• Title/Summary/Keyword: 산소 주입

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Development of a Field Oxygenation Device and Its Practice in the Oxygen Depleted Water Mass (빈산소 수괴해역 용존산소 환경개선장치 개발과 현장 적용)

  • Lee, Yong-Hwa;Kim, Young-Suk;Shim, Jeong-Min;Kwon, Kee-Young
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.16 no.4
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    • pp.339-344
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    • 2010
  • Oxygen depleted water mass can damage aquatic animals not only in direct way but also in indirect way by generating toxic substances including occurrence of hydrogen sulfide and ammonia which are also highly detrimental to animal life in the water mass. An oxygen dissolution device was developed, which makes turnover of the oxygen rich (over 20 mg/L) surface water down to the bottom where hypoxia is evident and tested the device in terms of oxygen recovery in the oxygen depleted bottom water. the device with turnover rates of $3.6\;m^2$/min at the liquid oxygen injection rate of 48~26.3 L/min could recover dissolved oxygen level to 7~25 mg/L at depth 7 m to lead to the dissolution level of over 90% by the supply of liquid oxygen. The running advantage of the device is that it does not require any auxiliary tank and higher energy for operation. Therefore, it can be highly useful device to relieve damages to the farmed animals in the oxygen depleted waters.

The Effect of Adsorbed Oxygen Species on the Partial Oxidation of Ethylene over Ag/α-Al2O3 (Ag/α-Al2O3 촉매상에서의 에틸렌 부분산화반응에 미치는 흡착산소종의 영향)

  • Baik, Choong-Hoon;Lee, Sang-Gi;Yeo, Jong-Kee;Lee, Ho-In
    • Applied Chemistry for Engineering
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    • v.5 no.4
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    • pp.609-615
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    • 1994
  • Partial oxidation of ethylene over 10wt% $Ag/{\alpha}-Al_2O_3$ catalyst was studied with a pulse reactor which was connected directly to a G. C. When ethylene was injected after oxygen injection at the temperature where molecular adsorption of oxygen is difficult ethylene oxide was evolved. From the results, it is suggested that adsorbed atomic oxygen is related with the evolution of ethylene oxide. The selectivity to ethylene oxide decreased with the decrease of the amounts of adsorbed oxygen and bulk oxygen. Ethylene oxide was either decomposed to ethylene and adsorbed oxygen or isomerized to acetaldehyde. However, the isomerization of ethylene oxide to acetaldehyde was strongly suppressed by the preadsorbed oxygen.

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Synthesis of Nanosized TiO$_2$ Powder by Chemical Vapor Condensation Process(1) (화학기상응축법에 의한 TiO$_2$ 나노분말의 합성 (1))

  • 김신영;유지훈;이재성;김종렬;김병기
    • Journal of the Korean Ceramic Society
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    • v.36 no.7
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    • pp.742-750
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    • 1999
  • Nanosized TiO2 powders were synthesized using the chemical vapor conduensation (CVC) process with various precursor feeding rates (0.37 and 0.752 ml/min) and oxygen flow rates(1-2slm) conditions and powder characteristics were investigated in terms of formation of nanosized powder varying with the above processing conditions. For this study the main thermodynamic and fluid dynamic factors -supersaturation ratio collision frequency and residence time-were theoretically established and compared to the characteristics of formed TiO2 powder. The loosely combined anatase phase powders (including less than 3%of rutile phase) having 20-30nm crystallite size were obtained at overall conditions. The particle size and th degree of agglomeration for a precursor flow rate of 0.376 ml/min turn out to be smaller than for a flow rate of 0.742ml/min. And the decreasing of particles size and particle size distribution were observed with increasing oxygen flow rate as the residence time and collision frequency were reduced by increasing oxygen flow rate,. It appears that further scrutiny is needed to elucidate the influence of the individual thermodynamic and kinetic parameters mdependently.

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Effect of Dry Fog Injection on Waste Decomposition in an Aerobic Landfill (호기성매립지에서 드라이포그 주입에 의한 폐기물분해 촉진에 관한 연구)

  • Park, Jin-Kyu;Lee, Byung-Sun;Yoon, Seok-Pyo;Lee, Nam-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.2
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    • pp.43-51
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    • 2018
  • The objective of this research was to assess the effect of moisture content and water injection method into the landfill on waste decomposition in an aerobic landfill. Firstly, respirometric experiments were performed in order to assess the effect of initial moisture content (20%, 30%, 40% and 50% respectively) on landfilled waste decomposition. The cumulative oxygen uptake and oxygen uptake rate were highly increased with the increase of initial moisture content. Secondly, lysimeter experiments showed that in comparison with the vertical injection method, dry fog system enhanced decomposition of organic wastes. Also, dry fog system provided uniform moisture distribution more than the vertical injection method within landfill.

