• Journal of the Korean Chemical Society
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• v.44 no.2
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• pp.109-114
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• 2000

In this study, the optimum analytical condition of Differential pulse Voltammetry for the polymeric Sodium Alginate was studied and its reduction funtional groups were confirmed using Cyclic Vol-tammetry and IR spectroscopy. Optimum conditions were as followed; mercury drop size : medium size, accumulation time : 60sec, accumulation potential : -0.20V vs Ag/AgCl, scan rate : 100mV/sec, supporting electrolyte : 0.10M $NaClO_4$(pH 6.8). After polymeric Sodium Alginate was hydrolized at $100^{\circ}C$ in acidic condition, the current peaks of oligomer were compared with current peak of polymeric Sodium Alginate. In this optimum condition, calibration curve of polymer Sodium Alginate showed good linearity from 0.50ppm to 4.0ppm where as oligomeric Sodium Alginate showed good linearity from 0.05ppm to 0.24ppm.

• Journal of the Korean Chemical Society
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• v.39 no.8
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• pp.611-616
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• 1995

Oxovanadium(IV) complexes with salicylaldoxime, o-vanilline oxime, 2-hydroxy-4-methoxybenzaldoxime, 2-hydroxy-5-methoxybenzaldoxime and 2-hydroxy-5-nitrobenzaldoxime were synthesized. The complexes have been characterized by elemental analysis, electric conductivity measurement, infrared spectrometry, electronic spectrometry, mass spectrometry, and thermal analysis. The results of elemental analysis were well coincided with the theoretical values. The values of molar conductance of the complexes in DMF implicated that the complexes were non-electrolyte. The characteristic stretching frequency of V=O appeared strong band in the range of $980{\pm}20\;cm^{-1}.$ All the complexes showed two d-d transition in visible spectra and two charge transfer transitions in ultraviolet spectra. Results of mass spectrometry of $VO(sal)_2\;and\;VO(van)_2$ indicated two peaks corresponding to vanadium containing ion(I) of 1 : 2(metal to ligand) chelate and a fragment ion(II) of 1 : 1 chelate due to loss of ligand radical from ion(I). The thermal analysis showed the endothermic peak due to the thermal decomposition.

• Analytical Science and Technology
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• v.14 no.2
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• pp.123-130
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• 2001

Determination of cadmium(II) ion with a perfluorinated sulfonated polymer-ethylenediamine(nafion-en) modified glassy carbon electrode was studied. It was based on the chemical reactivity of an immobilized layer(nafion-en) to yield complex $[Cd(en)_2]^{2+}$. The reduction peak potential by differential pulse voltammetry(DPV) was observed at $-0.780({\pm}0.005)V$ vs. As/AgCl. The linear calibration curve was obtained in cadmium(II) ion concentration range $5.0{\times}10^{-7}-2.0{\times}10^{-5}M$, and the detection limit(3s) was $2.20{\times}10^{-7}M$. The detection limit of nafion-en modified glassy carbon electrode has been shown about 14 higher sensitivity than a bare glassy carbon electrode.

• Journal of the Korean Chemical Society
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• v.43 no.2
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• pp.161-166
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• 1999

Transfer of lanthanide ions across the liquid/liquid interface facilitated by ionopore ETH4120 has been studied by using cyclic voltammetry (CV) and chronopotentiometry with cyclic linear current-scanning (CPCLCS) under the condition where the concentration of ETH4120 in nitrobenzene was much smaller than the concentration of lanthanide ions in aqueous solution. One cathodic current peak (transfer from aqueous to nitrobenzene phase) and two anodic current waves (transfer from nitrobenzene to aqueous phase) were observed. The cathodic wave was due to the formation of 1:1 (metal:ligand) complex and two anodic waves showed successive formation of 1:2 and 1:3 complexes in nitrobenzene solution. But there was no cathodic wave corresponding to two anodic waves. The ion transfer mechanism has also been discussed.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.10 no.2
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• pp.96-99
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• 2000

