• Journal of the Korean Society of Safety
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• v.6 no.3
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• pp.27-34
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• 1991

This paper is for the properties of the oxidation-proof of the partially discharged and of the molecular motion on chlorinated PE Film. this paper also shows the properties of the molecular motion of the ${\gamma}$ ray irradiated PE Film. 1 In the surface of the PE Film enforce chlorination, C-Cl be distributed up to 10 $\mu$m deep. 2. In according to the development of the chlorination, the measure of crystalization decreased and cross link occured. 3. Chlorination PE Film control the oxidation on ozone to occuratlon by partial discharge and it lost bonding chlorine. 4. in according to chlorination, ${\gamma}$ absorption in motion of CH2 main chain of PE drcreased by chlorine stbstitution.

• Journal of the Korean Chemical Society
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• v.19 no.3
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• pp.149-155
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• 1975

Pivalic acid, which has a globular shape and is a plastic crystal, has been examined by means of temperature-dependent with-line proton magnetic resonance spectroscopy. Results of temperature-dependent line width, second moment, and spin-lattice relaxation time studies of pivalic acid were interpreted in terms of dynamic behavior and hydrogen bonding. The dynamic behavior consists of superimposed reorientation of the methyl groups about their three-fold axes$(C_3) and of the molecule about the central C-C bond(C_3'),$ general molecular reorientation about the center of gravity, and molecular self-diffusion. Activation energies for the motional processes have been obtained from line width measurements using the modified Bloembergen, Purcell, and Pound theory and from spin-lattice relaxation time measurements. The results were compared with the Pople-Karasz theory of fusion and the agreement was found to be poor. The discrepancy was interpreted in terms of hydrogen bonding in this molecule.

• Proceedings of the Korea Water Resources Association Conference
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• 2020.06a
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• pp.89-89
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• 2020

본 연구에서는 GPU 가속화 기반의 Boussinesq 모형인 Celeris Advecnt에 수심 적분된 2차원 이송-확산방정식을 추가하여 인터렉티브 시스템 기반의 추적자 이동 모형을 개발하였다. Celeris Advent는 최초로 개발된 인터렉티브 시스템을 갖춘 Boussinesq 모형으로, 시뮬레이션 중에 사용자가 모형의 파라미터뿐 아니라 모델 도메인 내 수위 및 수심을 바꿀 수 있다. 이를 통해 사용자는 모의가 진행되는 도중에 모델의 안정성 및 효율성을 위해 시간 간격을 조정할 수 있을 뿐 아니라 방파제 설치 등과 같은 지형 변화를 고려하기 위해 도메인 내 격자별 수심을 조정할 수 있다. 본 연구에서는 연안에서의 추적자 이동 모의를 위해 Boussinesq 방정식과 더불어 이송-확산방정식을 풀이하는 추적자 이동 모형을 개발하였다. 추적자의 확산항의 경우 분자 자체의 확산과 더불어 쇄파에 따른 난류 확산을 고려하였다. 난류 확산계수는 슈미트 수를 1로 두어 와동점성계수와 동일하게 두었으며, 와동점성은 단순화된 형태의 쇄파모형을 고려하여 계산하였다. 쇄파모형의 고려로 인해 이송-확산방정식과 더불어 운동량 방정식에서도 쇄파에 따른 운동량 소산이 고려되었다. 마지막으로, 추적자 농도에 대한 인터렉티브 시스템을 추가하여, 모델 구동 중에도 사용자가 수심적분된 추적자 농도를 조정할 수 있도록 하였다. 기수행된 2개의 수리실험 조건과 관측값을 이용하여 벤치마크 테스트를 수행하였으며, 관측값과 대체로 일치하는 것을 확인하였다.

