• Elastomers and Composites
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• v.35 no.2
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• pp.149-156
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• 2000

trans-octylene rubber(TOR) was melt-blended with an incompatible NBR/EPDM (70/30) blend. Mixing torque and temperature were reduced as TOR was added to the NBR/EPDM blend. Rheometer results indicated that TOR participated in vulcanization and became a part of network. A scanning electron micrograph demonstrated that EPDM was dispersed in NBR matrix in the blend and the addition of TOR led to a finer dispersion of EPDM particles. On the addition of TOR, the tensile strength, the tensile strain as well as the modulus of the blend vulcanizates increased. The ozone resistance of the blends determined in terms of critical stress-strain parameter was significantly enhanced in the blend as TOR was added. Improvements in the properties were believed to be associated with fine morphology and the increase in crosslink density due to the chain entanglement of the ternary blends.

• Journal of the Korean Chemical Society
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• v.34 no.3
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• pp.267-279
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• 1990

The adsorption mechanisms of phenols on XAD-2 and XAD-7 resins were studied by using the distribution coefficient(log Kd) measured in the optimum adsorption conditions. It was observed that the Langmuir adsorption isotherm, indicating a molecular size-dependent adsorption, was appropriate for characterizing the adsorption behaviors of phenols on XAD-2 and XAD-7 resins. The adsorption energies of phenols on XAD resins were calculated by Lennard-Jones potential equation. In the calculation of the adsorption energy, the molecular radii and dipole moments of the resins and phenols were calculated by their van der Waals volumes and Debye equation, respectively. The stacking factor (F) were determined from the radio of the equilibrium distance to the stacking distance of molecules. In order to explain the adsorption energy calculated from the stacking factor it was compared with the adsorption enthalpy for each of phenols which was experimentally determined by batch adsorption shake method. It was observed that the adsorption enthalpy of phenolate ions on the XAD resins was likely to be more seriously affected by dispersion interaction than by a dipole or a charge interaction.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.32 no.6
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• pp.375-381
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• 2019

Structural health monitoring to determine structural conditions at an early stage and to efficiently manage the energy requirements of buildings using systems that collects relevant data, is under active investigation. Structural monitoring requires cutting-edge technology in which construction, sensing, and ICT technologies are combined. However, the scope of application is limited because expensive sensors and specialized technical skills are often required. In this study, a Raspberry Pi module, one of the most widely used single board computers, a Lora module that is capable of long-distance communication at low power, and a high-performance accelerometer are used to construct a wireless edge computing system that can monitor building response over an extended time period. In addition, the Raspberry Pi module utilizes an edge computing algorithm, and only meaningful data is obtained from the vast amount of acceleration data acquired in real-time. The raw data acquired using Wi-Fi communication are compared to the Laura data to evaluate the accuracy of the data obtained using the system.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.6 no.4
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• pp.389-396
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• 1994

We analyze existing time-dependent mild-slope equations, which were developed by Smith and Sprinks (1975) (or, equivalently, Radder and Dingemans (1985)) and Kubo et al. (1992), in terms of the dispersion relation and energy transport. One-dimensionally in the horizontal direction, we compare the modulation of wave amplitudes for the time-dependent mild-slope equations against the linear Scrodinger equation. In view of the dispersion relation and modulation of wave amplitudes, Smith and Sprinks' model is more accurate in shallower water (kh$\leq$0.2$\pi$) and satisfies the linear Scrodinger equation in very shallow water (kh>0.2$\pi$) and satisfies the linear Scrodinger equation at a point of intermediate water depth (kh=0.3$\pi$). In view of the energy transport, Kubo et al.'s model is more accurate but yields singular solutions at some higher frequency range.

• Membrane Journal
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• v.29 no.1
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• pp.61-65
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• 2019

Anisotropic particles have been issued in various fields due to their unique physical properties. Herein, a novel dynamic phase separation method (DPS) is introduced to fabricate anisotropic acorn-like nanoparticles. DPS consists of two dynamic conditions; solvent evaporation and nonsolvent induced precipitation. The bottom layer is controlled by feeding the water as a non-solvent diluent, and the phase separation of the upper layer relies on the diffusion and evaporation of a volatile good solvent. At this condition, the acorn-like particles were fabricated. Under a closed box filled with water (spontaneous phase separation), monodisperse polystyrene (PS) particles were synthesized. At the coexistence between DPS and spontaneous phase separation, the sizes of cap and particle were changed. Also, the volume of PS solutions influences on the particle shape. Since the unique structures could be utilized into various applications, if advanced techniques such as membrane-based controlled water feeding is developed, monodisperse acorn-like particles could be tuned.

