• Title/Summary/Keyword: 부식억제

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Adsorption rate of Phosphate Corrosion Inhibitor in Carbon Steel pipe (탄소강관에서의 인산염 부식억제제농도 감소의 반응속도상수 평가)

  • Woo, Dalsik;Hwang, Byunggi
    • Journal of Environmental Impact Assessment
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    • v.14 no.1
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    • pp.17-24
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    • 2005
  • This study was performed to evaluate the adsorption rate of phosphate corrosion inhibitor and reaction rate constant in drinking water distribution systems. The optimum concentration of corrosion inhibitor would vary depending on the quality of water, pipe materials, and condition of metal surfaces. The current adsorption study indicated that the residual phosphate concentration of the corrosion inhibitor decreased with the time as it adsorbed on the surface of pipe material. As time went by, the residual phosphate concentration became constant. It means that the formation of the corrosion protection film on metal surfaces is completed.

Effects of Temperature and Partial Pressure of ${CO_2}/{O_2$ on Corrosion Behavior of Stainless Steel in Molten Li/Na Carbonate Salt (Li/Na계 용융탄산염에 대한 스테인레스강의 부식에 미치는 온도와 ${CO_2}/{O_2$ 분압의 영향)

  • 황응림;하흥용;임태훈;홍성안
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.05a
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    • pp.225-228
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    • 1999
  • MCFC의 장수명화를 위해 기존의 Li$_2$CO$_3$-K$_2$CO$_3$계 전해질을 Li$_2$CO$_3$-$Na_2$CO$_3$계 용융탄산염으로 대체함으로써, 전지 수명을 단축시키는 NiO의 용출을 억제하고자하는 연구가 진행중에 있다. 이러한 대체 Li$_2$CO$_3$-$Na_2$CO$_3$ 전해질은 실제 전지에서 사용되고 있는 분리판 재료인 스테인레스강의 안정성에도 기존의 Li$_2$CO$_3$-K$_2$CO$_3$ 혼합염과는 다른 경향을 보이는 것으로 알려져 있다.(중략)

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Role of chloride ions with Zwitterions and phosphate groups on the improvement of the passive film in alkaline environment (알칼리성 환경에서 부동태 피막 개선에 대한 양쪽성 이온 및 인산염 그룹을 갖는 염화물 이온의 역할)

  • Tran, Duc Thanh;Lee, Han-seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.43-44
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    • 2022
  • In this study, the optimum amount of chloride ions is used to collaborate with hybrid corrosion inhibitor for carbon steel rebar treatment in simulated pore concrete (SCP) solution is discovered. The corrosion inhibition performance of hybrid inhibitors is carried on by open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization (PP). The highest corrosion inhibition resistance is found in case of LP-C2 after 240 h exposure. Surface studies including scanning electron microscopy (SEM), and atomic force microscopy (AFM) were used to figure out the surface morphology of the steel rebar treated with hybrid inhibitors in order to collaborate well with electrochemical studies. Anodic type inhibition action was confirmed by potentiodynamic polarization study.

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Mitigation of Steel Rebar Corrosion Embedded in Mortar using Ammonium Phosphate Monobasic as Hreen Inhibitor (제 1 인산 암모늄 사용량에 따른 시멘트 모르타르의 철근방청성능 평가에 관한 실험적 연구)

  • Tran, Duc Thanh;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.112-113
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    • 2021
  • Phosphate based inhibitor is playing a decisive role in inhibiting the corrosion of steel rebar in chloride condition. We have used different amount of ammonium phosphate monobasic (APMB) as corrosion inhibitor in mortar with different amount of chloride ions. The compressive strength, flexural strength, open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), potentiodynamic polarization resistance (PPR), scanning electron microscopy (SEM) and Raman spectroscopy were performed to access the effect of inhibitor on corrosion resistance. As the amount of inhibitor is increased, the compressive strength increased. The electrochemical results show that as the amount of inhibitor and chloride ions are increased, the total impedance and corrosion resistance of steel rebar increased attributed to the formation of the stable oxide films onto the steel rebar surface. It is suggested that APMB can work in high concentration of chloride ions present in concrete where phosphate ion helps in formation of stable and protective phosphate based oxide film.

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Anti-Corrosion Behaviour of Rebar in Cement Mortar by Electrochemical Chloride Extraction (전기화학적 염소 추출법에 의한 시멘트 모르터내의 철근 방식)

  • Nam Sang Cheol;Lim Young Chang;Cho Won-Il;Cho Byung Won;Chun Hai Soo;Yun Kyung Suk
    • Journal of the Korean Electrochemical Society
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    • v.3 no.1
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    • pp.31-38
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    • 2000
  • Anti-corrosion behaviour of rebar embedded in cement mortar containing chloride ions was investigated by electrochemical chloride extraction(ECE). $43\%$ of the initial chloride ions of the cement mortar was fixed to Friedel salts and the soluble chloride ions were successfully extracted by ECE method. Concentration profiles of the chloride ions were estimated by Fick's 2nd law with time and depth, and it was close to the real value. The corrosion potential increased to anodic direction after ECE test, and the corrosion of rebar was reduced as a result of AC impedance spectroscopy.

