• Title/Summary/Keyword: 불소수지

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Fuorine-Containing High Temperature Polymers for Microelectronic Applications (불소를 함유하는 전자재료용 내열성 고분자)

  • Kim, Sang Youl
    • Polymer Science and Technology
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    • v.3 no.1
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    • pp.36-43
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    • 1992
  • Trifluoromethyl group을 내열성고분자의 주쇄에 도입하면 내열성의 큰 손실없이 용해도의 증가 및 유전상수의 감소등 절연재료로서의 성능을 향상시켜 주지만, 유연한기의 도입에 따른 $T_g$의 저하등 부정적인 효과도 나타낸다. 분자구조설계에 의해 기존 고분자재료의 성능을 향상시키려는 시도는 흔히 향상되어지는 성질들에 반비례하여 어는 다른 성질의 저하를 초래하는 경향이 있으나, 유전상수나 가공성 이외에도 낮은 열팽창계수를 갖는 polyimides, 열경화성수지인 poly(benzocyclobutene) 등의 packaging 재료로서의 개발등, 낮은 절연율, 내열성, 가공성, 접착력, 적절한 열팽창계수 및 기계적 성질 등 가능한 모든 필요성질을 동시에 최대한 만족시키는 고분자재료에 대한 개발노력이 계속되어지고 있으며 장차 혁신적인 새로운 고분자 재료의 등장도 이루어지리라고 본다.

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PFA 라이닝 밸브의 헬륨누설 측정 및 비산배출 평가

  • Lee, Won-Ho;Lee, Won-Seop;Lee, Jong-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.121.2-121.2
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    • 2016
  • PFA 라이닝 밸브 (PFA Lined Valve)는 고온 (~120oC) 고압 (~10 bar)에서 강한 부식성을 갖은 화학물질 (염산, 황산, 질산 등)을 이송시킬 수 있도록 내식성, 비점착성, 내열성 향상을 위한 불소계 수지 PFA (Perfluoroalkoxy)가 밸브 내면부에 가공되어 있으며, 고순도 화학약품 및 반도체 LCD 석유화학 제철 제약 분야 등의 제조공정에서 사용되고 있다. 미국 EPA (Environmental Protection Agency)에서는 석유화학 플랜트에서 발생되는 비산배출 (fugitive emission)의 대부분인 60% 정도가 밸브에서 발생된다고 보고하고 있으며, 근래 빈번한 불산 노출사고 내용을 매스컴에서 접할 수 있는 것처럼 PFA 라이닝 밸브가 설치되는 산업현장에서는 미소 누설에도 치명적인 인명피해 사고가 발생하기 때문에 국제규격에 따른 PFA 라이닝 밸브의 기밀누설에 관한 규제 및 관리가 중요하다. 본 논문에서는 가압진공법을 이용하여 PFA 라이닝 볼밸브의 비산배출 측정하였으며, 작동횟수/온도변화에 따른 PFA 라이닝 볼밸브의 비산배출 특성을 고찰하였다.

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Fabrication of EHD(Electrohydrodynamic) nozzle using surface hydrophobic coating and SU-8 photoresist (SU-8 포토레지스트와 표면 소수처리를 이용한 전기 수력학 노즐 제작)

  • Lim, Byung-Jik;Lee, Kyoung-Il;Kim, Seong-Hyun;Kim, Seon-Min;Lee, Churl-Seung;Lee, Hyun-Joo;Byun, Sang-Un;Cho, Jin-Woo
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1706-1707
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    • 2011
  • SU-8 감광제를 이용하여 전기 수력학에 응용할 수 있는 내경 $50{\mu}m$인 평면형 노즐 구조와 외경 $100{\mu}m$, 내경 $50{\mu}m$인 돌출형 노즐 구조를 제작하고 노즐 표면에 불소계 수지를 건식 증착하여 소수 처리를 하였으며 이를 통해 전기수력학 방식의 잉크 토출을 구현하였다.

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Electromagnetic Indirect Induction Fluid Heating System using Series Resonant PWM Inverter and Its Performance Evaluations (직렬공진 PWM인버터를 이용한 전자간절유도가열 열유체 에너지시스템과 그 성능평가)

  • 김용주;김기환;신대철
    • The Transactions of the Korean Institute of Power Electronics
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    • v.7 no.1
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    • pp.48-54
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    • 2002
  • This paper is described the indirect induction heated boiler and induction heated hot air producer using the voltage-fed series resonant high-frequency inverter which can operate in the frequency range from 20 kHz to 50 kHz. A specially designed induction heater is composed of laminated stainless plates, which have many tiny holes and are interconnected by spot welding. This heater is inserted into the ceramic type vessel with external working coil. This working coil is connected to the inverter and turbulence fluid through this induction heater to moving fluid generates in the vessel. The operating performances of this unique appliance in next generation and its effectiveness are evaluated and discussed from a practical point of view.

