• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2017.05a
• /
• pp.67.1-67.1
• /
• 2017

구리는 탄성이방성이 큰 재료로 Si 박막상에 성장시키면 (111) 방향으로 우선 배향된 박막을 얻을 수 있다. 본 연구는 이러한 (111) 우선 방위를 갖는 Cu 박막의 전기도금층의 재결정 후의 매우 평탄한 표면을 갖는 박막에서 에칭에 따른 박막의 단차와 표면형상을 통해 결정방위별 에칭 특성을 비교 분석한 결과이다. 10 vol% 질산용액에서 에칭한 결과는 구리의 용해에 따라 각 결정면에 대한 고유의 facetted surface morphology를 나타내며, 대표적인 결정 방위인 (111), (110), (100)에 대해 triangular flake, ridge and rectangular pyramidal shapes을 나타내는 것을 알 수 있었다. 에칭속도의 정량적 측정을 위해 120초간 2.2M 농도의 질산용액으로 에칭을 실시하였고, nanosize의 as-plated initial region, (111), (110), (100) oriented regions의 각각에서 383, 270, 276, 317 nm/min의 에칭속도를 갖는 것을 확인하였다. Facet surface의 관찰을 통해 에칭반응이 (111) front surface를 갖는 열역학적 평형상태에서 일어나며, 이러한 결정방위별 에칭속도 차이는 각 결정S면이 갖는 Kink or ledge의 밀도의 차이에 기인할 것으로 판단된다. 즉, 에칭이 평형상태에서 step flow mechanism에 의해 열역학적 평형상태를 유지하면서 진행이 된다. 본 연구는 향후 다양한 에칭관련 용액 효과, 구리 박막의 응력 및 불순물에 의한 효과를 볼 수 있는 기본 방법을 제공해 줄 것으로 기대한다.

• Polymer(Korea)
• /
• v.35 no.4
• /
• pp.350-355
• /
• 2011

A soluble polyamide containing photosensitive l,4-phenylenediacrylic acid (PDA) in main chain with biphenyl moiety was synthesized. The chemical structure of synthesized polyamide was investigated by means of $^1H$ NMR spectroscopy. The polymer was stable up to $280^{\circ}C$ and soluble in organic solvents, giving a good quality of thin films. The photoreaction of unpolarized LTV irradiated films was investigated by means of UV-vis absorption spectroscopy and FTlR spectroscopy, and liquid crystals (LCs) alignment property was examined by exposing to linearly polarized UV light (LPUVL) of 260~380 nm. The polyamide in film has excellent photoreactivity to unpolarized UV light. Direction selective photoreaction of PDA moiety in Lhe film was found to further induce nematic liquid -crystals to align along a perpendicular direction with respect to the electric vector of LPUVL, regardless of exposure energy of LPUVL. In addition, pretilt angle was measured by means of crystal rotation method. LPUVL-exposed polymer film induced the alignment of liquid-crystals (LC) with a pretilt angle of 0.2~$0.5^{\circ}$.

• The Journal of the Petrological Society of Korea
• /
• v.16 no.3
• /
• pp.129-143
• /
• 2007

We have studied orientational characteristics of microcracks in Mesozoic granites and granitic dyke rocks from Seokmo-do, Ganghwa-gun. Microcracks on horizontal surfaces of rock samples from 14 sites were investigated by image processing. Orientations of these microcracks compared with those of 18 sets of joints in Mesozoic granites from Seokmo-do. From the related chart, microcrack sets show strong preferred orientations which obviously are coincident with the direction of vertical common joints. It follows that the formation of macroscopic joints may be the results of further growth and step-wise jointing of pre-existing microcracks. Orientations of microcracks from this result also compared with those of vertical rift and grain planes for Jurassic and Cretaceous granite quarries in Korea. As shown in the distribution chart, the congruence of distribution pattern among microcracks and rift and grain planes suggests that similar microcrack systems probably occur regionally in Jurassic and Cretaceous granites from Korea. In particular, whole domain of the distribution chart was divided into 16 groups in terms of the phases of distribution of microcracks and planes. These microcrack sets in each domains construct complex composite microcrack systems which have formed progressively by different geologic processes and under varying conditions.

• Journal of Korean Society of Steel Construction
• /
• v.13 no.1
• /
• pp.53-60
• /
• 2001

Theories for advanced composite structures are too difficult for such design engineers for construction and some simple but accurate enough methods are necessary. The senior author has reported that some laminate orientations have decreasing values of $D_{16}$, $B_{16}$, $D_{26}$ and $B_{26}$ stiffnesses as the ply number increases. For such plates the fiber orientations given above behave as specially orthotropic plates and simple formulas developed by the senior author. Most of the bidge and building slabs on girders have large aspect ratios For such cases frurther simplification is possible by neglecting the effect of the longitudinal moment terms(Mx) on the relevant partial differential equationsof equilibrium In this paper, the result of the study on the subject problem is presented.

• The Journal of Engineering Geology
• /
• v.23 no.1
• /
• pp.47-55
• /
• 2013

To analyze lateral displacement of excavation walls exposed during the construction of Subway Line 1 in the Daegu region, inclinometer measurement data for sites D4, D5, and Y6 are investigated from the perspective of engineering geology. The study area, in the Banyawol Formation, Hayang Group, Gyeongsang Supergroup, is in the lower part of bedrock of andesitic volcanics, calcareous shale, sandstone, hornfels, and felsite dykes that are unconformably overlain by soil. The rock mass around the D4 site is classified as RMR-V grade and the maximum lateral displacement of 101.39 mm, toward N34W, was measured at a bedding-parallel fault, at a depth of 12 m. The rock mass around the D5 site is classified as RMR-IV grade and the maximum lateral displacement of 55.17 mm, toward the south, was measured at a lithologic contact between shale and felsite, at a depth of 14 m. The rock mass around the Y6 site is classified as RMR-III grade and the maximum lateral displacement of 12.65 mm, toward S52W, was measured at an unconformity between the soil and underlying bedrocks, at a depth of 7 m. The directions of lateral displacement in the excavation walls are vector sums of the directions perpendicular to the excavation wall and horizontally parallel to the excavation wall. Lateral displacement graphs according to depth in the soil profile show curvilinear trajectories, whereas those in bedrock show straight and rapid-displacement trajectories.

