• 제목/요약/키워드: 부식감소량

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원전 출력감발 운전에 따른 방사성 부식생성물 거동 분석

  • 성기방
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11a
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    • pp.103-109
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    • 1996
  • 고리 원자력 1호기 14주기(‘95년도) 운전기간 중 증기발생기 세관 열전달 용량 저하로 전출력 운전 기간동안 정격출력보다 15% 감발 운전한 경험이 있었는데, 이 기간중 냉각재내 방사성 부식생성물(CRUD) 농도가 약 80% 감소됨을 발견하였다. 이때 출력감소 비율보다 많은 CRUD 감소현상 규명을 위해 냉각재 수질관리인자와 EPRI 피복재 부식모델인 PFCC코드를 사용한 피 복재 산화물 두께변화 등을 비교한 결과, 운전중 용출되는 방사성 부식생성물은 핵연료 표면의 피복재 산화물에 흡착된 Co핵종이 피복재 산화물 이탈시 함께 거동하는 것으로 확인되었으며, 피복재 산화물 이탈은 산화막 두께 및 열유속에 주로 의존함이 밝혀졌다. 따라서 냉각재내에서 방사성 부식 생성물의 생성률 저감을 위해서는 정상운전시 핵연료 표면의 산화막 증가를 억제할 수 있는 수질 조건을 도출하고 그에따른 운전을 통해 원전 작업자의 방사선 피폭량 저감 및 방사성폐기물의 발생을 줄일 수 있을 것으로 여겨진다.

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Corrosion resistance of gallium-doped zinc oxide film depending on the hydrogen content (수소가스 함유량에 따른 Gallium-doped Zinc Oxide(GZO) 박막의 내식성 평가)

  • Jo, Su-Ho;Choe, In-Gyu;Kim, Sang-Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.188-188
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    • 2016
  • GZO 박막은 상업적으로 사용되는 ITO를 경제적으로 대체할 수 있는 유망한 투명 전도 물질이며, 인체에 무해하고, 공급이 쉬우며, 화학적으로 안정하다. 특히, CIGS와 같은 광전변환 소자 전극에서는 부식 저항이 매우 중요한데, 습한 환경에서 견뎌낼 수 있다는 장점이 있다. GZO는 3가 갈륨이 2가 아연에 도핑된 n타입의 반도체 물질이다. 그리고 육각형의 황화아연 물질의 전기 전도도는 산소 결핍에 매우 의존한다. GZO의 수소는 산소 결핍 집중에 영향을 끼친다. 따라서 이 연구에서는 RF 마그네트론 스퍼터링 실험 동안 수소 함유량을 다양화 시키고, 면 저항, 광 투과도, 부식저항의 효과를 조사한다. 수소량이 증가할수록, 면 저항은 향상되어지고, 특정 지점을 넘으면 감소한다. 분극 실험에 의해 측정되어진 부식 저항은 박막의 미세조직과 결정립계의 특성에 더 의존되어진다. 훨씬 더 많은 수소를 함량한 비정질이 부식 저항성에 있어서 유효한 차이를 나타내지 못하는 동안 결정 내에서 많은 수소를 지닌 작은 결정의 결정립계는 낮은 분극저항, 즉 낮은 부식 저항성의 결과를 도출한다.

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Damage Estimation of Steel Bridge Members by Fatigue Vulnerability Curves Considering Deterioration due to Corrosion with Time (시간에 따른 부식열화가 고려된 피로취약도 곡선을 이용한 강교의 손상 평가)

  • Kim, Hyo-Jin;Lee, Hyeong-Cheol;Jun, Suk-Ky;Lee, Sang-Ho
    • Journal of the Korean Society of Hazard Mitigation
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    • v.7 no.4
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    • pp.1-12
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    • 2007
  • A method for assessing fatigue vulnerability of steel bridge members considering corrosion and truck traffic variation with time is proposed to evaluate the reduction of fatigue strength in steel bridge members. A fatigue limit state function including corrosion and traffic variation effect is established. The interaction between the average corrosion depth and the fatigue strength reduction factor is applied to the limit state function as the reduction term of strength. Three types of truck traffic change is modeled for representing real traffic change trend. Monte-Carlo simulation method is used for reliability analysis which provides the data to obtain fatigue vulnerability curves. The estimation method proposed was verified by comparing with the results of reference study and applying to the steel bridges in service.

