• Title/Summary/Keyword: 방오도료

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Evaluation of Acute Toxicity about Leakage Waters of Antifouling Paints on Sebastes shlegeli and Artemia (방오도료 용출수의 조피볼락과 알테미아에 대한 급성독성 평가)

  • Kim, Pil-Geun;Park, Maeng-Eon;Lee, In-Won;Chun, Ho-Hwan;Park, Hyun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.16 no.4
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    • pp.361-367
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    • 2010
  • The use of antifouling(AF) paints is the effective method for the protection of underwater structures from the development of marine fouling organisms. The ban on harmful substances in antifouling paints requires the development of new antifouling strategies although Tributyitin (TBT) compound had been used extensively as an active ingredient Alternatives should be as effective as conventional paints but have lower toxicity. In the present study, a TBT-free self-polishing (Cu SPC) AF paint containing $Cu_2O$, a Cu free SPC AF paint, and a Foul-release silicone AF paint, which were commercially available, were examined to investigate environmental erects of leakage waters employing Sebastes shlegeli and Artemia. Survival rates were inversely proportional to the concentration of leakage waters from AF paints and the acute toxicity of SPC AF paints was relatively higher than that of foul release AF paints.

Real Environment Anti-Fouling Performance Test of Silyl Type SPC A/F Coatings (Silyl계 방오도료의 실환경 방오성능 평가)

  • Jeong, Hyeong-Jun;Jo, Yeon-Ho;Kim, Dae-Gyeong;Cheon, Je-Il;Han, Myeong-Su;U, Jong-Sik
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.83-83
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    • 2014
  • 선박건조에 사용되는 도료 중 SPC(self-polishing copolymer) A/F(anti-fouling) 도료의 주된 기능은 해양생물의 부착 등 해양생물에 의한 오염을 방지하는 방오성능으로 인식되어 왔으나, 최근 방오성능 뿐 아니라 선박의 운항 시 선체저항을 줄임으로써 발생되는 연료절감효과와 선박의 미관을 위한 변색지연 등 SPC A/F 도료의 다른 기능에 많은 관심을 가지게 되었다. 이러한 관심과 사용자의 요구에 따라 도료사에서는 항력의 감소를 가져 올 수 있는 Silyl acrylate copolymer로 디자인 된 Silyl acrylate SPC A/F 도료를 개발하였으나 SPC A/F 도료의 방오제(biocides) 종류에 따른 방오성능 차이를 비교 평가 할 수 있는 객관적 자료가 부족하여, 본 연구를 통해 SPC A/F 도료의 종류 별 방오성능을 평가하고자 한다.

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Tin-free 방오도료가 북방대합 (Pseudocardium sachalinensis) 약물대사 효소계에 미치는 영향

  • 전중균;이지선;심원준;이수형;전영하;함영래
    • Proceedings of the Korean Society of Fisheries Technology Conference
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    • 2002.10a
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    • pp.257-258
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    • 2002
  • 유기주석화합물은 방오도료로 효과가 뛰어나지만 수생생물에게 생식독성을 보이는 등 환경호르몬 (endocrine disrupors)으로 작용하는 것이 밝혀지면서 국제적으로는 사용을 규제하는 추세이다. 따라서 이를 대체할 수 있는 새로운 방오화합물을 개발하려는 시도가 여러 나라에서 이루어지고는 있지만, 실제로 영국을 제외하고는 antifouling 화합물의 실제 사용량에 대한 정보는 매우 제한적인 실정이다(Voulvoulis 등, 1999). (중략)

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Full Scale Frictional Resistance Reduction Effect of a Low Frictional Marine Anti-fouling Paint based on a Similarity Scaling Method (상사축척법에 기반한 저마찰 선박 방오도료의 실선 마찰저항 저감성능 추정)

  • Yang, Jeong Woo;Park, Hyun;Lee, Inwon
    • Journal of the Society of Naval Architects of Korea
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    • v.54 no.1
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    • pp.71-81
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    • 2017
  • In this study, a series of full-scale extrapolation procedures based on the Granville's similarity scaling method, which was employed by Schultz (2007), is modified and then applied to compare the resistance performance between two different anti-fouling coatings. As an analysis example, the low frictional AF coating based on a novel skin-friction reducing polymer named FDR-SPC (Frictional Drag Reduction Self-Polishing Copolymer), which had been invented by the present author, is employed. The low frictional coating, which gives 25.4% skin frictional reduction in lab test, is estimated to give 18.2% total resistance reduction for a 176k DWT bulk carrier.