The photoluminescened experiments at temperature of 10K were carride out for ZnSe epilayers grown by hot-wall epitaxy. The upper and lower polariton peaks of the neutral dound exciton $I_2$($D^{\circ}$,X) for as-grown epilayer have been dominantly observed.For the heat-treatment under Se ambient,the origin of $I_2$ emission is confirmed to be related to Se-vacancy.The extra neutral acceptor bound exciton $I_1$$^d$ is also observed.The ZnSe epilayer shows the self-compensation effect and it is hard to be converted into p-type ZnSe epilayer.However,the photoluminescence spectrum of the annealed sample in Se ambient shows the intense $I_1$$^d$ emission.This indicates that in the annealed ZnSe epilayer,there are many acceptor levels due to the opical p-type converstion. The binding energy of acceptor-impurity is ecaluated to the value of 268meV and the self-activated emission is disappeared by thermal annealing under Se ambient,which indicates the association with Se-vacancy.

• KSBB Journal
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• v.30 no.6
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• pp.326-331
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• 2015

The anti-inflammatory effect of tuna heart water extract (THWE) was investigated using lipopolysaccharide-induced inflammatory response in this study. Anti-inflammatory effect was detected by the cell proliferation and the production levels of nitric oxide, pro-inflammatory cytokines such as interleukin-6 (IL-6), IL-$1{\beta}$, and tumor necrosis factor-alpha. As a result, there were no cytotoxic effects on proliferation of macrophages treated with THWE compared to the control. The production of pro-inflammatory cytokines was remarkably suppressed compared with that of the LPS only group. These results suggest that THWE exerts the anti-inflammatory property by inhibiting production of inflammatory factors and may be a potential material for anti-inflammatory therapy.

• Analytical Science and Technology
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• v.9 no.3
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• pp.235-243
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• 1996

A carbon paste electrode were chemically modified using ${\alpha}$-cyclodextrin. Characteristics of chemically modified carbon paste electrodes were studied on the basis of the inclusion complex formation of ${\alpha}$-cyclodextrin and p-nitrophenol in solution. Cyclic voltammetry and differential pulse voltammetry were used to monitor the efficiency of the chemical modification. When the ${\alpha}$-cyclodextrin and carbon powder ratio of 2 : 1 in weight were used, the reduction peak current of p-nitrophenol was decreased almost completely, whereas those of o-nitrophenol and hydroquinone were not changed much. This result is due to the large difference in the inclusion complex formation constants of p-nitrophenol and the other probes with ${\alpha}$-cyclodextrin. Taking advantage of this difference, we can determine the concentration of o-nitrophenol even in the presence of p-nitrophenol.

• Analytical Science and Technology
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• v.7 no.1
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• pp.25-31
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• 1994

As for analytes which did not represent the differences of the selectivity on the stationary and mobile phase, secondary chemical equilibrium theory was applied to study pH effects on the separation of alkylphenols. Mobile phase was consisted of an aqueous sodium carbonate-bicarbonate buffer and acetonitrile. The maximum selectivity for adjacent peak pairs was predicted from those values of $k^{\prime}_{HA}/k^{\prime}_{A-}$ and ${\Delta}pK$. The optimum pH determined by this method was 11.18 pH and solvent selectivity were considered at the same time to invoke the full range of selectivity effects possible for separations. Quaternary mixture composed of methanol, acetonitrile, tetrahydrofuran and water was adjusted to optimum pH 11.18. As the statistical simplex technique of an overlapping resolution map (ORM) was used to predict the optimized solvent system. The optimum solvent, which gives complete separation of alkylphenols, was determined as follws MeOH : ACN : THF = 14.4 : 81.8 : 2.8.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.156-156
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• 2003

