• Title/Summary/Keyword: 산성우

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제강분진을 반응촉매로 이용한 침출수의 연속산화처리공정

  • 강정우;장윤석;지원현;김성용;배범한;장윤영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.09a
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    • pp.164-167
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    • 2001
  • 본 연구에서는 포항제철소에서 제철부산물로 발생되는 제강분진을 전처리 없이 산화촉매로 사용하여 김포 수도권 매립지의 침출수 처리공정에서 펜톤산화조에 유입되는 원수를 대상으 로 과산화수소를 이용한 연속식 산화처리 실험을 수행하였다. 먼저 회분식 실험결과를 바탕 으로 최적 반응조건에서 lab-scale 연속식 기초반응실험과 자체 설계.제작한 연속산화공정에서의 처리실험을 수행하였다. 또한 기존의 펜톤산화공정에서 Fe 공급원으로 사용되고 있는 FeSO$_4$.7($H_2O$)와의 반응성 비교실험도 수행하였다. 반응기간동안 일정 pH를 유지하기 위해 pH controller를 사용하였으며 침출수 수질은 CODcr로 나타내었다. 반응 pH 3.5, 체류시간 1 hr, 과산화수소 주입량 1,500mg/1에서 제강분진과 FeSO$_4$.7($H_2O$)를 각각 주입하여 수행한 연속처리 기초실험에서는 제강분진을 산화반응촉매로 사용한 경우에 침출수CODcr 처리율 62%, 과산화수소의 분해율 52%를 나타내었다. FeSO$_4$.7($H_2O$)를 산화반응 촉매로 사용한 경우에는 약 65-70%정도의 다소 높은 처리효율을 나타낸 반면에 과산화수소의 소비량은 제강분진의 경우보다 약 20%이상의 높은 값을 나타내었다. 연속산화공정 실험에서는 운전 3시간 이후에 유출수 중의 CODcr과 $H_2O$$_2$의 농도가 안정된 값을 나타내었다. 이 때 산화 반응조의 침출수 CODcr 제거효율은 약 43%이었으며, 처리수의 농도는 현재의 침출수 방류기준 이하로 나타났다. 결론적으로 침출수의 연속식 산화처리 실험결과, 처리효율과 경제성에서 제강분진의 산화촉매활용 공정의 개발 가능성이 매우 높은 것으로 나타났다.ell에 의해 완전분해 되었으며, 함께 존재시 TC는 Fe$^{\circ}$만으로는 분해가 되지 않았지만 cell에 의해 완전분해 되었으며, 함께 존재시 TCE분해에 저해작용을 미치는 것으로 나타났다.술의 첨가가 요구되고 있다. 따라서, 산성광산배수 오염지대에 대해 획일적으로 같은 처리방법을 채택하여 사용하는 것보다 각 지역 또는 광산산성폐수가 유출되어 나오는 광산폐기물의 특성 등을 고려하여 거기에 맞는 기술들을 복합적으로 또는 단독으로 사용하되 처리방법 채택 시 신중을 기할 것이 요망된다.정시에는 SeaWiFS 위성과 관련된 global algorithms 중에서 490nm와 555nm의 복합밴드를 포함하는 OC2 알고리즘(ocean color chlorophyll 2 algorithm)을 사용하는 것이 OC2 series 및 OC4 알고리즘보다 좋은 추정 값을 도출할 수 있을 것으로 기대된다.환경에서는 5일에서 7월에 주로 이 충체의 유충이 발육되고 전파되는 것으로 추측되었다.러 가지 방법들을 적극 적용하여 금후 검토해볼 필요가 있을 것이다.잡은 전혀 삭과가 형성되지 않았다. 이 결과는 종간 교잡종을 자방친으로 하고 그 자방친의 화분친을 사용할 때만 교잡이 이루어지고 있음을 나타내고 있다. 따라서 여교잡을 통한 종간잡종 품종육성 활용방안을 금후 적극 확대 검토해야 할 것이다하였다.함을 보이고 있다.X> , ZnCl$_{3}$$^{-}$같은 이온과 MgCl$^{+}$, MgCl$_{2}$같은 이온종을 형성하기 때문인것 같다. 한편 어떠한 용리액에서던지 NH$_{4}$$^{+}$의 경우 Dv값이 제일 작았다. 바. 본 연구의 목적중의 하나인 인체유해 중금속이온인 Hg(II), Cd(II)등이 NaCl같은 염화물

