• Journal of the Mineralogical Society of Korea
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• v.31 no.1
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• pp.33-46
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• 2018

Traditional inorganic pigments applied to dancheong, buddhist painting, and wall painting were produced from natural minerals which were later replaced by synthetic pigments, resulting in the loss of the recipe to prepare mineral pigments. This study examined the domestic occurrence and mineralogical characteristics of green and blue mineral pigments required for the conservation of cultural heritage. Cuprous green-blue mineral pigments were found as the weathering products of waste dumps and ores of abandoned Cu-Pb-Zn sulfide mines. Mineralogical analyses using X-ray diffraction and scanning electron microscopy identified diverse hydrous copper sulfate pigments of green (brochantite and devilline) and blue color (linarite, bechererite, and schulenbergite) with minor green pigments of antlerite and atacamite commonly associated with cerussite, smithsonite, anglesite, and cuprite. Noerok, a green silicate pigment, replaced the fractured basalt lava. Celadonite was responsible for the green color of Noerok, closely associated with opal in varying ratio. Glauconite, green silicate pigment, was identified in the Yellow Sea sediments. Malachite and azurite, the most important green and blue pigments of Korean cultural heritage, were not identified in this study.

• Journal of the Mineralogical Society of Korea
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• v.31 no.2
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• pp.123-135
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• 2018

This study tried to find the clue to Seokrok province by comparing Seokrok used in painting culture properties with Seokrok ore from domestic occurrence and imported Seokrok ore. To this end, chemical and mineralogical characteristics of painting cultural properties were identified with portable X-ray Florescence (p-XRF), micro X-ray diffraction (micro XRD) and SEM/EDS Analysis. To obtain Pb isotopic ratio, the Pb contained in Seokrok has been analyzed with Thermal Ionization Mass Spectrometer. Atacamite (or botallackite) and small quantity of brochantite were identified from Seokrok in Dancheong, and malachite was also identified from Buddhist painting besides those two ingredients. Without distinction of type, most Seokrok used in painting cultural properties is atacamite composed of Cu and Cl. From Pb isotope analysis, it was found that Seokrok in painting cultural properties was closer to that of north Korea, north China and Japan than south Korea as in regional division for East North Asia suggested by Mabuchi. The Pb isotopic ratio of domestic green mineral belongs to the distribution of Seokrok inside the painting cultural properties but imported malachite showed considerably difference. Considering the fact that atacamite, the main mineral of Seokrok in painting cultural properties is rarely produced from southern mine of the Korean Peninsula and the result of Pb isotope analysis.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.2
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• pp.119-126
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• 2014

The object of this study was to evaluate the combined toxic interactions of the perfluorooctanoic acid (PFOA) or perfluorooctane sulfonate (PFOS) with six heavy metals (Cu, Zn, Cr, Cd, Hg, and Pb). The individual and combined toxic effects were assessed using the Vibrio fischeri assay. In case of the individual toxicity, PFOA was higher toxic than PFOS and toxicity of PFOA and PFOS were lower than heavy metal. In the toxicity of heavy metals, the $Hg^{2+}$ was found to be most toxic followed by $Pb^{2+}$, $Cr^{6+}$, $Cu^{2+}$, $Zn^{2+}$, and $Cd^{2+}$. The combined toxicity of PFOA or PFOS with $Cr^{6+}$ were synergistic effect because the $EC_{50}$ mix values were less than 1 TU. PFOA + $Zn^{2+}$, PFOS + $Zn^{2+}$, PFOA + $Cd^{2+}$ and PFOS + $Cd^{2+}$ produced addictive effect. Except in these case, all of binary mixtures show antagonistic effect. This study proved potential risk of coexistent with perfluorinated compounds and heavy metals in water environment.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.4
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• pp.240-246
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• 2013

$SF_6$ is the most important greenhouse gas with the highest GWP (global warming potential). The $SF_6$ decomposition study was performed with silicon carbide with aluminium oxide by microwave irradiation. DRE (Decomposition and Removal Efficiencie) of $SF_6$ were evaluated by GC-TCD unit using 3,000 ppm $SF_6$ gas. DRE of $SF_6$ was increased by $Al_2O_3$ contents to 10~30 wt%, otherwise $Al_2O_3$ content of 40~50 wt% was decreased. DRE of $SF_6$ up to 99.99% have been achieved in SiC-$Al_2O_3$ (20 wt%) and SiC-$Al_2O_3$ (30 wt%) above $900^{\circ}C$. Also, the DRE of SiC-$Al_2O_3$ (30 wt%) at $700^{\circ}C$ showed 96.72%. In addition to consideration microwave input energy and $Al_2O_3$ content, SiC-$Al_2O_3$ (30 wt%) can be suggested the best material to control $SF_6$. The results of this study suggest it is important to control content of $Al_2O_3$ in SiC for decomposition of $SF_6$ with microwave energy.