Effects of UV Sterilization on Quality of Acer mono Sap (자외선 살균이 고로쇠 수액의 품질에 미치는 영향)

  • Choe, Su Bin;Han, Sang Jin;Han, Ouk Hee;Kim, Hak Su;Kang, Sung Tae
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.1
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    • pp.148-152
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    • 2013
  • An ultraviolet (UV) sterilization system was developed to decrease the number of microorganisms in filtered Acer mono sap (FAS). The Acer mono sap (AS) was passed through 18 strips of PTA fluoroplastic tubing with 30 UV lamps (total 1,170 W). During passage, the AS was effectively exposed to the UV rays. The total bacteria, coliform group and fungi were sterilized at a flow rate ranging from 852 to 1,358 mL/min and a UV power higher than 156 W. Although the sensory score of the UV-sterilized AS was significantly lower than that of the untreated AS, the sensory score was better under the condition of 390 W and 852~1,358 mL/min than under the other conditions examined. ANOVA did not reveal a significant difference in pH, total acidity, sugar content and color characteristic under all conditions tested (p<0.05). Considering the overall attributes of the AS quality, the optimum sterilization condition was determined to be 390 W and 852~1,358 mL/min.

Effect of Fluorination of Carbon Nanotubes on Physico-chemical and EMI Shielding Properties of Polymer Composites (고분자 복합재의 물리화학적 및 전자파차폐 특성에 미치는 탄소나노튜브의 불소화 영향)

  • Lee, Si-Eun;Kim, Doyoung;Lee, Man Young;Lee, Min-Kyung;Jeong, Euigyung;Lee, Young-Seak
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.114-121
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    • 2015
  • Mutli-walled carbon nanotubes (MWCNTs) were surface-modified by a hydrofluoric acid solution to remove impurities and improve interfacial bonding and dispersion of nanotubes in an epoxy matrix. The crystallinity on the surface of treated MWCNTs was investigated by X-ray photoelectron spectroscopy and Raman spectroscopy. The mechanical properties were characterized by tensile test, and the enhancement of mechanical properties of the modified MWCNTs/epoxy composites was indicated by a 33% increase in tensile strength. The electromagnetic interference shielding effectiveness (EMI-SE) of modified MWCNTs/epoxy composites was improved with an increase in concentration of hydrofluoric solution, and EMI-SE showed the maximum increase with 25% HF. However, mechanical and EMI-SE properties didn't show further increase with over 50% HF concentration because the properties of MWCNTs were influenced by degradation of crystallinity and intrinsic properties of MWCNTs. The mechanical and electrical property enhancements of the polymer composites are attributed to the modification of MWCNTs which improve crystallinity of MWCNTs and dispersion in the epoxy resin.

OCULODENTODIGITAL SYNDROME : A CASE REPORT (Oculodentodigital syndrome의 1 증례)

  • Kang, Ho-Seung;Jeong, Tae-Sung;Kim, Shin
    • Journal of the korean academy of Pediatric Dentistry
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    • v.26 no.3
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    • pp.492-498
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    • 1999
  • Oculodentodigital syndrome(ODD) was first reported by Lohmann in 1920 and termed by Meyer Schwicketath, which they called "dysplasia oculo-dento-digitalis" in 1957. It is somewhat rare heritable disease. ODD is generally inherited in an autosomal dominant pattern with a complex phenotype. The characteristic features are : (1) unique facial features, (2) microphthalmos, (3) syndactyly and camptodactyly of 4th and 5th fingers, (4) osseous anomalies of the middle phalanges of 5th fingers and toes, (5) enamel hypoplasia, (6) dry lusterless hair. We found several occlusal wearing and yellow discoloration of succedaneous teeth, multiple caries lesions, premature loss and pulpal involvement of primary teeth with associated enamel abnormalities caused by generalized enamel hypoplasia in a fairly constant oral finding. Occasionally partial anodontia, microdontia and cleft lip and palate can be manifested. This case, a 9-year-old female with repaired bilateral syndactyly was referred to pediatric dental clinic, Pusan National University Hospital for evaluation of severe attrition of teeth and caries lesions. She had most of the above mentioned typical manifestations of the syndrome. Dental treatment including caries control, stainless steel crown were performed.

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A Study on the Development of Superheater Using High-Frequency Resonant Inverter for Induction Heating (유도가열용 고주파 공진형 인버터를 이용한 과열증기 발생장치 개발에 관한 연구)

  • 신대철;권혁민;김기환;김용주
    • The Transactions of the Korean Institute of Power Electronics
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    • v.9 no.2
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    • pp.119-125
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    • 2004
  • This paper is described the indirect induction heated boiler system and induction heated hot air producer using the voltage-fed series resonant high-frequency inverter which can operate in the frequency range from 20〔KHz〕 to 50〔KHz〕. A specially designed Induction heater, which is composed of laminated stainless assembly with many tiny holes and interconnected spot welding points between stainless plates, is inserted into the ceramic type vessel with external working coil. This working coil is connected to the resonant inverter. In the induction heater, it's primary heating section creates low-pressure saturated steam and secondary heating section generates heat distribution evaporating fluid from the turbulence fluid which is flowing through the vessel. The operating performances of this unique appliance in next generation and its effectiveness are evaluated and discussed from the practical point of view.