• The Journal of Engineering Geology
• /
• v.9 no.2
• /
• pp.119-134
• /
• 1999

Joints developed around the Moryang fault were investigated by traverse and inventory methods in order to characterize their orientation, spacing and density. The results of the traverse method show that the orientation of the dominant joint sets of the study area is NNE and EW, and that joint spacing distribution is a negative exponential distribution to the center of the fault and a log-normal distribution to the margin of the fault. The results of the inventory method show that the orientation of the dominant joint sets on joint map is NW and NE, and that joint density tends to increase toward the center of the fault. Fractal dimension was determined by using Box-counting method and Cantor's dust method to quantify the distribution of joint network and to evaluate the dimension around the fault. The dimension determined by Box-counting method ranges from 1.31 to 1.70 and shows the tendency of increasing value toward the center of the fault. Comparing fractal dimension by Box-counting method with joint density, fractal dimension is directly proportional to joint density. Nevertheless, fractal dimension could be varied due to the different distribution patterns of the joints with same density. The dimensions determined by Cantor's dust method show different values with respect to the orientation of scan lines. This results form the anisotropy of joint distribution.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2003.03a
• /
• pp.211-211
• /
• 2003

PbTiO$_3$ 씨앗층을 이용하여 완화형 강유전체 Pb(Mg$_{1}$3/Ta$_{2}$3/)O$_3$ (PMT) 박막의 페로브스카이트 상안정화와 열처리 조건에 따른 미세구조변화, 이에 따른 전기적 특성 변화에 관하여 조사하였다. PbTiO$_3$ 박막을 스핀코팅법으로 3000 rpm에서 20초간(111) 방향으로 배향된 Pt / Ti / SiO$_2$/ Si 기판에 증착하여 안정화된 페로브스카이트 박막을 얻었다. 이렇게 제조된 PbTiO$_3$를 Buffer 층으로 사용하고 그 위에 Pb(Mg$_{1}$3/Ta$_{2}$3/)O$_3$를 박막을 Spin coating방법으로 증착한 후, 급속열처리 방법(RTA)으로 550- $650^{\circ}C$ 사이에서 열처리하였다. 제조된 박막의 열처리 온도에 따른 미세구조 변화와 결정성을 XRD, SEM, TEM으로 분석하였고 박막의 저온 강유전 특성을 RT66A를 이용하여 평가하였다. Pb(Mg$_{1}$3/Ta$_{2}$3/)O$_3$ 박막의 경우 씨앗층이 없는 경우에는 pyrochlore상이 주상이었지만 씨앗층을 사용한 경우 페로브스카이트 상이 주상임을 확인하였고 열처리 온도가 증가할수록 페로브스카이트상의 상대적 양이 증가함을 확인하였다. 미세구조와 상의 변화에 따른 전기적 특성 변화에 관하여 자세하게 논의할 것이다.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.1 no.2
• /
• pp.94-103
• /
• 1991

ZnO-$P_2O_5$ system glasses containing 45 to 60 mol% ZnO have been melted at$1200^{\circ}C$and crystallized through controlled heat treatment. The properties of the base glass and crystallized glass were examined with XRD. FTIR. density. thermal expansion, electric conductivity, hardness. The principal crystalline phase was identified as zinc metaphosphate [$Zn(PO_3)_2$ in crystallized glasses containing 45-55mol% ZnO and zinc pyrophosphate ($Zn_2P_2O_7$) in the sample of 60mol% ZnO with X - ray diffraction analysis. Thermal expansion coefficient and DC electrical conductivity were varied with direction of oriented crystalline in the samples containing 50-60mol% ZnO. This suggests the existance of the oriented crystalline.

• Composites Research
• /
• v.13 no.6
• /
• pp.30-38
• /
• 2000

In this paper, a system of falling weight impact tester was built up to evaluate the impact energy absorbing characteristics and impact strength of CFRP laminate plates in consideration of stress wave propagation theory. Delamination area of impacted specimens for the different ply orientation was measured with ultrasonic C-scanner to find correlation between impact energy and delamination area. Absorbed energy of quasi-isotropic specimen having four interfaces was higher than that of orthotropic laminates with two interfaces. The more interfaces, the more absorbed energy. Hybrid specimen containing GFRP layer was higher than that of normal specimens.

• Korean Journal of Materials Research
• /
• v.4 no.5
• /
• pp.581-589
• /
• 1994

Magnetic properties and microstructures of the $Co_{83}Cr_{17}$ films growing under the applied magnetic field were studied. In comparison, those of the films growing without magnetic field were also studied. Magnetic field does not affect saturation magnetization and in-plane coercivity of the films. On the contrary perpendicular coercivity and effective perpendicular anisotropy field decreased. Grain size and the thickness of the so-called transition layer were not affected and the C-axis alignment of the films was slightly deteriorated due to magnetic field. Also, microstructures of the sputtered films showed larger grain sizes of strong (002) preferred orientation for thicker film specimens independent of applied magnetic field.