• Title/Summary/Keyword: 부분산화

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Growth Characteristics of Nitrite Oxidizing Bacteria Isolated from Anaerobic Digestion Liquor (혐기소화액에서 분리한 아질산 산화세균의 생장특성)

  • Jang, Hyun-Min;Jang, Jae-Eun;Kim, Young-Jun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.1
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    • pp.73-80
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    • 2010
  • Two nitrite oxidizing bacteria, NOB1 and NOB2, were isolated from anaerobic digester liquer of food wastewater and analyzed for their growth characteristics and the ability to oxidize nitrite under different temperature, pH, and DO( dissolved oxygen) concentrations. Both of the isolated strains have shown the best growth at pH 7.0 and at $35^{\circ}C$, and also shown higher growth rate with the increasing dissolved oxygen concentrations. As the factors to restrict the growth of these strains, parameters such as pH and DO were found to be effective ones, by increasing (up to 9.0) or decreasing pH (up to 5.0), or lowing DO below 1.0 ppm. Especially, the ability to oxidize nitrite in both strains was about 50% lower in below 1.0 ppm of DO than above of 1.0 ppm. NOB2 was found to be two times greater in both the growth rate and the nitrite-oxidizing ability than NOB1.

Effects of Forest Environmental Changes on Soil Characteristics by Forest Fire (산화에 의한 산림환경변화가 토양의 특성에 미치는 영향)

  • Nam, Yi;Min, Ell-Sik;Chang, Kwan-Soon;Park, Kwan-Soo;Lee, Yoon-Won
    • Journal of Korea Soil Environment Society
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    • v.3 no.2
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    • pp.61-70
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    • 1998
  • This research has been made for influence of forest environmental changes, such as tree-clearcutting affecting to soil chemical and physical properties, on water storage capacity at forest fire land in Keumsan, Chungnam. The analyzed factors were bulk density, porosity, field moisture saturated hydraulic conductivity air permeability and organic matter content, Field moisture saturated hydraulic conductivity and air permeability at uncutting sites were higher than those at clearcutting sites, especially the most differences were appeared at lower slope. After 2 years passed since forest fire, the most changeable parts of soil characteristics were 5-l5cm depth below soil surface. Total Porosity, coarse pore and fine pore at uncutting sites were higher than those at clearcutting sites. Also, as soil depth increased, total porosity and coarse pore were decreased. Bulk density at uncutting sites was lower than that at clearcutting sites, and was decreased as soil depth increased. The order of the change trend in field moisture saturated hydraulic conductivity, air permeability and porosity was slope lower>middle>upper. Organic matter content at uncutting sites were higher than those at clearcutting sites, and decreased as soil depth increased. As soil depth increased, bulk density had the positive correlation, in other hand, porosity, coarse pore, field moisture saturated hydraulic conductivity, air permeability and organic matter content had the negative correlation. It was concluded that forest environmental changes by forest fire degrade soil physical and chemical properties.

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A study on the oxide etching using multi-dipole type magnetically enhanced inductively coupled plasmas (자장강화된 유도결합형 플라즈마를 이용한 산화막 식각에 대한 연구)

  • 안경준;김현수;우형철;유지범;염근영
    • Journal of the Korean Vacuum Society
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    • v.7 no.4
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    • pp.403-409
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    • 1998
  • In this study, the effects of multi-dipole type of magnets on the characteristics of the inductively coupled plasmas and $SiO_2$ etch properties were investigated. As the magnets, 4 pairs of permanent magnets were used and, to etch $SiO_2, C_2F_6, CHF_3, C_4F_8, H_2$, and their combinations were used. The characteristics of the magnetized inductively coupled plasmas were investigated using a Langmuir probe and an optical emission spectrometer, and $SiO_2$ etch rates and the etch selectivity over photoresist were measured using a stylus profilometer. The use of multi-dipole magnets increased the uniformity of the ion density over the substrate location even though no significant increase of ion density was observed with the magnets. The use of the magnets also increased the electron temperature and radical densities while reducing the plasma potential. When $SiO_2$ was etched using the fluorocarbon gases, the significant increase of $SiO_2$ etch rates and also the increase of etch uniformity over the substrate were obtained using the magnets. In case of gas combinations with hydrogen, $C_4F_8/H_2$ showed the highest etch rates and etch selectivities over photoresist among the gas combinations with hydrogen used in the experiment. By optimizing process parameters at 1000 Watts of inductive power with the magnets, the highest $SiO_2$ etch rate of 8000 $\AA$/min could be obtained for 50% $C_4F_8/50% H_2$.

