• Title/Summary/Keyword: 분산 에너지

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유연소재 천 기반의 슈퍼캐패시터 저장체의 전기화학적 성능 향상

  • Yun, Tae-Gwang;O, Min-Seop;Hu, Liangbing;Hyeon, Seung-Min;Han, Seung-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.697-698
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    • 2013
  • 최근에 유연한 성질을 갖는 전자기기들의 수요가 증가하면서, 그에 따라서 유연 전자기기를 뒷받침 해줄 수 있는 에너지 저장체의 유연한 성질도 중요성이 점점 부각되고 있으며 많은 연구가 진행되고 있다. 유연한 에너지 저장체의 많은 연구들이 유연한 금속 박막이나 특수 공정처리가 필요한 고분자를 이용하고 있으나, 대부분의 유연 에너지 소자들은 에너지 저장체의 성능에 비해 고온과 산 약품과 같은 환경이 필요하며, 비용과 시간이 많이 소모되고 있다. 그에 반해 섬유는 앞에서와 같이 특수 공정 처리가 따로 필요하지 않으며 상온에서도 손 쉽게 이용 가능하며, 신축성이 뛰어난 장점이 있기 때문에 효율적, 비용적으로 유연한 에너지 저장체에 유리한 소재이다. 몸에 해로운 산과 같은 약품처리의 필요도 없으며, 용매를 흡수하는 능력이 뛰어나기 때문에 용매를 이용한 도포 방법을 사용하면 다양한 물질을 폭넓게 적용 가능하다. 그리고 적용 분야에 맞춰서 섬유의 종류를 조절하면 다양한 성질을 갖는 천 기반의 에너지 저장체가 형성되며, 면 섬유가 수소 결합과 높은 반데르 발스 결합에 의해 탄소나노튜브와 결합하여 높은 에너지 밀도를 갖는 에너지 저장체를 형성하는 것을 분석한 논문들도 보고되고 있다. 면 섬유의 특수한 성질을 이용하여 에너지 저장체를 제작하고 이를 확인하기 위해서 일반 합성 섬유인 polyester와 면 섬유를 비교 제작하였으며, 용매의 형태로 손쉽게 도포 가능한 물질은 탄소 계열의 활물질들이며, 탄소 나노 튜브나 그래핀 등이 분산된 용액을 이용해 천에 도포 가능하다. 탄소 계열의 활물질들은 대표적인 슈퍼캐패시터 물질이며, 천에 도포를 함으로써 천 기반의 슈퍼캐패시터를 제작하였다. 일반 합성 섬유 polyester와 CNT를 결합한 형태의 전극은 최대 에너지 축전 용량(Maximum specific capacitance)이 53.6 F/g으로 나타났으며, 면 섬유와 CNT를 결합한 형태의 전극은 최대 에너지 축전 용량이 122.1 F/g으로 나타났다. 따라서 면 섬유에서 높은 에너지 저장 능력을 보이는 것을 실험적으로 확인하였으며, 에너지 저장 능력이 뛰어난 면 섬유를 다음 전극 디자인에서도 일률적으로 적용하였다. 슈도캐패시터의 대표적 물질인 금속 산화물인 망간 산화물(MnO2)을 3전극 도금 시스템을 이용하여 에너지 축전 용량과 에너지 밀도를 올리는 전극을 제작하였다. 특히 망간 산화물의 형태는 표면적을 극대화하기 위해서 평균 지름은 200~300 nm 정도 되는 나노 입자의 형태로 제작하였다. 그 결과, 확연하게 에너지 축전 용량이 향상되었으며, 최대 에너지 축전 용량은 282.0 F/g, 에너지전력 밀도는 14.2 Wh/kg으로 나타나서 금속 산화물의 형태가 주는 효과를 확인할 수 있었다. 하지만 나노 입자의 형태로 제작된 금속 산화물은 문제점이 발생하였다. 금속 산화물의 전기 전도성이 매우 낮기 때문에, 전기 전도성에 비례해서 전력 밀도의 값이 표현되는데, 전기 전도성이 급격히 감소하기 때문에 전력 밀도도 급격한 감소가 나타난다. 다음과 같이 전기 전도성 물질을 첨가하는 방법은 추가의 공정이 필요한 단점이 있지만 오직 기계적인 인장응력만을 가해서 에너지 밀도와 전력 밀도를 증가시키는 전극을 제작하였다. 인장응력을 섬유 기반의 전극에 가했을 시에 가닥들간의 접촉 증가와 CNT가 정렬되면서 특정 변형률(strain) 이전에서는 전기 전도성이 최대 50% 이상 증가하는 것을 확인할 수 있었으며, 선행 연구에서 보고되었다. 이를 이용해서 전기 전도성과 직결되는 전력 밀도의 양도 증가시키고 에너지 밀도의 증가 여부까지 확인한 결과 인장을 가하기 전 면 섬유의 전력 밀도와 에너지 밀도는 6.4 kW/kg and 6.1 Wh/kg으로 나타났으나 30% 변형 인장 후에는11.4 kW/kg과 7.1 Wh/kg으로 나타났다. 그리고 망간 산화물을 첨가한 전극 역시 4.9 kW/kg과 14.2 Wh/kg으로 나타났었으나 인장 이후 전력 밀도는 14.2 kW/kg, 에너지 밀도는 17.6 Wh/kg으로 확연하게 증가한 것을 확인하였다.

