• Proceedings of the Korea Water Resources Association Conference
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• 1998.05a
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• pp.395-403
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• 1998

오염원의 이송확산에 관한 많은 연구들이 수행되어 왔으나 특히 비포화 영역에서 오염원 이송확산을 측정하는 것은 매우 어려운 것으로 알려지고 있다. 비포화 토양에서의 오염원 이송확산은 매질의 함수량 변화에 영향을 받기 때문에 오염원 거동특성을 이해하려면 비포화 흐름 분석을 선행한 후 오염원의 이송확산 특성을 분석하여야 한다. 본 연구에서는 비포화 영역에서의 오염원 이송특성을 분석하기 위하여 TDR(Time Domain Reflectometry)을 이용하여 비포화 흐름 및 오염원 이송을 측정하였다. 이를 위하여 본 연구에서는 TDR을 이용하여 오염원 이송을 측정하는 방법을 개발하였으며, 이 방법을 이용하여 1차원의 토양기둥시료에서 비포화 흐름 및 오염원 이송확산에 관한 실험을 수행하고 수치모형을 적용함으로써 비포화 영역에서 오염원의 이송확산에 관한 거동특성을 규명하였다. 본 연구에서는 두 종류의 국내 토양시료(SUS, KUS)를 사용하였는데, 토양의 물리적 특성을 예비실험을 통하여 규명한 후 토양기둥시료를 이용한 본실험을 수행하였다. 비포화 천이흐름하의 오염원 이송확산 실험에서는 급격한 습윤전선의 전진에 따른 종형의 함수량변화를 관측할 수 있었고, 이때 오염원의 농도는 함수량의 천이구간의 중심점으로부터 전방영역의 농도분포가 습윤전선에서의 함수량 분포와 유사한 종형을 이루고 있음을 관측할 수 있었다. 비포화 정상흐름하의 오염원 이송확산 실험에서는 오염원이 이송하며 농도 천이구간이 확장되어지는 전형적인 형태를 보였다. 또한 예비실험에서 측정한 매개변수를 입력자료로하여 수행한 수치결과와 실험결과를 비교하였는데 비포화 흐름특성은 실험결과와 수치결과가 정량적으로 일치하는 경향을 보였으나, 오염원 이송확산 특성은 정량적으로 수치결과가 실험결과보다 더 많이 확산되는 경향을 보였다. 따라서 수치모형을 현장에 적용할 경우 확산지수 결정에 주의하여야 할 것으로 판단된다. 즉, 수치모형에 적용할 확산지수는 BTC 실험을 통하여 측정한 확산지수, 수치확산, 흡착계수, 적용영역의 크기 등을 고려하여 결정하여야 한다. 특히 본 논문에서는 TDR을 이용하여 최초로 천이상태의 함수량과 오염원 농도를 측정하였는데 이를 위하여 전기전도도와 함수량관계를 추정하는 식을 제안하였으며, 전기전도도와 토양수 농도, 전기전도도와 함수량의 관계를 이용한 천이상태의 오염원 농도 측정방법을 개발하였다. 특히 제안식에서는 한계함수량의 개념을 도입하여 전기전도도와 함수량관계를 추정하므로 추정식의 실험값 반영 정도를 증가시켰다. 본 연구에서 제안된 식을 이용하여 추정된 전기전도도와 함수량관계는 다른 제안식에 비하여 개선된 결과를 보여 주었고, 본 연구에서 개발한 오염원 농도 측정법을 이용하여 측정한 결과 함수량이 0.15이하에서는 측정오차가 크지만 함수량이 0.15이상일 경우 매우 좋은 결과를 보였는데 질량평형을 검토한 결과 약 5-10%의 오차율을 보였다. 따라서 본 논문에서 개발된 천이상태의 오염원 농도측정법은 용존 오염물질의 이송에 관한 정확한 실험을 제공할 것으로 판단된다.