Reduction of the Flow Accelerated Corrosion within Low Pressure Evaporator Connection Pipe by Interception of Hydrazine for Water Treatment (탈산소제 차단 수처리에 의한 배열회수보일러 저압증기발생기 연결배관내의 유동가속부식 저감)

  • Son, Byung-Gwan;Lee, Jae-Heon
    • Plant Journal
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    • v.9 no.4
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    • pp.26-30
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    • 2013
  • Based on case that HRSG low pressure steam generator tube was damaged by FAC in 500 MW A CCPP. This case analyzed the effect of application about the block of hydrazine water treatment which is applied for increasing dissolved oxygen. And also try to deduce the major factor of FAC Which is caused by lacking of dissolved oxygen of boiler feed system. After 1 year of water treatment, the figure of dissolved oxygen in the boiler feed water has increased from 0.15 ppb to 3~5 ppb and the figure of oxidation reduction potential has increased from -245 mV to 170 mV. And Iron content, the corrosion products by FAC has decreased from 18.5 ppb to 5~7 ppb. According to the result of experiment, we could able to confirm that the interception of hydrazine of water treatment is effective to reduce FAC.

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Changes in Corrosion Progress and Ultimate load of Tendon Under 20% and 40% of Ultimate Loading Conditions (파괴하중의 20% 및 40% 인장조건에서 텐던 부식 진행 및 파괴하중 변화)

  • Ryu, Hwa-Sung;An, Gi Hong;Hwang, Chul-Sung;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.4
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    • pp.47-52
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    • 2017
  • PSC (Prestressed Concrete) structures have been used widely for its engineering advantage with using total concrete area as effective compressive section. However tendon inside is exposed to such a high tensile stress that and more attentions should be paid for corrosion control. This work is for changing corrosion current and ultimate strength in tendon with increasing prestressing force in a constant corrosive condition. With increasing prestressing force, corrosion current, corrosion amount, and ultimate load are changed linearly. When prestressing force increases from 20.0 % to 40.0 %, corrosion current increases to 124.4 % and 168.0 % and ultimate load decreases to 87.8 % and 78.4 %, respectively. With inducing constant electrical potential, increasing corrosion current and reduction of strength are evaluated to be linearly related with increasing prestressing load.

A Fundamental Study on Evaluation of Web Crippling Strength of Corroded H-Beams (부식 H형 강재의 복부좌굴강도 추정에 관한 기초적 연구)

  • Kim, In-Tae;Shin, Chang-Hee;Cheung, Ji-Young
    • Journal of Korean Society of Steel Construction
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    • v.22 no.5
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    • pp.421-433
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    • 2010
  • The most typical deterioration of steel structures is corrosion damage. However, a method to evaluate residual load-carrying capacity of corroded steel structures is not yet established. It is difficult to check current serviceability and safety of the structures. In this study, compressive tests and finite element analyses were conducted on H-beams with corroded web. Then, the effect of corrosion damage on web crippling strength and evaluation methods of the web crippling strength are studied. Based on the tests, 4 H-beam specimens used in a subway construction site and 9 H-beam specimens with different web-thickness and damaged-height underwent compression-tests. To consider loading and supporting areas in the site, compressive loading was applied in the entire region of the upper and bottom flange in 5 H-beam specimens and applied partially on the regions of the upper and bottom flange in 8 specimens. The finite element analysis of 38 parametric model specimens simulating different corrosion damages was also carried out. From experimental and analytical results, the relationships between corrosion damages in the web and residual web crippling strength are presented. Factors web crippling strength was reduced are formulated by using residual average thickness and the standard deviation of the corroded web thickness. Also, a simple evaluation method of residual web crippling strength was proposed.

Mo 첨가 및 소둔 열처리에 따른 합금 690의 부식 저항성 및 기계적 특성

  • 전유택;박용수;김영식
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05b
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    • pp.597-602
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    • 1995
  • 원자력 발전소 증기발생기 전열관 재료인 합금 600의 대체재료로써 설계된 합금 690의 내식성의 향상을 위해서 염소 이온이 다량 포함된 환경에서의 부식 저항성을 크게 향상시킨다고 보고된 Mo을 첨가하여 부식 및 기계적 특성에 미치는 영향을 알아보았다. 미세조직상 Mo를 첨가함에 따라 기지에 미세한 석출물이 석출되어 입자의 미세화를 얻을 수 있었으며 연신율의 감소없이 항복 강도, 인장 강도 및 경도의 향상을 얻을 수 있었다. 공식 저항성은 Mo의 첨가량이 증가함에 따라 부식 속도가 감소하였다. 양극 분극 시험에서도 5$0^{\circ}C$, 3.5wt% NaCl 용액과 0.5N HCl 용액 모두에서 Mo의 함량이 증가할수록 부동태화 전류 밀도 및 임계 부동태화 전류 밀도가 감소하여 전반적으로 현저한 내식성의 향상을 관찰할 수 있었다.

