• Title/Summary/Keyword: 분자선

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Effect of N2 flow rate on growth and photoluminescence properties of GaN nanorods grown by using molecular beam epitaxy (분자선 에피택시를 이용하여 GaN 나노로드를 성장시 구조 및 광학적인 특성에 미치는 N2의 양의 효과)

  • Park, Y.S.
    • Journal of the Korean Vacuum Society
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    • v.16 no.4
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    • pp.298-304
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    • 2007
  • We have studied the effect of $N_2$ flow rate on the structural and optical properties of GaN nanorods grown on (111) Si substrates by radio-frequency plasma-assisted molecular-beam epitaxy. The hexagonal shape nanorods with lateral diameters from 80 to 190 nm with increasing $N_2$ flow rate from 1.1 to 2.0 sccm are obtained. However, the ratio of length (thickness) and compact region increases with increasing $N_2$ flow rate up to 1.7 sccm and then saturate. From the photoluminescence, free exciton transition is clearly observed for GaN nanorods with low $N_2$ flow rate. And the PL peak energies are blue-shifted with decreasing diameter of the GaN nanorods due to size effect. Temperature-dependent photoluminescence spectra for the nanorods with $N_2$ flow rate of 1.7 sccm show an abnormal behavior like "S-shape" with increasing temperature.

Effects of Gamma Irradiation on Color Changes and Biological Activities of Ethanol Extract of a Mechanically Pressed Juice of Bokbunja (Rubus coreanus Miq.) (감마선 조사에 의한 복분자 착즙액 에탄올 추출물의 색상 및 생리활성 변화)

  • Kim, Hee-Jung;Jo, Cheor-Un;Kim, Hyun-Joo;Shin, Dong-Hwa;Son, Jun-Ho;Byun, Myung-Woo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.3
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    • pp.271-277
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    • 2006
  • A mechanically pressed juice of Bokbunja (Rubus coreanus Miq.) extract was prepared using 70% ethanol solution. The extract was subjected to gamma-irradiation treatment (20 kGy) and investigated for its change of color and biological activities. Hunter $L^*$ values of the irradiated Bokbunja extract were increased in comparison with the non-irradiated extracts, and the $a^*\;and\;b^*$values decreased by the irradiation treatment. The content of the total phenolic compounds in the non-irradiated and irradiated extracts were 58.4 and 56.5 mg/g, respectively. The 1,1-diphenyl-2-picrylhydrazyl(DPPH) radical scavenging activities of non-irradiated and irradiated extracts at a 250 ppm level were 80% and 79%, respectively. Lipid oxidation was retarded by addition of Bokbunja powder. Nitrite scavenging activity was the highest in the Bokbunja powder at pH 1.2 and the effect was not changed by irradiation. The Bokbunja powder showed antimicrobial activity against Salmonella Typhimurium and Bacillus cereus. However, irradiation of Bokbunja did not affect any physiological functions (p>0.05). A Salmonella mutagenicity assay indicated that the irradiated Bokbunja extract did not show any mutagenicity. Therefore, Bokbunja extract could be used in various applications as a functional material, such as ingredients of food and cosmetic, compositions with functions.

"Dust, Ice and Gas In Time" (DIGIT): Embedded Objects

  • Lee, Jeong-Eun;DIGIT team, DIGIT team
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.1
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    • pp.81.1-81.1
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    • 2012
  • Herschel Key Program 중의 하나인 "Dust, Ice and Gas In Time (DIGIT)"의 관측 및 분석결과를 발표하고자 한다. 특히 DIGIT 천체들 중 Photodetector Array Camera and Spectrometer (PACS)로 관측된 별생성 초기 단계에 있는 embedded objects들의 FIR SED와 CO, $H_2O$, OH, [OI], [CII]의 FIR 천이선들의 공간분포와 생성기작을 분석한다. 뿐만 아니라, 원시성의 특성들($L_{bol}$$T_{bol}$)과 이들 각 분자/원자선에 의한 냉각률의 관계를 통계적으로 분석한 결과를 제시한다.