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Tide and Tidal Currents Around the Archipelago on the Southwestern Waters of the South Sea, Korea (한국 남서해 다도해역의 조석·조류 특성)

  • Choo, Hyo-Sang;Kim, Dong-Sun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.19 no.6
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    • pp.582-596
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    • 2013
  • In order to estimate the tide and flow properties around the archipelago, around Dolsan, Choyak, Geogeom and Jindo which located in the southwestern waters of the south sea of Korea, tidal currents, residual flows and tidal energy dissipation were investigated by using 2-dimensional numerical model. The maximum speeds of tidal currents are small around Dolsando(31.92 cm/s) and large around Jindo(87.55 cm/s). The residual flow is fastest around Choyakdo where many channels and islands as compared with other study areas. The area around Jindo has the highest currents speed, but shows the flat movements. The margins between the maximum and the minimum dispersion rates of tidal energy in the areas are estimated and designate the order of values around Dolsando($392.6{\times}10^7$ erg/s), Geogeumdo($125.7{\times}10^7$ erg/s) and Jindo($23.1{\times}10^7$ erg/s) sequently. These circumstances are same as in the amplitude of M2 constituent. This means that rapid depth changes and narrow channels play an important role in tide and tidal currents energy in archipelago.

Micromorphology and Chemical Composition of a Sialolith in the Submandibular Gland Duct (악하선 내 타석의 미세형상 및 화학적 조성)

  • Im, Yeong-Gwan;Song, Ho-Jun;Kim, Byung-Gook
    • Journal of Oral Medicine and Pain
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    • v.36 no.3
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    • pp.161-167
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    • 2011
  • Sialolith is one of the most common pathologic conditions found in the salivary glands. The mechanisms responsible for the formation of sialoliths have not been elucidated so far. In this article, the chemical composition and micromorphology of a sialolith of a 58-year old female patient suffering from chronic sialoadenitis of the submandibular gland was analyzed using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). In a SEM evaluation, the highly mineralized amorphous core surrounded by lamellar and concentric structures was revealed, however no foreign body, organic material, or signs of microorganism were observed in the core of the sialolith. EDX analysis showed the central core was composed of only Ca, O and P, and that a high level of C was detected near the central area as well. These results indicated that the inorganic composition of the sialolith was hydroxyapatite crystals, and that inorganic and organic substances existed around the central cores. This study suggests that the sialolith was composed mainly of hydroxyapatite crystals and the formation of the nucleus of the sialolith in the submandibular gland duct was secondary to sialadenitis, which favors the growth of an inorganic crystalline nucleus.