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저방사화 Cr-Mn-W-V계 스테인리스강의 미세 조직 특성 및 부식 저항성에 미치는 질소첨가와 소둔 열처리의 영향

  • 장현영;박용수;김영식
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05b
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    • pp.591-596
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    • 1995
  • 핵융합로 제1벽재로서 주목받고 있는 저방사화 Cr-Mn-W계 오스테나이트 스테인리스강에 소량의 V을 첨가하고 그 기본 조성에 시그마상의 생성억제와 합금의 고온강도 향상에 효과가 있는 질소함량을 변화시켜 미세 조직 특성 및 부식 저항성에 미치는 영향을 살펴보았다. 질소함량의 변화에 의한 영향과 더불어 소둔열처리 온도의 영향도 살펴보았다. 부식저항성 평가를 위해서는 양극분극시험, 침지시험, Huey시험을 행하였으며, 기계적 성질 평가를 위해서는 경도시험 및 인장 시험을 행하였다 그 결과 질소량이 증가할수록 오스테나이트상이 안정화되어 그 양이 증가하며 고용강화에 의해 경도치도 함께 증가함을 알 수 있었다 경도치는 또한 소둔온도가 증가함에 의해 감소함을 알 수 있었다. 한편 소둔온도가 증가할수록 페라이트량이 증가함을 확인하였다. 부식저항성은 질소량이 증가할수록 소둔온도가 증가할수록 향상됨을 알 수 있었다.

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Evaluation of Relative Corrosion Rate depending on Local Location and Installation of Structural Member in Steel Water Gate (강재 수문의 부재 위치 및 설치 방향에 따른 상대 부식속도 평가)

  • Ha, Min-Gyun;Jeong, Young Soo;Park, Seung hun;Ahn, Jin-Hee
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.7
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    • pp.16-24
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    • 2019
  • The corrosion amounts of steel structures can be different depending on their installation condition and height. Thus, their corrosion maintenance should be considered depending on installation conditions of local structural members. In this study, an atmospheric exposure test was conducted to evaluate the corrosion amount and the corrosion rate depending on the installation condition and height of a steel water gate using monitoring steel plates and corrosion environment measuring sensors. The mean corrosion depth was evaluated using the weight loss method and the galvanic corrosion current was measured by corrosion environment measuring sensors. Local corrosion rate of local structural member in steel water gate was estimated using measured mean corrosion depths and galvanic corrosion currents. From this measurement results, the corrosion damage in horizontal member of the cross beam was highly evaluated than those of other structural member as skin plate, etc. The relative difference in the corrosion rate of a local structural member could be highly affected by local corrosion environments of steel water gate members. Therefore, an appropriate maintenance method should be considered for local corrosion damages of local structural members determined by local corrosion environments of a steel water gate.

Relationship between Half Cell Potential and Corrosion Amount Considering Saturated Cover depth and W/C ratios in Cement Mortar (습윤상태의 피복두께와 물-시멘트비를 고려한 반전위와 철근 부식량의 상관성)

  • Ryu, Hwa-Sung;Park, Jae-Sung;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.3
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    • pp.19-26
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    • 2017
  • Concrete is a construction material with porous media and corroded steel inside affects negatively to durability and structural safety. This study aims a derivation of quantitative relationship between measured HCP (Half Cell Potential) and corrosion amount considering cover depth and W/C (water to cement) ratio. For the work, cement mortar specimens with 3 different W/C ratios and 4 different cover depths are prepared, HCPs are measured with 3 different corrosion level. HCP measurement significantly increases in the saturated condition and linear relationship is observed between corrosion level and acceleration period. With increasing corrosion level and W/C ratio, and decreasing cover depth, HCP measurement increases. Considering total corrosion level and HCP measurements, relatively low COV(Coefficient of Variation) of 0.67 is evaluated through multi-linear regression analysis, however higher COVs over 0.90 can be obtained considering level of HCP measurement. In the room condition, corrosion level can be evaluated through measured HCP in the given conditions of cover depth, W/C ratio. diameter of steel inside.