• Title/Summary/Keyword: 밴드구조

Search Result 902, Processing Time 0.025 seconds

Microfluidic Assisted Synthesis of Ag-ZnO Nanocomposites for Enhanced Photocatalytic Activity (광촉매 성능 강화를 위한 미세유체공정 기반 Ag-ZnO 나노복합체 합성)

  • Ko, Jae-Rak;Jun, Ho Young;Choi, Chang-Ho
    • Clean Technology
    • /
    • v.27 no.4
    • /
    • pp.291-296
    • /
    • 2021
  • Recently, there has been increasing demand for advancing photocatalytic techniques that are capable of the efficient removal of organic pollutants in water. TiO2, a representative photocatalytic material, has been commonly used as an effective photocatalyst, but it is rather expensive and an alternative is required that will fulfill the requirements of both high performing photocatalytic activities and cost-effectiveness. In this work, ZnO, which is more cost effective than TiO2, was synthesized by using a microreactor-assisted nanomaterials (MAN) process. The process enabled a continuous production of ZnO nanoparticles (NPs) with a flower-like structure with high uniformity. In order to resolve the limited light absorption of ZnO arising from its large band gap, Ag NPs were uniformly decorated on the flower-like ZnO surface by using the MAN process. The plasmonic effect of Ag NPs led to a broadening of the absorption range toward visible wavelengths. Ag NPs also helped inhibit the electron-hole recombination by drawing electrons generated from the light absorption of the flower-like ZnO NPs. As a result, the Ag-ZnO nanocomposites showed improved photocatalytic activities compared with the flower-like ZnO NPs. The photocatalytic activities were evaluated through the degradation of methylene blue (MB) solution. Scanning electron microscopy (SEM), x-ray diffraction (XRD), and energy-dispersive x-ray spectroscopy (EDS) confirmed the successful synthesis of Ag-ZnO nanocomposites with high uniformity. Ag-ZnO nanocomposites synthesized via the MAN process offer the potential for cost-effective and scalable production of next-generation photocatalytic materials.

A Study on the Characteristics of CdS Thin Film by Annealing Time Change (열처리시간 변화에 의한 CdS 박막 특성에 관한연구)

  • Chung, Jae-Pil;Park, Jung-cheul
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
    • /
    • v.14 no.5
    • /
    • pp.438-443
    • /
    • 2021
  • This paper uses a multiplex deposition sputter system and aims to improve transmittance and reduce production costs by depositing a CdS thin film on an ITO glass substrate. When manufacturing CdS thin films, we wanted to find excellent conditions when manufacturing solar cells by changing heat treatment time. It was observed that thickness and sheet resistance were not significantly different depending on heat treatment time changes. The specific resistance was measured from a minimum of 6.68 to a maximum of 6.98. When the heat treatment time was more than 20 minutes, the transmittance was measured to be more than 75%. When the heat treatment time was 10 minutes, the bandgap was 3.665 eV and more than 20 minutes was 3.713 eV, which was measured as the same result. The XRD analysis showed that the structure of CdS was hexagonal and only CdS thin films were deposited without any other impurities. The result of calculating the FWHM was a maximum of 0.142 when the heat treatment time was 20 minutes, and a minimum of 0.133 when the heat treatment time was 40 minutes, so there was no significant difference in the FWHM when the heat treatment time was changed. The particle size was measured at 11.65 Å when the heat treatment time was 40 minutes, and at 10.93 Å when the heat treatment time was 20 minutes.

