important that recovery of acid value from waste and conversion of iron bearing waste to useful materials for development of new beneficiation processes of ilmenite.

• Journal of the Korean Society of Propulsion Engineers
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• v.24 no.1
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• pp.58-63
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• 2020

THPP is a type of metallic complex explosive used in initiators, consisting of TiH₂ and KClO₄. In this case KClO₄ includes ClO₄^- which is a harmful substance that may cause thyroid dysfunction or tumors. In this study KIO₄ is applied to a new type of environmentally friendly explosive as a substitute to the conventional KClO₄. Tests were carried out to see if KIO₄ can be made a successful replacement for KClO₄.