• Title/Summary/Keyword: 부식현상

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Electrochemical Impedance Study on the Rebar Corrosion in Cement Mortar Containing Chloride Ions (전기화학적 임피던스법을 이용한 염함유 시멘트 모르터내의 철근부식 연구)

  • Nam, Sang Cheal;Paik, Chi-Hum;Cho, Won Il;Cho, Byung Won;Yun, Kyung Suk;Chun, Hai Soo
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.811-816
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    • 1998
  • Rebar corrosion in cement mortar containing chloride ions was investigated by electrochemical AC impedance spectroscopy. Corrosion of mild steel bar was accelerated by an acceleration test equipment in short period. Impedance values obtained from AC-impedance method could be adapted to the proposed electrochemical equivalent circuit model and they were consistent with calculated values obtained by CNLS fitting method. The weight loss of rebar could be calculated by charge transfer resistance($R_2$) with time and it was close to real value.

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Electrochemical Corrosion Characteristics of the Iron-based Damping Alloy (철기제진합금의 전기화학적 부식특성)

  • Shim, Hyun Yee;Jee, Choong Soo;Lee, Jin Hyung;Lee, Kyu Hwan;Shin, Myung Chul
    • Analytical Science and Technology
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    • v.8 no.1
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    • pp.85-90
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    • 1995
  • Corrosion characteristics of 4 kinds of the Fe-Al damping alloys has been studied in the 3.5% NaCl solution and compared with a cold rolled mild steel and pure Ti, No passivation, besides Ti, was observed in the Fe-Al damping alloys and a cold rolled mild steel. Corrosion rate was decreased with lower carbon concentration. In the case of Mn addition for improving damping capacity, corrosion rate was decreased in scrap iron but was not decreased in electrolytic iron. It has been shown that corrosion rate of Fe-Al damping alloys lays between that of the pure Ti and that of a cold rolled mild steel.

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The analysis of the edge overplating phenomenon by numerical simulation (도금 시뮬레이션을 이용한 모서리부 과도금 현상 분석)

  • Hwang, Yang-Jin;Park, Yong-Ho;Lee, Gyu-Hwan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.206-206
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    • 2015
  • 자동차 외장 부품은 미려한 외관과 경량화를 통한 연비향상을 위해 ABS수지 위에 다층 도금 공법이 적용된다. 하지만, 필드에서 종종 도금층의 부식에 대한 문제가 야기 되고 있다. 부식문제의 한 인자로 도금 두께의 불균일성을 들 수 있다. 도금공정에서 용액의 유동성, 제품이 걸리는 위치, 도금액의 불순물 등등 여러 가지 현장요소로 인해 도금 두께 편차가 생겨난다. 이러한 현장 요소와 함께 피도금물의 외형 형상 또한 도금 불균일의 주요한 원인이 된다. 특히, 제품 모서리 부분에서는 문제가 되는 과도금 현상이 쉽게 발생한다. 따라서, 도금 두께 편차를 줄이기 위해서는 도금 현장 요인을 분석하는 것도 중요하지만, ABS 제품의 외형 형상 디자인에 있어서 체계적인 접근이 필요하다. 그러나, 디자인의 구조적인 접근을 위해 현장에서 검증하려면 많은 비용과 시간이 소요된다. 이에 본 연구에서는 모서리 부분에서의 과도금 현상을 시뮬레이션을 활용하여 형상관점에서 과도금 형태 및 원인을 분석하고자 하였다.

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Reaction Phenomena of the Ferrite Steel by Water Leakage into Liquid Sodium (소듐분위기에서 물 누출로 인한 Ferrite Steel에서의 반응현상)

  • Jeong, Kyung-chai;Kim, Byung-ho;Kwon, Sang-woon;Kim, Kwang-rag;Hwang, Sung-tai
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.268-272
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    • 1998
  • Water leak phenomena in the liquid sodium which is a coolant of liquid metal reactor, were investigated by carrying out sodium-water reaction experiment. It was confirmed that sodium and water react each other by the analysis of material composition of aspecimen at the end of experiment. When steam of $100kg/cm^2$ was passed through the leak path of the specimen for 4 hours, reaction products from sodium-water reaction were observed on the leak site. However, re-opening phenomena were not observed at this condition. It was interpretted that the reaction product precipitated on leak path and thermal transient caused self-plugging and re-openning phenomena, respectively.

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Performance Evaluation of Various Concrete Repair Materials to Corrosion Prevent of Rebar (철근의 부식 방지를 위한 다양한 콘크리트 보수재료들의 성능평가)

  • Tae-Kyun Kim;Jong-Sub Park
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.458-466
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    • 2023
  • Structures in our surroundings deteriorate over time due to environmental and chemical factors, resulting in a decrease in their performance. The primary causes of degradation in concrete structures are carbonation, salt damage, and freeze-thaw cycles. Various maintenance methods exist to address these degradation issues. However, research and technological development for existing maintenance methods have been ongoing, but the accuracy and effectiveness of repair materials and techniques have not been extensively validated. Therefore, in this study, we conducted a material performance evaluation of various manufacturers' repair materials. Based on this evaluation, we applied corrosion inhibitors and epoxy, which are the methods most closely related to crack repair, to assess the durability performance against carbonation, salt damage, and freeze-thaw cycles. The results show approximately a two-fold performance improvement against carbonation and salt damage, and a 5% enhancement in repair performance against freeze-thaw cycles. Thus, it is considered effective in preventing rebar corrosion when appropriate maintenance is carried out according to environmental and chemical factors during structural repairs.

