• Applied Chemistry for Engineering
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• v.32 no.1
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• pp.35-41
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• 2021

VWTi, which is used as a commercial catalyst in NH3-SCR, exhibits excellent denitrification performance at 300 to 400 ℃, but there is a problem that efficiency decreases at low temperatures below 300 ℃. Research on catalysts containing promoter to increase low-temperature denitrification efficiency is steadily progressing. However, research on the cause of the improvement in low-temperature denitrification efficiency of the catalyst and the catalyst properties is insufficient. In this study, it was confirmed that by adding Sb to VWTi, denitrification performance was improved by more than 10% in NH3-SCR reaction below 300 ℃. At this time, the space velocity and the size of the catalyst particles were controlled to exclude the influence of external/internal diffusion. In addition, the catalytic properties according to the presence or absence of Sb were investigated by performing BET, TEM/EDS, O2-TPD, H2-TPR and DRIFTs analysis. It was judged that the addition of Sb increased the adsorbed oxygen species on the surface of the catalyst, thereby enhancing the redox properties of the catalyst at low temperature and exhibiting excellent denitrification performance.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.8 no.3
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• pp.424-430
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• 1998

Film characteristics of thin ONO dielectric layers for MONOS (metal-oxide-nitride-oxide-semiconductor) EEPROM was investigated by AES, SIMS, TEM and AFM. The ONO films with different dimension of tunneling oxide, nitride, and blocking oxide were fabricated. During deposition of the LPCVD nitride films on tunneling oxide, this thin oxide was nitrized. When the blocking oxide were deposited on the nitride film, the oxygen not only oxidized the nitride surface, but diffused through the nitride. The results of ONO film analysis exhibits that it is made up of $SiO_2$(blocking oxide)/O-rich SiOxNy (interface)/ N-rich SiOxNy(nitride)/O-rich SiOxNy(tunneling oxide). In addition, the SiON phase is distributed mainly near the tunneling oxide/nitride and nitride/blocking oxide interfaces, and the $Si_2NO$ phase is distributed mainly at nitride side of each interfaces and in tunneling oxide.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.8 no.3
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• pp.401-406
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• 1998

For the applications in optical waveguides and devices, LiNbO_3$ single crystals need to overcome the weakness of optical damage due to the inhomogeneities of laser-induced refractive index. This problem can be solved by doping of Mg in LiNbO_3$ and proton exchange of LiNbO_3$. In this study, to understand the mechanism of optical damage resistance in LiNbO_3$, the changes of lattice defects in LiNbO_3$ caused by MgO doping and acid treatment were observed indirectly by $OH^-$ absorption bands using a FT-IR spectrophotometer. The effect of lattice defects on temperature, heat-treatment and polishing were also investigated. It is shown that MgO doping increases optical damage resistance by generating the defects of $Mg_{Nb}^{2+}$ in the lattice of LiNbO_3$, and that proton exchange by implantation of $H^+$ ion in the hexagonally closest packed oxygen layers on the surface of LiNbO_3$, makes lattice defects, which diffuse into the crystal after heat-treatment above $400^{\circ}C$.

• Applied Chemistry for Engineering
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• v.2 no.3
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• pp.279-288
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• 1991

Mg- and Zn-ferrites having spinel structure, a kind of complex oxides showing the advantageous properties of constituent single metal oxides, were selected to find a relationship between their catalytic activities in the dehydrogenation of ethylbenzene to styrene and the catalytic properties. For the structural and physical analyses of ferrites, XRD, BET, TG/DTA, ESCA, TEM, and TPD methods were employed. The effects of Cr-substitution were intensively studied by the experimental methods mentioned above. Chromium which showed a preferential tendency to diffuse to the surface acted as a structural promoter by increasing surface area and stability of catalyst structure. In the dehydrogenation of ethylbenzene, catalytic activity, and the effects of Cr-substitution were investigated. Oxygen mobility was decreased with the amount of Cr-substitution in $MgCr_xFe_{2-x}O_4$, which resulted in the increase of selectivity to styrene and the suppression of total oxidation.