Electrical Resistivity of Natural Graphite-Fluorine Resin Composite for Bipolar Plates of Phosphoric Acid Fuel Cell(PAFC) Depending on Graphite Particle Size (인산형 연료전지 분리판용 천연흑연-불소수지계 복합재료의 흑연입도에 따른 전기비저항 변화)

  • Lee, Sang-Min;Beak, Un-Gyeong;Kim, Tae-Jin;Roh, Jae-Seung
    • Korean Journal of Materials Research
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    • v.27 no.12
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    • pp.664-671
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    • 2017
  • A composite material was prepared for the bipolar plates of phosphoric acid fuel cells(PAFC) by hot pressing a flake type natural graphite powder as a filler material and a fluorine resin as a binder. Average particle sizes of the powders were 610.3, 401.6, 99.5, and $37.7{\mu}m$. The density of the composite increased from 2.25 to $2.72g/cm^3$ as the graphite size increased from 37.7 to $610.3{\mu}m$. The anisotropy ratio of the composite increased from 1.8 to 490.9 as the graphite size increased. The flexural strength of the composite decreased from 15.60 to 8.94MPa as the graphite size increased. The porosity and the resistivity of the composite showed the same tendencies, and decreased as the graphite size increased. The lowest resistivity and porosity of the composite were $1.99{\times}10^{-3}{\Omega}cm$ and 2.02 %, respectively, when the graphite size was $401.6{\mu}m$. The flexural strength of the composite was 10.3MPa when the graphite size was $401.6{\mu}m$. The lowest resistance to electron mobility was well correlated with the composite with lowest porosity. It was possible the flaky large graphite particles survive after the hot pressing process.

Estimation of Domestic Greenhouse Gas Emission of Refrigeration and Air Conditioning Sector adapting 2006 IPCC GL Tier 2b Method (국내 냉동 및 냉방부문 온실가스 배출량 산정 - 2006 IPCC GL Tier 2b 적용 -)

  • Shin, Myung-Hwan;Lyu, Young-Sook;Seo, Kyoung-Ae;Lee, Sue-Been;Lim, Cheolsoo;Lee, Sukjo
    • Journal of Climate Change Research
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    • v.3 no.2
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    • pp.117-128
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    • 2012
  • The Government of South Korea has continued its effort to fixate virtuous circle of economic growth and climate change response to cope with international demands and pressure to commitment for greenhouse gas reduction effectively. Nationally, Korean Government has established "Enforcement of the Framework Act on Low carbon, Green Growth"(2010. 4. 13) to implement national mid-term GHG mitigation goal(30% reduction by 2020 compare to BAU), which established the foundation for phased GHG mitigation by setting up the sectoral and industrial goal, adopting GHG and Energy Target Management System. Also, follow-up measures are taken such as planning and control of mid-term and short-term mitigation target by detailed analysis of potential mitigation of sector and industry, building up the infrastructure for periodic and systematic analysis of target management. Likewise, it is required to establish more accurate, reliable and detailed sectoral GHG inventory for successfully establishment and implement the frame act. In comparison to the $CO_2$ emission, Especially fluorinated greenhouse gases (HFCs, PFCs, $SF_6$) are lacking research to build the greenhouse gas inventories to identify emissions sources and collection of the applicable collection activities data. In this study, with the refrigeration and air conditioning sector being used to fluorine refrigerant(HFCs) as the center, greenhouse gas emission estimation methodology for evaluating the feasibility of using this methodology look over and mobile air conditioning, fixed air conditioning, household refrigeration equipment, commercial refrigeration equipment for the greenhouse gas emissions were calculated. First look at in terms of methodology, refrigeration and air conditioning sector GHG emissions in developing country-specific emission factors and activity data of the industrial sector the construction of the DB is not enough, it's 2006 IPCC Guidelines Tier 2a (emission factor approach) rather than the Tier 2b (mass balance approach) deems appropriate, and each detail by process, sectoral activity data more accurate, if DB is built Tier 2a (emission factor approach) can be applied will also be judged. Refrigeration and air conditioning sector in 2009 due to the use of refrigerant greenhouse gas emissions ($CO_2eq.$) assessment results, portable air conditioner 1,974,646 ton to year, fixed-mount air conditioner 1,011,754 ton to year, household refrigeration unit 4,396 ton to year, commercial refrigeration equipment 1,263 ton to year was estimated to total 2,992,037 tons.