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미터표준원기급 옥소안정화 헤륨 네온 레이저 개발

  • 강선모;강선모;원종옥
    • Proceedings of the Optical Society of Korea Conference
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    • 1988.06a
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    • pp.98-103
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    • 1988
  • 1983년 10월에 개최된 제 17차 국제도량형 총회에서 '미터는 비칭 진공속에서 299 792 458분의 1초동안 진행한 경로의 길이이다.'로 정의 됨에 따라서 미터의 현장장비인 분자의 초미세 구조 흡수선에 주파수 안정화한 레이저의 광주파수 및 진공파장이 표준선으로 추천되었다. (1) 본 연구에서는 이들 주파수 안정화 레이저 중 하나인 옥소안정화 헬륨 네온 레이저 (파장 633㎚)를 개발하고 이에 대한 연구의 결과를 기술하였다.

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The Crystal Structure of Thiourea of Derivatives(I) (Thiourea Deirvatives의 결정과 분자구조 (제1보))

  • Park Young Ja;Suh Chung Sun;Koo, Chung Hoe
    • Journal of the Korean Chemical Society
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    • v.21 no.5
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    • pp.307-319
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    • 1977
  • The crystal structure of $N-({\alpha}-dimethyl\;{\beta}-hydroxy)ethyl\;N'-cyclohexyl\;thiourea,\;C_{ll}H_{22}N_2OS)$, has been determined by X-ray diffraction method. The compound crystallizes in the orthorhombic space group Pbca with a = 10.33(3), b = 11.82(3), c = 22.57(4)${\AA}$ and Z = 8. A total of 1414 observed reflections collected by the Weissenberg photographs and was solved by heavy atom method and refined by block diagonal least-squares methods to the R value of 0.13. The cyclohexane ring has a normal chair conformation and the thiourea unit is planar. The primary alcoholic group O-H bonded to C(l) makes an intramolecular hydrogen bond with N(2), which leads to stablize the molecule. There are two independent hydrogen bonds in the structure. One of them is of the type N-H${\cdot}{\cdot}{\cdot}$O intramolecular hydrogen bond with the length 2.71${\AA}$, another is of the type O-H${\cdot}{\cdot}{\cdot}$S intermolecular hydrogen bond with the length 3.21${\AA}$ parallel to the b axis. Apart from the hydrogen bonding system the molecules are held together by van der Waals forces in the crystal.

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Graft Polymerization of Acrylic Acid onto nylon 6

  • Park, Jae ho;Lee, Chong-Kwang
    • Nuclear Engineering and Technology
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    • v.8 no.3
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    • pp.159-168
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    • 1976
  • Acrylic acid has been grafted onto nylon fabric with ceric salts and ${\gamma}$-rays from Co-60 as initiators. The distribution of molecular weight of the grafted polyacrylic acid has been determined and it was found that the ratio of weight-average and number-average molecular weight was higher in room temp. than in low temp. (-184$^{\circ}C$). The weight-average molecular weight of the polyacrylic acid was calculated from viscosity measurements in sodium hydroxide solution. The factors affecting graft polymerization of acrylic acid onto nylon were examined. A possible mechanism that the oxidation of nylon probably takes place at the methylene group attached to nitrogen to give a free-radical was discussed.

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Model and Experimental Isotherms of Soluble Proteins at Water Surfaces (수용성 단백질의 계면상 등온곡선의 모델과 실험적 규명)

  • Sung Hyun Kwon;Daechul Cho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.4 no.3
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    • pp.230-235
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    • 2003
  • 수용성, 구형의 단백질 분자는 기능성(효소, 유화제, 중화제 등)에 따라 센서나 유사생체기관에 응용성이 크다. 본 연구는 물-공기 계면에서 형성되는 단백질의 표면상태방정식(일명 표면등온선)을 이론적으로 도출하고 그 결과를 실험적으로 확인하여 단백질 분자의 기능적 이용에 활용하고자 한 것이다. 아미노산 부분사슬간, 분자와 물과의 인력, 정전기적 인력을 고려하여 종합적 상태방정식을 도출하였으며 탄소 14로 tagging한 albumin실험과 비교하여 상당히 일치하는 경향을 확인할 수 있었다.

