• Title/Summary/Keyword: 분해성

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Comparative study on microbial degradation characteristics of liquid and solid n-alkanes by Acinetobacter sp. (Acinetobacter sp. 에 의한 액체, 고체 알칸의 미생물 분해특성 비교연구)

  • Dong-Hyuk CHOI
    • Journal of Korea Soil Environment Society
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    • v.4 no.3
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    • pp.95-104
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    • 1999
  • Comparative biodegradation studies of liquid and solid alkanes and of two different solid alkanes were conducted by an isolated Acinetobacter sp., which degraded crude oil alkanes simultaneously. for the determination of degradation mechanism of hydrophobic crude oil constituents. Also a model oil experimental system composed of a solid alkane. heneicosane, as a substrate and a non-degradable non-aqueous phase liquid. pristane, as an oil matrix was established and studied. It was proposed that the Acinefobacter sp. utilized hydrophobic substrates directly on the surface of them with no difference in the degradation rates between the liquid and solid alkanes. On the basis of the results from the heneicosane/pristane system which imitates crude oil matrix containing solid constituents. the crude oil matrix was considered to reduce the bioavailability of contained substrates by reducing the specific surface area of substrates to contact with microorganisms.

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Enhancement of anaerobic digestion of sewage sludge by combined process with thermal hydrolysis and separation (하수슬러지 혐기성 소화 효율 향상을 위한 열가수분해-고액분리 결합 공정)

  • Lee, See-Young;Han, Ihn-Sup
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.4
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    • pp.99-106
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    • 2021
  • The purpose of this study was to evaluate the performance of novel process with thermal hydrolysis and separation as pre-treatment of anaerobic digestion (AD). The dewatered sludge was pre-treated using THP, and then separated. The separated liquid used as substrate for AD and separated solid was returned on THP(Thermal Hydrolysis Process). The degree of disintegration (DD, based on COD) using only THP found 45.1-49.3%. The DD using THP+separation found 76.1-77.6%, which was higher than only THP. As result from dual-pool two-step model, the ratio of rapidly degradable substrate to total degradable substrate found 0.891-0.911 in separated liquid, which was higher than only THP. However, the rapidly degradable substrate reaction constant (kF) of only THP and THP+separation were similar. This results found that dewatered sludge was disintegrated by THP, and then rapidly degradable substrate of hydrolyzed sludge was sorted by separation.

Dissolution Conditions of Solid Radioactive Wastes Generated from NPP for the Analysis of Radionuclides Using a Closed-vessel Microwave Acid Digestion System (원전 발생 고체 방사성폐기물 내 핵종 분석을 위한 극초단파 산분해 장치를 이용한 용액화 조건)

  • 표형열;이정진;전종선;이창헌;지광용
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.158-166
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    • 2004
  • The optimal conditions are obtained for the decomposition of solid radioactive wastes, including ion exchange resin, zeolite, active charcoal, and sludge from nuclear power plant. In the process of decomposing the radioactive wastes were used the microwave acid digestion method with mixed acid. The solution after acid digestion by the following method was colorless and transparent. Each solution was analyzed with ICP-AES and AAS and the recovery yield for 5 different elements added the simulated radioactive wastes were over 94%. As an effective pre-treatment, the proposed microwave acid digestion conditions concerning the chemical trait of each radioactive waste are expected to be generally applied to above-mentioned radioactive wastes from nuclear power plant hereafter.

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Assessment of the Organic and Nitrogen Fractions in the Sewage of the Different Sewer Network Types by Respirometric Method (미생물 호흡률 측정에 의한 관거시스템 유형별 하수의 기질 분율 평가)

  • Park, Jong-Bu;Hur, Hyung-Woo;Kang, Ho;Chang, Sung-Oun
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.8
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    • pp.649-654
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    • 2009
  • Respirometric analysis of domestic sewage by measuring oxygen uptake rate(OUR) was carried out for the experimental assessment of the organic and biomass fractions. The data of the organic and biomass fractions in sewage is essential for the activated sludge model to optimize the biological treatment plant. As a result of this study, the fractions of readily biodegradable substrate($S_S$), slowly biodegradable substrate($X_S$), inert soluble substrate($S_I$), inert particular substrate($X_I$) and heterotrophic biomass($X_{HAB}$) were about 26.6%, 41.5%, 8.5%, 14.7% and 8.7% on the basis of chemical oxygen demand($COD_{Cr}$), respectively. And the fractions of nitrogen were also studied. The fractions of soluble nitrate nitrogen($S_{NO}$), soluble ammonia nitrogen($S_{NH}$), soluble nonbiodegradable organic nitrogen($S_{NI}$), soluble biodegradable organic nitrogen($S_{ND}$) and slowly biodegradable organic nitrogen($X_{ND}$) were about 3.7%, 64.9%, 4.7%, 9.4% and 17.4%, respectively.