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Oxidative Stress and Antioxidant Responses in Poplar Clones Irrigated with Livestock Waste Leachate (양돈폐수 처리에 의한 포플러클론의 산화스트레스와 항산화반응)

  • Je, Sun-Mi;Yeo, Jin-Gi;Woo, Su-Young
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.13 no.3
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    • pp.140-147
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    • 2011
  • We studied the influence of livestock waste leachate on oxidative damage and antioxidative responses in poplar clones in August which increase the demand of antioxidants because of high temperature and high light during this period. We measured ion leakage, antioxidant enzyme activities (APX, GR), and carotenoid contents. Oxidative damage and antioxidative responses by treated livestock waste leachate in poplar clones showed various results. We divided poplar clones into three groups using the criteria based on ion leakage which represent cell damage induced oxidative stress. Eco 28, 62-10, Bonghwa1 and Dorskamp belonged to the first group in which the cell damaged level was lower than that of the control. The results suggest that this group augmented for demand of antioxidative in summer because high concentration of nitrogen induced by treatment of live stock wastes acted as environmental stress. Consequently, they failed to keep up the homeostasis of reactive oxygen species. The second group in which the cell damaged level was similar to that of the control was Suwon, 72-30 and 72-31 clones. Finally, 97-18 clone belonged to the third group in which the cell damaged level was lower than that of the control group. In this case, nitrogen treated by livestock waste leakage decreased oxidative stress. 97-18 clone was the clones with the least damage in summer oxidative stresses treated by livestock waste leakage. These results suggest that the high concentration nitrogen due to the livestock waste leakage can act differently upon the clones. We speculate that the added oxidation damage in the summer (growing season) may have an effect on the total fresh weight and also influence the purification ability for livestock waste leakage. However, further studies are needed for the confirmation.

Analysis on Propagation Characteristics and Experimental Verification of $A_1$ Circumferential Waves in Nuclear Fuel Rods Coated with Oxide Layers (산화막 피복 원전 연료봉에서 $A_1$ 원주파의 전파 특성 해석과 실험적 검증)

  • Joo, Young-Sang;Ih, Jeong-Guon;Jung, Hyun-Kyu;Cheong, Yong-Moo
    • Journal of the Korean Society for Nondestructive Testing
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    • v.19 no.3
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    • pp.189-199
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    • 1999
  • The resonance scattering of acoustic waves from the cylindrical shells of nuclear fuel rods coated with oxide layers has been theoretically modeled and numerically analyzed for the propagation characteristics of the circumferential waves. The normal mode solutions of the scattering pressure of the coated shells have been obtained. The pure resonance components have been isolated using the newly proposed inherent background coefficients. The propagation characteristics of resonant circumferential waves for the shells coated with oxide layers are affected by the presence and the thickness of an oxide layer. The characteristics have been experimentally confirmed through the method of isolation and identification of resonances. The change of the phase velocity of the $A_1$ circumferential wave mode for the coated shell is negligible at the specified partial waves in spite of the presence of the oxide layer and the increase in coating thickness. Utilizing the invariability characteristics of the phase velocity of the $A_1$ mode, the oxide layer thickness of the coated shells can be estimated. A new nondestructive technique for the relative measurement of the coating thickness of coated shells has been proposed.

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Characteristics of Heavy Metal Distribution in Surface Sediments from the south Sea of Korea (남해 대륙붕 표층퇴적물 중 중금속 원소의 분포 특성)

  • 조영길;이창복
    • 한국해양학회지
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    • v.29 no.4
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    • pp.338-356
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    • 1994
  • Sediment samples from the continental shelf of the South Sea of Korea are analysed to determine the concentration of Al, Fe, Mn, cu, Ni, Zn, Co, Cr and Pb. among these samples, fine-grained sediments were also analysed by a sequential extraction technique to know geochemical forms of the metals in this environments. The total concentration of Al, Fe, Cr, Ni, Cu and Zn in bulk sediments decreased gradually with the increase of distance from the coastal zone. This distribution patterns are well coincide with grain size distribution. However, the patterns of Mn, co and Pb do not follow such and overall distribution. The concentration of Pb, particularly, did not show any features in areal distribution, which may be result from different pathways to the sediments, compared to the other metals. the speculation data show that a considerable amount of Cd, Mn and Co are bounded in the carbonate fraction, accounting for 42.8%, 40.3% and 30.6%, respectively. Cu, Zn, Mn and Fe are largely associated to oxide fraction with proportions of 34.4%, 23.1%, 15.5% and 13.7%, respectively. However, the metals in residual fraction account for more than 50% of the total metal concentration, except for Mn. These observations emphasize that residual fraction in the dominant component controlling the elemental concentration.quartz and glauconite grains.Accordingly,these sediments are interpreted as an extension part of transgressive sand deposit that are widely distributed on the continental shalf floor of southern Yellow Sea.

