DOI QR코드

DOI QR Code

Relationship between Half Cell Potential and Corrosion Amount Considering Saturated Cover depth and W/C ratios in Cement Mortar

습윤상태의 피복두께와 물-시멘트비를 고려한 반전위와 철근 부식량의 상관성

  • 류화성 ((주)한양E&C) ;
  • 박재성 (한남대학교 건설시스템공학과) ;
  • 권성준 (한남대학교 건설시스템공학과)
  • Received : 2017.01.11
  • Accepted : 2017.03.21
  • Published : 2017.05.01

Abstract

Concrete is a construction material with porous media and corroded steel inside affects negatively to durability and structural safety. This study aims a derivation of quantitative relationship between measured HCP (Half Cell Potential) and corrosion amount considering cover depth and W/C (water to cement) ratio. For the work, cement mortar specimens with 3 different W/C ratios and 4 different cover depths are prepared, HCPs are measured with 3 different corrosion level. HCP measurement significantly increases in the saturated condition and linear relationship is observed between corrosion level and acceleration period. With increasing corrosion level and W/C ratio, and decreasing cover depth, HCP measurement increases. Considering total corrosion level and HCP measurements, relatively low COV(Coefficient of Variation) of 0.67 is evaluated through multi-linear regression analysis, however higher COVs over 0.90 can be obtained considering level of HCP measurement. In the room condition, corrosion level can be evaluated through measured HCP in the given conditions of cover depth, W/C ratio. diameter of steel inside.

콘크리트는 다공성 건설재료이며, 매립된 철근의 부식은 내구성 및 안전성에 큰 영향을 미친다. 본 연구는 비파괴 검사인 반전위측정값과 생성된 부식량과의 상관성을 피복두께, 물-시멘트비를 고려하여 도출하는 것이다. 이를 위해, 3가지 수준의 물-시멘트비와 4가지 수준의 피복두께를 가진 시멘트 모르타르 시편이 제조되었으며, 3가지 수준의 촉진부식기간을 고려하여 부식량 및 반전위를 측정하였다. 습윤상태에서는 반전위가 크게 증가하였으며, 부식량과 촉진기간은 선형적인 관계를 가지고 있었다. 부식량이 증가할수록, 피복두께가 감소할수록, 물-시멘트비가 증가할수록 반전위는 증가하였다. 전체의 반전위 측정값을 부식량과 비교할 경우 0.67의 낮은 결정계수를 가지고 있었으나 부식량(촉진기간)을 고려하여 3가지 수준을 고려할 경우 0.90이상의 높은 결정계수를 가지고 있었다. 실내조건과 같이 온도가 일정하고 포화상태일 경우, 측정된 반전위는 부식량과 선형적인 상관성을 가지고 있었으며, 피복두께, 물-시멘트비, 철근직경, HCP의 측정범위를 알 수 있다면, 매립된 철근의 부식량을 예측할 수 있다고 판단된다.