수종 점막증 메치오닌엔케팔린 및 유사체의 분해 특성

  • 전인구;이치호;신영희
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1992.05a
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    • pp.61-61
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    • 1992
  • 여러 점막 추출액증 Met-Enk의 효소적 분해는 매우 신속하였고 1차식에 따랐으며 점막측 추출액에서의 분해속도는 직장>눈>질>비강점막의 순이었다. 비강, 직장, 질점막의 점막측 및 장막측 추출액 간의 분해속도에는 유의성 있는 차이는 없었으나 눈점막의 경우 내피측 추출액에서의 분해속도 (1.03 $\times$ $10^{-3}$ $min^{-1}$)가 표피측 추출액에서보다 현저히 낮았다. 모든 추출액에서 검출된 주요 분해산물은 Tyr 및 Des-Tyr-Met-Enk로 천연 Met-Enk의 점막 추출액중 분해는 주로 aminopeptidase류가 관여되고 있음을 알았으며 Tyr-Gly, Tyr-Gly-Gly등의 분해산물이 소량 출현함으로 보아 endopeptidase류도 분해에 다소 관여하고 있음을 알았다. YAGFM은 Met-Enk보다 분해가 현저히 지연되었으며 그 분해속도도 직장>질>비점막의 순이었다. 이러한 분해는 분해산물로 Tyr이 검출되지 않은점으로 보아 YAGFM의 점막 추출액중 분해는 주로 endopeptidase류가 주로 관여되는 것으로 추정된다.

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Enhancement of Anaerobic Degradation by Organic Stimulants Addition (반응촉진 유기물 첨가에 의한 혐기성 분해율의 향상에 관한 연구)

  • 손부순;허준무;배형석;서성철;박종안
    • Journal of environmental and Sanitary engineering
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    • v.13 no.1
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    • pp.32-43
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    • 1998
  • 혐기성대상과정중 메탄생성균(methanogenic bacteria)에 의한 메탄생성시 주요 기질인 아세트산 (acetic acid)을 분해할 경우에 여러 가지 복합기질 중 아미노산 첨가에 의한 분해속도증가에 미치는 영향과 투입한 아미노산이 미생물에 의하여 생체량으로 합성되는 정도를 고찰하였다. 실험결과 메탄생성균은 glycine, serine, threonine, aspartic acid, trytophan 등의 혐기성미생물의 생체량합성에 필요한 물질을 투입할 경우에 아세트산의 분해속도가 증가하였으며, 여러 가지 아미노산을 혼합하여 주입한 결과 분해속도가 17% 향상되었다. 한편, 메탄생성균의 lysing에 의하여 생성된 유기물은 메탄이나 이산화탄소의 최종산물로 전환되기보다는 새로운 메탄생성균의 생체량을 형성하는데 직접 이용되었으며, 아세트산의 분해속도를 52% 증가시켰다. 단순기질(sole substrate)과 복합기질(complex substrate)의 분해는 미생물의 생체량합성에 필요한 여러 가지 중간대사산물간의 상호자극효과에 의하여 복합기질이 용이한 것으로 나타났으며, 유입기질내 활성이 강한 슬러지의 농도는 혐기성처리에 매우 중요한 부분을 차지하였다.

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Improvement of Rheological and Functional Properties of Salmon FPC by Enzymatic Partial Hydrolysis 1. Production of Salmon FPC Hydrolysates and Their General Properties (효소적 부분 가수분해에 의한 연어 FPC(Fish Protein Concentrates)의 물성 및 기능성 개선 1. 연어 FPC의 가수분해물 제조와 일반적인 성상)

  • LEE Jong-Ho;LEE Keun-Tai;PARK Seong-Min;PARK Chan-kyu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.1
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    • pp.132-138
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    • 1998
  • To improve functional properties and enhance application of FPC in food industry, modified salmon FPC with enzyme treatment was produced and its general properties were investigated. Salmon FPC has over $84\%$ of protein and less than $0.18\%$ of lipid. Solubilities of FPC extracted with IPA and ethanol were very poor as less than $3\%$ in every pH range. In case of enzyme : substrate ratio of 1 : 100, degree of hydrolysis significantly increased until 4 hours and then slightly increased. No considerable differences were observed in general components of hydrolysates. Results of SDS-PAGE showed one unique band in each case and their molecular weight was less than 6,500. The flow properties of hydrolysates showed newtonian flow. Whiteness of hydrolysates were higher than that of salmon FPC as $5\~7$. There was no significant differences in the amount of peptide, but that of free amino acid slightly increased from 0.17 to 0.21 mg/ml.