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Characteristic of Partial Oxidation of Methane and Ni Catalyst Reforming using GlidArc Plasma (GlidArc 플라즈마를 이용한 메탄 부분산화 및 Ni 촉매 개질 특성)

  • Kim, Seong-Cheon;Chun, Young-Nam
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.12
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    • pp.1268-1272
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    • 2008
  • Low temperature plasma applied with partial oxidation is a technique to produce synthesis gas from methane. Low temperature plasma reformer has superior miniaturization and start-up characteristics to reformers using steam reforming or CO$_2$ reforming. In this research, a low temperature plasma reformer using GlidArc discharge was proposed. Reforming characteristics for each of the following variables were studied: gas components ratio (O$_2$/CH$_4$), the amount of steam, comparison of reaction on nickle and iron catalysts and the amount of CO$_2$. The optimum conditions for hydrogen production from methane was found. The maximum Hydrogen concentration of 41.1% was obtained under the following in this condition: O$_2$/C ratio of 0.64, total gas flow of 14.2 L/min, catalyst reactor temperature of 672$^{\circ}C$, the amount of steam was 0.8, reformer energy density of 1.1 kJ/L with Ni catalyst in the catalyst reactor. At this point, the methane conversion rate, hydrogen selectivity and reformer thermal efficiency were 66%, 93% and 35.2%, respectively.

A Study on Ammonia Partial Oxidation over Ru Catalyst (Ru 촉매에서의 암모니아 부분산화에 대한 연구)

  • SANGHO LEE;HYEONGJUN JANG;CHEOLWOONG PARK;SECHUL OH;SUNYOUP LEE;YONGRAE KIM
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.6
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    • pp.786-794
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    • 2022
  • Green ammonia is a promising renewable energy carrier. Green ammonia can be used in various energy conversion devices (e.g., engine, fuel cell, etc.). Ammonia has to be fed with hydrogen for start-up and failure protection of some energy conversion devices. Ammonia can be converted into hydrogen by decomposition and partial oxidation. Especially, partial oxidation has the advantages of fast start-up, thermally self-sustaining operation and compact size. In this paper, thermodynamics, start-up and operation characteristics of ammonia partial oxidation were investigated. O2/NH3 ratio, ammonia flow rate and catalyst volume were varied as operation parameters. In thermodynamic analysis, ammonia conversion was maximized in the O2/NH3 range from 0.10 to 0.15. Ammonia partial oxidation reactor was successfully started using 12 V glow plug. At 0.13 of O2/HN3 ratio and 10 LPM of ammonia flow rate, ammonia partial oxidation reactor showed 90% of ammonia conversion over commercial Ru catalyst. In addition, Increasing O2/NH3 ratio from 0.10 to 0.13 was more effective for high ammonia conversion than increasing catalyst volume at 0.10 of O2/NH3.

Synthesis of Methanol and Formaldehyde by Partial Oxidation of Methane over Mixed Oxide Catalysts (복합산화물 촉매 상에서 메탄의 부분산화에 의한 메탄올 및 포름알데히드의 합성)

  • Hahm, Hyun-Sik;Shin, Ki-Seok;Ahn, Sung-Hwan;Kim, Song-Hyoung;Hong, Seok-Young;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.3
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    • pp.223-229
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    • 2006
  • Methanol and formaldehyde were produced directly by the partial oxidation of methane over mixed oxide catalysts. The catalysts were composed of Mo and Bi with late-transition metals, such as Mn, Fe, and Co. The reaction was carried out at $450^{\circ}C$, 50 bar in a fixed-bed differential reactor. The prepared catalysts were characterized by $O_2-TPD$ and BET apparatus. Among the catalysts used, the catalyst composed of 1:1:2.5 molar ratio of Mo:Bi:Mn showed the best methane conversion and methanol selectivity. The change in ratio of methane to oxygen affected at the conversion and selectivity, and the most proper ratio was 10:1.5. Methane conversion, methanol and formaldehyde selectivities increased with the surface areas of the catalysts. From the $O_2-TPD$ result, it was found that the oxygen species responsible for this reaction might be the lattice oxygen species desorbed at high temperature around $800^{\circ}C$.

Petrological Characteristics and Deterioration phenomena of the rocks consisting the Naju-Dongmunoi-Seogdanggan(Stone Stele) (나주동문외석당간 구성암석의 암석학적 특징과 훼손양상)

  • Lee, Sang-Hun
    • Journal of Conservation Science
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    • v.19
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    • pp.57-66
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    • 2006
  • The rock consisting the Naju-Dongmunoi-Seogdanggan (Stone Stele)(Treasure number 49) is biotite granite of medium to coarse grains which might be taken from nearby area. The rock is mainly composed of quartz, plagioclase, alkali feldspar and biotite. Due to strong weathering grail peel-off and surface exfoliation are well developed. The rock surface is changed into pale brown or pale black colors according to weathering, organism and weathering product of iron band. Major deterioration phenomena are grain peel-off, surface exfoliation, cracks and damage which may be originally classified into weathering, effect of weathering product of iron band, organisms, structural unstabilities and impact.

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