Dental Caries Suppression Effect and Other Physiological Properties of Erythritol (에리스리톨의 난충치성 및 기타 생리 특성)

  • Byun, Sang-Hee;Lee, Cherl-Ho
    • Korean Journal of Food Science and Technology
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    • v.30 no.2
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    • pp.446-449
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    • 1998
  • Dental caries suppression effect and other physiological properties of erythritol were measured in comparison with those of sucrose, xylitol and sorbitol. The susceptibility test for dental caries by using Streptococcus mutans KCTC 3065 and Lactobacillus acidophillus indicated that erythritol was as effective as xylitol in suppressing dental caries. In lactic acid fermentation test, erythritol showed the least growth of bacteria among the tested sweeteners. The tolelerance test by using mice showed that diarrhea began by feeding once 1500 mg erythritol/kg b.w., 1500 mg xylitol/kg b.w. and 1000 mg sorbitol/kg b.w. respectively.

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A Study on Characteristics of pH Control with Amines in the Secondary Side of Nuclear Power Plants (원전 2차 계통에서 아민의 pH 제어 특성 연구)

  • Rhee, In-H.;Ahn, Hyun-Kyoung;Park, Byung-Gi;Jun, Gwon-Hyuk;Ho, Song-Chan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.8
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    • pp.3112-3118
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    • 2010
  • The pH control agent in PWRs, to insure the integrity of steam generator, was changed from ammonia to ethanolamine(ETA) which decreased pH at condensate system and low pressure feedwater heater drain system, so that several amines were investigated for the selection of the optimum amine. There was no single alternative amine to meet the optimum condition. The more volatile ammonia provides the higher pH in condensate, while the less volatile ETA increases the pH in wet steam area. Thus, the combined amine of ammonia and ETA is able to equally raise the pH in both region so that the flow accelerated corrosion be reduced in the every system of the secondary side and the integrity of steam generator be also improved in pressurized water reactors (PWRs).

A study on the technology and application of cathodic protection to reinforced concrete (철근콘크리트의 방식기술 및 음극방식의 적용에 관한 고찰)

  • Jeong, Jin-A;Ha, Ji-Myung;Oh, Se-Jin
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.7
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    • pp.599-604
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    • 2016
  • Cathodic protection was first introduced as a technology for preventing the corrosion of metals in seawater and underground environments in the early 19th century, eventually leading to the introduction of cathodic protection to the reinforced concrete technology sector in the 1970s. In the 1990s, it was demonstrated that the effectiveness of corrosion protection had increased through a number of developments and studies. Recently, cathodic protection was applied to some reinforced concrete structures and has gradually expanded in scope in South Korea. Technical expertise is necessary to understand the underlying electrochemical principles and also because cathodic protection is important for normal physical maintenance. Therefore, in this study, we introduce the technical details and examples of applications of the cathodic protection of reinforced concrete, including the basic theory, principles, and other criteria.

Service Life Prediction and Cost Estimation of Repaired Concrete Structures Under Marine Environment (염해 환경 하 보수된 콘크리트 구조물의 사용수명 예측 및 보수 비용 평가)

  • Shim, Hyun Bo;Ann, Ki Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.1
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    • pp.226-234
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    • 2011
  • The service life of concrete structures exposed to a marine environment can be extended by controlling the amount of chloride in cover concrete. Patching is one of the appropriate maintenance techniques for chloride contamination. Chloride-contaminated cover concrete is removed and replaced with sound one. It can provide less risk of corrosion of steel, so that the structure can be maintained for required service life. In this study, a quantitative assessment of the service life subjected to the chloride attack is proposed to determine the effective repair options such as repair depth, repair material and timing of repair. The Crank-Nicolson based finite difference formulation from Fick's second law is proposed to predict the profiles of chloride ion in a repaired concrete structure, considering ingress of chloride from outer and redistribution of residual chloride from the substrate concrete. Therefore, the repair application times and maintenance cost for the target service life can be estimated. Finally, the numerical examples are presented to ensure its applicability.

An Experimental Study on the Fundamental Properties and Durability of Sewer Type Restorative Mortar Spread with Antibiotics (항균제를 도포한 하수시설용 단면복구 모르타르의 기초물성 및 내구특성에 관한 실험적 연구)

  • Kim, Moo-Han;Kim, Gyu-Yong;Kim, Jae-Hwan;Cho, Bong-Suk;Lee, Dong-Heck
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.3
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    • pp.195-202
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    • 2006
  • Deterioration of sewer concrete is representative that biochemical corrosion according to the $H_2S$ has growth by inhabit sulfur-oxidzing bacteria because of special environment in sewer. But in case of domestic, fundamentally, sulfur-oxidzing bacteria could moderate development of repair material method is need because of corrosion prevent method is inconsideration with carry out to improve project. In this paper, after development of spread type antibiotic with antibio-metal, antibacterial performance about sulfur-oxidzing bacteria of antibiotic and tested to estimate fundamental properties of bonding strength, abrasion contents, contents of water absorption, contents of air permeability, carbonation depth, chloride ion penetration depth and chemical resistance of spread with antibiotic restorative mortar.