• Title/Summary/Keyword: 복합 염색

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Development of quick molding composite materials and lightweight parts for automotive applications (고속성형 복합소재 및 수송용 경량부품 개발)

  • Kwon, Yong-Won;Jang, Ho-Yun;Kim, Jin-Hong;Min, Byeong-Hwan;Park, Jong-Seung
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.20-20
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    • 2012
  • 최근, 수송기기 분야는 국제 환경규제 강화에 따른 CO2 절감, 연비향상, 경량화를 위한 기술적 수요가 증대되고 있으며, 그린카, 그린선박 등 친환경 수송기기에 대한 연구가 활발히 진행되고 있다. 하지만, 기존의 금속소재가 가지는 경량화의 한계를 극복하기 위해서는 CFRP, GFRP 등 금속대체 복합소재를 적용한 수송용 경량부품 개발에 대한 필요성이 요구되고 있다. 복합소재는 섬유사이에서 응력을 전달하는 기지(Matrix)와 하중을 전달하는 섬유(Fiber)의 종류와 양 및 적층 각도에 따라 수송용 부품에 적합한 기계적 특성을 얻을 수 있고, 높은 비강도와 비강성의 값을 갖게 되어 경량화가 용이한 장점이 있다. 반면, 섬유재의 종류, 성형방법, 경화온도 등에 따라 물리적 특성에 큰 변화가 발생하며, 수지의 경화조건에 따라 성형시간이 많이 소요되는 단점을 가지고 있다. 따라서, 본 연구에서는 자동차, 선박, 항공기, 철도차량 등 각종 수송기기의 경량화를 목적으로 생산성 향상 및 성형시간 절감을 위해 열가소성 수지, 저온속경화 수지를 적용하여, 경화 시간을 단축시키고, 3D-fabric 및 다층구조 직물을 Vacuum Infusion 공법으로 성형하여, 기존의 섬유재 적층시 소요되는 작업 공정을 간소화 할 수 있도록, 고속성형 복합소재를 적용한 수송용 경량부품 개발에 관한 연구를 수행하였다.

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Multi-Functional Finish of Polyester and P/C blend Fabrics by Corona Discharge(II) - Multifunctional finish- (코로나 방전처리에 의한 폴리에스테르 및 P/C 혼방직물의 복합기능화 가공(II) - 복합 기능화 가공 -)

  • Lee, Bang One;Pak, Pyong Ki;Yeo, Joo Hong;Lee, Hwa Sun
    • Textile Coloration and Finishing
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    • v.9 no.3
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    • pp.1-9
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    • 1997
  • Plasma techniques permit modification of the surface layers of the substrate while maintaining its bulk properties. The use of plasma treatment on textile fibers and fabrics is very limited, however, the limitations, plasma treatments have been used to modify surface properties of textiles. In this study, multifunctional finish was performed by corona discharge technique for surface functionalization. Electron spectroscopy for chemical analysis(ESCA) was used to determine the ratios of carbon, oxygen, nitrogen, and phosphor at a 20$\AA$ sampling depth. K/S value and limiting oxygen index(LOI) value were used to obtain information on the effect of the finished fabrics. The mechanism of the flame retardancy was analyzed by the thermogravimetry-and the residue number. In ESCA, relative N1s intensity increased in case of mixtrure. The flame retardancy of the polyester and polyester/cotton fabrics treated with JA-6034 and JA-6050 was found to be operative mainly in the condensed phase mechanism. The multifunctional finish was better effect for the post treated finish agent.

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Color Development of combination Dyeing of Indian Indigo and Turmeric Extracts, Gardenia Extracts (인도쪽과 울금 및 치자의 복합염색에 의한 색상 변화)

