• Title/Summary/Keyword: 분극 곡선

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Calculation of Polarization Curves using CFD Analysis (CFD 해석을 통한 분극곡선 계산)

  • Im, Gyeong-Hwan;Lee, Gyeong-U
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.75-75
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    • 2012
  • 전기도금 공정에서 분극곡선은 도금액의 전기화학적 특성을 나타낸다. 도금 실험에서는 도금액의 특성 및 실험 계획수립을 위해 필요하고, 도금 계산에서는 시뮬레이션의 경계조건으로 사용되기 때문에 분극곡선 측정은 실험 및 계산에 앞서서 수행되는 중요 과정이다. 이러한 분극곡선 측정을 실험으로 얻는 대신 CFD(Computational Fluid Dynamics) 해석을 통하여 계산으로 분극곡선을 얻는 방법을 시도하였고, 이 때 회전속도를 변수로 하여 유동과 분극곡선 사이의 관계를 분석하였다.

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Improvement of Precision in Ferroelectric Polarization Hysteresis Measurement (강유전체 분극 이력곡선의 측정 정밀도 향상)

  • Jae Hwan Park
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.3
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    • pp.51-55
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    • 2023
  • Measurement of the ferroelectric polarization hysteresis curve is an important means of overall evaluation and interpretation of the ferroelectric structure and dielectric properties. If a resistive component is included in the ferroelectric sample, an error is included in the measured value of the spontaneous polarization. When configuring the electrical circuit to measure the polarization, by properly utilizing the external resistance corresponding to the resistive component included in the sample, the error due to the resistive loss of the sample was excluded and the size of the ferroelectric polarization induced inside could be accurately measured. It is expected that the displacement and dielectric characteristics of ions inside the ferroelectric can be more accurately evaluated through the evaluation of such an accurate polarization hysteresis curve.

Characteristics of quasi-MFISFET device with various ferroelecric thin films (강유전체 박막의 특성에 따른 Quasi-MFISFET 소자의 특성)

  • Lee, Guk Pyo;Yun, Yeong Seop;Gang, Seong Jun
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.38 no.3
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    • pp.12-12
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    • 2001
  • PLZT(10/30/70), PLT(10) 및 PZT(30/70) 와 같은 강유전체 박막의 이력곡선을 field-dependent polarization 모델을 이용하여 시뮬레이션하고, 측정한 실험적 결과와 비교, 분석하였다. PZT(30/70) 박막의 경우, 5V 이상의 인가전압에서 분극의 포화현상이 둔감하게 나타나고 시뮬레이션 값과의 차이도 심해 강유전체 분극이 순수한 dipole 외에도 다양한 전하의 영향을 받아 형성된다는 사실을 알 수 있다. 또, quasi-MFISFET 소자의 드레인 전류는 field-dependent polarization 모델의 강유전체 이력곡선에서 얻은 파라미터를 square-law FET 모델에 적용시켜 효과적으로 추출하였고, 모델링 결과는 실험값과 유사하였다. 그리고, quasi-MFISFET 소자의 gate 에 -10V의 ′write′ 전압을 인가한 상태에서 PZT(30/70) 박막을 사용한 경우, PLZT(10/30/70), PLT(10) 박막 보다 빨리 채널이 형성되었는데, 그 원인은 강유전체 박막에 따른 retention 특성에서 PZT(30/70) 박막의 분극 감소가 PLZT(10/30/70), PLT(10) 박막의 분극 감소 보다 약 3∼4 배 이상 크다는 점에서 찾을 수 있다.

Errors and Their Corrections in the Measurement of Dielectric Hysteresis in Ferroelectrics (강유전체의 유전이력특성 측정에서의 오차요인 및 보정)

  • 박재환
    • Journal of the Korean Ceramic Society
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    • v.38 no.7
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    • pp.667-671
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    • 2001
  • Sawyer-tower 회로를 이용한 강유전 이력곡선의 측정과정에서의 주요 오차 원인을 살펴보고 이에 대한 대안을 제시해 보았다. 강유전체 시편에 존재하는 직류 누설성분에 의해 잔류분극과 항전계는 과대평가될 수 있는 위험성이 항상 있음을 알 수 있었으며 이러한 오차의 보정에 대하여 논의하였다. 또한 강유전 이력곡선의 측정에서 측정하는 시간이 증가되면서 시편의 발열로 인해서 시편의 온도가 증가하게 되어 잔류분극 값과 항전계 값이 감소하는 경향으로 나타남을 관찰하였고, 그 대책을 제안하였다.

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Micro Electrochemical Machining using Anodic Polarization Curve (양극분극곡선을 미용한 미세 전해가공)

  • 최영수;강성일;전종업;박규열
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.05a
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    • pp.999-1002
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    • 2002
  • In this research, the mechanism of micro-ECM was investigated with potentiodynamic method and the optimal condition for micro-ECM was selected by voltage-current-time curve with potentiostatic method. From the experimental result. it was confirmed that anodic voltage curve could be used very effectively for determining the optimal condition of micro-ECM, and the micro part which has extremely fine surface could be fabricated by use of micro-ECM with point electrode method.

