• Title/Summary/Keyword: 불활성 기체

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Modification of Hydrogen Determinator for Total Hydrogen Analysis in Irradiated Zircaloy Cladding Tube (수소분석기 개조 및 조사후 지르칼로이 피복관의 총수소분석)

  • Park, Soon-Dal;Choi, Kwang-Soon;Kim, Jong-Goo;Joe, Kih-Soo;Kim, Won-Ho
    • Analytical Science and Technology
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    • v.12 no.6
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    • pp.490-497
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    • 1999
  • A hydrogen determinator was modified and installed in the glove box to analyse total hydrogen content in irradiated zircaloy tube. The analysis method of hydrogen is Inert Gas Fusion(IGF)-Thermal Conductivity Detection(TCD). The hydrogen recoveries of no tin method using Ti and Zr matrix standards, respectively, were available within $3{\mu}g$ of hydrogen. Also the smaller size of sample showed the better hydrogen recovery. It was found that the hydrogen standard of Ti matrix is avaliable to hydrogen analysis in zircaloy sample. The mean radioactivity of irradiated zircaloy sample was 10 mR/hr and hydrogen concentration was 130 ppm.

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Measurement of Rn-222 Gas Concentration of Newly Constructed Apartment House in Gwangju Gwangsan-Gu (광주광역시 광산구 소재 신축 아파트 라돈가스 농도 계측)

  • Jang, Hee jun;Lee, Sang bock
    • Journal of the Korean Society of Radiology
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    • v.9 no.4
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    • pp.257-261
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    • 2015
  • Radon is produced after the Uranium-238 and thorium-232 undergone radioactive decay process is a colorless, odorless inert gas is stored in a basement or an enclosed space. Building materials are made by a rock or soil materials. Form of radon gas is introduced into the lungs through the respiratory tract and deposited in the lungs or bronchial Daughter nuclides radon causes lung cancer. In this study, To subject the Constructed Apartment in Gwangju Gwangsan-Gu, the position is closed window and opened window was measured using a measuring instrument for radon. The measured results indicate that the measurement was carried out in concentrations of radon gas measured at Newly Constructed Apartment is low than United states in the radon concentration in air public 4 pCi called radon gas baseline maximum allowable concentrations. The exposure caused by radon concentration of new construction apartment when on the measurement results is expected to be insignificant. However, when radon gas like this is that it accumulates in the body and lungs get damaged due to exposure, such as lung cancer often open the windows to reduce the radon concentration measurements, such as in radiation protection aspects to the ventilation to reduce exposure it is considered necessary.

QA/QC for 222Rn analysis in groundwater (지하수 중 222Rn 분석을 위한 정도관리)

  • Jeong, Do Hwan;Kim, Moon Su;Kim, Hyun Koo;Kim, Hye Jin;Park, Sun Hwa;Han, Jin Seok;Ju, Byoung Kyu;Jeon, Sang Ho;Kim, Tae Seung
    • Analytical Science and Technology
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    • v.26 no.1
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    • pp.86-90
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    • 2013
  • $^{222}Rn$ concentrations in the groundwater samples without standard material due to the short half-life (3.82 day) were measured through the establishment of the counting efficiency of LSC (Liquid Scintillation Counter) using a standard source of $^{226}Ra$. This study for Quality Assurance/Quality Control (QA/QC) of $^{222}Rn$ analysis was performed to analyze blank samples, duplicate samples, samples of groundwater sampling before and after. In-situ blank samples collected were in the range of 0.44~6.28 pCi/L and laboratory samples were in the range of 1.66~4.95 pCi/L. Their correlation coefficient was 0.9691 and the source contamination from sampling, migration and keeping of samples were not identified. The correlation coefficient between original and duplicate samples from 65 areas was 0.9987. Because radon is an inert gas, in case of groundwater sampling, it is considered to affect the radon concentration. We analyzed samples separately by groundwater sampling before and after using distilled water, but there is no significant difference for $^{222}Rn$ concentrations in distilled waters of two types.