지하수 오염 정화에서 ORC(Oxygen Release Compound)의 적용성 연구

  • 배광옥;임인규;차장환;정형재;이강근
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.263-267
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    • 2003
  • 물만 주입한 1군과 물-토양을 주입한 2군, 물-ORC를 주입한 3군, 물-토양-ORC를 전부 주입한 4군의 4개군으로 조건을 차별화하여 2$0^{\circ}C$ 항온 OER시험을 실시하였다. 1군은 약4mg/L, 2군은 3mg/L, 3군은 12~13mg/L, 4군은 11~12mg/L의 DO를 나타내었다. ORC를 투여하지 않은 1군과 2군은 2$0^{\circ}C$ 용존산소 포화선인 Bmg/L에 크게 못미치는 것으로 나타났고 ORC를 투여한 3군과 4군은 포화선보다 3~4mg/L 높은 수치를 나타내었다. 토양을 주입한 2군과 4군에서는 토양 미생물의 영향을 받아 DO가 감소하나 ORC를 투입한 4군에서는 그 영향이 미미하게 나타난다. TCE 분해능 시험은 15$^{\circ}C$에서 항온으로 30일간 시험하였다. 초기 농도 5000ppb가 30일 경과 후 약 4000ppb로 약20%의 분해율을 나타내었고, 메탄을 첨가했을 때 더 잘 분해됨을 보여주었다.

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Reaction Gas Composition Dependence on the Properties of SnO2 Films on PET Substrate by ECR-MOCVD (반응가스조성이 PET기판위에 ECR 화학증착법에 의해 제조된 SnO2 박막특성에 미치는 영향)

  • Kim, Yun-Seok;Lee, Joong-Kee
    • Journal of the Korean Electrochemical Society
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    • v.8 no.3
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    • pp.139-145
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    • 2005
  • [ $SnO_x$ ] films on the flexible substrate of PET film were prepared at ambient temperature under a $(CH_3)_4Sn(TMT: tetra-methyl tin)-H_2-O_2$ atmosphere in order to obtain transparent conductive polymer by using ECR-MOCVD(Electro Cyclotron Resonance Metal Organic Chemical Yfpor Deposition) system. The prepared $SnO_x$ thin films show generally over $90\%$ of optical transmittance at wavelength range of 380-780nm and about $1\times10^{-2\~3}ohm{\cdot}cm$ of electrical resistivity. In the present study, effects of $O_2/TMT\;and\;H_2/TMT$ mole ratio on the properties of $SnO_x$ films are investigated and the other process parameters such as microwave power, magnetic current power, substrate distance and working pressure are fixed. Based on our experimental results, the $SnO_x$ film composition ratio of Sn and O directly influences on the electrical and optical properties of the films prepared. The $SnO_x$ film with low electric resistivity and high transmittance could be obtained by controlling the process parameters such as $O_2/TMT\;and\;H_2/TMT$ mole ratio, which play an important role to change the composition ratio between Sn and O. An increase of $O_2/TMT$ mole ratio brought on the increases 0 content in the $SnO_x$ film. On the other hand, an increase of $H_2/TMT$ mole ratio lead to decreases the oxygen content in the film. The optimized composition ratio of oxygen : tin Is determined as 2.4: 1 at $O_2/TMT$ of 80 and $H_2/TMT$ of 40 mole ratio, respectively.

An Experimental Study on the Characteristics of Sodium Fires (나트륨 화재 특성의 실험적 연구)

  • Bae, Jae-Heum;Ahn, Do-Hee;Kim, Young-Cheol;Mann Cho
    • Nuclear Engineering and Technology
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    • v.26 no.4
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    • pp.471-483
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    • 1994
  • A sodium fire facility with a test chamber of 1.7㎥ volume was constructed and operated to carry out experiments of sodium fires such as pool, spray, and columnar fires which might take place in sodium-related facilities. The experimental results of pool fires showed that the increase of temperature and pressure in the test chamber was much smaller than that of spray and columnar fires even though their amount of sodium injection in the chamber was much larger compared to other types of fires. And it was found in pool fires that the temperatures of sodium pool and the gas temperature in the test chamber had been maintained much longer than other types of fires, and that the chamber pressure had come to vacuum due to depletion of the oxygen for a large amount of sodium injection in the chamber. The experimental results of spray fires showed that sprayed sodium of small particles instantly reacted with oxygen, and that its reaction heat increased gas temperature and pressure of the test chamber rapidly and decreased them shortly. And the maximum gas temperature and pressure of the test chamber in spray fires ore greatly changed according to the inlet sodium temperature in the test chamber. The characteristics of the columnar fires were almost similar to those of spray fires, but the maximum temperature and pressure of the test chamber were much smaller even for a large amount of sodium injection. And it was shown in spray and columnar fires that the temperatures at each measurement position in the test chamber were quite different due to the instantaneous sodium oxidation in comparision with pool fires. Finally, the graphex powder was proved to be a very effective extinguisher against sodium pool fires.

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