• Journal of The Korean Association For Science Education
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• v.22 no.1
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• pp.93-101
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• 2002

This study investigated the effect of small group discussion for science concept learning in cooperative learning environments that encourage verbal interaction with peers upon students' understanding of the concepts at the particulate level, application abilities, perceptions of students' negotiation, and communication apprehension. Two classes of 7th grade at a coed middle school were assigned to the control and the treatment groups. They were taught about change of states and motion of molecules for 7 class periods. Two-way ANCOVA results revealed that the scores of a conceptions test for the treatment group were significantly higher than those for the control group, and that the low-achievers in the treatment group performed better than those in the control group. However, the scores of two groups did not differ significantly in an application test. The perceptions of students' negotiation for the treatment group were more positive, but the scores of the communication apprehension for two groups were not significantly different.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.349-349
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• 2011

인공관절은 노인성 질환이나 자가 면역질환, 신체적인 외상 등으로 인하여 발생하는 관절의 손상 부위를 대체하기 위해 고안된 관절의 인공 대용물이다. 인공 관절 중 인공 고관절의 경우 관절 운동을 하는 라이너(Liner)와 헤드(Head) 부분이 인공관절의 수명을 결정하게 되는데, 헤드 부분에 메탈소재와 라이너 부분에 고분자 소재를 사용하는 MOP(metal on polymer) 구조의 인공관절은 충격흡수의 장점이 있는 반면 wear debris에 의한 골용해로 인하여 관절이 느슨해지는 문제점이 발생하여 재 시술의 주요 원인이 되고 있다. 현재 인공관절의 수명을 늘리기 위해 DLC, ZrO, TiN 등의 높은 경도 값을 갖는 박막을 금속헤드 위에 증착하여 상대재인 인공관절용 고분자 소재의 마모량을 줄이고자 하는 연구가 활발하게 진행되고 있다. 따라서 본 연구에서는 PIII&D(Plasma Immersion Ion Implantation & Deposition)공정을 이용하여 Co-Cr-Mo 합금 소재에 질소 이온을 주입 한 후 NbN 박막을 증착하여 상대재인 초고분자량 폴리에틸렌(UHMWPE)의 마모량을 줄이고자 하였다. NbN 박막의 특성을 평가하기 위해 XRD, XPS, AFM 등의 분석을 수행하였으며, 상대재인 초고분자량 폴리에틸렌의 마모량을 측정하기 위해 Pin-on-disk tribometer를 이용하여 마모 실험을 진행하였다. 마모 실험 결과, NbN 박막을 단순 증착한 경우, 현재 인공관절용 헤드(Head) 소재로 가장 널리 사용되고 있는 Co-Cr-Mo 합금에 비하여, 상대재인 초고분자량 폴리에틸렌의 마모량을 약 20% 감소시키는 것을 알 수 있었다. 또한, Co-Cr-Mo 합금 소재에 질소 이온주입을 하여 표면을 개질한 후, NbN 박막을 증착한 경우, 마모량이 최대 50%까지 감소하는 것을 확인할 수 있었다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.12
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• pp.1035-1042
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• 2014

Reducing the friction of engine parts is an important issue in engine design. The loss of energy in the piston assembly due to mechanical friction ranges from 40 to 55%, and there is an increase in the total energy of about 5% if the friction of the piston can be removed. In order to reduce the friction loss at the level of each engine part, it is necessary to perform a comparative analysis with other engines to determine the important factors affecting the energy loss. Several studies have been performed to analyze the lubrication based on hydrodynamic modeling, since a piston lubrication system has dimensions in the nanoscale to microscale domain. Therefore, it is necessary to determine the correlations between the molecular and continuum systems. In this study, we investigated the friction changes due to the various interactions between molecules in the wall/fluid interface, where a microscopic movement of the oil film occurs along the cylinder liner of the engine.

• Journal of Nutrition and Health
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• v.48 no.2
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• pp.133-139
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• 2015