Fabrication of Ionization Chamber to Measure the Burnup of Spent Fuel (사용후핵연료 연소도 측정을 위한 이온 챔버 제작)

  • Park, Se-Hwan;Eom, Sung-Ho;Shin, Hee-Sung;Lim, Hye-In;Ha, Jang-Ho;Kim, Han-Soo
    • Journal of Radiation Protection and Research
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    • v.35 no.1
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    • pp.21-25
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    • 2010
  • Burnup of spent fuel should be determined accurately for the safety control of spent fuel. Especially, it is necessary to measure the burnup profile along the nuclear fuel axis. In the present work, an ionization chamber was designed and fabricated to measure the gamma ray profile inside the guide tube of spent fuel. The ionization chamber was composed of three parts; induction part, gas-inlet part, and sensor part. The sensor part had two electrodes; cathode and anode. A guide electrode was considered in the ionization chamber design to make the ionization chamber to be inserted easily into the guide tube. Pure gas (argon and xenon) was inserted into the ionization chamber, and the leakage current and saturation curve were measured to determine the operation characteristics of the ionization chamber. The gamma ray radiation was also measured in relatively high dose environment. The gamma ray profile of the spent fuel will be measured with the ionization chamber.

Measurement of Oblique ion-induced by electric fields secondary electron emission coefficient($\gamma$) and work function ${\Phi}w$ of the MgO protective layer in plane structure AC-PDPs (면방전 구조의 AC-PDP에서 전기장에 의해 기울어진 이온빔에 의한 MgO 보호막의 이차전자방출계수 ($\gamma$)와 일함수 (${\Phi}w$) 측정)

  • Lee, H.J.;Son, C.G.;Yoo, N.L.;Han, Y.G.;Jung, S.H.;Lee, S.B.;Lim, J.E.;Lee, J.H.;Song, K.B.;Oh, P.Y.;Jung, J.M.;Ko, B.D.;Moon, M.W.;Park, W.B.;Choi, E.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05a
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    • pp.135-138
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    • 2005
  • 현재 널리 상용되어 있는PDP는 3전극 변방전형이다. 3전극 면장전형 PDP는 주방전이 유전체 아래에 서로 평행하게 위치하고 있는 ITO투명전극 사이에서 발생한다. 따라서 방전시의 전기장은 MgO 보호막 위에서 아치형태로 형성되게 된다. 플라스마 방전 시 전자에 의해 이온화된 이온 입자들은 전기장에 의해 그 방전경로가 정해지게 된다. 물론 전기장은 표면에서 수직이지만 전기장에 의해 가속되어진 이온입자들은 MgO 보호막에 기울어져서 입사하게 된다. 따라서 플라스마 방전시의 이온들의 MgO 보호막으로의 입사각은 매우 다양하다. $\gamma$-FIB (Focused ion beam) 시스템은 이온입사에 의한 물질의 이차전자방출계수 측정에 효과적인 장비이다. 본 실험은 이러한 $\gamma$-FIB 시스템을 이용하여 다양한 각도로 입사하는 이온빔에 의한 MgO 보호막의 이차전자방출계수를 측정하였다. 또한 이온화 에너지가 다른 여러 종류의 불활성 기체를 사용하여 이온의 입사하는 각도에 따른 MgO 보호막의 일함수를 측정하였다. 이온빔의 입사각은 각각 $0^{\circ}$, $10^{\circ}$, $20^{\circ}$, $30^{\circ}$로 변화시키면서 이차전자방출계수 및 일함수를 측정하였다. 이러한 실험을 통해 입사각이 클수록 이차전자방출계수는 증가하고 일수는 감소하는 것을 확인 할 수 있었다.

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Multiphonon relaxation and frequency upconversion of $Er^{3+}$ ions in heavy metal oxide glasses ($Er^{3+}$첨가 중금속 산화물 유리의 다중포논 완화와 주파수 상향 전이 현상)