• Nuclear Engineering and Technology
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• v.26 no.1
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• pp.90-99
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• 1994

One of the major phenomena occurring in defective fuel rods is the oxidation of UO$_2$ fuel pellets from UO$_2$ to UO$_{2+}$x/ by the oxygen Produced from the dissociation of the steam in the Pellet-to-clad gap, which leads to the enhancement of fission gas release. In this paper, the oxidation kinetics of defective fuel rods was analyzed on the basis of operating conditions of the reactor and defective fuel rod itself. Oxidation kinetics of the fuel pellet was determined under the assumption that the gap is filled with the saturated steam of 150 atm and an enhancement factor for fission gas release was introduced to take into account the effect of fuel oxidation on fission gas release. Comparison with experimental data shows that the enhancement factor predicts well the increased fission gas release due to the oxidation of UO$_2$fuel pellets.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2003.05a
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• pp.772-777
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• 2003

선박이 배출하는 안정수(ballast water)는 외부로부터 유해 생물들이 유입되어 전파해 오는 주요경로로써 해양환경의 매우 중요하고 위험한 일종의 하나이지만, 이에 대한 효과적인 처리방법은 아직까지도 개발되지 못하였다. 그러나 최근 강 전리방전을 이용하여 고 밀집 산소와 물분자를 고농도 수산자유기(OH: hydroxyl radical)로 전리, 활성입자를 발생시켜 신속히 확산시키면 넓은 범위에서 비교적 낮은 농도로 유해성 침입 생물을 잔류물 없이 저렴한 비용으로 살균제나 촉매제의 사용 없이 소멸시켜 처리하는 효과적인 새로운 녹색방법을 제안하였다. 또한, 수산기는 강 산화제로써(산화환원 전위는 2.80 eV), 적조생물을 신속, 효과적으로 사멸시켜 잔유물과 오염물 발생 없이 이상적으로 해양적조현상을 처리할 수 있는 활성물질이다. 고출력 강 전리장치를 활용하면 수산기 활성제의 발생 농도를 Sr104 이상으로 얻을 수 있으므로, 해양적조처리에 요구되는 문턱 값 농도(~l$\times$$10^{-6}$)를 충족시킬 수 있으며, 이 경우 적조생물 소멸처리시간은 불과 10 sec 내외이므로 선박 안정수 처리문제와 함께 적조발생의 난문제를 해양동력학적으로 동시에 해결할 수 있는 효과적인 기술이다. 실험결과로부터 시간당 1 k톤의 활성물질을 발생하는 수산기활성제 제조장치의 경우, 약 4$\times$$10^2$ $\textrm{km}^2$/h의 적조해면을 처리할 수 있으며, 그 비용은 약 US$l,000 정도에 상당하므로, 적조에 따른 경제손실과는 비교될 수 없는 저렴하고 효과적인 방법이다. 활성물질의 생성시간과 가공시간은 불과 수십 $\mu\textrm{s}$ 및 수 sec 에 불과하므로, 1 kton/h 용량의 수산기활성제 제조장치의 환산소비동력은 약 200 kW이고, 장치의 체적은 10~30 ㎥의 공간으로 충분하므로, 소형선박으로 상당면적의 적조피해를 효과적으로 해결할 수 있다.

• Journal of the Korean Society of Combustion
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• v.10 no.2
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• pp.26-34
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• 2005

The performance of oxygen combustion with $CO_2$ feeding was investigated in a pyrex tube furnace. The inverse type multi-hole burner was used for improving mixing and wide operating range. It introduced oxygen, fuel, and oxygen, respectively, from center tube to outer tubes. Oxygen combustion characteristics with excess oxygen ratio, oxygen feeding ratio, and $CO_2$ feeding flow rate were studied to optimize the operating condition and to apply the oxygen combustion with recirculation of flue gas to a real furnace. This paper presents results on the effect of $CO_2$ feeding flow rate on the structure of the flames and concentrations of NO and CO emissions. The visible flame length was shortest due to well mixing between fuel and oxygen when the oxygen feeding ratio was 0.25. The NO emission was reduced drastically regardless of excess oxygen ratio when the $CO_2$ feeding flow rate was larger than 15 lpm. The CO emission is varied by changing the $CO_2$ feeding flow rate but the CO emission characteristics is highly affected by excess oxygen ratio. When the excess oxygen ratio is below $\lambda=1.1$, the CO emission increased as the $CO_2$ feeding flow rate increased.

• 한국방재학회:학술대회논문집
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• 2011.02a
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• pp.63-63
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• 2011