수평 전기로에서 ZnIn$_2$S$_4$ 다결정을 합성하여 HWE(Hot Wall Epitaxy)방법으로 2nIn2S4단결정 박막을 반절연성 GaAs(100)기판 위에 성장시켰다. ZnIn2S4 단결정 박막은 증발원의 온도를 610 $^{\circ}C$, 기판의 온도를 450 $^{\circ}C$로 성장시켰고 성장 속도는 0.5 $\mu\textrm{m}$/hr로 확인되었다. ZrIn2S4 단결정 박막의 결정성의 조사에서 10 K에서 광발광(photoluminescence) 스펙트럼이 433 nm (2.8633eV)에서 exciton emission스펙트럼이 가장 강하게 나타났으며, 또한 이중결정 X-선 요동곡선(DCRC)의 반폭치(FWHM)도 133 arcsec로 가장 작아 최적 성장 조건임을 알 수 있었다. Hall 효과는 van der Pauw방법에 의해 측정되었으며, 온도에 의존하는 운반자 농도와 이동도는 293K에서 각각 8.51$\times$$10^{17}$ electron/$cm^{-3}$ 291 $\textrm{cm}^2$/v-s였다. ZnIn2S4 단결정 박막의 광전류 단파장대 봉우리들로부터 10 K에서 측정된 $\Delta$Cr(crystal field splitting)은 0.1678 eV, $\Delta$So(spin orbit coupling)는 0.0148 eV였다. 10 K의 광발광 측정으로부터 고품질의 결정에서 볼 수 있는 free exciton 과 매우 강한 세기의 중성 주개 bound exciton등의 피크가 관찰되었다. 이때 중성 주개 bound exciton의 반치폭과 결합 에너지는 각각 9 meV와 26 meV 였다. 또한 Haynes rule에 의해 구한 불순물의 활성화 에너지는 130 meV 였다.다.

• Journal of Korean Society of Transportation
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• v.20 no.3
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• pp.55-67
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• 2002

구간검지체계를 기반으로 한 첨단교통정보제공시스템(Advanced Traveler Information Systems)은 그 기능 수행시 다음의 중요 고려사항을 지닌다. 첫째는 제공 정보의 신뢰성이며, 둘째는 정보수집비용에 관련한 수집자료수의 한계이다. 본 논문에서는 이러한 한계성 극복을 위해 보다 대표성 있는 교통정보 형태의 설정 및 통계적으로 신뢰성 있는 정보산출을 위해 요구되는 적정표본수의 결정에 대한 연구를 수행하였다. 도시고속도로(올림픽대로)와 도시간선도로(천호대로)의 실측 구간통행시간분포 분석결과 단일교차로 구간의 경우 다른 구간들의 단일봉(unimodal)의 정규분포형태와는 다른 두 개의 봉우리를 지닌 분포형태(bimodal)가 나타났다. 따라서 이러한 구간은 기존과는 다른 새로운 교통정보 형태가 필요하며, 본 논문에서는 모든 통과차량들의 평균통행시간으로 정의되는 한 개의 대표치가 아닌 신호주기에 의한 정지여부에 따라 분리되는 주행시간과 지체시간 또는 주행속도와 통행속도 개념의 세분화된 정보형태를 설정하였다. 또한 중심극한정리를 기초로 한 통계적인 표본수 결정식을 이용하여 설정된 신뢰수준 하에서의 정보산출을 위해 요구되는 적정 표본수를 산출하였다. 그 결과, 교통이 혼잡할수록 요구되는 표본수는 적어지는 것으로 나타났다. 우선 적정 표본수 만큼의 표본추출을 하고 제안된 정보산출 방법에 의해 교통정보를 산출한 후 실측치와의 오차를 비교하였다. 그 결과 산출된 교통정보는 신뢰수준 95%와 허용오차 5㎞/h를 만족하였다. 다음으로 구간검지체계를 이용하여 정보를 산출하는 타시스템 교통정보와의 오차율을 비교하였다. 그 결과, 실측치와 본 연구의 산출방법에 의한 교통정보, 로티스교통정보 및 차량번호판 인식시스템의 교통정보와의 비교 결과 제안된 교통정보형태의 타당성을 볼 수 있었다.