• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.86.2-86.2
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• 2011

저온형 연료전지인 직접 메탄올 연료전지(Direct Methanol Fuel Cells, DMFC)는 친환경적인 발전 시스템, 높은 에너지 효율의 장점 때문에 주목을 받고 있으나 연료극의 촉매로 사용되는 금속은 고가의 귀금속인 Pt와 Ru가 요구되어 제조비용이 비싸기 때문에 촉매의 양을 줄이고, 반응 도중 생성되는 CO에 의한 촉매의 피독 문제 등 해결하여야 할 점이 산적해 있어 연료전지 중 촉매의 활성을 높이는 연구들이 활발히 이루어지고 있다. 종래의 MEA의 촉매층 제조공정은 우선 환원석출법에 의해 Pt-Ru/C를 합성하고 Nafion 용액에 혼합하여 Pt-Ru/C 슬러리를 제조한다. 이 방법에서는 carbon sheet에 spray 방법으로 Pt-Ru/C 촉매층이 만들어지기 때문에, Pt-Ru 촉매가 Nafion에 의해 부분적으로 매몰되어 촉매의 전기화학적 활성이 떨어지는 문제점이 있다. 이를 해결하는 방안으로 펄스전류를 이용하여 Pt-Ru 합금입자를 carbon sheet에 전기화학적으로 담지 시켜 Nafion에 매몰되는 것을 방지하는 펄스전해법 연구가 진행되고 있다. 그러나 촉매의 입자크기가 일반적으로 50~70 nm 이상으 크기 때문에 촉매의 낮은 활성이 문제점으로 야기되고 있다. 본 연구에서는 Pt-Ru/C 촉매층 제조 문제점을 해결하고, 촉매의 전기화학적 활성을 증가시키기 위해서 2~4 nm Pt-Ru 콜로이드를 전해액으로 사용하고, 전기영동법을 이용하여 Pt-Ru 나노 입자를 carbon sheet($1{\times}1cm^2$) 에 담지 시켰다. 전기영동법에서 균일한 Pt-Ru 촉매층의 제조를 위해 전류인가 방법으로는 펄스전류를 사용하였고, 실험변수로는 전해액 pH, duty cycle, 담지시간을 선정하였다. 합성된 Pt-Ru 콜로이드를 TEM분석으로 나노입자의 크기와 분산성 분석하였고, 콜로이드 나노입자의 표면전하 상태를 분석하기 위해 zeta-potential을 분석하였다. Pt-Ru/C의 촉매의 전기화학적 활성을 분석하기 위하여 0.5 M H_2SO_4$ 와 1 M $CH_3OH$ 혼합용액에 CV(Cyclic Voltammetry)실시하였고, carbon sheet 전극 상 Pt-Ru의 분산성 확인을 위하여 FE-SEM분석을 수행하였다.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2001.05a
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• pp.786-792
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• 2001

In this paper, the identification of connections for a vibration system has been presented using FRF-based substructural sensitivity analysis. The substructural design sensitivity formula is derived and plugged into a commercial optimization program, MATLAB, to identify connection stiffness of an air-conditioner system of passenger car. The air-conditioner system, composed of a compressor and a bracket is analyzed by using FRF-based substructural(FBS) method. To obtain the FRFs, FE model is built for the bracket, and the impact hammer test is performed for the compressor. Obtained FRFs are combined to calculate the reaction force at the connection point and the system response. Connection element properties are determined by minimizing the difference between a target FRF and calculated one. It is shown that the proposed identification method is effective even for a real problem.

• Polymer(Korea)
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• v.33 no.2
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• pp.158-163
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• 2009

In this study, we synthesized a series of dendritic polystyrene-b-linear poly (t-butyl acrylate) copolymers with well-defined molecular architectures. The hydroxyl group located at the focal point of the second generation dendron bearing polystyrene ($M_n$ = 1000 g/mol) peripheries was converted into amine group via the following stepwise reactions: 1) tosylatoin, 2) azidation, and 3) reduction. On the other hand, the linear poly (t-butyl acrylate)s were prepared by an atom transfer radical polymerization (ATRP) of t-butyl acrylate where benzyl 2-bromopropanoate and Cu(I)Br/PMDETA were used as initiator and catalyst, respectively. To convert the end group of prepared poly (t-butyl acrylate) s into carboxylic acid, a debenzylation was performed using Pd/C catalyst under $H_2$ atmosphere. In the final step, dendritic-linear block copolymers were obtained through a simple amide coupling reaction mediated by 4-(dimethylamino) pyridine(DMAP) and N,N'-diisopropylcarbodiimide(DIPC). The resulting diblock copolymers were shown to have well-defined molecular weights and narrow molecular weight distributions as supported by $^1H$-NMR spectroscopy and gel permeation chromatography(GPC).

