• Title/Summary/Keyword: 분자선

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Transient State Theory of Significant Liquid Structure applied to Water (액체구조에 관한 천이상태이론의 물에 대한 적용)

  • Pak, Hyung-Suk;Chang, Sei-Hun
    • Journal of the Korean Chemical Society
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    • v.10 no.2
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    • pp.91-97
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    • 1966
  • The partition function for liquid water is developed according to the transient state theory of significant liquid structure proposed by Pak, Ahn and Chang. This theory assumes that the molecules may possess solid-like, transient and gas-like degrees of freedom in liquid state. Although liquid water has several special properties, for example, minimum molar volume at 4^{\circ}C$, the general theory of liquid can be applied successfully. The theoretically calculated values for thermodynamic properties at the liquid temperature range and for the critical properties are in good agreement with the observed values.

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Combustion Characteristics of HTPB/AP/Zr Propellant (HTPB/AP/Zr 추진제의 연소 특성)

  • Min Byoung-Sun;Hyun Hyung-Soo;Yim Yoo-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • v.y2005m4
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    • pp.61-65
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    • 2005
  • In HTPB/AP propellants, zirconium(Zr) addition to formulation was shown to be less specific impulse than aluminum(Al) by the theoretical calculation because of the lower flame temperature and higher molecular weight of Zr oxide. It was found that the burning rate was faster with the finer size of Zr and the more content of $2{\mu}m$ Zr the faster burning rate is in HTPB/AP/Zr propellants caused by the more conduction energy transfer from Zr flame to the burning surface. Also the burning rate of HTPB/AP/Zr propellant could be reduced by addition of 150nm Al, depending on AP size distribution in formulation with Butacene and $1{\mu}m$ AP.

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Development of Multiscale Simulation Technique for Multiphase Fluid System (다상 유체 시스템의 다중 스케일 시뮬레이션 기법에 관한 연구)

  • Han, Min-Sub
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.6
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    • pp.569-577
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    • 2010
  • A multiscale particle simulation technique that can be applied to a multiphase fluid system has been developed. In the boundary region where the macroscopic- and microscopic-scale models overlap each other, three distinctive features are introduced in the simulation. First, a wall is set up between the gas and liquid phases to separate them and match the phases respectively to the macroscopic conditions stably. Secondly, the interfacial profile is obtained near the matching region and the wall translates and rotates to accommodate the change in the liquid-vapor interfacial position in the molecular model. The contact angle thus obtained can be sent to the macroscopic model. Finally, a state of mass and temperature in the region is maintained by inserting and deleting the particles. Good matching results are observed in the cases of the complete and partial wetting fluid systems.

Measurement of the Ar Recovery Time of a Cryopump and Analysis on the Ar Instability (크라이오펌프 알곤 회복시간 측정과 알곤 불안정성 분석)

  • In, Sang Ryul;Lee, Dong Ju
    • Journal of the Korean Vacuum Society
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    • v.22 no.5
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    • pp.225-230
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    • 2013
  • Cryopump removes gas molecules by condensation and adsorption. Therefore, cryo-surface temperature and corresponding vapor pressure influence directly the pumping performance. If the surface temperature of any part is neither low nor high, there occurs the desorption of gas molecules condensed or adsorbed, and the emitted molecules can be captured again, which leads to a time-consuming and fluctuating change of the pressure. Though every gas can show such a pressure instability at a specified temperature range, the instability generated in a sputter system using Ar as a working gas and operating with a cryopump is especially undesirable. In this paper the cause of the argon instability is analyzed and corrective is provided through the measurement of the Ar recovery time.

Synthesis and Characterization of Intercalation Compounds of Alkylsulfonate into Hydrated and Dehydrated Zinc (수화된 아연과 탈수된 아연에 알킬술폰이 층간 삽입된 화합물의 합성과 구조)

  • Huh, Young Duk;Park, Sung Hun;Jun, Tae Hyun;Park, Yong Jun;Park, Yang Sun
    • Analytical Science and Technology
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    • v.13 no.3
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    • pp.338-345
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    • 2000
  • The intercalated compounds of alkylsulfonate into hydrated and dehydrated zinc were synthesized. From the XRD, FT-IR, TGA, elemental analysis data, and the molecular size, the orientation of the intercalated alkylsulfonates was determined. For the hydrated compounds, alkylsulfonates were intercalated into hexaqua zinc layer with the bilayer structure of $32.9^{\circ}$ angle of inclination. For the dehydrated compounds, alkylsulfonates were directly bonded to zinc ion with the bilayer structure of $51.4^{\circ}$ angle of inclination.

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Sturdy of analysis of Xanthan gum as watersoluble-polymer in cosmetics (화장품 중 수용성 고분자인 Xanthan gum 분석연구)

  • Lee, Yong-Hwa;Yang, Jae-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.4
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    • pp.664-671
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    • 2013
  • Determination of xanthan gum as watersoluble-polymer in commercial cosmetic samples was carried out by High Perfomance Liquid Chromatography(HPLC). An $C_{18}$ reversed-phase column and the selected ELSD detector was applied. The 25mM ammonium acetate/acetonitrile was used for the mobile phase of gradient conditions. The analysis results of HPLC showed good linearity with correlation coefficient of $r^2=0.9993$ in the rage of $50.3{\sim}604.1{\mu}g/ml$ and detection limit of $12.0{\mu}g/ml$.

