• Title/Summary/Keyword: 부식화도

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Effect of Relative Humidity on the Atmospheric Corrosion of Mild Steel Using the Electrochemical Wet/Dry Method (전기화학적 wet/dry 법을 이용한 탄소강의 대기부식에 미치는 상대습도의 영향에 관한 연구)

  • Yeon Jei-Won;Pyun Su-Il;Lee Woo-Jin;Choi In-Kyu;Chun Kwan-Sik
    • Journal of the Korean Electrochemical Society
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    • v.3 no.1
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    • pp.5-10
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    • 2000
  • In the present work, corrosion rate W and corrosion potential tow were simultaneously measured as a function of relative humidity RH employing the electrochemical wet and dry method as an accelelated atmospheric corrosion method. The W versus (vs.) RH curve is classified into .three regions, namely, the first W plateau region, the second region of the linear relationship between logarithmic W and RH, finally, followed by an abrupt decay region. Based upon the atmospheric corrosion mechanism of mild steel, we introduced another diagram of $\varepsilon_{corr}$ vs. RH which is divided into three regions. In the first region, the corrosion scales are composed of single lepidocrocite-phase $(\gamma-FeOOH)$; in the second region, $\gamma-FeOOH$-phase coexists with magnetite-phase $(Fe_3O_4)$ in the scales and finally the oxide scales change into a single Fe304-phase in the third region. The three distinct regions of both representations share almost each other, which is validated by FT-IR (Fourier transform infra-red) analysis and surface observation. Both representations prove to be convenient and complementary for surveying the spectrum of the atmospheric corrosion of mild steel.

Changes of Humus Types Affected by Application of Animal Manures Compostin Jeju Upland Soil (가축분 퇴비의 시용량에 따른 제주 밭토양의 부식의 형태별 함량 변화)

  • Hwang, Ki-Sung;Yoo, Bong-Sik
    • Korean Journal of Environmental Agriculture
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    • v.24 no.4
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    • pp.364-369
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    • 2005
  • In Jeju island, the southernmost island of Korea, the field soils are mostly consisted of volcanic and non-volcanic soils. Animal manures of 0, 50, 100, and 150 MT/ha were treated to analyse the humus content changes by application amounts and the soil types. The results are as follows; Humus distribution type was A in the most of the volcanic soils while a few soils was type B, and it was possible to confirm that the humus process has occurred in the soils. Most of the non-volcanic soils was Rp and B type, therefore, the humus content change pattern was different from the volcanic soils. The nitrate-nitrogen content and the humus content showed positive correlation of $R^2=0.5263$ in the volcanic soils, while that of non-volcanic soils was $R^2=0.524$. The carbon content and the humus content showed positive correlation of $R^2=0.469$ in the volcanic soils, while that of non-volcanic soils was $R^2=0.550$.

Corrosive Characteristics of Metal Materials by a Sulfate-reducing Bacterium (황산염환원미생물에 의한 금속재료의 부식 특성)

  • Lee, Seung Yeop;Jeong, Jongtae
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.4
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    • pp.219-228
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    • 2013
  • To understand characteristics of biogeochemical corrosion for the metal canisters that usually contain the radioactive wastes for a long-term period below the ground, some metal materials consisting of cast iron and copper were reacted for 3 months with D. desulfuricans, a sulfate-reducing bacterium, under a reducing condition. During the experiment, concentrations of dissolved metal ions were periodically measured, and then metal specimen and surface secondary products were examined using the electron microscopy to know the chemical and mineralogical changes of the original metal samples. The metal corrosion was not noticeable at the absence of D. desulfuricans, but it was relatively greater at the presence of the bacterium. In our experiment, darkish metal sulfides such as mackinawite and copper sulfide were the final products of biogeochemical metal corrosion, and they were easily scaled off the original specimen and suspended as colloids. For the copper specimen, in particular, there appeared an accelerated corrosion of copper in the presence of dissolved iron and bacteria in solution, probably due to a weakening of copper-copper binding caused by a growth of other phase, iron sulfide, on the copper surface.

The Development of GIS Interconnected Corrosion Prediction System for Underground Buried Gas Pipelines (GIS연계형 지중매설 가스배관의 부식 예측시스템 개발)

  • Bae Jeong-Hyo;Kim Dae-Kyeong;Kim Ki-Joon
    • Journal of the Korean Institute of Gas
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    • v.4 no.3 s.11
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    • pp.39-45
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    • 2000
  • In general, most of the GIS only deal with materials and geometric data which just include position, radius, length of the structure. Therefore it's hard to get corrosion data from it. But the one that an owner of metallic structures want to know is the integrity of the structure. Cathodic Protection System can not protect corrosion on the underground facilities perfectly but protect corrsion effectively. It therefore is necessary to monitor the facilities continually So, we need the development of GIS interconnected a corrosion prediction system on the view point of the efficiency of operation and the protection for a big accident. The results of the development of its system are described in this paper. It can do life prediction and interference analysis and also newest corrosion data should be updated regularly.