  • Choi, yong-Gyu;Kim, Kyong-Hon;Heo, Jong
    • Korean Journal of Optics and Photonics
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    • v.9 no.4
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    • pp.221-226
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    • 1998
  • Ternary heavy metal oxide glasses in the $PbO-Bi_2O_3-Ga_2O_3$ system doped with $Er_2O_3$ were prepared and their spectroscopic properties, such as radiative transition probability, calculated and measured radiative lifetimes and cross-sections of 1.5 $\mu\textrm{m}$ and 2.7 $\mu\textrm{m}$ emissions were analyzed. Enhanced quantum efficiencies of some electronic transitions were evident mainly because of the low vibrational phonon energy ($~500cm^{-1}$) inherent in the host glasses. This seems to be the main reason for obtaining the 2.7 $\mu\textrm{m}$ luminescence which is normally quenched in the conventional oxide glasses. In addition, green and red fluorescence emissions were observed through the frequency upconversion processes of the 798 nm excitation. Non-radiative transition due to the multiphonon relaxation is a dominant lifetime-shortening mechanism in the 4f-4f transitions in $Er^{3+}$ ion except for the $^4S_{3/2}{\rightarrow}^4I_{15/2}$ transition where a non-radiative transfer to band-gap excitation of the host glasses is dominant. Melting of glasses under an inert gas atmosphere and (or) addition of the typical glass-network former into glasses is necessary in order to enhance the quantum efficiency of the transition.

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Occurrence of Uranium-238 and Rn-222 in Groundwater and Its Relationship with Helium Isotope (지하수 내 우라늄-238 및 라돈-222 산출과 헬륨 동위원소와의 상관성 연구)

  • Jeong, Chan Ho;Lee, Yu Jin;Lee, Yong Cheon;Hong, Jin Woo;Kim, Cheon Hwan;Nagao, Keisuke;Kim, Young-Seog;Kang, Tae-Seob
    • The Journal of Engineering Geology
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    • v.31 no.4
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    • pp.659-669
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    • 2021
  • The purpose of this study is to elucidate the relationship between occurrence of natural radioactive materials such as 238U and 222Rn and original mixing ratio of helium isotope of groundwater from various geology, and to suggest the underground aquifer environment from helium original mixing data. 9 groundwater samples were collected from five study areas, and 238U, Rn-222 and helium isotope were analyzed. A high 238U content of the range of 218~477 ㎍ /L in the groundwater occurs in the twomica granite. 4He air-crust mixing ratio and the Rn-222 content show a rough relation, that is, Rn-222 content increases according to the increase of 4He crust mixing ratio. Because of helium and radon are an inert gas, their behavior in underground environment is assumed as an analogous. The 238U content and He isotope in groundwater does not show any distinct correlation. The groundwater can be classified as three groups (air, air-crust mixing, crust-mantle mixing origin) on the diagram of 3He/4He vs 4He/20Ne, which is composed of original mixing line from air-crust-mantle end members. This original mixing of helium can provide the information of underground aquifer characteristic such as the connection with surface environment or isolation condition from air environment.

Long-term Variation of Radon in Granitic Residual Soil at Mt. Guemjeong in Busan, Korea (화강암 잔류 토양의 토양 가스 중 라돈의 장기적 변화 특성)

  • Moon, Ki-Hoon;Kim, Jin-Seop;Ahn, Jung-Keun;Kim, Hyun-Chul;Lee, Hyo-Min
    • The Journal of the Petrological Society of Korea
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    • v.18 no.4
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    • pp.279-291
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    • 2009
  • Radon is a natural radionuclide originated from radioactive decay of radium in rocks and soil. It is colorless, odorless and tasteless elements that mainly distributed as gaseous phase in soil pore space. The present study analyzed the characteristics of long-term radon variation in granitic residual soil at Mt. Guemjeong in Guemjeong-gu, Busan and determined the effects of atmospheric temperature, rainfall and soil temperature and moisture. Periodic measurements of radon concentrations in soil gas were conducted by applying two types of in-situ monitoring methods (chamber system and tubing system). Radon concentration in soil gas was highest in summer and lowest in winter. The variations in soil temperature and atmospheric temperature were most effective factors in the long-term radon variations and showed positive co-relations. The air circulation between soil air and atmosphere by the temperature difference between soil and atmosphere was analyzed a major cause of the variation. However, other factors such as atmospheric pressure, rainfall and soil moisture were analyzed relatively less effective.