• Journal of Korea Water Resources Association
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• v.32 no.6
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• pp.751-762
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• 1999

In this study, a 1-D laboratory experiment was conducted to investigate the characteristics of transient unsaturated solute transport by using two kinds of soils of which properties were known by test. Especially the TDR method which is proposed in this study was used to measure water content and solute concentration. As results, in the transient flow, the wetting front moves down rapidly, and the distribution of solute concentration near the wetting front showed the similar type of the water content distribution(semi-bell type). A numerical model HYDRUS was used to compare with the experimental results. Numerical results for the water movement are similar to experimental result. However, numerical results of the distribution of solute concentration are more scattered than experimental results. It means that measured dispersivity, numerical dispersion, adsorption coefficient, and soil sample size etc. should be considered in order to determine the dispersivity used in the numerical model. The present measuring method was proved to be superior to other formula and to be an available method to apply to solute transport test. The measuring error of the developed method is estimated smaller than 10% while water content is larger than 0.15.

• Journal of Soil and Groundwater Environment
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• v.9 no.3
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• pp.20-26
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• 2004

In-situ photolysis is one of the most promising ways to clean up a soil contaminated with 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD). This study focuses on the mathematical description and model development of the convective upward transport of an organic solvent driven by evaporation and photodecomposition at the surface as the major transport mechanism in the clean up process. A finite-element-based numerical model was proposed to incorporate effects of multiphase flow on the distribution of each fluid, gravity as a driving force, and the use of van Genutchen equation for more accurate description of k-S-p relations. This paper presents results of extensive numerical calculations conducted to investigate the various parameters that play a role in the solvent migration through a laboratory-scale unsaturated soil column. The numerical results indicate that gravity affects significantly on the fluids distribution and evaporation for highly permeable soils. The soil texture has a profound influence on the fluid saturation profile during evaporation process. The amount of solvent convective motion increases with increasing evaporation rates and decreasing initial water saturation. Simulations conducted in this study have shown that the developed model is very useful in analyzing the effects of various parameters on the convective migration of an organic solvent in the soil environments.

• Proceedings of the Korea Water Resources Association Conference
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• 1997.05a
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• pp.475-479
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• 1997

다공질매체에서의 포화-비포화 흐름 거동을 파악하기 위하여는 시간에 따른 함수량의 변화과정을 정확하고 빠르게 측정하여야 한다. 본 연구는 실험실에서 함수량을 측정하는 방법의 하나로서 TDR(Time Domain Reflectometer)을 사용하는 실험 방법에 관한 연구이다. TDR 이란 전기신호의 전도특성 이용하여 토양내 설치된 탐침(probe)의 전기신호 반향시간을 측정하는 기기로서 이 반향시간과 토양의 유전율상수(dielectric constant)의 관계를 이용하여 함수량을 추정할 수 있다. 본 연구에서는 TDR의 원리설명과 이를 이용한 함수량측정방법을 제시하고 있다.

• Journal of Korea Water Resources Association
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• v.31 no.2
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• pp.123-132
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• 1998

Monitoring solute transport has been known to be difficult especially for the unsaturated soil. The object of this study is to investigate the TDR application to monitoring solute concentration in the vadose zone. The TDR calibration test was conducted for soil samples with various water contents and concentrations. The voltage attenuation of electromagnetic wave of TDR was used to estimate the bulk electrical conductivity of a soil. The relationship between the bulk soil electrical conductivity and the solute concentration was assumed to be linear at a constant volumetric soil water content. In this study four proposed relationships were compared using data obtained from KCI solution at three different concentrations. Relationships given by Topp, Daltaon, Yanuka showed the linearity between the bulk soil electrical conductivity and the solute concentration, which were more pronounced than Zegelin's. The three relationships were found to be useful to measure the solute concentration in the vadose zone. In addition, TDR method was proven to be a viable technique in monitoring solute transport through unsaturated soils in transient flow condition.

• Water for future
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• v.24 no.1
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• pp.109-117
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• 1991

The governing equation of flow in porous media is developed on the bases of the continuity equation of fluid for transient flow through a saturated-unsaturated zone, and substitution of Darcy's law. The numerical solutions are obtained by finite element method based on the Galerkin principles weighted residuals. The analysis are carried out by using the unsteady storm data observed and rainfall intensities which are obtained by using the rainfall excess model in considering of the initial losses. The functional relationships between the hydraulic conductivity, capillary pressure head and volumetric water content are applied to the flow of water through unsaturated soil varied with changes of water content.

