• Resources Recycling
• /
• v.18 no.5
• /
• pp.52-62
• /
• 2009

This research was carried out to formulate environmentally friendly wood preservatives with okara and to investigate the effects of the acid concentration used for the hydrolysis of okara and salt type on the decay resistance of the preservatives. Okara-based preservatives were formulated with okara hydrolyzates, which were prepared with 0, 1%, and 2% sulfuric acid at $25^{\circ}C$ for 1 hr, and salts such as copper chloride and/or sodium borate. The preservatives were treated into wood blocks by vacuum-pressure method, and then the treated wood blocks were leached in $70^{\circ}C$ hot water for 72 hrs. The fungal treatments of the leached wood blocks were conducted by brown-rot fungus, Tyromyces palustris, and white-rot fungus, Trametes versicolor, to examine the decay resistance of the preservatives. As the acid concentration used for hydrolysis of okara increased, the treat-ability and decay resistance of the preservatives were improved, which the leachability was decreased. Wood blocks treated with the okara/copper or okara/copper/borax, showed very good decay resistance against T. palustris and T. versicolor. However, wood blocks treated with the okara/borax and okara-free preservative solutions, were observed the fungal decay by T. palustris. The optimal conditions for the preparation of okara-based wood preservatives were formulated with okara hydrolyzed with 1% sulfuric acid, copper chloride and borax.

• Korean Chemical Engineering Research
• /
• v.54 no.5
• /
• pp.587-592
• /
• 2016

Sodium borohydride, $NaBH_4$, shows a number of advantages as hydrogen source for portable proton exchange membrane fuel cells (PEMFCs). Properties of $NaBH_4$ hydrolysis reaction using unsupported Co-P-B Co-B, catalyst at high concentration $NaBH_4$ solution were studied. In order to enhance the hydrogen generation yield at high concentration of $NaBH_4$, the effect of catalyst type, $NaBH_4$ concentration and recovery of condensing water on the hydrogen yield were measured. The yield of hydrogen evolution increased as the boron ratio increased in preparation process of Co-P-B catalyst. The hydrogen yield decreased as the concentration increased from 20 wt% to 25 wt% in $NaBH_4$ solution during hydrolysis reaction using 1:5 Co-P-B catalyst. Maximum hydrogen yield of 96.4% obtained by recovery of condensing water and thinning of catalyst pack thickness in reactor using Co-P-B with Co-B catalyst and 25 wt% $NaBH_4$ solution.

• 한국신재생에너지학회:학술대회논문집
• /
• 2010.11a
• /
• pp.53.1-53.1
• /
• 2010

결정질 실리콘 태양전지의 효율을 향상시키기 위하여 수광면에 서로 다른 도핑농도를 가지는 고농도 도핑영역과 저농도 도핑영역으로 이루어진 emitter를 형성하는 것이 요구되며 이를 selective emitter라 칭한다. Selective emitter를 형성하면 고농도 도핑영역에서 금속전극과 저항 접촉이 잘 형성되기 때문에 직렬 저항이 최소화되고 저농도 도핑영역에서는 전하 재결합의 감소로 인하여 태양전지의 변환효율이 상승하는 이점이 있다. Selective emitter의 형성방법은 이미 다양한 방법이 제안되고 있으나, 본 연구에서는 기존에 제시된 방법과는 다르게 열산화 시 dopant redistribution에 의한 Boron depletion 현상을 이용하여 selective emitter를 형성하는 방법을 제안하였고, 이를 Simulation을 통하여 검증하였다. 초기 emitter 확산 후 junction depth는 0.478um, 면저항은 $104.2{\Omega}/sq.$ 이었으며, nitride masking layer 두께는 0.3um로 설정하였다. $1100^{\circ}C$에서 30분간 습식산화 공정을 거친 후 nitride mask가 있는 부분의 junction depth는 1.48um, 면저항은 $89.1{\Omega}/sq$의 값을 보였고, 산화막이 형성된 부분의 junction depth는 1.16um, 면저항은 $261.8{\Omega}/sq$의 값을 보였다. 위 조건의 구조를 가진 태양전지의 변환 효율은 19.28%의 값을 나타내었고 Voc, Jsc 및 fill factor는 각각 645.08mV, $36.26mA/cm^2$, 82.42%의 값을 보였다. 한편 일반적인 구조로 설정한 태양전지의 변환 효율, Voc, Isc 및 fill factor는 각각 18.73%, 644.86mV, $36.26mA/cm^2$, 80.09%의 값을 보였다.