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A Study on the Change of the Plant Community Structure for Five years in Puk′ansan National Park (북한산 국립공원 삼림군집구조의 5년간 변화 연구)

  • 최송현;이경재
    • Korean Journal of Environment and Ecology
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    • v.7 no.1
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    • pp.35-48
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    • 1993
  • To compare ecological succession stage between 1987 and 1992, this study was executed in Mt. Puk'an. 26 sample plots of 500$m^2$ were set up. The results were summarized as follows; 1. To analysis plant community structure, the classification by TWINSPAN and CCA, DCA and RA ordination were applied to the study area. That of Mt. Puk'an was divided 4 groups by altitude. The dividing groups are Robinia pseudo-acacia-Quercus spp. community, mixed forest community, Q. serrata community, and Q. mongolica community. The successional trends of tree species over 500m seem to be from Pinus densiflora to Q. mongolica and below 500m in altitude seem to be from Robinia pseudo-acacia through Quercus acutissima, Q. mongolica, Prunus sargentii, Sorbus alnifolia to Q. serrata in the canopy layer. In the case of understory and shrub layer, the successional trends to be from Corylus sieboldiana, Zanthoxylum schinifolium through Rhus trichocarpa, Rhododendron mucronulatum, Rh. schlippenbachii to Acer pseudo-sieboldianum. 2. In comparing successional trends with 1987', the advanced data was not obtained in 1992. It was postulated that succession is not progressed by human disturbance and air pollution.

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UV Curing and Peeling Characteristics of Acrylic Coating Ink with Various Amounts of Photoinitiator, Oligomer and Talc (광개시제, 올리고머 그리고 Talc 함량에 따른 아크릴계 코팅제의 UV경화 및 박리특성)

  • Yang, Jee-Woo;Seo, Ah Young;Lee, Chul Woo
    • Applied Chemistry for Engineering
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    • v.24 no.5
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    • pp.499-506
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    • 2013
  • As the usuage of tempered glass for touch panel increased rapidly with the development of industry, the amount of UV curable coating solution used to protect glass surfaces during a tempered glass manufacturing process increased as well. The UV curable coating has advantages compared to thermal curing such as shortened curing time and non-solvent. Appropriated polymer and monomer were used as an acid polymer to grant an alkali peeling ability. The monomers were 2-hydroxyl methylacrylate, 1,6-hexanediol diacrylate and dipentaerythritol hexaacrylate which have acryl groups of 1, 2, and 6, respectively. The combination of three different types of photoinhibitors were used and bisphenol A epoxy diacrylate was used as an oligomer. In this study, experiments were carried out by controlling the amount of photoinitiator, oligomer, and additive while maintaining the constant content of the acid polymer and the acrylic monomer. The changes in physical properties according to the additive content were investigated. It was found that the combination of photoinitiators was necessary to achieve the hardness above 4H and it was possible to control the delamination type of the coating film from a sheet to pieces by the addition of TPO as an initiator. The increase in oligomer contents increased the hardness and adhesiveness alongside dissection time. Talc content of 20 wt% showed the best results.

Experiment of Reactive Media Selection for the Permeable Reactive Barrier Treating Groundwater contaminated by Acid Mine Drainage (산성광산배수로 오염된 지하수 정화용 투수성 반응벽체 반응매질 선정 기초실험)

  • Ji Sang Woo;Cheong Young Wook
    • Economic and Environmental Geology
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    • v.38 no.3 s.172
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    • pp.237-245
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    • 2005
  • The batch tests were performed to evaluate the applicability of the permeable reactive barrier (PRB) to in-situ treatment of groundwater with high concentration of heavy metals. The lead\chates used in this study were collected from waste rock dump of the Imgy mine, and have a low pH and high metal concentration. The acidity loading was 65kg as $CaCO_3/day$, metal loading of Fe+Al+Mn was 11.6kg/day. This type of water could be treated with biological-mediated sulfate reduction using the organic carbon mixture as a reactive media. The batch tests were carried out with five mixtures that were composed with different mixing ratios of mushroom compost, pine-tree bark, and limestone cheep. Results indicated that the PRB could reduce the acidity loading $CaCO_3/day$ to 12.3kg and reduce the metal loading to 3.3kg/day. Considering about the low pH and high metal loading, the contaminated water may be ameliorated by passing it through the buffering PRB composed with inorganic carbonate materials and then through the PRB composed with the organic carbon mixture which can induce sulfate reduction.