Keywords

References

  1. Alonso, C., Andrade, C., and Gonzalez, J. A. (1988), Relation between Resistivity and Corrosion Rate of Reinforcements in Carbonated Mortar made with Several Cement Types, Cement and Concrete Research, 18(5), 687-698. https://doi.org/10.1016/0008-8846(88)90091-9
  2. Adams, R. D., and Cawley, P. (1989), Defect types and non destructive testing techniques for composites and bonded joints, Construction and Building Materials, 3(4), 170-183. https://doi.org/10.1016/0950-0618(89)90011-1
  3. Andrade, C. (1993), Calculation of chloride diffusion coefficients in concrete from ionic migration measurement, Cement and Concrete Research, 23(3), 724-742. https://doi.org/10.1016/0008-8846(93)90023-3
  4. Andrade, C., and Alonso, C. (1996), Corrosion rate monitoring in the laboratory and on-site, Construction and Building Materials, 10(5), 315-328. https://doi.org/10.1016/0950-0618(95)00044-5
  5. ASTM C876-09 (2009), Standard Test Method for Corrosion Potentials of Uncoated Reinforcing Steel in Concrete, American Society of Testing and Materials, 1-6.
  6. Broomfield, J. P. (1997), Corrosion of Steel in Concrete: Understanding, Investigation and Repair, E&FN, London, 1-15.
  7. Baek, S. H., Xue, W., Feng, M. Q., and Kwon, S. J. (2012), Nondestructive Corrosion Detection in RC through Integrated Heat Induction and IR Thermography, Journal of Non Destructive Evaluation, 31(2), 181-190.
  8. Chung, L., Jay kim, J. H., and Yi, S. T. (2008), Bond Strength Prediction for Reinforced Concrete Members with Highly Corroded Reinforcing Bars, Cement and Concrete Composites, 30(7), 603-611. https://doi.org/10.1016/j.cemconcomp.2008.03.006
  9. DuraCrete Final Report. (2000), DuraCrete Probabilistic Performance Based Durability Design of Concrete Structures.
  10. Elsener, B., Andrade, C., Gulikers, J., Polder, R., and Raupach, M. (2003), Hall-Cell Potential Measurements-Potential Mapping on Reinforced Concrete Structures, Materials and Structures, 36(7), 461-471. https://doi.org/10.1007/BF02481526
  11. Elsener, B. (2005), Corrosion Rate of Steel in Concrete Measurements beyond the Tafel law, Corrosion Science, 47(12), 3019-3033. https://doi.org/10.1016/j.corsci.2005.06.021
  12. Ferreira, M., Arskog, V., Jalali, S., and Gjorv, O. E. (2004), Probability- Based Durability Analysis of Concrete Harbor Structures, Proceedings of CONSEC04, 999-1006.
  13. Kwon, S. J., and Park, S. S. (2012), Non Destructive Technique for Steel Corrosion Detection using Heat Induction and IR Thermography, Journal of the Korea Institute for Structural Maintenance and Inspection, 16(2), 40-48. https://doi.org/10.11112/jksmi.2012.16.2.040
  14. Kwon, S. J., Na, U. J., Park, S. S., and Jung, S. H. (2009), Service Life Prediction of Concrete Wharves with Early-aged Crack: Probabilistic Approach for Chloride Diffusion, Structure and Safety, 31(1), 75-83. https://doi.org/10.1016/j.strusafe.2008.03.004
  15. Kim, K. B., Park, K. T., and Kwon, S. J. (2013), Evaluation of Half Cell Potential Measurement in Cracked Concrete Exposed to Salt Spraying Test, Journal of the Korea Concrete Institute, 25(6), 621-630. https://doi.org/10.4334/JKCI.2013.25.6.621
  16. Kim, Y. Y., Kim, J. M., Bang, J. W., and Kwon, S. J. (2014), Effect of Cover Depth, w/c ratio, and crack width on half cell potential in cracked concrete exposed to salt sprayed condition, Construction and Building Materials, 54(15), 636-645. https://doi.org/10.1016/j.conbuildmat.2014.01.009
  17. Liu, T., and Weyers, R. W. (1998), Modeling the Dynamic Corrosion Process in Chloride Contaminated Concrete Structures, Cement and Concrete Research, 28(3), 365-379. https://doi.org/10.1016/S0008-8846(98)00259-2
  18. Lim, Y. C. (2012), A Study on the Estimation of Moisture Condition of Concrete by Resistivity Method, Journal of Korea Architecture Institute, 28(12), 69-76.
  19. Maierhofer, C. H., Arndt, R., Röllig, M., Rieck, C., Walther, A., Scheel, H., and Hillemeier, B. (2006), Application of Impulse-Thermography for Nondestructive Assessment of Concrete Structures, Cement and Concrete Composites, 28(4), 393-401. https://doi.org/10.1016/j.cemconcomp.2006.02.011
  20. Maekawa, K., Ishida, T., and Kishi, T. (2009), Multi-Scale Modeling of Structural Performance, Journal of Advanced Concrete Technology, 1(2), 322-325.
  21. Park, S. S., Kwon, S. J., and Jung, S. H. (2012), Analysis technique for chloride penetration in cracked concrete using equivalent diffusion and permeation, Construction and Building Materials, 29(2), 183-192. https://doi.org/10.1016/j.conbuildmat.2011.09.019
  22. RILEM. (1994), Durability Design of Concrete Structures, Report of RILEM Technical Committee 130-CSL, E&FN, London, 28-52.
  23. Saraswathy, V., Muralidharan, S., and Srinivasan, S. (2003a), Electrochemical Studies on the Corrosion Performance of Activated Fly ash Blended Cements, Materials Engineering, 14(3), 261-283.
  24. Saraswathy, V., Muralidharan, S., Thangavel, K., and Srinivasan, S. (2003b), Influence of Activated Fly ash on Corrosion Resistance and Strength of Concrete, Cement and Concrete Composites, 25(7), 673-680. https://doi.org/10.1016/S0958-9465(02)00068-9
  25. Song, H. W., Kwon, S. J., Byun, K. J., and Park. C. K. (2005), A Study on analytical technique of chloride diffusion considering characteristics of mixture design for high performance concrete using mineral admixture, Journal of KSCE, 25(1A), 213-223.
  26. Song, H. W., and Saraswathy, V. (2006), Studies on the Corrosion Resistance of Reinforced Steel in Concrete with Ground Granulated Blast-Furnace Slag-An overview, Journal of Hazardous Materials, 138(2), 226-233. https://doi.org/10.1016/j.jhazmat.2006.07.022
  27. So, H. S. (2006), Environmental Influences and Assessment of Corrosion Rate of Reinforcing Bars using the Linear Polarization Resistance Technique, Journal of Korea Architecture Institute, 22(2), 107-114.
  28. Sakurada, S., Irie, H., and Yoshida, Y. (2008), Development of Reinforced Concrete Corrosion Amount Presumption Method by Ultrasonic Method, 17th World Conference on Nondestructive Testing, Shanghai, China, 1-6.
  29. Song, H. W., Lee, C. H., and Lee, K. C. (2009), A Study on Corrosion Potential of Cracked Concrete Beam according to Corrosion Resistance Assessment, Journal of the Korea Institute for Structural Maintenance and Inspection, 13(1), 97-105.
  30. Thomas M. D. A., and Bamforth, P. B. (1999), Modeling chloride diffusion in concrete: Effect of fly ash and slag, Cement and Concrete Research, 29(4), 487-495. https://doi.org/10.1016/S0008-8846(98)00192-6
  31. Yokozeki, K., Okada, K., Tsutsumi, T., and Watanabe, K.(1998), Prediction of the service life of RC with crack exposed to chloride attack, Japan Symposium of Rehabilitation of Concrete Structure, 10(1), 1-6.