• Journal of the Korean Institute of Telematics and Electronics D
• /
• v.36D no.4
• /
• pp.48-56
• /
• 1999

In this paper, we have investigated experimentally the effects of initial oxygen concentration on oxygen pileup phenomenon and the diffusion of implanted impurities. 1.2 MeV $^{11}B^{+}$ and 2.2 MeV $^{31}P^{+}$ ions were implanted into p-type (100) Si wafers with a dose of 1${\times}10^{15}$ / $\textrm{cm}^2$. Secondary ion mass spectrometry(SIMS) measurements were carried out to obtain depth distribution profiles for implanted impurities and oxygen atoms after two-step annealing of $700^{\circ}C$(20 hours)+$1000^{\circ}C$(10 hours). Residual secondary defect distribution and annealing behabiour were also studied by cross-sectional transmission electron microscopy(TEM) observations. Oxygen pileup nearly $R_p$(projected range) were observed by SIMS measurements and considerable amount of residual secondary defect layer were observed by TEM observations. It can be seen that oxygen atoms are trapped at the secondary defects by the experimental results. Enhanced diffusions of boron and phosphorus to the bulk direction were observed with the increasing of initial oxygen concentration.

• Journal of the Korean Vacuum Society
• /
• v.10 no.1
• /
• pp.104-111
• /
• 2001

B-doped hydrogenated amorphous silicon carbide (a-SiC:H) thin films were prepared by plasma-enhanced chemical-vapor deposition in a gas mixture of $SiH_4, CH_4,\;and\; B_2H_6$. Physical and chemical properties of a-SiC:H films grown with varing the ratio of $B_2H_6/(SiH_4+CH_4)$ were characterized with various analysis methods including scanning electron microscopy (SEM), X-ray diffractometry (XRD), Raman spectroscopy, Fourier-transform infrared (FTIR) spectroscopy, secondary ion mass spectroscopy (SIMS), UV absorption CH_4spectroscopy and electrical conductivity measurements. With the B-doping concentration, the doping efficiency and the micro-crystallinity were decreased and the film became amorphous when $B_2H_6/(SiH_4{plus}CH_4)$ was over $5{\times}10^{-3}$. The addition of $B_2H_6$ gas during deposition decreased the H content in the film by lowering the quantity of Si-C-H bonds. Consequently, the optical band gap and the activation energy of a-SiC:H films were decreased with increasing the B-doping level.

• Tribology and Lubricants
• /
• v.35 no.6
• /
• pp.343-349
• /
• 2019

According to a report in 2011, hexagonal boron nitride demonstrated good solubility in pure water, even without surfactants or organic functionalization. Hexagonal boron nitride nanosheets are an effective lubricant additive, and their solubility in pure water has motivated lubrication engineers to utilize aqueous solutions containing these nanosheets as water-based lubricants. In this study, we measure the width and height of the hexagonal boron nitride nanosheets dispersed in pure water by using the Zetasizer and atomic force microscopy. Without surfactants or functionalization, aqueous solutions containing 0.10, 0.07, 0.05, and 0.01 wt% of hexagonal boron nitride nanosheets are synthesized via sonication-assisted hydrolysis. The Zetasizer provides only a one-dimensional size of approximately 410 nm, regardless of the concentration of the solution. Thus, it does not allow the estimation of the shape of the nanosheet. To acquire the three-dimensional size of the nanosheets, atomic force microscopy is employed. The aqueous solutions containing 0.10, 0.07, 0.05, and 0.01 wt% of the hexagonal boron nitride nanosheets show average values of 740, 450, 700, and 610 nm in width, and 37, 26, 33, and 32 nm in thickness, respectively. No significant trend is observed between the concentration of the solution and size of the nanosheets. Therefore, when preparing a water-based lubricant, it may be appropriate to adjust conditions such as ultrasonication time rather than the concentration.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.39 no.7
• /
• pp.627-633
• /
• 2011

Performance of a hydrogen generator for a fuel cell unmanned aircraft was evaluated as the change of temperature environment. Sodium borohydride ($NaBH_4$) was used as a hydrogen source due to its high hydrogen content and good storability. The hydrogen gas was generated by the hydrolysis reaction using a catalytic reactor. Reaction chambers were set up with the range of temperatures from -20 to $60^{\circ}C$. The hydrogen generation rate and temperatures changes of reactor and separator were measured at the $NaBH_4$ concentrations of 20 and 25wt.%. As a result, the hydrogen generation rate was decreased as the repeated reaction cycles. It showed that the hydrogen generation rate was stable at low temperature, while at high temperature the hydrogen generation rate was rapidly decreased. The performance degradation was mainly caused by the catalyst loss and $NaBO_2$ deposition on the catalyst surface.