A Study on the Removal Method of Radioactive Corrosion Product using its Magnetic Property (방사성 부식생성물의 자기적 성질을 이용한 제거방법에 대한 연구)

  • 송민철;공태영;이건재
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.1 no.1
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    • pp.73-79
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    • 2003
  • In a pressurized water reactor, radioactive corrosion products (CRUD) in primary coolant system are one of the major sources for the occupational radiation exposure of the personnel in a nuclear power plant. Through the recent trend of long term fuel cycle in a nuclear power Plant, radioactive corrosion products deposited in reactor core for a long time are also the cause of Axial Offset Anomaly (AOA) having m effect on reactor power by the hideout of boron. CRUD consist primarily of magnetite, nickel ferrite, cobalt ferrite, and so on. They have the characteristic of strong magnetism. Therefore it is performed the conceptual design to develop the filter which removes the CRUD by magnetic field that is generated by an arrangement of permanent and electric magnets. Contrary to the conventional filter, the proposed filter does not interrupt the fluid flow, so there is little pressure drop and it can be used continuously. It is expected to be applied as one of the technologies for removal of the CRUB.

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Effect of V and Sb on the Corrosion Behavior and Precipitate Characteristics of Zr-based Alloys for Nuclear Fuel Cladding (핵연료 피복관용 Zr합금의 부식거동 및 석출물 특성에 미치는 V, Sb 첨가의 영향)

  • Jeon, Chi-Jung;Kim, Seon-Jin;Jeong, Yong-Hwan
    • Korean Journal of Materials Research
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    • v.8 no.12
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    • pp.1099-1109
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    • 1998
  • To investigate the effect of V and Sb on the corrosion behavior of Zr- based alloys, corrosion tests were performed on 6 kinds of Zr alloys in an autoclave at $360^{\circ}C$ for 100 days. The transition of the corrosion rate occurred in the sample containing 0.1wt.%V after 10 days but did not occur in the samples containing 0.2wt.%V and 0.4wt.%V. The corrosion resistance of V containing alloys increased with increasing V contents from 0.1 to 0.4wt.% and the alloys containing 0.4wt.%V showed the best corrosion resistance. In the ternary alloys containing 0.1wt.%Sb and 0.4wt.%Sb, the corrosion rate increased significantly from the short exposure time. It was observed that the optimal Sb content for corrosion resistance was 0.2wt.%. The size and volume fraction of precipitates increased with increasing V and Sb contents. The superior corrosion resistance was observed in the Zr alloy having precipitate size of 0.11-0.13$\mu\textrm{m}$. From the result of corrosion behavior and the obserbation of precipitates, the optimal size of the precipitate appear to control the electron conduction in the cathodic reaction and play an important role in maintaining a stable oxide microstructure.

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The metal corrosion caused by museum indoor air pollutants (박물관 실내 대기오염물질에 의한 금속 부식 영향)

  • Kang, Dai-Ill
    • Journal of Conservation Science
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    • v.22
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    • pp.5-14
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    • 2008
  • The effect of air pollutants coming from internal museum materials such as wood-based products and cements on metal corrosion have been investigated. The Oddy test and the Chamber test was employed as a corrosion test. The metal pieces after the Oddy test had different corrosion types caused by the internal museum materials. The most effective wood based product was 18T HS(E0) and 9mm plywood(F0,E0). Iron(Fe) and copper(Cu) also bronze of the Chamber test had corrosion caused by Formic acid, Acetic acid, and Acetaldehyde. The packing materials in high humidity had caused more corrosion on the surface of the metal pieces than in low humidity.

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Iodine Stress Corrosion Cracking of Zircaloy-4 Tubes

  • Moon, Kyung-Jin;Lee, Byung-Ho
    • Nuclear Engineering and Technology
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    • v.10 no.2
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    • pp.65-72
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    • 1978
  • In this paper, it is attempted to investigate the phenomena of iodine stress corrosion cracking of Zircaloy-4 cladding failures in reactor through the results of similar out-of-pile test in iodine vapour. The main result of this experiment is a finding of the relation between the threshold stress which can lead to iodine stress corrosion cracking of Zircaloy-4 tube and the iodine concentration. The values of critical stress and the critical iodine concentration are also obtained. A model which relates failure time of Zircaley-4 tube to failure stress and iodine concentration is suggested as follows: log t$_{F}$ =5.5-(3/2)log$_{c}$-4log $\sigma$ where t$_{F}$ : failure time, minutes c: iodne concentration, mg/㎤ $\sigma$: stress, 10$^4$psi.

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Evaluation of Fatigue Strength Share Effect of the Rust Due to Corrosion at Ship Structural Plate (선체구조 판부재에서 해수부식현상에 기인하는 부식층의 피로강도분담효과에 관한 연구)

  • Kim, Won Beom
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.5
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    • pp.2063-2068
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    • 2013
  • Ship and offshore structures, those are to be used under the seawater conditions are prone to corrosion. In this research, the effect of rust existence on the fatigue strength at structural member of ship and offshore structure was investigated. For this purpose, fatigue tests for the rust removed specimen were conducted. In addition, the comparison of fatigue strength between rust removed specimen and rusted specimen was conducted. With these test results, fatigue strength share effect was investigated. Finally, at this research, it was found that there is fatigue strength share effect on the rust. In comparison of fatigue strength reduction factor, fatigue strength of the rust removed specimen is 18.1% lower than that of the rusted specimen. From the above, it was known that as far as there are not any harmful ingredients in it, rust on the steel plate is beneficial in an aspect of fatigue strength.