• Korean Security Journal
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• no.21
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• pp.35-52
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• 2009

The guard system in the last period of the Joseon Dynasty, established at the time of the struggle of invading world powers and the loss of the Dynasty rights, was strengthened to protect the Royal family and the Dynasty from the attacks of foreign powers. While investigating both the military system and the guard system from the beginning of King Gojong's direct royal governing to the time of Japanese annexation of Korea, we realize that the Joseon Dynasty not only lost the support of the public but also had little power to cope with the aggression of foreign countries. The reformation and strengthening by Daewongun, King Gojong's father, was made in preparation for King Gojong's direct royal rule. Nevertheless, the intervention of foreign countries in the domestic affairs of the Joseon Dynasty got worse. As opposed to their intervention, Queen Minbi had engaged in politics, which resulted in murderous attempts on her. The Joseon Dynasty had tried to reform and intensify the guard system. New names such as Muwiso, Chingunyeong, and Siwidai, had been given respectively. Such reformation and intensification had little effect because of two successive victories at the Sino-Japanese War and the Russo-Japanese War of Japan. Japan occupied the Joseon Dynasty by force after all. The guard system of Daehan-jeguk(the Empire of Korea) was eventually incapacitated; an army in the cause of justice was raised instead. However, The state of things and the guard system at that incapacitated period gives a good lesson for the establishment of a modern guard system at the present day.

• Journal of Plant Biotechnology
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• v.43 no.3
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• pp.272-280
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• 2016

Chrysanthemum is one of the top floriculture species with ornamental and medicinal value. Although chrysanthemum breeding program has contributed to the development of various cultivars so far, it needs to be advanced from the traditional phenotype-based selection to marker-assisted selection (molecular breeding) as shown in major cereal and vegetable crops. Molecular breeding relies on trait-linked molecular markers identified from genetic, molecular, and genomic studies. However, these studies in chrysanthemum are significantly hampered by the reproductive, genetic, and genomic properties of chrysanthemum such as self-incompatibility, inbreeding depression, allohexaploid, heterozygosity, and gigantic genome size. Nevertheless, several genetic studies have constructed genetic linkage maps and identified molecular markers linked to important traits of flower, leaf, and plant architecture. With progress in sequencing technology, chrysanthemum transcriptome has been sequenced to construct reference gene set and identify genes responsible for developments or induced by biotic or abiotic stresses. Recently, a genome sequencing project has been launched on a diploid wild Chrysanthemum species. The massive sequencing information would serve as fundamental resources for molecular breeding of chrysanthemum. In this review, we summarized the current status of molecular genetics and genomics in chrysanthemum and briefly discussed future prospects.

• Applied Chemistry for Engineering
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• v.10 no.6
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• pp.913-916
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• 1999

Fluorine modified diisocyanate(FMD) was synthesized from tris(6-isocyanatohexyl)isocyanurate(TIHI) and N-ethyl-N-2-hydroxyethyl-perfluorooctanesulfonamide(HFA). Fluorine modified polyurethane(FMPU) was also synthesized from FMD and poly(tetramethylene) glycol(PTMG). Modified polyurethanes were made by blending FMPU into the polyester type base polyurethane(BPU). Surface and thermal properties of the blended BPU film was measured by contact angle measurement and DSC. As the amounts of FMPU was increased from 0 wt % to 1 wt %, the surface energy was dramatically decreased from 47.82 dyne/cm to 17.64 dyne/cm. But we observed little change of the contact angle with further increase in the amount of the FMPU up to 10 wt %. The data meant that the surface of the blended polyurethanes was hydrophobic due to the surface arrangement of the fluorine containing moiety in FMPU. Phase separation was induced by the incompatibility of FMPU and BPU for the samples having over 5 wt % of FMPU. The thermal analysis data of these samples showed the thermal behavior of the FMPU itself.

• Journal of Oriental Neuropsychiatry
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• v.14 no.2
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• pp.213-218
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• 2003

This is a case report of a patient with Tourett's disorder treated by Ukgan-san. We evaluated the patient Tourett's disorder by behavior and sound. His tic behaviors like eye blinking, shoulder shrugging, head jerking, facial frimace have been shown frequently, and His phonic tic symptoms like coughing, throat clearing, sniffing have been presented frequently, too. We diagnosed his condition as Wind-syndrome Caused by Hyperactivity of Liver-yang by patient's redish face, taut pulse, Left umbilical throb. So we treated the patient with Ukgan-san. and the score of Yale Global Tic Severity Scale(YGTSS) was 30 at the start of treatment. and the score of YGTSS was 3 at the end. We found that Ukgan-san was effective for the patient with Tourett's disorder.