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Determination of optimum protection potential for cathodic protection of offshore wind-turbine-tower steel substructure by using potentiostatic method (정전위법에 의한 해상풍력 타워 구조물용 강재의 음극방식을 위한 최적방식전위 결정)

  • Lee, Jung-Hyung;Jung, Kwang-hu;Park, Jae-Cheul;Kim, Seong-Jong
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.3
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    • pp.230-237
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    • 2017
  • In this study, electrochemical methods were used to determine the optimum protection potential of S355ML steel for the cathodic protection of offshore wind-turbine-tower substructures. The results of potentiodynamic polarization experiments indicated that the anodic polarization curve did not represent a passivation behavior, while under the cathodic polarization concentration, polarization was observed due to the reduction of dissolved oxygen, followed by activation polarization by hydrogen evolution as the potential shifted towards the active direction. The concentration polarization region was found to be located between approximately -0.72 V and -1.0 V, and this potential range is considered to be the potential range for cathodic protection using the impressed current cathodic protection method. The results of the potentiostatic experiments at various potentials revealed that varying current density tended to become stable with time. Surface characterization after the potentiostatic experiment for 1200 s, by using a scanning electron microscope and a 3D analysis microscope confirmed that corrosion damage occurred as a result of anodic dissolution under an anodic polarization potential range of 0 to -0.50 V, which corresponds to anodic polarization. Under potentials corresponding to cathodic polarization, however, a relatively intact surface was observed with the formation of calcareous deposits. As a result, the potential range between -0.8 V and -1.0 V, which corresponds to the concentration polarization region, was determined to be the optimum potential region for impressed current cathodic protection of S355ML steel.

Numerical Analysis of the electrochemical performance of a zinc-air fuel cell (수치해석을 이용한 아연공기전지의 전기화학적 성능 연구)

  • Kim, Jungyun;Park, Sangmin;Oh, Taeyoung;Lee, Hoil
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.74.1-74.1
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    • 2010
  • 수치해석을 이용하여 형상 및 운전 조건에 따른 금속공기전지의 전기화학적 성능 변화를 조사하였다. 저전류밀도 영역에서의 전지 성능은 농도손실에 의한 영향이 미미하므로 활성화 손실과 저항손실만을 고려한 수치해서 모델을 적용하였다. 지배방정식은 전기전도식을 이용하였으며 전극 표면의 활성화손실을 모사하기위해 아연극(음극)에는 butler-volmer식을, 공기극(양극)에는 tafel식을 적용하였다. 실험결과와의 비교/분석을 통하여 수치해석 모델의 타당성을 검증하였다. 또한, 아연극과 공기극 사이의 간격과 전해질 농도 변화에 따른 아연공기전지 내부에서의 전류밀도분포를 조사하였으며, 분극곡선을 통해 전기화학적 성능을 평가하였다.

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The Study on the Behavior of Polarization curve of Reinforcement with Oxidation Layer (산화피막이 있는 철근의 분극곡선의 거동에 대한 연구)

  • 한정섭
    • Journal of Ocean Engineering and Technology
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    • v.14 no.1
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    • pp.60-66
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    • 2000
  • In order to study for corrosion behavior of reinforcing steel with oxidation layer. Experiments were done with various NaCl concentrations and with immersion time in simulated concrete pore solution(SPS) the characteristics of corrosion behavior were measured by polarization resistance method and cyclic potentiodynamic method. reinforcements were coated by epoxy except corrosion without oxidation layer and it also showed two anodic-nose. by the result of potention dynamic test the potential curve shift to low with time and anodic-nose was appeared with 3% NaCl solution after 15 days. By result of cyclic Potentiodynamic test the type of corrosion was different accoding to concentration.

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Characteristics of Quasi-MFISFET Device with Various Ferroelectric Thin Films (강유전체 박막의 특성에 따른 Quasi-MFISFET 소자의 특성)

  • Lee, Guk-Pyo;Yun, Yeong-Seop;Gang, Seong-Jun
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.38 no.3
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    • pp.166-173
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    • 2001
  • Hysteresis loops of the ferroelectric thin films such as PLZT(10/30/70), PLT(10) and PZT(30/70) was simulated using the field-dependent polarization model and compared to the measured loops. In case of PZT(30/70) thin film, as the real saturation or polarization at the applied voltage or larger than 5V appears slack and its value is quite different from the simulated one, it is deduced that the ferroelectric polarization of PZT(30/70) is generated not only by the pure dipoles but also by various electric charges. The drain current of quasi-MFISFET is expressed by using the square-law FET and field-dependent polarization models. The modeling results are analogous to the experimental values. The channel of quasi-MFISFET using PZT(30/70) forms more quickly compared to that of quasi-MFISFET using PLZT(10/30/70) or PLT(10) in the state of 'write' gate voltage of -10V. This may be because the decrease rate of the polarization in the PZT(30/70) thin film is 3~4 times more rapid than that of the polarization in the PLZT(10/30/70) or the PLT(10) thin film in the retention characteristics.

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