Survey on the Rain Components in Kyungbuk Province (경상북도(慶尙北道) 지역(地域)의 강수성분(降水成分) 조사(調査))

  • Suh, Myung-Soon;Kim, Yeung-Seok;Kim, Bok-Jin
    • Korean Journal of Environmental Agriculture
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    • v.10 no.1
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    • pp.59-66
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    • 1991
  • This study was carried out to investigate the chemical characteristics of the rain water in rural, urban and industrial areas which are located in Kyongbuk province, namely. Songju, Kumi, Kimchon, Yongdok and Teagu. The experiments were sampled the rain by amount of rain water from July to August in 1989, and analyzed the pH. EC, $SO_4\;^{2-}$, $NO_3^-$ and $Cl^-$ contents in the rain water. The results are summarized as follows : 1. The acid rain showed at the begining rain water of all surveyed sites, but there were difference by sites, and particulary severe in Kumi. 2. The content of $SO_4\;^{2-}$ in rain water was high in urban and industrial area, such as Teagu, Kumi and Kimchon. 3. According to the increasing rain water amount, the pH in rain water was high, and the contents of other components were low. This phenomenon remarkably presented at higher concentration of components and earlier rain water. 4. The electric conductivity was high significantly positive correlation with contents of $SO_4\;^{2-}$, $NO_3\;^-$ and $Cl^-$ in rain water, and pH was high significantly negative correlation with contents of $SO_4^{2-}$ and $NO_3\;^-$ in rain water, respectively.

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Characteristics of Polysaccharide Extracted from the Cultured Mycelia of Schizophyllum commune (치마버섯 균사체 배양물로부터 분리한 다당류의 이화학적 특성)

  • Lee, June-Woo;Kim, Yong-Seok
    • The Korean Journal of Mycology
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    • v.37 no.1
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    • pp.91-95
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    • 2009
  • To examine physico-chemical properties of the polysaccharide extracted from liquid-cultured mycelia of Schizophyllum commune, each the polysaccharide was extracted with hot water treatment and then fractionated with ethanol, alkaline solution and ultrafiltration. And we determined carbohydrate contents, composition of amino acids, infra-red spectrum and viscosity. Carbohydrate contents of polysaccharide treated with ethanol and ultrafiltration were 72.0% and 62.3%, and proteins content were 15.3% and 32.0% respectively. The carbohydrate consisted of four monosaccharides and the protein contained 16 amino acids. The polysaccharide obtained from ultrafiltration was shown an absorption band characteristic of the ${\beta}$-glycosidic linkage by infra red spectra. These results suggest that the polysaccharide extracted from Schizophyllum commune showed the characteristics of proteinbounded polysaccharide, and it was ${\beta}$-glycosidic linkage with strong viscosity.

Effects of Simulated Acid Rain on the Growth, Nutrient Status of Korean Pine (Pinus koraiensis) Seedlings and Soil Acidification (인공산성우(人工酸性雨)가 잣나무 묘목(苗木)의 생장(生長), 영양상태(營養狀態) 및 토양산성화(土壤酸性化)에 미치는 영향(影響))

  • Jin, Hyun-O;Kim, Eun-Young;Lee, Choong Hwa
    • Journal of Korean Society of Forest Science
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    • v.89 no.3
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    • pp.422-430
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    • 2000
  • Three-year-old Pinus koraiensis seedlings, transplanted in brown forest soils originating from granite were treated with simulated acid rain of pH concentrations 5.6(control), 4.0, 3.0, 2.5 and 2.0 for 210 days from April 21 to November 17, 1999. Visible injury of the seedlings were observed at the pH 2.0 and pH 2.5 treatments. The total dry weight of the seedlings decreased at pH 2.0 treatment compared with that of the control, and T/R ratio increased at pH 2.0 treatment compared with others. The elements in each part of the seedlings, concentrations of Ca, P and content of chlorophyll in needles increased at the pH 2.0 treatment compared with the control. The concentration of N in the needles of the seedlings increased as the soil pH decreased. As the treated pH was lowered, soil pH has decreased, and concentrations of Ca, Mg, Al, and Mn increased, especially at pH 4.4. In addition, there was a strong correlation(r=0.90, p<0.05 ; r=-0.94, p<0.01) between the dry weight of the seedlings and the pH and Al concentration of the soils. Therefore, the pH and Al concentration in the soil may be useful indicator for assessing the effect of acid rain on the growth of woody plants.