• Proceedings of the KAIS Fall Conference
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• 2010.05b
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• pp.1209-1212
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• 2010

본 연구는 제주지역 일부 초, 중학생들의 간접흡연 실태와 그로 인한 현재 흡연 여부 관계를 분석하여 초, 중학생들의 흡연 예방 교육 계획 및 수립에 기초 자료를 제공하고자 본 연구를 시도하였다. 자료 수집 기간은 2009년 6월 29일부터 7월 11일까지 제주특별자치도내 초등학교 5, 6학년 아동 464명과 중학생 475명을 대상으로 설문지를 이용하여 조사하였다. 연구 대상자들의 간접흡연 노출 관련성은 가정불화, 성적, 친구관계스트레스가 있는 대상자에게서 높게 조사되었고, 가족 및 주변인의 흡연유무에 따른 간접흡연 실태는 부모 및 친구의 흡연으로 간접흡연에 노출되었으며 통계적으로 유의한 차이를 보였다. 간접흡연의 주제공자는 아버지며, 주 간접흡연 피해 장소는 집으로 나타났다. 간접흡연 노출 유무를 종속변수로 한 로지스틱 회귀분석 결과는 흡연하는 아버지를 둔 대상자가 그렇지 않은 대상자에 비해 간접흡연 노출이 높았으며, 흡연하는 친구를 둔 대상자는 그렇지 않은 대상자에 비해 간접흡연 노출이 높게 나타났다. 현재흡연 여부를 종속변수로 한 로지스틱 회귀분석의 결과는 남학생이 여학생에 비해, 중학생이 초등학생에 비해 현재흡연율이 높았고, 엄한 가정 분위기 속에서 생활하고 있는 대상자와 흡연하는 친구를 둔 대상자는 그렇지 않은 대상자에 비해 현재흡연율이 높았으며, 간접흡연에 노출 되었던 대상자에게서 현재흡연율이 높게 나타났다. 이상의 결과를 종합하여 볼 때 초, 중학생의 간접흡연 실태는 심각한 사회문제이다. 또한 대상자들의 현재 흡연은 간접흡연 노출과 관련이 있는 것으로 볼 수 있었다. 이러한 간접흡연의 노출 및 그로 인한 흡연율을 줄이기 위해서는 가정 및 학교와 공공장소 등에서 간접흡연에 노출되지 않는 제도적 및 환경적인 조치들이 우선되어야 할 것이며, 학생들을 대상으로 간접흡연에 대한 간접흡연 예방 교육 및 대처방안 교육이 조기에 지속적으로 실시되어야 하겠다. 또한 유치원에서부터 고등학교에 이르기까지 모든 학생들에게 필수적으로 흡연예방 교육을 수강하게 하고, 교사들을 위한 연수교육 실시, 학교 흡연예방사업에 부모나 가족을 참여, 흡연예방 사업의 정기적인 평가 실시 등 국가적인 정책이 동반되어야 할 것이다.

• Analytical Science and Technology
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• v.30 no.5
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• pp.240-251
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• 2017

1,1,1,2-Tetrafluoroethane (HFC-134a), which is used as refrigerant in air conditioners, has been recently regulated as a greenhouse gas and is recommended for reuse by refining. It is very important to quantitatively analyze trace impurities present in the refrigerant to evaluate the criteria for reuse. In this study, trace impurities including C, H, Cl, and F, which are difficult to quantify because there are no reference materials, were quantitatively analyzed by a gas chromatograph-atomic emission detector (GC/AED); for this analysis, this was preceded by a qualitative analysis with a GC-mass selective detector (GC/MSD). In addition, the AED response was investigated using a hydrocarbon mixed reference material, which was proportional to the number of atoms in the component. Fifteen refrigerant components were detected as trace impurities in HFC-134a by qualitative analysis of trace impurities including C, H, Cl, and F in the samples. Based on the results of the qualitative analysis, quantitative analysis of trace impurities using AED showed that the highest mole fractions were for the $CHClF_2$ component ($45438.38{\mu}mol/mol$) in one sample and for the $C_2H_2ClF_3$ component ($1311.47{\mu}mol/mol$) in another sample. From this study, it has been shown that it is possible for this analytical method to be applied to the qualitative and quantitative analysis of trace compounds in refrigerants, which are difficult to quantify because of the absence of reference materials.