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A Preliminary Study on the Reused Channel-Type Lining Board with Corrosion-Damage (부식 강재 복공판의 재사용성 평가에 관한 기초적 연구)

  • Kim, In-Tae;Kim, Dong-Woo;Choi, Hyoung-Suk;Cheung, Jin-Hwan
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.4 s.56
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    • pp.170-179
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    • 2009
  • Channel-type lining board(CLB) is a welded steel structure used in the field of open cut subway excavation and building basement construction. Lining board is generally installed at the underground environment which is exposed to corrosion factors such as humidity, temperature and corrosive gases. This study evaluates reusability of the corroded lining board by experimental and analytical method. Static loading tests were performed to know serviceability of corroded CLB after checking thickness loss of the used CLB parts. Strain of the plates and middle point deflection was measured simultaneously. According to experimental test results and comparison with numerical analysis, the thickness loss of the plates by corrosion makes more vertical displacements and stresses in members under the DB vehicle load considering impact factor. As a result, this paper is proposed a way to evaluate used and corroded CLB by checking the plates thickness and it makes construction engineers easy to know optimal time to replace their old CLBs with new one.

Evaluation of Core Residence Time of Fuel Cruds from Hanul Unit 1 Cycle 17 (한울1호기 17주기 연료 크러드의 노내 체류시간 평가)

  • Lee, Doo Ho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.3
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    • pp.211-216
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    • 2014
  • Corrosion products are released to the primary coolant in the corrosion process of structural materials. They are deposited on fuel surfaces and activated on exposure to a neutron flux with formation of radionuclides that can become incorporated into out-of-core surface films. To get a clear understanding of activated crud formation process, the specific activity and core residence time of fuel cruds was calculated as a function of exposure time to the core neutron flux on the assumption that parent nuclide is being deposited continuously. Fuel cruds were sampled in the fuel scraping campaign from Hanul Unit 1 Cycle 17 and analyzed for elemental concentration and radioisotope activity.

Aerobic Composting of Waste water Sludge (슬러지의 호기성(好氣性) 퇴비화(堆肥化))

  • Lee, Chan Ki;Kim, Young Rai
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.71-76
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    • 1987
  • The purpose of this study was to know reduction of organic matter, degree of humification and composting period by corp. posting of night soil sludge. Laboratory reactor was used for this study. Samples being used in this experimentation was sludge of night soil treatment plant. The degree of composting was investigated by changing moisture content. The laboratory study indicated that the degree of humification was about 175, C/N ratio was about 11~13, composting period was about 10 days and COD reduction was 37mg/l/day in case of 60% moisture content.

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Element Compositions of Rice Husk and Rice Husk Ash in Korea (우리나라 왕겨 및 왕겨재의 화학적 조성 성분)

  • 박승제
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 1999.07a
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    • pp.307-312
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    • 1999
  • 현재 우리나라에서 매년 생산되는 농산부산물은 볏짚, 왕겨 등이 주를 이루는데 에너지원으로서 적당한 것은 왕겨이다 하지만 왕겨는 단순히 농업의 부산물로 여겨질 정도로 농민들의 소득증대에의 기여도가 매우 낮다. 또한 왕겨는 내외피가 규소로 치밀하게 피복되어 있으므로 부식퇴기 어려움에도 불구하고 왕겨를 축사의 깔개로 이용 후 퇴비화함에 따라 농지내 왕겨 환원속도가 부식속도 보다 빨라서 토양속에 미부식 왕겨가 누적되어 농지내 토양환경을 열악하게 하고 있으며 왕겨를 축사내 깔개로 이용함에 따라 어린 가축의 생육장애 등이 제기피고 있으며 장래에는 악취로 인한 대기오염 문제와 가축의 질병 문제 등이 추가로 제기될 가능성이 많다. (중략)

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Effect of Heat Treatment on Corrosion Resistance of Zn-Mg Alloy Thin Films (Zn-Mg 합금 박막의 내식성에 미치는 열처리 온도의 영향)

  • Kim, Yeon-Won;Bae, Il-Yong;Jeong, Jae-In;Gwak, Yeong-Jin;Kim, Tae-Yeop;Lee, Myeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.05a
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    • pp.227-227
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    • 2009
  • Zn-Mg 합금박막 강판의 열처리 온도에 따른 내식특성 변화를 연구하기 위하여 XRD 분석 및 전기화학적 실험을 실시하였다. 실험 결과에 의하면, 부식전위(Ecorr)상승을 통해 합금화 정도를 간접적으로 측정할 수 있었음은 물론 부식전류밀도(Ecorr) 측정을 통해 내식성을 비교 평가 할 수 있었다.

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