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Structure of Cholesteryl Hemisuccinate (Cholesteryl Hemisuccinate의 구조)

  • Park, Young-Ja
    • Korean Journal of Crystallography
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    • v.15 no.1
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    • pp.29-34
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    • 2004
  • The crystal structure of cholesteryl hemisuccinate ($C_{31}H_{50}O_4$) was investigated by X-ray diffraction method. The cholesterol fragment of the title compound were in good agreement with those for related cholesterol derivatives. The unit cell contains four cholesteryl hemisuccinate molecules that are not related by crystal symmetry and have their tetracyclic system almost parellel to each other. There are two pairs of hydrogen-bonded dimer between A and D molecules and B and C molecules. These two hydrogen-bonded dimers are parallel to the c-axis, and are closely packed.

A Study on Crack-Prevention of Pinus Rigida during Drying by Suction Treatment of Polyetylene Grycogen (PEG흡입처리에 의한 Rigida 소나무의 건조균열방지에 관한 연구)

  • Yu, Hyo-Seon;Jeong, Se-Hui
    • Korean Journal of Materials Research
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    • v.7 no.1
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    • pp.15-20
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    • 1997
  • 목재의 건조 균열방지를 위한 진공흡입기술의 새로운 목재처리방법에 대해 연구를 수행하였다. 목재의 건조균열 방지를 위해 사용된 ployetylene grycogen(PEG) 처리재들은 PEG-1540, PEG-2000, PEG-4000, PEG-10000이었으며, 진공펌프의 감압정도는 85kPa과 39kPa 이었다. 시험결과, 진공흡입처리에 의한 PEG액의 흡입은 방사단면에 걸쳐 고르게 이루워졌음을 확인 할 수 있었다. 또한 PEG의 분자량이 증가할수록 단위시간당 PEG의 분자량이 증가할수록 단위시간당 PEG의 흡입량과 처리전.후의 함수률의 차인$\Delta$ M.C 는 PEG-2000을 변곡점으로 하여 감소하였다. 그리고 리기다 소나무의 건조균열 방지를 위한 약제 흡입처리에 있어 최적의 PEG 분자량과 농도 그리고 감압력의 조건은 각각 PEG-2000과 30%(wt.)그리고 85kPa임을 알 수 있었다.

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Separation of Colloidal Particles by Holow Fiber Flow Field Flow Fractionation Using Osmotic Sink (삼투압을 이용한 중공사막 흐름장 흐름 분획법에 의한 콜로이드 입자의 분리)

  • 신세종;이원주;전용한;이경현;민병렬
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.110-112
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    • 1998
  • 1. 서론 : 분석화학의 중요한 과제중 하나 고효율(high efficiency)과 고해상도(high resolution)를 가지고서 혼합물에서 분자나 입자의 분리능을 개선하는 것과 낮은 수준의 농도에서 이런 분획들(fractions)을 정량화 하는 것이다. 현재의 추세는 분리하고자 하는 분자의 상한선을 증가시키는 것이 순수과학과 산업에서 중요하게 되었다. 이런 분리 기술의 응용은 거대분자(macromolecules)와 입자들(particles)인 cell fragments, plasmides, chromosomes, liposomes, synthetic polymers 등에 적용되고 있는데, 고전적인 분석방법으로는 한외여과, 원심분리, 크기배제 크로마토그래피 등이 있지만 시간이 걸리고 해상도와 효율에 제한이 있다.

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