Occurrence Characteristics of Uranium and Radon-222 in Groundwater at ○○ Village, Yongin Area (용인 ○○마을 지하수내 우라늄 및 라돈-222의 산출특성)

  • Jeong, Chan Ho;Yang, Jae Ha;Lee, Yong Cheon;Lee, Yu Jin;Cho, Hyeon Young;Kim, Moon Su;Kim, Hyun Koo;Kim, Tae Seong;Jo, Byung Uk
    • The Journal of Engineering Geology
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    • v.26 no.2
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    • pp.261-276
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    • 2016
  • The occurrence of natural radioactive materials such as uranium and radon-222 in groundwater was examined with hydrogeochemistry and geology at ○○ village in the Yongin area. Two rounds of 19 groundwater and 5 surface water sampling were collected for analysis. The range of pH value in groundwaters was 5.81 to 7.79 and the geochemical types of the groundwater were mostly Ca(Na)-HCO3 and Ca(Na)-NO3(Cl)-HCO3. Uranium and radon-222 concentrations in the groundwater ranged from 0.06 to 411 μg/L and from 5.56 to 903 Bq/L, respectively. Two deep groundwaters used as common potable well-water sources exceeded the maximum contaminant levels of the uranium and radon-222 proposed by the United States Environmental Protection Agency (US EPA). Three groundwater samples from residential areas contained unsuitable levels of uranium, and 12 groundwater samples were unsuitable due to radon-222 concentrations. Radioactive materials in the unsuitable groundwater are naturally occurring in a Jurassic amphibole- and biotite-bearing granitic gneiss. High uranium and radon-222 groundwater concentrations were only observed in two common wells; the others showed no relationship between bedrock geology and groundwater geochemical constituents. With such high concentrations of naturally occurring radioactive materials in groundwater, the affected areas may extend tens of meters for uranium and even farther for radon-222. Therefore, we suggest the radon-222 and the uranium did not originate from the same source. Based on the distribution of radon-222 in the study area, zones of higher radon-222 concentrations may be the result of diffusion through cracks, joint, or faults. Surface radioactivity and uranium concentrations in the groundwater show a positive relationship, and the impact areas may extend for ~200m beyond the well in the case of wells containing high concentrations of uranium. The highest uranium and thorium concentrations in rock samples were detected in thorite and monazite.

Occurrences of Uranium and Radon-222 from Groundwaters in Various Geological Environment in the Hoengseong Area (횡성지역 다양한 지질환경에서 지하수 중 우라늄 및 라돈-222 산출특성)

  • Jeong, Chan Ho;Yang, Jae Ha;Lee, Yu Jin;Lee, Yong Cheon;Choi, Hyeon Young;Kim, Moon Su;Kim, Hyun Koo;Kim, Tae Seong;Jo, Byung Uk
    • The Journal of Engineering Geology
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    • v.25 no.4
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    • pp.557-576
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    • 2015
  • Groundwaters in granite, gneiss, and two-mica granite formations, including faults, in the Hoengseong area are examined to determine the relationship between their uranium and radon-222 contents and rock types. The chemical compositions of 38 groundwater samples and four surface water samples collected in the study area were analyzed. Sixteen of the samples showing high uranium and radon-222 contents were repeatedly analyzed. Surface radioactivities were measured at 30 points. The uranium and radon-222 concentrations in the groundwater samples were in the ranges of 0.02-49.3 μg/L and 20-906 Bq/L, respectively. Four samples for uranium and 35 samples for radon had concentrations exceeding the alternative maximum contaminant level of the US EPA. The chemical compositions of groundwaters indicated Ca(Na)-HCO3 and Ca(Na)-NO3(HCO3+Cl) types. The pH values ranged from 5.71 to 8.66. High uranium and radon-222 contents in the groundwaters occurred mainly at the boundary between granite and gneiss, and in the granite area. The occurrence of uranium did not show any distinct relationship to that of radon-222. The radon-222, an inert gas, appeared to be dissolved in the groundwater of the aquifer after wide diffusion along rock fractures, having been derived from the decay of uranium in underground rocks. The results in this study indicate that groundwater of neutral or weakly alkaline pH, under oxidizing conditions and with a high bicarbonate content is favorable for the dissolution of uranium and uranium complexes such as uranyl or uranyl-carbonate.