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.18 no.8
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• pp.8-17
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• 2019

In this study, a model reduction technique was used to develop a precise noise and vibration prediction model for the individual components of a driveline system. The dynamic reduced-order model generated by the Craig-Bampton method was applied to perform dynamic analysis of an electric agricultural power cart. The natural frequency and acceleration response results were analyzed according to the different number of dominant sub-structural modes contained in the reduced-order models. Through the analysis results, it was confirmed that a sufficient number of dominant sub-structures to satisfy the operating conditions should be selected to construct an optimal reduced-order model.

• Transactions of the Korean hydrogen and new energy society
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• v.16 no.2
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• pp.111-121
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• 2005

이 연구는 광화학적 물분해 수소제소 기술의 일환으로 수행 중인 광촉매와 바이오촉매를 복합한 시스템 활용 기술에서 광촉매가 갖는 물리적 특성의 영향을 파악하고자 진행되었다. 다양한 물리적 특성을 갖는 광촉매 얻기 위하여 상용광촉매, 수열화법(HT-TiON), 리고 저온합성법(LT-TiON) 등을 이용하여 샘플을 준비하였다. 가시광 감응을 위하여 암모니아나 triethylamine 처리를 하여 질소를 도핑도 시도하였다. 시도된 복합시스템은 인위적인 전자주개 없이 수소를 발생시키는 결과를 보여주었으나, 광촉매로부터 엔자임으로의 전자전달 부분이 율속단계로 확인되었다. 사용된 광촉매 샘플에 따라 수소발생량에 차이가 나타난 결과로 광촉매의 미세구조 (결정상, 결정도, 기공 크기 및 비표면적 등)이 중요한 역할을 하는 것으로 판단되었다. 얻어진 결과들을 활용하여 재료들이 고정화된 새로운 시스템 구성을 제안하였다.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.11 no.7
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• pp.287-294
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• 2001

The identification of connection stiffnesses of bolted structures is presented using FRT-based substructural sensitivity analysis. The substructural design sensitivity formula is derived and plugged into the optimization module of MATLAB to identify connection stiffnesses of an air-conditioner compressor or passenger Car. The air-conditioner composed of a compressor and a bracket, is analysed by using the FRT-based substructural(FBS) method to obtain FTRs an FE model is generated for the bracket, and the impact hammer test is performed for the compressor, Obtained FRTs are combined to calculate the reaction force at the connection point and the system response. By minimizing the difference between a target FRT and calculated one the connection element properties of the air-conditioner syste are identified It is shown that the proposed identification method is effective for a real problem.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.3
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• pp.253-261
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• 2014

In this paper, vibration analysis of power differential gear train for 2.5MW wind turbine system is analyzed. which system is composed of two planetary gear set, one helical gear set and main shaft that connected by flange. Planetary gear set, helical gear set, main shaft are modeled in MASTA program and housing, torque arm, carrier, flange components are modeling by finite element method. Each models are combined by component mode superposition. To analysis of natural vibration characteristic about 2.5MW wind turbine gear train was performed and check about critical speed with wind load, mass unbalance, angle misalignment excitation frequency.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.4A
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• pp.457-463
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• 2008

The longitudinal stiffener performs its role to increase the local buckling strength by making simple support upon compression flange. In the recent researches, it is investigated that compression flange with point supports on certain arrangement reveals the same strength with longitudinal stiffeners. From this results, it is predictable that shear stud could perform the role of longitudinal stiffener if shear stud embedded in concrete satisfies the requirement to point-support under yield stress of the compression flange. In this study, the researches were performed to investigate the optimally required arrangement space of longitudinal point-support for which the shear stud replacing the longitudinal stiffeners and simultaneously determine the required numbers and space of shear stud for completely composite behavior between compression bottom flange and bottom concrete on the double composite girder system.

• Journal of Korean Society of Steel Construction
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• v.10 no.4 s.37
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• pp.759-767
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• 1998

Full-depth precast concrete deck bridge has shear pockets for shear connectors that give composite action with steel girder. Strength and shear stiffness of shear connection that is needed to design shear connectors in case that shear pockets are filled with nonshrink mortar are investigated. In case that simple span full-depth precast concrete deck bridge is designed by allowable stress design, distribution of shear connector is suggested and details of precast panel that is placed on the support are proposed. Appropriate distribution of shear connectors in strength design and fatigue design is investigated through parameter analyses using partial interaction theory. The effects of nonshrink mortar strength is studied using the results of experiments and analyses and adequate strength is proposed.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.37 no.6
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• pp.519-526
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• 2009

This paper describes a research result of a external shape optimization study to maximize the range of the guided missile with canards and tailfins in atmospheric flight. For this purpose, the external shape optimization program which can enhance the range of a missile was developed, incorporated with the trajectory analysis and the optimization technique. In the trajectory analysis part, Missile DATCOM which utilizes the semi-empirical method was directly connected to the trajectory code to supply the aerodynamic coefficients efficiently at every time step. In the gliding flight trajectory after apogee, a maximum $C_L/C_D$ trim condition calculation module was attached under the assumption of the missile continuously flying at maximum $C_L/C_D$ condition. In the optimization part, a Response Surface Method(RSM) was adopted to reduce the computing time.