  • 정진순;설정화
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.2
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    • pp.325-336
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    • 2002
  • This study investigated color change of combination dyeing silk fabrics dyed with Turmeric extracts and Gardenia extracts after dyeing of Indian indigo. Experimental variables include the condition of dyeing time and concentration of Turmeric extracts, Gardenia extracts, arid dyeing cycle of Indian indigo. Surface color of silk fabrics dyed with Turmeric 77tracts after one cycle dyeing, two cycles dyeing, four cycles dyeing of Indian indigo was changed from 5.1GY to 0.3GY, 1.5G to 3.5GY and 6.5G to 5.8GY by increase of concentration of Turmeric extracts. On the other hand, Surface color of silk fabrics dyed with Gardenia extracts after one cycle dyeing, two cycles dyeing, four cycles dyeing of Indian indigo was changed from 7.5Y to 3.9Y, 1.2GY to 6.7Y and 4.0GY to 8.6GY by increase of concentration of Gardenia extracts. Its range of surface color was changed to green and yellowish green by increase of dyeing time with concentration of Turmeric extracts. On the other hand, its range of surface color was changed to yellowish and yellow by increase of dyeing time with concentration of Gardenia extracts.

Mechanical Properties of Carbon Fiber/Nylon 6 Composite Introducing Coupling Agent (II) -Increasing Interfacial Strength of Composite- (카플링제를 도입한 탄소섬유/나일론 6 복합재료의 기계적 성질(II) -복합재료의 계면강도 증가-)

  • Park, Chan Hun;Lee, Yang Hun;Shin, Eun Joo
    • Textile Coloration and Finishing
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    • v.9 no.4
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    • pp.47-53
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    • 1997
  • To improve the interfacial bonding of carbon fiber-nylon 6 composite, carbon fiber(CF) were oxidized by nitric acid treatment, and two types of graft polymer(GP) of nylon 6-g-polyacrylamide (PAAm) -water dispersable GP(WDGP) and m-cresol solu ble GP(CSGP) were treated as coupling agents. Introduction of polar groups such as -COOH, -OH, etc, on the surface of the oxidized CF was confirmed by IR spectra. The stem polymer of nylon 6 in the coupling agent (GP) could be compatible with'matrix nylon 5, and the grafted branch of PAAm on GP could react to the polar groups on the oxidized CF in composite. The interfacial strength was measured by the transverse tensile test to the fiber direction for single CF embedded nylon 6 film especially prepared and by the pull-out test method. The interfacial strength of the composite reinforced with oxidized CF is greater than that reinforced with unoxidized CF. The interfacial strength of the composite was increased by treatment of coupling agents(GPs) considerably, and the increasing tendency by the WDGP is greater than that by the CSGP. The optimum conditions of coupling agent treatment are as follows: the concentration, adsorption tlme of GP, and curing temperature are 2%, 20 minutes, and $170^{\circ}$, respectively.

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Dyeing of Flame Retardant Polyester Fabric developed by using Low-melting-point Bicomponent Filament (저융점 복합사를 이용한 난연 폴리에스터 직물의 염색)

  • Lee, Shin-Hee
    • Fashion & Textile Research Journal
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    • v.15 no.3
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    • pp.467-476
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    • 2013
  • This study investigates the dyeability and the fastness of flame retardant polyester fabric developed by a thermal bonding with a low melting component of flame retardant bicomponent filament (LMFRPC). The fabrics were prepared with flame retardant polyester filaments (FRP) as warp and blended filaments of FRP and LMFRPC as weft. The LMFRPC have a sheath and a core where the core comprises a flame retardant polyester and the sheath comprises a thermoplastic polyester with a low-melting point. The thermal bonding of fabric was conducted in a pin tenter at $170^{\circ}C$ for 60 seconds. Fabric dyeing was conducted with an infrared dyeing machine at various dyeing temperatures and dyeing times. The dyestuffs used in this study were CI disperse Yellow 54, Red 60 and Blue 56 of E-type dyestuff and Orange 30, Red 167 and Blue 79 of S-type dyestuff. This study investigated the morphology of thermal bonded fabric, dyeability and fastness of dyed fabric. Dyeability increased with an increased dyeing temperature. The thermal bonded area increased with the increased LMFRPC content. The dyeability of S-type dyestuff was higher than E-type dyestuff; in addition, the saturated dyeing time was about 20minutes at $130^{\circ}C$ for E and S-type dyestuff. The fastness to washing and rubbing were excellent at a 4-5 Grade.