Discrimination of Geographical Origin for Scutellaria baicalensis Using Energy Dispersive X-ray Fluorescence Spectrometer (에너지 분산형 X-선 형광분석기를 이용한 황금의 원산지 판별)

  • Moon, Ji-Young;Lee, Ye-Ji;Kang, Jung-Mi;Cho, Soon-Jun;Noh, Bong-Soo
    • Korean Journal of Food Science and Technology
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    • v.44 no.4
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    • pp.484-487
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    • 2012
  • A discrimination technique for domestic and imported Scutellaria baicalensis was developed using an energy dispersive X-ray fluorescence spectrometer (ED-XRF). Mineral content ratios, of a total of 43 species, including P, S, Cl, K, Ca, Mn, Fe, Cu, and Zn, were measured among 204 samples. Macro element content ratios and trace element content ratios were determined using the standardless fundamental parameters (SLFP) analysis. Inorganic element ratios of P, S, K, Ca, Cl, Mn, and Fe were significantly different between domestic and imported samples. The result from the canonical discriminant analysis showed that the accuracy of geographical origin discrimination was 95.15%; the correlation coefficient was 0.888. It was concluded that this technique could be used as a useful method in discriminating the geographical origins between domestic and imported Scutellaria baicalensis.

An Energy-Efficient Clustering Scheme in Underwater Acoustic Sensor Networks (수중음향 센서 네트워크에서 효율적인 저전력 군집화 기법)

  • Lee, Jae-Hun;Seo, Bo-Min;Cho, Ho-Shin
    • The Journal of the Acoustical Society of Korea
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    • v.33 no.5
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    • pp.341-350
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    • 2014
  • In this paper, an energy efficient clustering scheme using self organization method is proposed. The proposed scheme selects a cluster head considering not only the number of neighbor nodes but also the residual battery amount. In addition, the network life time is extended by re-selecting the cluster heads only in case the current cluster head's residual energy falls down below a certain threshold level. Accordingly, the energy consumption is evenly distributed over the entire network nodes. The cluster head delivers the collected data from member nodes to a Sink node in a way of multi-hop relaying. In order to evaluate the proposed scheme, we run computer simulation in terms of the total residual amount of battery, the number of alive nodes after a certain amount of time, the accumulated energy cost for network configuration, and the deviation of energy consumption of all nodes, comparing with LEACH which is one of the most popular network clustering schemes. Numerical results show that the proposed scheme has twice network life-time of LEACH scheme and has much more evenly distributed energy consumption over the entire network.

Energy/Distance Estimation-based and Distributed Selection/Migration of Cluster Heads in Wireless Sensor Networks (센서 네트워크의 에너지 및 거리 추정 기반 분산 클러스터 헤드 선정과 이주 방법)

  • Kim, Dong-Woo;Park, Jong-Ho;Lee, Tae-Jin
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.44 no.3 s.357
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    • pp.18-25
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    • 2007
  • In sensor networks, sensor nodes have limited computational capacity, power and memory. Thus energy efficiency is one of the most important requirements. How to extend the lifetime of wireless sensor networks has been widely discussed in recent years. However, one of the most effective approaches to cope with power conservation, network scalability, and load balancing is clustering technique. The function of a cluster head is to collect and route messages of all the nodes within its cluster. Cluster heads must be changed periodically for low energy consumption and load distribution. In this paper, we propose an energy-aware cluster head selection algorithm and Distance Estimation-based distributed Clustering Algorithm (DECA) in wireless sensor networks, which exchanges cluster heads for less energy consumption by distance estimation. Our simulation result shows that DECA can improve the system lifetime of sensor networks up to three times compared to the conventional scheme.

An Adaptive Routing Protocol with a Balanced Energy Consumption For Wireless Ad-hoc Networks (애드혹 네트워크에서 에너지 소비 균형을 고려한 적응형 라우팅 프로토콜)

  • Kim, Yong-Hyun;Hong, Youn-Sik
    • The KIPS Transactions:PartC
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    • v.15C no.4
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    • pp.303-310
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    • 2008
  • To increase the lifetime of ad-hoc networks, a ratio of energy consumption for each node should be kept constant by equally distributing network traffic loads into all of the nodes. In this paper, we propose a modified AODV routing protocol to determine a possible route by considering a remaining battery capacity of a node and the degree of its usage. In addition, to reduce the amount of energy consumption during the path rediscovery process due to the huge amount of the AODV control messages the limited number of possible routes are stored into a routing table of a source node. When some links of a route fail, another possible path can be looked up in the table before the route discovery process should be initiated. We have tested our proposed method with a conventional AODV and a MMBCR method which is one of the power-efficient energy routing protocols based on the three performance metrics, i.e., the total remaining battery capacity, network lifetime and the ratio of data packets received by the destination node to compare their performance.