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Creating Cultural Heritage though 'Silkroadpia' - Reconstructing the Routes of the Baekje Restoration Movement ('실크로드피아(Silkroadpia)'의 활용과 문화유산의 창출 - 백제부흥운동의 경로복원을 중심으로)

  • Cho, Daeyoun
    • The Journal of the Convergence on Culture Technology
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    • v.6 no.1
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    • pp.343-350
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    • 2020
  • In this paper, we present the results of research on the reconstruction of ancient routes of ancient civilization exchange that were once present in the North Jeolla region, which was undertaken by adopting a convergent approach to develop 'Silkroadpia', which is an online platform for the curation and sharing of archaeological and historical spatial data, and 'MEPTA(Multiple Evidence Based Path and Territory Finding Algorithm)'. The results of the research make it possible to reconsider the region's historical identity and its important role in facilitating cultural exchange on the Korean Peninsula and in East Asia. The results can also be used to provide the theoretical basis for the government's land planning policies and for the production of cultural contents that can be used for local regeneration. The ancient route associated with the Baekje Restoration Movement, that took place after the fall of Sabi in 660 CE, was the case study examined in this paper, which discusses the academic value of reconstructing the ancient route, as well as its future use in providing cultural contents.

Growth of Pinus densiflora Seedlings in Artificially Acidified Soils (인위적인 토양 산성화가 소나무 묘목의 생장에 미치는 영향)

  • Lee, Choong-Hwa;Lee, Seung-Woo;Kim, Eun-Young;Kim, Young-Kul;Byun, Jae-Kyoung;Won, Heong-Gyu;Jin, Hyun-O
    • The Korean Journal of Ecology
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    • v.28 no.6
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    • pp.389-393
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    • 2005
  • This study was carried out to investigate the effects of soil acidification on the growth of 3-year-old Pinus densiflora seedlings grown for 21 weeks in brown forest soils acidified with $H_2SO_4$ solution. The concentrations of Al in the acidified soils were increased with increasing amount of $H^+$ added to the soil. The total dry weight of the seedlings was reduced by the addition of the $H_2SO_4$ solution. In addition, there was a strong positive correlation (r=0.97, p<0.01) between the dry weight of the seedlings and the molar (Ca+Mg+K)/Al ratio of the soil. The seedlings with the molar (Ca+Mg+K)/Al ratio of 1.0 resulted from approximately 50% growth reduction compared with the control value. The results suggest that the molar (Ca+Mg+K)/Al ratio of the soil may be a useful indicator for assessing the critical load of acid deposition.

Evaluation of the Milk Productivity and Nutrient Balance of Forage Sources for Organic Dairy Farms in Korea (유기 조사료 급여 농가의 영양소 균형 및 유생산성 평가)

  • Na, Y.J.;Shin, K.M.;Rim, J.S.;Bang, J.W.;Lee, S.R.
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.36 no.2
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    • pp.98-103
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    • 2016
  • This study was conducted to evaluate the milk productivity and nutrient balance in organic dairy farms located at Gochang-gun of Korea with different feed sources. The total number of organic dairy farms was 12 in 2012, 13 in 2013, and 14 in 2014. The numbers of farms and dairy herds were increased each year. The average milk yields in 2012, 2013, and 2014 were 25.5, 24.6, and 24.4 kg/d, respectively. The average milk fat contents in 2012, 2013, and 2014 were 3.5%, 3.6%, and 3.7%, respectively. The average milk protein contents in 2012, 2013, and 2014 were 3.3%, 3.4%, and 3.4% in 2012, 2013, and 2014, respectively. Although the average milk yield of organic dairy farms was 9 kg/cows/d less than the average milk yield of other dairy farms in Korea, milk fat and protein contents of organic dairy farms were higher than those of other dairy farms. Alfalfa hay, oat hay, corn silage, rye grass silage, Sudan grass silage, rice straw, and barley silage were commonly used as forage sources in organic dairy farms. The average silage intake (15.6 kg/cow/d) of organic dairy farms in 2013 was higher (P < 0.05), while the average hay intake (5.1 kg/cow/d) in 2014 was higher (P < 0.05) than that of other feed intake. Net energy for lactation ($NE_L$) and metabolizable protein (MP) were calculated in accordance with NRC (2001). Net energy for lactation intake was higher (P < 0.05) while MP intake was lower (P < 0.05) than NRC recommendation values in 2013 and 2014. These results indicate that domestic organic dairy farms should use feed considering energy and protein balance recommended by NRC.