• Clean Technology
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• v.13 no.1 s.36
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• pp.22-27
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• 2007

Pacquer traditionally has been used to varnish. Many reports have revealed that lacquer has durability and antimicrobial activities. Therefore, we expect that lacquer will be used as a good antifouling agent to solve the environmental problem. Here we chemically synthesized urushiol, a major component in lacquer and two urushiol derivatives, urusiol regioisomer and cardanol. We also analyzed the antimicrobial activities of these molecules to examine the inhibitory effect on the formation of the biofilms. Our results showed that synthesized urushiol and its derivatives have strong antifungal activities. Urushiol also exhibited inhibitory effect on the growth of gram positive bacteria specifically. However urushiol derivatives have low antibacterial activities.

• Corrosion Science and Technology
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• v.13 no.1
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• pp.15-19
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• 2014

Recently, anti-fouling paints which does not include the poison components such as tin(Sn), copper(Cu) have been increasingly developed in order to inhibit the environmental contamination of the sea water. Moreover, the wear ratios of these anti-fouling paints are very important problem to prolong their life time in economical point of view. In this study, five types of anti-fouling paints as self polishing type were investigated on the relationship between their polarization characteristics and wear ratios. It was verified that there was apparently a good relationship between the wear ratio and polarization characteristics, for example, the wear ratio increased with increasing the impedance ratio, and increased or decreased with the corrosion potential shifting in the negative or positive direction respectively. In addition, the wear ratio decreased with decreasing the corrosion current density. Consequently, it is suggested that we can qualitatively expect the wear ratio by only measuring the polarization characteristics. Therefore, before the examination of the wear ratio was actually carried out in the field, the evaluation of polarization property in the laboratory may give a available reference data for their developments.

• Korean Journal of Environmental Biology
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• v.41 no.3
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• pp.256-265
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• 2023

Chlorothalonil is continuously introduced into the marine environment and has significant toxic effects on various marine organisms, however, research on its effect on seaweed is limited. Therefore, we analyzed the impact of chlorothalonil on the early life stages of major aquaculture species in Korea, Undaria pinnatifida. U. pinnatifida female gametophytes were exposed to different concentrations of chlorothalonil (0, 0.03, 0.05, 0.10, 0.20, and 0.40 mg L^-1), and their survival rate and relative growth rate were analyzed. The no observed effect concentration (NOEC), lowest observed effect concentration (LOEC), and median lethal concentration (LC50) for female gametophyte survival were determined as 0.05, 0.10, and 0.141(0.121-0.166)mg L^-1. NOEC, LOEC, and median effective concentration (EC50) for relative growth rate were 0.10, 0.20, and 0.124 (0.119-0.131) mg L^-1. Therefore, female gametophytes of U. pinnatifida are expected to experience toxic effects at concentrations above 0.05-0.10 mg L^-1 of chlorothalonil. These research findings are anticipated to serve as crucial reference data for evaluating the effects of chlorothalonil on the health of U. pinnatifida in the early life stages.

• Journal of Navigation and Port Research
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• v.28 no.8
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• pp.767-773
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• 2004

IMO(International Maritime Organization) is strongly proceeding with adoption of a new maritime environmental convention and coming into r1fed for regulation enhancement about the pollutants which are happened in a ship recently. Study about the conventions that our country currently comes into r1fect, and there is during forwarding and correspondence must be performed effectively. In this paper, International convention on the control of harmful Anti-Fouling system on ship, Ballast water management, Prevention of air pollution from ships, treat a main pending problem in ocean related environmental regulation convention.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.19 no.1
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• pp.1-7
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• 2014

Butyltin compounds (BTs) were determined in surface sediment samples from Ulsan Bay in 2009 and 2011, to assess the contamination status and the effectiveness of tributylin (TBT) restriction of Korea. Dibutyltin and TBT concentrations in sediments in 2011 ranged from 19.5 to 980 and 14.2 to 1204 ng Sn $g^{-1}$ dry weight, respectively. The highest TBT concentration was found in a big shipyard complex and the next highest was found in harbor, suggesting that harbor and shipyard activities are a major contamination source of TBT in Ulsan Bay. Concentrations of BTs in Ulsan Bay sediments were significantly lower in 2009 and 2011 than that in 2003 survey previously reported, probably as a consequence of the legislative action in Korea. However, TBT concentrations in sediments still exceeded ecotoxicological values. Therefore, it will be important to monitor and reduce TBT contamination in sediments until the levels fall well below ecotoxicological levels.

• Journal of Marine Life Science
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• v.5 no.1
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• pp.9-16
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• 2020

We evaluated the toxic effects of antifouling paint (irgarol and diuron) on the population growth rate (r) of the marine diatom, Skeletonema costatum. The r of S. costatum was determined after 96 hrs of exposure to irgarol (0, 0.31, 0.63, 1.25, 2.5 and 5 ㎍ l^-1) and diuron (0, 7.81, 15.63, 31.25, 62.5 and 125 ㎍ l^-1). It was observed that r in the control (absence of irgarol and diuron) were greater than 0.04, while r in the treatment groups decreased with increasing irgarol and diuron concentrations. Irgarol and diuron reduced r in a dose-dependent manner with significant decreases occurring at concentrations above 0.63 and 15.63 ㎍ l^-1, respectively. The EC₅₀ values of r in irgarol and diuron exposure were 1.09 and 45.45 ㎍ l^-1. No observed effect concentration (NOEC) were 0.31 and 7.81 ㎍ l^-1, the lowest observed effect concentration (LOEC) were 0.63 and 15.63 ㎍ l^-1. This result indicate that a concentration of greater than 0.63 ㎍ l^-1 of irgarol and 15.63 ㎍ l^-1 of diuron in marine ecosystems induced to decreasing r of S. costatum. Also, these toxic values can be useful as a baseline data for the toxic evaluation of irgarol and diuron in marine ecosystems.