화재란 사람의 의도에 반하거나 고의에 의해 발생하는 연소현상으로서 소화시설 등을 사용하여 소화할 필요가 있는 것을 말한다. 사람의 의도에 반한다고 하는 것은 과실에 의한 화재를 의미하며 화기취급 중 발생하는 실화뿐만 아니라 부작위에 의한 자연발화도 포함하며, 고의에 의한다고 하는 것은 일정한 대상에 대하여 피해발생을 목적으로 화재발생을 유도하였거나 직접 방화한 경우를 말한다. 연소현상이라 함은 가연성 물질이 산소와 결합하여 열과 빛을 내며 급속히 산화되어 형질이 변경되는 화학반응을 말한다. 소화시설 등을 사용하여 소화할 필요가 있다는 것은 화재란 연소현상으로서 소화의 필요성이 있어야 하며 소화의 필요성의 정도는 소화시설이나 그와 유사한 정도의 시설을 사용할 수준 이상이어야 한다. 화재원인조사란 발화부를 판단하고 화재에 이르게 된 발화원을 규명하며, 발화부로부터 연소확대된 경과를 조사하는 일련의 행위로서 화재원인조사시 가장 중요한 사항은 발화부 판단인 바, 이는 화재원인이 발화부에만 존재하기 때문이다. 최근에는 다양한 소재의 사용으로 인해 일단 화재로 진행될 경우 인명 및 재산상 피해가 증가하게 되어 있으며, 이로 인해 화재조사시 화학, 물리, 전기, 건축, 기계, 소방 등 다양한 지식과 화재현장에 대한 이해가 요구된다. 화재현장 조사시 발화부 판단의 과학적 접근은 매우 중요한 것으로서, 화재원인의 명쾌한 규명으로 책임한계 구분은 물론, 유사사고의 재발방지를 위한 연구가 필요하다. 본 연구에서는 기 발생한 화재사례에서 얻은 화재패턴을 분석하여 얻은 자료를 통해 발화부를 판단할 수 있는 조사방법을 다음과 같이 제시하였다. 1) 화재시 열전달과 화염확산 과정에서 건축구조물, 내장재, 집적물 및 각종 설치물의 구조, 재질 등에 따라 다양한 화재패턴을 형성하게 됨을 알 수 있다. 2) 화재패턴의 종류로는 화재플럼에 의한 삼각형, 주상, V, U 패턴 등이 있으며, 연소 생성물인 화염, 연기, 열 등에 의해 다양한 형태를 보임을 알 수 있다. 3) 위와 같은 결과를 종합하여 연소의 상승성, 불꽃 및 연기 흔적, 열에 의한 흔적 등에 의해 연소의 방향성을 알 수 있다. 4) 결국 화재현장에서 명확한 화재원인을 규명하기 위해서는 화재패턴에 의해 연소확대과정을 역으로 추적하여 발화부를 결정한 다음, 발화부내에서 화재원인을 찾아내야 할 것이다.

• Microbiology and Biotechnology Letters
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• v.17 no.1
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• pp.74-80
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• 1989

For improvement of photobiological hydrogen production, Rhodopseudomonas El5-1, a photo-synthetic becterium capable of producing n high yield of hydrogen, was immobilized and conditions for hydrogen production by immobilized cells were examined. The optimum concentration for the combined matrix was obtained when sodium alginate was used at final concentration of 4%. The immobilized cells may reduce the inhibitory effects of nitrogen or oxygen. To minimize the diffusion resistance of the nutrients in alginate gel, the bend size less than 2 mm in diameter was desirable. The immobilized cells were also able to utilize n wide range of organic substrates for the production of hydrogen. The hydrogen producing activity of the immobilized cells was maintained for 20 days without loss of activity during semi-continuous operation of the reactor by feeding of new medium periodically and continuous production of hydrogen could be successfully performed for 30 days.

• 한국연소학회:학술대회논문집
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• 2005.10a
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• pp.170-178
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• 2005

Multi-hole type oxygen combustion burner was developed for industrial gasification and smelting furnace. We investigated characteristics of flame, radiation transfer, and soot emission in the convectional oxygen burner with respect to the feeding condition of fuel and oxygen. Regarding the results of the conventional burner, we designed new burners which have larger fuel consumption rate and radiation heat transfer. We changed the size and hole number and shape of the exit plane of the burner. In addition, the performance of the burner was tested with respect to the feeding condition of the fuel and air: Normal Diffusion flame(NDF) and Inverse Diffusion Flame(IDF). We investigated the flame configuration, radiation heat transfer, and soot formation by using a CCD camera, heat flux meter, and Laser Induced Incadescence(LII), respectively. The stable operating condition was obtained by the flame configuration and the flame of the burner which has dented exit plane was more stable in whole operating conditions. The characteristics of radiative heat transfer were sensitive to the feeding condition of reactants and the flame of 75% primary oxygen and 25% secondary oxygen of the IDF case shows maximum radiation heat transfer. The soot volume fraction of the flame was measured in the axial direction of the flame and the amount of soot volume fraction is proportion to the radiation heat transfer. As a result, we can get the optimal operating condition of the newly designed burner which enhances the characteristics of flame stabilization and radiation heat transfer.