A Study on Creativity in the Funk Drumming: Focused on David Garibaldi (펑크(Funk) 드럼 연주기법에 나타난 창의성에 대한 연구: 데이비드 가리발디(David Garibaldi)를 중심으로)

  • Kim, Kwan-jin;Cho, Tae-seon
    • Journal of Digital Convergence
    • /
    • v.19 no.9
    • /
    • pp.217-228
    • /
    • 2021
  • The purpose of this study is to analyze drum performance techniques, focusing on the representative artists of funk music, who had a revival starting in the 1970s. The purpose of this study is to analyze the creativity shown in David Garibaldi's playing technique, which had a great influence on drum majors with his funk drum playing technique. As a research method, 'James Brown', 'Earth, Wind & Fire' and 'Tower of Power' with David Garibaldi as drummer were selected as representative bands. For the study period, the drum performance was examined by selecting two representative songs from among the songs released between 1965 and 1975, when the development of the corresponding funk music began. David Garibaldi's creative performance in this study is as follows. First, we tried to create a new rhythm in the form of changing the beat or resting the beat out of the frame of contemporary drum performance. Second, the 'Paradiddle', 'Accent', and 'Swiss Army triplet' rudiment techniques were applied to the entire drum kit, bringing innovation to the rhythm. Third, the samba pattern of Latin rhythm and the form of 'Afro-Cuban' were grafted onto funk music. Fourth, the idea of Unison Rhythm obtained from the structure of Latin music was applied to funk music. Based on this study, it is hoped that research on drum performance techniques of various genres will be conducted.

The Study for Enhancing Resilience to Debris Flow at the Vulnerable Areas (토석류 재해발생 시 레질리언스 강화를 위한 연구)

  • Kim, Sungduk;Lee, Hojin;Chang, Hyungjoon;Dho, Hyonseung
    • Journal of the Korean GEO-environmental Society
    • /
    • v.22 no.8
    • /
    • pp.5-12
    • /
    • 2021
  • Climate change caused by global warming increases the frequency of occurrence of super typhoons and causes various types of sediment disasters such as debris flows in the mountainous area. This study is to evaluate the behavior of debris flow according to the multiplier value of the precipitation characteristics and the quantity of debris flow according to the typhoon category. For the analysis of the debris flow, the finite difference method for time elapse was applied. The larger the typhoon category, the higher the peak value of the flow discharge of debris flow and the faster the arrival time. When the precipitation characteristic multiplier is large, the fluctuation amplitude is high and the bandwidth is wide. When the slope angle was steeper, water discharge increased by 2~2.5 times or more, and the fluctuation of the flow discharge of debris flow increased. All of the velocities of debris flow were included to the class of "Very rapid", and the distribution of the erosion or sedimentation velocity of debris flows showed that the magnitude of erosion increased from the beginning, large-scale erosion occurred, and flowed downstream. The results of this study will provide information for predicting debris flow disasters, structural countermeasures and establishing countermeasures for reinforcing resilience in vulnerable areas.

Thermoelectric Properties of the Reaction Sintered n-type β-SiC (반응소결법으로 제조한 n형 β-SiC의 열전특성)

  • Pai, Chul-Hoon
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.20 no.3
    • /
    • pp.29-34
    • /
    • 2019
  • Silicon carbide is considered to be a potentially useful material for high-temperature electronic devices, as its large energy band gap and the p-type and/or n-type conduction can be controlled by impurity doping. Particularly, electric conductivity of porous n-type SiC semiconductors fabricated from ${\beta}-SiC$ powder at $2000^{\circ}C$ in $N_2$ atmosphere was comparable to or even larger than the reported values of SiC single crystals in the temperature region of $800^{\circ}C$ to $1000^{\circ}C$, while thermal conductivity was kept as low as 1/10 to 1/30 of that for a dense SiC ceramics. In this work, for the purpose of decreasing sintering temperature, it was attempted to fabricate porous reaction-sintered bodies at low temperatures ($1400-1600^{\circ}C$) by thermal decomposition of polycarbosilane (PCS) impregnated in n-type ${\beta}-SiC$ powder. The repetition of the impregnation and sintering process ($N_2$ atmosphere, $1600^{\circ}C$, 3h) resulted in only a slight increase in the relative density but in a great improvement in the Seebeck coefficient and electrical conductivity. However the power factor which reflects the thermoelectric conversion efficiency of the present work is 1 to 2 orders of magnitude lower than that of the porous SiC semiconductors fabricated by conventional sintering at high temperature, it can be stated that thermoelectric properties of SiC semiconductors fabricated by the present reaction-sintering process could be further improved by precise control of microstructure and carrier density.