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Monitoring on Characteristics of Soybean Flour Hydrolyzed by Various Proteolytic Conditions (콩분말의 단백질 가수분해 조건에 따른 특성 모니터링)

  • Jeong Kyo-Ho;Seo Ji-Hyung;Kim Jeong-Hoon;Kim Kwang-Soo;Jeong Yong-Jin
    • Food Science and Preservation
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    • v.13 no.1
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    • pp.71-76
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    • 2006
  • We monitored the characteristics of soybean hydrolysate prepared under various hydrolysis condition using response surface methodology. The yield was affected by protease content but 1be effect of hydrolysis time to yield gradually increased at over $0.4\%$ of protease, while the $R^2$ of polynomial equation was 0.978 (p<0.01). The soluble solid enlarged by increase of both variables and the $R^2$ of polynomial equation was 0.954 (p<0.01). The degree of hydrolysis was affected by protease content at low (under $0.4\%$) protease and maximized at $0.57\%$ protease and 5.49 hrs. The $R^2$ of polynomial equation for the degree of hydrolysis was 0.916 (P<0.05). The calcium intolerance capacity showed similar pattern like yield but the effect of hydrolysis time was rapidly increased at over $0.4\%$ protease. The $R^2$ of polynomial equation for calcium intolerance capacity was 0.932 (p<0.05). The total phenolic compounds increased in proportion to protease content and hydrolysis time, while the $R^2$ of polynomial equation was 0.920 (p<0.05). According to the results of this study, the optimal conditions for soybean hydrolysis were predicted to be $0.51\~0.66\%$ of protease and $6.5\~9.0\;hrs$, and the predicted values and actual values of each response variable were similar to each other when the hydrolysis was performed at a random point within the optimal range.

A Study on the Biodegradable Properties of Polyesters associated with their Chemical Structures (폴리에스테르의 화학적 구조에 따른 생분해 거동에 관한 연구)

  • Woo, Je-Wan;Sohn, Myung-Ho;Cha, Hye-Young;Park, Yang-Sung;Chang, Kil Sang;Whang, Young-ae;Park, Sang-Soon
    • Clean Technology
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    • v.8 no.4
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    • pp.223-228
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    • 2002
  • The biodegradable Properties of various polyester resins with different chemical structures have been studied by applying the controlled compost test and soil burial test. Celluose was taken as a fully biodegradable reference resin while PVC and PE were empolyed as non-biodegradable reference chains or ester group were rather easily degraded by hydrolase, meanwhile copolymer type polyesters which contain aromatic rings showed relatively low biodegradability. According to the results from controlled compost test, cellulose(the positive reference) showed 70.6% degradation after 45 days, whereas synthetic poly(butylene adipate-co-succinate), poly(butylene succinate), poly(butylene adipate-co-succinate-co-terephthalate) showed 44.0%, 32.0% and 23.4% degradation respectively. In this regard, it was concluded that biodegradable properties of polymers are largely dependant on the chemical structures constituting the polymers.

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Degradative Solidification/Stabilization of Liquid Waste Containing Chloroform and Methylene Chloride by Cement/Slag/Fe(II) Systems (Cement/Slag/Fe(II) 시스템에 의한 클로로포름과 메틸렌클로라이드 함유 액상폐기물의 분해성 고형화/안정화)

  • Seong, Joseph;An, Cheol-Hong;Choi, Won-Ho;Park, Joo-Yang
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.10
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    • pp.1034-1038
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    • 2008
  • Degradative Solidification/Stabilization(DS/S) is a modification of conventional Solidification/Stabilization(S/S) that incorporates degradative processes for organic contaminant destruction with the low cost of conventional S/S. Inorganic contaminants are immobilized and chlorinated organic contaminants are destroyed by DS/S treatment. In this study, a DS/S using cement/slag/Fe(II) systems as binder was investigated to assess its effectiveness in degrading chloroform(CF) and methylene chloride(MC) contained in hazardous liquid wastes. The initial concentration of CF was 0.26 mM, 1.0 mM, 8.4 mM, 25 mM and 42 mM and Fe(II) was 200 mM. The result showed that degradation of CF in various concentration was in one kind reaction as pseudo-first-order and 95% of 0.26 mM initial concentration of CF was removed in five days. 50 mg/L of heavy metal was added in order to accelerate the rate of degradation of MC and initial concentration of MC was 3.50 mM however, degradation did not occur in system. Thus additional studies needed for degradation of MC and more studies on other reaction pathways products will help elucidate reaction mechanisms and pathways for chlorinated methanes in cement/slag/Fe(II) systems.