A Scalability based Energy Model for Sustainability of Blockchain Networks (블록체인 네트워크의 지속 가능성을 위한 확장성 기반 에너지 모델)

  • Seung Hyun Jeon;Bokrae Jung
    • Journal of Industrial Convergence
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    • v.21 no.8
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    • pp.51-58
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    • 2023
  • Blockchains have recently struggled to design for the ideal distributed trust networks by solving scalability trilemma. However, local conflicts between some countries lead to imbalance on energy distribution. Besides, blockchain networks (e.g., Bitcoin) currently consume enormous energy for transaction and mining. The existing data volume based trust model evaluated an increasing blockchain size better than Lubin's trust model in scalability trilemma. In this paper, we propose a scalability based energy model to evaluate sustainability for blockchain networks, considering energy consumption for transaction, time duration, and the blockchain size of growing blockchain networks. Through the rigorous numerical analysis, we compare the proposed scalability based energy model with the existing model for the satisfaction and optimal blockchain size. Thus, the scalability based energy model will provide an assessment tool to choose the proper blockchain networks to solve scalability trilemma problem and prove sustainability.

Preparation of Monodispersed Silica-Rubitherm®Microparticles Using Membrane Emulsification and Their Latent Heat Properties (막유화법을 이용한 단분산성 실리카-루비덤® 마이크로 입자의 제조 및 잠열 특성)

  • Kim, Soo-Yeon;Jung, Yeon-Seok;Lee, Sun-Ho;You, Jin-Oh;Youm, Kyung-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.2
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    • pp.215-225
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    • 2015
  • Recently, the importance of energy saving and alternative energy is significantly increasing due to energy depletion and the phase change material (PCM) research for saving energy is also actively investigating. In this research, the membrane emulsification using SPG membrane was used to make various microencapsulated phase change material (MPCM) particles which were comprised of $Rubitherms^{(R)}$ (RT-21 and RT-24) core and silica coating. We investigated the pressure of the dispersion phase, the concentration of surfactant, and the ratio of $Rubitherm^{(R)}$ and silica to prepare various MPCM particles. The DSC and TGA were used to examine the heat stability and latent heat properties. Also, PSA, SEM, and optical microscopy were used to confirm the size of $Rubitherm^{(R)}$ particles and the thickness of silica shell. The average of particle size was $7-8{\mu}m$. And, FT-IR was also used to enforce the qualitative analysis. Finally, the MPCM particles obtained from membrane emulsification showed monodispersed size distribution and the heat stability and latent heat were kept up to 80% compared to pure $Rubitherm^{(R)}$. So, it can be effectively used for wallpaper, buildings and interior products for energy saving as PCMs.

Measurement of GPR Direct Wave Velocity by f-k Analysis and Determination of Dielectric Property by Dispersive Guided Wave (f-k 분석에 의한 레이다파 속도 측정 및 레이다파의 분산성 가이드 현상을 이용한 지하 물성 계산)

  • Yi, Myeong-Jong;Endres, Anthony L.;Kim, Jung-Ho
    • Geophysics and Geophysical Exploration
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    • v.9 no.4
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    • pp.304-315
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    • 2006
  • We have examined the applicability of f-k analysis to the GPR direct wave measurement for water content to characterize vadose zone condition. When the vadose zone consists of a dry surface layer over wet substratum, we obtained f-k spectra where most of the energy is bounded by the air and dry soil velocities. In this case, dry soil velocity was successfully estimated by using high frequency data. On the other hands, when wet soil overlies dry substratum, the f-k spectra show a contrasting response where most of the energy travels with the velocity bounded by dry and wet soil velocities. In this case, the radar waves are trapped and guided within wet soil layer, exhibiting velocity dispersion. By adopting modal propagation theory, we could formulae a simple inversion code to find two layer's dielectric constants as well as layer thickness. By inverting the velocity dispersion curve obtained from f-k spectra of synthetic modeling data, we could obtain good estimates of dielectric constants of each layer as well as first layer thickness. Moreover, we could obtain more accurate results by including the higher mode data. We expect this method will be useful to get the quantitative property of real subsurface when the field condition is similar.