• Journal of the Korean Electrochemical Society
• /
• v.3 no.4
• /
• pp.200-203
• /
• 2000

Boron doped conducting diamond thin films were grown on Si substrate by microwave plasma chemical vapor deposition from a gaseous feed of hydrogen, acetone/methanol and solid boron. The doping level of boron was ca. $10^2ppm\;(B/C)$. The Si substrate was tilted ca. $10^{\circ}$ to make Si substrate, which have different height and temperature. Experimental results showed that different crystalline of diamond thin films were made by different temperature of Si substrate. There appeared $3\~4$ steps of different crystalline morphology of diamond. To characterize the boron-doped diamond thin film, Raman spectroscopy was used for identification of crystallinity. To survey surface morphology, microscope was used. Grain size was changed gradually by different temperature due to different height. The Raman spectrum of film exhibited a sharp peak at $1334cm^{-1}$, which is characteristic of crystalline diamond. The lower position of diamond film position, the more non-diamond component peak appeared near $1550 cm^{-1}$.

• Nuclear Engineering and Technology
• /
• v.26 no.1
• /
• pp.149-159
• /
• 1994

노심설계의 검증을 통하여 설계의 신뢰성을 확인하며 이는 발전소 운전의 안전성과 경제성을 향상시킬 수 있는 발판이 된다. 본 보고서는 국산핵연료를 장전한 고리 3호기 7주기의 운전자료 중에서 핵설계와 관련한 인자의 측정치를 설계치와 비교 분석하고 평가하였다. 비교대상이 된 핵특성인자는 반응도 관련 자료인 임계붕소농도, 제어봉가, 등온온도계수 및 감속재온도계수등이고 출력분포 관련자료인 핵반응률 분포, 집합체 출력분포, 반경방향 첨두출력 F$\Delta$H/$^{N}$ , 축방향 출력분포, 축방향 첨두출력 Fq(z)및 노심 평균 축방향 출력편차(AO)등이다. 이들 인자들에 대한 설계치는 측정치와 잘 일치하였으며, 모두 안전성 관련 제한치이내로 만족함을 확인하였다. 또한 이러한 비교 분석을 통하여 후속주기의 핵설계에 운전자료를 반영할 수 있는 근거를 마련하였다.

• THE HEALTH and ORGANIC FARMING
• /
• no.221
• /
• pp.1-12
• /
• 2005

제27회 한국유기농업대회 성황리 개최/농림부장관 격려사/우리의 산야초/겨울철 토양의 영양관리는 이동성이 어려운 칼슘과 고토 그리고 붕소를/제27회 한국유기농업대회 이모저모/'자원순환형농업 활성화 방안'/"우수 농축산물 합리적 생산이력 관리 방안"세미나/"농업,환경 문제와 연계 필요"/"충북,근교농업 준비 갖춰야"/전남,친환경농업기금 500억조성/농어업특위,'도시민을 농어촌으로'/태안군,웰빙 6쪽마늘 생산단지 조성/우리조상들이 연구한 물이야기/착각하고 있는 잘못된 웰빙/토양다발성 병해 예방/바이러스병 어떻게 전파되며, 어떻게 막아낼것인가?/시설채소의 병해방제/협회저농약9호/"금수강산"가격인상 안내/우수농산물코너/본 협회 인증위원회 개최/12월중 협회 일정 안내/배추 무사마귀병은 무와 윤작으로/미.영,급식등 '어린이영양'법제화/11월중 새식구 명단/협회소식/약이되는 웃음,약이 되는 웃음 운동/다층식 지렁이 사육시스템 개발/친환경 먹거리 대체의학센터 충주에 건립/미국?, 화학원료 넣어도 유기농산물?/멕시코도 유기농 제품 바람/과일껍질 이용한 아이디어 살림법/서식환경의 파괴