Photocatalytic Decomposition of Rhodamin B over Bi2MoO6 Prepared Using Hydrothermal Process (수열합성법으로 제조된 Bi2MoO6에서 로다민 B의 광촉매 분해 반응)

  • Hong, Seong-Soo
    • Clean Technology
    • /
    • v.25 no.2
    • /
    • pp.123-128
    • /
    • 2019
  • $Bi_2MoO_6$ catalysts were successfully synthesized using ethylene glycol monomethyl ether (EGME), glycerol (GL), ethylene glycol (EG), and water as solvents by a conventional hydrothermal method. The synthesized catalysts were characterized by XRD, DRS, BET, SEM, and PL, and we also investigated the photocatalytic activity of these materials for the decomposition of Rhodamin B under visible light irradiation. The XRD results revealed the successful synthesis of 12-18 nm, well-crystallized ${\gamma}-Bi_2MoO_6$ crystals with an Aurivillius structure regardless of solvent. In addition, the $Bi_2MoO_6$ catalysts prepared below $140^{\circ}C$ showed an amorphous phase; however, those prepared above $160^{\circ}C$ showed well-crystallized ${\gamma}-Bi_2MoO_6$ crystals. All the catalysts have a similar absorption spectrum from the ultraviolet region up to the visible region less than 470 nm. This result suggests that all the $Bi_2MoO_6$ catalysts are potential visible-light-driven photocatalysts. The $Bi_2MoO_6$ catalysts prepared using EGME as a solvent showed the highest photocatalytic activity. In addition, the $Bi_2MoO_6$ catalysts prepared at $180^{\circ}C$ showed the highest photocatalytic activity. The PL peaks appeared at about 560 nm at all catalysts and the excitonic PL signal was proportional to the photocatalytic activity for the decomposition of Rhodamin B. This suggests that the stronger the PL intensity, the larger the amount of oxygen vacancies and defects, and the higher the photocatalytic activity.

Electrical Properties for Enhanced Band Offset and Tunneling with a-SiOx:H/a-si Structure (a-SiOx:H/c-Si 구조를 통한 향상된 밴드 오프셋과 터널링에 대한 전기적 특성 고찰)

  • Kim, Hongrae;Pham, Duy phong;Oh, Donghyun;Park, Somin;Rabelo, Matheus;Kim, Youngkuk;Yi, Junsin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.34 no.4
    • /
    • pp.251-255
    • /
    • 2021
  • a-Si is commonly considered as a primary candidate for the formation of passivation layer in heterojunction (HIT) solar cells. However, there are some problems when using this material such as significant losses due to recombination and parasitic absorption. To reduce these problems, a wide bandgap material is needed. A wide bandgap has a positive influence on effective transmittance, reduction of the parasitic absorption, and prevention of unnecessary epitaxial growth. In this paper, the adoption of a-SiOx:H as the intrinsic layer was discussed. To increase lifetime and conductivity, oxygen concentration control is crucial because it is correlated with the thickness, bonding defect, interface density (Dit), and band offset. A thick oxygen-rich layer causes the lifetime and the implied open-circuit voltage to drop. Furthermore the thicker the layer gets, the more free hydrogen atoms are etched in thin films, which worsens the passivation quality and the efficiency of solar cells. Previous studies revealed that the lifetime and the implied voltage decreased when the a-SiOx thickness went beyond around 9 nm. In addition to this, oxygen acted as a defect in the intrinsic layer. The Dit increased up to an oxygen rate on the order of 8%. Beyond 8%, the Dit was constant. By controlling the oxygen concentration properly and achieving a thin layer, high-efficiency HIT solar cells can be fabricated.