A MOLECULAR BIOLOGICAL STUDY ON THE EXPRESSION PATTERN AND FUNCTIONAL PROTEIN STRUCTURES OF PROLINE-RICH PROTEINS IN HUMAN SALIVARY GLANDS (사람의 타액선에서 proline-rich protein의 발현양상과 기능적 단백 구조에 대한 분자생물학적 연구)

  • Joo, Jae-Yong;Lee, Suk-Keun;Park, Young-Wook
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.28 no.1
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    • pp.31-41
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    • 2002
  • Proline-rich proteins (PRPs) are major components of human saliva. In order to know the biological roles of PRPs, we explored the expression pattern and functional protein structures of PRPs by the immunohistochemical and various molecular biological methods. Polyclonal antibody against human gPRP was generated from rabbit by the injection of oral exfoliated cells specially treated by urea and SDS buffer. The PRPs began to be expressed both in the acinar cells and ductal cells from the EIDS (Early Intermediate Developmental Stage) of fetal salivary glands and became intense in the salivary epithelium in the LDS (Late Developmental Stage) and adult salivary glands. The polyclonal antibody against the gPRP showed the cross-reactivity with aPRP and bPRP, these results were relevant to the high homology among subtypes of PRP. However, the simulated protein structures of PRPs showed the characteristic repetitive whorling domains except the N-terminal signal peptide. The whorling domains were also contained the multiple amino acids of glutamine and glycine, which may provide the receptor binding or cross-linking sites of PRPs.

Biochemical Characteristics of Spodoptera exigua Nuclear Polyhedrosis Virus (파밤나방 핵다각체병 바이러스의 생화학적 특성)

  • 진병래;박범석;재연호;강석권
    • Korean journal of applied entomology
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    • v.30 no.2
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    • pp.144-149
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    • 1991
  • Biochemical characteristics of Spodoptera uigua nuclear polyhedrosis virus (SeNPV) isolated in Jinju were studied. SeNPV contained a number of nucleocapsids within a viral envelope embeded in polyhedra. The polyhedral protein of SeNPV was composed of a single polypeptide with a M. W. of 30kd. Double-immunodiffusion test showed that the polyhedral protein of SeNPV had common antigenic determinants with SINPV and BmNPV. Virion proteins of SeNPV were resolved into 49 polypeptides by silver staining after SDS-PAGE. The approximate genome size of SeNPV by restriction endonuclease analysis was 1l0kb.

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OBSERVATIONS OF THERMAL TRANSITIONS OF SiO TOWARD THE SGR A MOLECULAR CLOUD (Sgr A 분자운의 열적 SiO 천이선 관측연구)

  • MINH Y. C.;ROH D.-G.;KIM S. J.;OHISHI M.
    • Publications of The Korean Astronomical Society
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    • v.16 no.1
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    • pp.15-20
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    • 2001
  • We observed the thermal transitions of SiO (J=I-0, 2-1) and $^{29}SiO$ (J=l-O) toward the Sgr A molecular clouds. The distribution and the velocity structure of SiO are very similar to previous results for 'quiet' interstellar molecules. We think· that the SiO has been well mixed with other molecules such as $H_2$ which may indicate that the formation of Sgr A molecular clouds was affected by the activities, such as shock waves or energetic photons, from the Galactic center in large scales. The total column density of SiO is about $4.1\times10^{14} cm^{-2}$ and the fractional abundance $SiO/H_2$ appears to be about 10 times larger than those of other clouds in the central region of our galaxy. The derived values are thought to be lower limits since the optical depths of the observed SiO lines are not very thin. The formation of SiO has been known to be critically related to shocks, and our results provide informative data on the environment of our Galactic center.

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A Study on the Polymerization of $\varepsilon$-Caprolactame in [RCOOH]-Montmorillonite Intercalations-Complex ([RCOOH]-Montmorillonite 층간화합물내에서의 $\varepsilon$-Caprolactame의 고분자화반응에 관한 연구)

  • 조성준
    • Journal of the Korean Ceramic Society
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    • v.36 no.2
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    • pp.151-158
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    • 1999
  • $\varepsilon$-Caprolactame as organic monomer was intercalated in the interlayer space of montmorillonite and polymerized by polymerization reaction so that the inorganic polymer and organic polymer could be combined each other by chemical bonding. The results of X-ray and IR analysis showed that the polymerization reaction of $\varepsilon$-caprolactame between the interlayer spaces has been performed sucessfully. In order to study polymeric reaction product in detail we have isolated the polymerized material from the interlayer space and analyzed it by X-ray diffractometer and IR-Spectrocopy. The comparison of these results with them of the analyses for thee pure polymer which has been synthesized by polymeric reaction of $\varepsilon$-carolactame without montmorillonite showed that the obtained both polymeric materials are the same compounds.

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