• Proceedings of KOSOMES biannual meeting
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• 2006.11a
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• pp.97-104
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• 2006

Though stringent guidelines are in place to protect the harbor environment, pollution from ships, from the ports terminals. Discharge from the ballast tanks of ships, though illegal, does occur. Such vessels, arriving from distant ports of call, can introduce exotic species of plants and animals, causing disruption of the local food web. Discharges rich in nitrogen can generate the rapid growth of plankton, eventually leading to a condition known as red tide that is lethal to some coastal organisms. In addition to the harbor's negative effects on marine organisms, the diesel engines of the ships and the trucks that haul cargo to and from the ports release large volumes of diesel exhaust into the atmosphere. IMO(International Maritime Organization) is strongly proceeding with adoption of a new maritime environment convention and coming into effect for regulation enhancement about the pollutants which are happened in a ship recently. Study about the conventions that our country currently comes into effect, and there is during forwarding and correspondence must be performed effectively. In this paper, International convention on the control of harmful Anti-Fouling system on ship, Ballast water management, Prevention of air pollution from ships, treat a main pending problem in ocean related environmental regulation convention.

• Journal of the Korean Society for Marine Environment & Energy
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• v.12 no.2
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• pp.68-74
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• 2009

Polycyclic aromatic hydrocarbons (PAHs), one of ubiquitous organic pollutants in marine environments, are major toxic components of petroleum and are produced during the incomplete combustion of organic materials. As shipyards are located inside of natural or artificial semi-enclosed bay, even a relatively weak environmental disturbance by ship-building activity can cause severe damage to marine ecosystem in the bay. Many studies of pollution in shipyard area have been focused on the antifouling agent, like tributyltin. This study aimed to investigate the effect of ship-building activity on PAH contamination. Total PAHs concentration was higher nearby and inside shipyard area than outside, implying that shipyard could be one of major source area of PAH contamination to pose harmful effects to surrounding environments. Through PAH profile and source recognition index, the source of PAHs inputs in this area was estimated to originate from both petrogenic and pyrogenic origin. PAH levels showed a significant correlation with total butyltins, indicating that ship-building activity influenced PAH concentration and distribution. Vertical distribution of PAHs historically confirmed the correlation between shipbuilding activity and PAHs contamination.

• Environmental Analysis Health and Toxicology
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• v.18 no.2
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• pp.89-94
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• 2003

Tributyltin (TBT) used world-wide in antifouling paints for ships is a widespread environmental pollutant and cause reproductive organs atrophy in rodents. At low doses, antiproliferative modes of action have been shown to be involved, whereas at higher doses apoptosis seems to be the mechanism of toxicity in reproductive organs by TBT. In this study, we investigated that the mechanisms underlying DNA fragmentation induced by TBT in the rat leyding cell line, R2C. Effects of TBT on intracellular Ca$\^$2+/ level and reactive oxygen species (ROS) were investigated in R2C cells by fluorescence detector. TBT significantly induced intracellular Ca$\^$2+/ level in a time-dependent manner. The rise in intracellular Ca$\^$2+/ level was followed by a time-dependent generation of reactive oxygen species (ROS) at the cytosol level. Simultaneously, TBT induced the release of cytochrome c from the mitochondrial membrane into the cytosol. Furthermore, ROS production and the release of cytochrome c were reduced by BAPTA, an intracellular Ca$\^$2+/ chelator, indicating the important role of Ca$\^$2+/ in R2C during these early intracellular events. In addition, Z-DEVD FMK, a caspase-3 inhibitor, decreased apoptosis by TBT. Taken together, the present results indicated that the apoptotic pathway by TBT might start with an increase in intracellular Ca$\^$2+/ level, continues with release of ROS and cytochrome c from mitochondria, activation of caspases,and finally results in DNA fragmentation.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.34 no.3
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• pp.254-259
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• 2001

In order to make clear the resistance of plane nettings u,sed widely in constructing net cages, the resistance R taken by $R=kSU^2$, where S was the wall area of nettings, U the flow velocity, and k the resistance coefficient, was measured in a circulating water channel by using nylon Raschel nettings and PE trawler-knotted nettings coated with anti-fouling paint or not and then the properties of coefficient k were investigated. The mesh size L and the angle $\phi$ between two adjacent bars was given by the function of Reynolds number ${\lambda}U/v$ in the region of ${\lambda}U/v<180$, i. e., $$k=350(\frac{\lambda U}{v})^{-0.25}$$.where $\lambda$ was the representative size of nettings expressed as $$\lambda=\frac{{\pi}d^2}{2L\;sin\;2{\phi}}$$On the other hand, the coefficient k was almost fixed between 92 and 102 ($kg{\cdot}s^2/m^4$) in the region of ${\lambda}U/v{\geq}180$ and varied according to the ratio $S_n/S$ of the total area $S_n$ of nettings projected to the plane perpendicular to the water flow to the wall area S of nettings, i.e., it was given by $$k=98.6(\frac{S_n}{S})^{1.19}$$ regardless of the coating of paint.