Zein Nanocomposites Prepared by Electrospinning Technique (전기방사법으로 제조된 Zein 나노복합체)

  • Kim, In-Kyo;Choi, Jae-Young;Kim, Young-Hwa;Yeum, Jeong-Hyun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.5-5
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    • 2011
  • 나노섬유를 제조하는 방법 중에는 상분리 현상을 이용한 방법, 자가 조립성을 이용한 방법, 템플레이트를 이용한 방법, 전기방사법이 있으며 특히 전기방사법은 연속적으로 균일한 나노섬유를 제조할 수 있다. 또한 전기방사법은 장비가 간단하며 고분자 blend ratio와 무기재료의 함량에 따라 뛰어난 특성을 나타내는 나노복합섬유를 만들 수 있다. 최근 식물에서 추출한 단백질을 전기방사법을 이용하여 나노입자 및 나노섬유를 제조하고 이를 의료 분야 등에 적용하기 위한 연구가 활발히 진행되고 있으며 이런 식물성 단백질은 동물성 단백질에 비하여 인체 적용이 용이하고 매장량이 풍부한 장점이 있다. 본 연구에서는 전기방사법을 이용하여 옥수수에서 추출한 단백질인 zein의 나노입자 및 나노섬유를 제조하였다. 또한 천연 추출물이 혼입된 복합 나노입자 및 나노섬유를 제조하여 zein이 가진 고유 특성 이외에 천연 추출물의 특성을 추가로 부여해서 더욱 발전된 나노입자 및 나노섬유를 제조하였다. 고분자 농도, 전압, 방사거리 등 다양한 공정변수를 조절하여 최적의 조건을 확립하였으며 제조된 나노입자 및 나노섬유는 field-emission type scanning electron microscope (FE-SEM), transmission electron microscopy (TEM), ultraviolet-visible spectroscopy (UV/vis), fourier transform infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC)를 이용하여 특성분석을 실시하였다.

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Development of Highly Durable Retroreflective Coating with Gravure Chemical Printing (그라비아 케미칼 프린팅 기술을 이용한 고내구성 재귀반사 코팅 직물 제조연구)

  • Sung Yong Yang;Bo Min Kim;Hyeji Park;Gyu Hwan Kim;Jaehyeung Park
    • Textile Coloration and Finishing
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    • v.35 no.2
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    • pp.98-106
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    • 2023
  • The recent surge in night walkers and pedestrian traffic accidents has led to an increased interest in retro-reflection-based products, leading to several studies on retro-reflection. Nonetheless, achieving high durability and dispersibility of retro-reflective glass beads in viscous polyurethane coating resin remains challenging. To address this issue, this study conduct to functionalize the surface of glass beads for covalent conjugation to coating resin to enhance their dispersibility and durability in the coating resin. The study evaluated the dispersibility, chemical composition, and retro-reflection properties of the functionalized glass beads and coating resin. The results showed that the functionalized glass beads conjugated to the polyurethane coating resin and exhibited excellent dispersibility, high durability, and maintained retro-reflection efficiency.

Effects of Electroacupuncture on the Alteration of Inflammation-related Proteins and Glycoconjugates in the Ankle Joint of Complete Freund's Adjuvant-injected Rats (전침이 Complete Freund's Adjuvant를 주사한 흰쥐의 거퇴관절내 염증관련 단백질 및 복합당질 변화에 미치는 연구)