• Journal of Korea Soil Environment Society
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• v.1 no.2
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• pp.91-101
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• 1996

In recent years, phytoremediation, the use of plants to detoxify hydrocarbons, has been a promising new area of research, particularly in situ cleanup of large volumes of slightly contaminated soils. There is increasing need for a mathematical model that can be used as a predictive tool prior to actual field implementation of such a relatively new technique. Although a number of models exist for solute-plant interaction in the vegetated zone of soil, most of them have focused on ionic nutrients and some metals. In this study, we developed a mathematical model for simulation of bioremediation of hydrocarbons in soil, associated with plant root systems. The proposed model includes root interactions with soil-water and hydrocarbons in time and space, as well as advective and dispersive transport in unsaturated soil. The developed model considers gas phase diffusion and liquid-gas mass exchanges. For simulation of temporal and spatial changes in root behavior on soil-water and with hydrocarbons, time-specific distribution of root quantity through soil was incorporated into the simulation model. Hydrocarbon absorption and subsequent uptake into roots with water were simulated with empirical equations. In addition, microbial activity in the rhizosphere, a zone of unique interaction between roots and soil microorganisms, was modeled using a biofilm theory. This mathematical model for understanding and predicting fate and transport of compound in plant-aided remediation will assist effective application of plant-aided remediation to field contamination.

• Journal of Korea Water Resources Association
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• v.32 no.6
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• pp.741-749
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• 1999

This study is to develop a method of measuring the soil water concentration by using TDR, which is based on the relationships between the bulk soil electrical conductivity of soil and the reflected wave of TDR. The proposed monitoring method is combined with two important relationships. One is that between the bulk soil electrical conductivity and the solute concentration, which is known to be linear at a constant volumetric soil water content and the other is that between the relative bulk soil electrical conductivity and the water content at a constant concentration. Some formulas have been proposed to solve the second relationship, but a new formula and the critical water content are proposed to improve the accuracy of measurement. This proposed formula estimates the relative bulk soil electrical conductivity for water contents which is divided to two regions, linear and nonlinear, by the critical water content. As the result of the comparison with other formulas, the proposed formula is proved to be superior to other formulas and to be an available method to apply to the unsaturated transient solute transport.

• Water for future
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• v.28 no.4
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• pp.215-222
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• 1995

The water retention function which has the hysteresis phenomena is required to analyze the Richards equation which is a governing equation of the unsaturated flow, and its hysteresis phenomena has influence upon the characteristics of the unsaturated flow. The accuracy of the published hysteresis models is compared by using experimental data of the water retention function. The apparatus to experiment the hysteresis phenomena on the soil is developed, and experimental data for the main wetting process and the main drying process of the water retention function are obtained. The parameters of the van Genuchten equation are calibrated by using experimentally obtained data. As a result of the comparison of the selected hysteresis models which simulate the main drying curve from the main wetting curve, the Model I-1(Mualem) overestimates and the Model II-1(Mualem) underestimates but the Model III-2(Park and Sonu) similarly estimates the experimental data of the main drying curve.

• Journal of Korea Water Resources Association
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• v.30 no.6
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• pp.587-595
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• 1997

Experimental study on unsaturated flow in the soil is important to understand the characteristics of the water flow. Measurement of unsteady-state water movement using the traditional equipment (e.g. tensiometer) has a problem that requires relatively a long response time. In this study a quick measurement method of soil water flow using TDR is introduced. TDR consists of an electronic function generator which generates a squared wave, and an oscilloscope which catches the reflected wave. The wave is reflected where both the impedance of the transmission line and the propagation velocity are changed. The water content can be obtained from the travel time measured by means of TDR because the dielectric constant is affected by the change of soil water content. From the result of TDR calibration. TDR measurement error for the oven dried soil was found to be less than 3.5%. This supports that TDR is a viable technique to measure the unsteady-state water movement.