Purpose: There is a fair amount of evidence indicating that increased risk of obesity and insulin resistance is associated with postmenopausal state, but can be modulated by diet and exercise. In this study, we explored whether a Pueraria lobata root-based supplement containing Rehmannia glutinosa (PR) and/or aerobic treadmill exercise can modify the metabolic changes associated with estrogen deficiency. Methods: Seventy rats were randomly assigned to the following groups for 8 weeks (n=10 per group): SHAM, sham-operated; PR0, ovariectomized (OVX) control; PR200, OVX with PR200 mg/kg B.W; PR400, OVX with PR400 mg/kg B.W; EPR0, OVX with exercise; EPR200, OVX with exercise and PR200 mg/kg B.W; EPR400, OVX with exercise and PR400 mg/kg B.W. Results: OVX induced significant increases in body weight, food intake, fat mass, LDL-cholesterol, and fasting blood glucose, confirming induction of menopausal symptoms. PR supplementation or exercise significantly suppressed the above mentioned changes through different regulatory elements in adipose tissue: PR supplement upregulated adiponectin gene expression and aerobic exercise upregulated adiponectin and insulin receptor gene expression and a combination of PR supplement and aerobic exercise showed an additive effect on adiponectin gene expression. Conclusion: Taken together, the results of this study suggest that PR supplement has a potential to provide health benefits in OVX rats through leptin and adiponectin secretion. In addition, the data suggest that combination of exercise and PR would have additive effects on metabolic dysfunction associated with estrogen deficiency.

• Journal of the Korean Chemical Society
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• v.21 no.5
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• pp.339-352
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• 1977

The authors' theory developed in the preceding Paper 1 was applied to plastic deformation of ceramics, metals, alloys and single crystals. For polycrystalline substances, the flow mechanisms due to dislocation movement and grain boundary movement appear together or separately according to the experimental conditions whereas for single crystals, only the mechanism of dislocation movement appears. The parameters appearing in the flow equations $({\alpha}_{d1},\;1/{\beta}_{d1})and\;({\alpha}_{gj}/X_{gj},\;1/{\beta}_{gj})$ (j = 1 or 2), and the activation enthalpies ${\Delta}H_{k1}^{\neq}$ (k = d or g) were determined and tabulated. Here, the subscript d1 indicates the first kind of dislocation flow units and gj expresses the jth kind of grain boundary flow units. The predictions of the theory were compared with experiment with good agreement. Concerning the activation enthalpies, it was found that ${\Delta}H_{d1}^{\neq}$ 〉{\Delta}H_{g1}^{\neq}$ and that the former agrees with the activation enthalpy for bulk self-diffusion whereas the latter agrees with the activation enthalpy for grain boundary self-diffusion. These facts support the adequacy of the authors' theory which is considered as a generalized theory of plastic deformation.

• Advances in pediatric surgery
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• v.8 no.1
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• pp.41-47
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• 2002

Abnormal distribution of the enteric nerves such as adrenergic, cholinergic and peptidergic nerves may cause the functional obstruction in Hirschsprung's disease (HD). Although the sustained contraction of the aganglionic segment is the main pathophysiology of HD, the etiology and pathogenesis is not thoroughly understood, With the recent progress of molecular biology and genetics,a more detailed approach to the pathogenesis of the HD can be undertaken. In this review, the roles of the nitric oxide, nitric oxide synthase and interstitial cells of Cajal on smooth muscle relaxation, the effects of extracellular matrix, cell adhesion molecules, neurotrophic factors on the migration and maturation of the neural crest cells are described. In the section of genetic factors, familial occurrences, association of chromosomal abnormalities, RET gene, glial cell line-derived neurotrophic factor gene, endothelin-3 gene and endothelin-B receptor gene and their r elationships to HD is briefly reviewed.

• The Korean Journal of Pharmacology
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• v.29 no.1
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• pp.157-163
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• 1993

Intramolecular excimer formation with the fluorescent probe 1,3-di(1-pyrenyl)propane (Py-3-Py) was used to investigate the effects of methanol, ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, 1-heptanol, 1-octanol, 1-nonanol and 1-decanol on the lateral diffusion of synaptosomal plasma membrane vesicles isolated from bovine cerebral cortex (SPMV). The n-alkanols increased the excimer to monomer fluorescence intensity ratio (I'/I) of Py-3-Py in the SPMV. In a dose-dependent manner, n-alkanols increased lateral diffusion of hydrocarbon region of bulk (inner+outer monolayers) SPMV lipid bilayers, and the potencies of n-alkanols up to l-nonanol increased with carbon chain length. It appears that the potencies in bilayer fluidization due to the lateral diffusion increase by 1 order of magnitude as the carbon chain length increases by two carbon atoms. The cut-off phenomenon was reached at 1-decanol, where further increase in hydrocarbon length resulted in a decrease in pharmacological activity.