  • Park, In-Bum;Yoon, Hyun-Min;Jang, Kyung-Jun;Kim, Cheol-Hong;Min, Young-Kwang;Song, Choon-Ho;Ahn, Chang-Beohm
    • Journal of Acupuncture Research
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    • v.25 no.2
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    • pp.105-117
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    • 2008
  • 목적 : 만성 염증성 질환에 대한 전침효과를 알아보기 위해 complete Freund's adjuvant(CFA) 유발 관절염 모델의 거퇴 관절 내 염증관련 단백질 및 복합당질의 변화를 살펴보았다. 방법 : Sprague-Dawley계 흰쥐의 족부에 CFA를 주사한 다음 3일 간격으로 2Hz, 15Hz 및 120Hz 전침자극을 주며 부종 형성여부를 plethysmometer로 측정하여 판정하였으며 30일째 거퇴관절을 취하여 4% paraformaldehyde에 고정하고 EDTA용액에서 탈회시켜 파라핀연속 절편을 얻어 $NF-{\kappa}B$를 비롯한 5종의 염증관련 단백질의 발현 및 복합당질 변화를 살펴보았다. 결과 : 관절연골 내 면역반응 중 연골기질은 반응이 없거나 약하고 연골세포는 $NF-{\kappa}Bp65$, $I-{\kappa}B{\alpha}$, iNOS 반응이 강하며 특히 유리연골층에서 더 현저하였으나 염증 및 전침자극에 따른 변화는 없었다. 관절낭에서 면역반응을 살펴보면 염증유발시 활액세포의 면역반응세포는 $I-{\kappa}B{\alpha}$가 감소한 반면 iNOS, $IL-1{\beta}$는 증가하며 특히 iNOS 증가가 현저하였으며 전침자극에 의해 iNOS 가 감소하였다. 활액막조직에서 모든 면역반응이 증가하며 특히 $NF-{\kappa}Bp65$, $I-{\kappa}B{\alpha}$, iNOS 반응이 현저한데 전침자극에 의해 $IL-1{\beta}$를 제외한 모든 반응이 감소하였다. 복합당질 염색성은 CFA를 주사한 염증유발 흰쥐군이 정상군에 비해 감소하였다. 관절연골 중 구역간질의 중성복합당질 및 연골세포피막의 산성복합당질이 현저히 감소하였다 Lectin반응도 DBA을 제외한 모든 발현이 염증유발시 감소하였다. 그러나 전침처리에 의해 정상군과 유사한 염색성과 lectin반응을 유지하였다. 특히 구역간질의 중성복합당질과 연골세포의 sWGA와 RCA-1 반응이 현저하였다. 결론 : 만성 염증성 동물모델의 거퇴 관절 내 염증관련 단백질은 관절연골보다 관절낭에서, 복합당질의 변화는 관절연골에서 큰 변화를 보였으며 전침의 자극에 의해 이들 변화가 억제되는 것을 알 수 있다. 이상의 결과로 보아 전침처치는 염증관련 단백질 발현 및 복합당질의 변화 억제를 통해 만성 관절염 질환에 효과적임을 알 수 있다.

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Dyeing Properties of Cotton/Polyester Composite Yarn in Different Yarn Twisting Processes -Focused on One/Two Bath Dyeing Systems with Reactive/Disperse Dyes- (연사방법에 따른 면/폴리에스터 복합사의 염색성에 관한 연구 -반응성/분산염료를 이용한 1욕 염색방법과 2욕 염색방법을 중심으로-)

  • Kim, So-Jin;Jeon, Dong-Won;Lee, Jung-In
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.2 s.150
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    • pp.275-285
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    • 2006
  • The purpose of this study was to examine the change of dyeing ability by K/S values, when dyed in different twisting processes and by one bath system and two bath system, to find possible ways of minimizing the color difference between cotton and polyester in composite yarn. The two types of composite yarn, which had one setting process(CP1) and two setting processes(CP2) were dyed with reactive/disperse dyes in both one bath dyeing system and two bath system. The dyeing ability according to the two different twisting processes was measured, and the values of the CP1 were higher compare to the values of CP2 in both one and two bath dyeing systems. This is because CP1 applied only one setting could shrink dyeing process at 130$^{circ}C$. This shrinkage increased the number of twists in the unit length and increased the yarn density, and this is the reason that the K/S values were measured higher than those of CP2. In wet shrinkage test, in opposition to CP2 only had 0.76$\%$ of the shrinkage rate, CP1 had 3.00$\%$ of the shrinkage rate. Also, the dyeing ability according to the two different dyeing methods was measured, and the values of CP1 and CP2 were both higher when dyed in two bath system. On the other hand, the color differences between cotton and polyester in composite yarns, were smaller for CP2 than that for CP1 and were also smaller in two bath dyeing system than in one bath dyeing system. Therefore, the ways of minimizing color difference between cotton and polyester in composite yarn are to apply enough setting in order to minimize shrinkage in dyeing process and to choose two bath dyeing system.