An Exploratory Study on the Authenticity Discourse Strategies of Popular Music Audition Programs - Focused on - (대중음악 오디션 프로그램의 진정성 담론 전략에 관한 탐색적 연구 - <미스터트롯>을 중심으로 -)

  • Lie, Jae-Won;Kim, Won-Gyum
    • Journal of Korea Entertainment Industry Association
    • /
    • v.15 no.6
    • /
    • pp.1-13
    • /
    • 2021
  • This study explored the mechanism by which Trot gained a superior position in the broadcasting contents market after the TV Chosun audition program was broadcast. We analyzed the narrative structure of the program to determine what differentiation and popularization strategy the trot audition program took from the existing audition program, and analyzed in-depth interviews with music experts and interviews with the production team. appealed to viewers with a strategy that reversed the success strategy of existing audition programs. First, the strong/non-competent participants did not compete with each other, but rather the strong/skilled players competed against each other. This trot audition set the singing ability as a new 'discourse on sincerity'. Second, we broke away from the 'demon editing', which was considered essential for audition programs, took a strategy of excluding villains. Third, we broke the practice of audition programs that were supposed to show expertise in specific genres, such as idol music, hip-hop, and bands, and combined trot with various genres. Fourth, unlike previous audition programs that mainly targeted specific generations or genders, the strategy was to expand the audience by targeting various age groups. Fifth, it has formed a middle-aged fandom with a 'subtitle strategy' that uses subtitles well to arouse viewers' interest and help empathize.

Aircraft Velocity and Altitude Estimation through Time Offset Calculation of KOMPSAT-3 Satellite (KOMPSAT-3 위성의 Time Offset 계산을 통한 항공기 속력 및 고도 추정)

  • Jung, Sejung;Shin, Hyeongil;Kim, Dohoon;Song, Ahram;Lee, Won Hee
    • Korean Journal of Remote Sensing
    • /
    • v.38 no.6_4
    • /
    • pp.1879-1887
    • /
    • 2022
  • In this study, a method of estimating the velocity and altitude of aircrafts photographed in a KOMPSAT-3 satellite was proposed. In the proposed method, parallax effect, which is a time offset between bands due to the photographing method of the KOMPSAT-3 satellite, the structure of the sensor, and the movement of the satellite's orbit, was calculated, and in this process, trucks running on the highway were used. In addition, the actual direction and the direction by parallax effect of the aircraft were calculated using the coordinates of the aircraft in the image, and the attitude information of the KOMPSAT-3 satellite was calculated using metadata to estimate the velocity and altitude of the aircraft. The estimated value through the proposed method was compared with the actual value, automatic dependent surveillance-broadcast (ADS-B), and the error rate was calculated here. As a result, it was confirmed that the velocity and altitude error rate of large aircraft (I1, I3, S2) were lower than that of light aircraft (I2, S2), and the estimated velocity and altitude were relatively high in large aircraft using the proposed method.

Identification and characterization of laccase genes in the Flammulina velutipes var. lupinicola genome (Flammulina velutipes var. lupinicola의 유전체 정보기반 laccase 유전자 동정 및 특성 규명)

  • Yu, Hye-Won;Park, Young-Jin
    • Journal of Mushroom
    • /
    • v.19 no.4
    • /
    • pp.285-293
    • /
    • 2021
  • The purpose of this study was to identify and characterize the laccase genes of Flammulina velutipes var. lupinicola. Five laccase genes (g1934, g1937, g2415, g2539, g5858) were selected based on the copper binding site and signal peptide analysis results using the laccase gene selected from the F. velutipes var. lupinicola genome. The size of the laccase genes of F. velutipes var. lupinicola were 1,488 bp~1,662 bp. As a result of cDNA sequence analysis, 14 to 17 introns were identified in the laccase genes. The cleavage site predicted as the signal peptide of the laccase gene was found to be located between 20 bp and 34 bp from the N-terminus. In addition, separation and purification were performed to characterize the F. velutipes var. lupinicola laccases, and the optimal activity of the separated and purified proteins were analyzed by pH, temperature and time. Five bands with laccase activity were found from zymogram analysis. The optimal pH of the reaction was 5.5, the optimal temperature was found to be 40℃. Therefore, characterization of the laccase genes identified in this study should help in better understanding the biomass decomposition of F. velutipes var. lupinicola.