• New Physics: Sae Mulli
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• v.68 no.11
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• pp.1183-1191
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• 2018

The plasmon behaviors in a superlattice of $GaAs/Al_xGa_{1-x}As$ multiple quantum wells with a half-parabolic confining potential due to different dielectric interfaces are studied under magnetic and electric fields perpendicular and parallel to the superlattice axis by using a previously published theoretical framework. From the density-density correlation functions by considering the intrasubband and the inter-subband transitions under the random phase approximation, we calculate the dispersion energies of the surface and the bulk states as functions of the composition of the multiple quantum well structure and of the magnetic field strength and the average electric field strength over the quantum well. The Raman intensities for various magnetic field strengths and average electric field strengths over the quantum well are also obtained as a function of the energy of the incoming light for these states.

• Korean Chemical Engineering Research
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• v.57 no.4
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• pp.512-518
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• 2019

To develop a membrane electrode assembly (MEA) with lower Pt loading and higher performance in proton exchange membrane fuel cells (PEMFCs), it is an important research issue to understand interfacial structure of Pt/C catalyst and ionomer and design the catalyst layer structure. In this study, we prepared short-side-chain Nafion-based ionomer dispersion using propylene glycol (PG) as a solvent instead of water which is commonly used as a solvent for commercially available ionomers. Cathode catalyst layers with different ionomer content from 20 to 35 wt% were prepared using the ionomer dispersion for the fabrication of four different MEAs, and their fuel cell performance was evaluated. As the ionomer content increased to 35 wt%, the performance of the prepared MEAs increased proportionally, unlike the commercially available water-based ionomer, which exhibited an optimum at about 25 wt%. Small size micelles and slow evaporation of PG in the ionomer dispersion were effective in proton transfer by inducing the formation of a uniformly structured catalyst layer, but the low oxygen permeability problem of the PG-based ionomer film should be resolved to improve the MEA performance.

• Korean Chemical Engineering Research
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• v.57 no.2
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• pp.244-252
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• 2019

This study investigated the effect of addition of aromatics such as Toluene/LCO/resin on the coke depression and asphaltene conversion. The experiment was carried out with vacuum residue as a feedstock with Molybdenum dispersed catalysts under the slurry-phase hydrocracking condition (Temp. of $425^{\circ}C$, $H_2$ pressure of 80 bar at $80^{\circ}C$, reaction time of 4 hr, Mo-concentration of 500 ppm). As results, the coke reduction was shown to be similar irrespective of types of aromatics, while asphaltene was more converted to gas and maltene when LCO and resin with higher dipole moment were added. The addition of aromatics with change of reaction time showed no difference in terms of depression of coke formation. But the addition of LCO rather increased the coke yield after 2 hr. And it was found that asphaltene in liquid phase had the higher aromaticity index so that asphaltene is difficult to disperse in oil phase.

• Geophysics and Geophysical Exploration
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• v.25 no.1
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• pp.14-25
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• 2022

The passive surface wave method measures seismic signals from ambient noises or vibrations of natural phenomena without using an artificial source. Since passive sources are usually in lower frequencies than artificial ones being able to ensure the information on deeper geological structures, the passive surface wave method can investigate deeper geological structures. In the passive method, frequency dispersion curves are obtained after data acquisition, and the dispersion curves are analyzed by assuming 1D-layered earth, which is like the method of active surface wave survey. However, when computing dispersion curves, the passive method first obtains and analyzes coherence curves of received signals from a set of receivers based on spatial autocorrelation. In this review, we explain how passive surface wave methods measure signals, and make data processing and interpretation, before analyzing field application cases.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.34 no.6
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• pp.266-274
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• 2022

In this study, a smoothing method was applied to improve the accuracy of peak wave period estimation using the water surface elevation observed from the Oceanographic and Meteorological Observation Tower located on the west coast of the Korean Peninsula. Validation of the application of the smoothing method was per- formed using variance of the surface elevation and total amount wave energy, and then the effect on the application of smoothing was analyzed. As a result of the analysis, the correlation coefficient between variance of the surface elevation and total amount wave energy was 0.9994, confirming that there was no problem in applying the method. Thereafter, as a result of reviewing the effect of smoothing, it was found to be reduced by about 4 times compared to the confidence interval of the existing estimated spectrum, confirming that the accuracy of the estimated peak wave period was improved. It was found that there was a statistically significant difference in proba- bility density between 4 and 6 seconds due to the smoothing application. In addition, for optimal smoothing, the appropriate number of smoothings according to the significant wave height range was calculated using a statistical technique, and the number of smoothings was found to increase due to the unstable spectral shape as the significant wave height decreased.