Antifouling Paint Resin Based on Polyurethane Matrix with Quaternary Ammonium Salt (Quaternary Ammonium Salt를 도입한 방오도료용 폴리우레탄 수지)

  • Kim, Dae-Hee;Jung, Min-Yeong;Park, Hyun;Lee, In-Won;Chun, Ho-Hwan;Jo, Nam-Ju
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.122-129
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    • 2015
  • Recently, the development of a new class of anti-fouling paint resin which has excellent anti-fouling performance and no persistence in the marine ecology is necessary. In this study, we first polymerized polyurethanes (PUs) as the other type of matrix which have carboxylic acid groups by using poly(ethylene glycol) (PEG), 4,4'-diphenylmethane diisocyanate (MDI), and 2,2'-bis(hydroxyl methyl)-propionic acid (DMPA). And next, we synthesized final resins having quaternary ammonium salts on pendant acid groups of PUs. After synthesis, the physical self-polishing property of resin by the measurement of reduced thickness in sea water was tested. The mechanical property of antifouling paint resin was good when the molecular weight of PEG was 600 or less. It was confirmed that the adhesion of PU resin was deteriorated when the content of quaternary ammonium salt was incorporated over specific value.

Image Analysis Method for the Performance Evaluation of Marine Antifouling Coatings (화상 분석을 통한 선박 방오도료의 성능 평가)

  • Park, Hyun;Chun, Ho Hwan;Lee, Inwon
    • Journal of the Korean Society of Visualization
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    • v.11 no.2
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    • pp.18-26
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    • 2013
  • An accurate and reliable performance evaluation technique is indispensable for the development of marine antifouling coatings. The existing standard practice is however, based on the visual observation of biofouling settlement area, which is prone to the subjective judgment of the inspector. In spite of the above mentioned importance, a systematic and objective fouling evaluation technique has not yet been introduced. In this study, a novel quantitative antifouling performance evaluation method for marine antifouling paints is devised based on the image analysis of panel immersion test results. The present image analysis method is to quantify settlement area for each fouling category by distinctive color. The fouling categories are set as unfouled, biofilm, green algae, brown algae, calcareous animal and spongy animal with specific HSL (Hue, Saturation, Lightness) color ranges. In order to assess the effectiveness of the proposed method, static immersion tests for three antifouling coatings were undertaken for two years.

Chemical Treatment of Fouling Organisms on Fishing Nets (어망에 부착하는 오손생물의 화학처리 방법)

  • HUR Sung-Bum;CHUN Seh-Kyu;KIM Hyung-Sun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.19 no.3
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    • pp.241-248
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    • 1986
  • New Paint, Stapol N-6200D, products from Song Woun Industrial Co. Ltd., was tested on its chemical effect on fouling organisms attached to fishing nets. Two kinds of fishing nets with different mesh size, 5 mm (cage culture net) and 33 mm (set net) were painted and attached to $1m^2$ PVC quadrates. The quadrates with painted or non-painted fishing nets were placed at the surface water layer of southern coast of Korea. Monthly species composition and abundance of fouling organisms were analysed as well as total weight of fouling organisms including mud on fishing nets. On the other hand, anti-fouling effect of the organisms and mud on different color paints was studied and the durability of chemical effect of painted fishing net on fouling organisms was also estimated.

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Development of a Novel Treatment System for TBT Paint Waste from Ship (TBT 방오폐인트 폐기물의 최적 처리시스템 연구)

  • 박상호;김인수;송영채;우정희;김동근
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2003.05a
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    • pp.206-211
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    • 2003
  • Bans on TBT based antifouling paints have been drafted since 1998 by meeting 42, 43, 45 and 46 for the MEPC(Marine Environmental Protection Committee) of the International Marine Organization, and decided finally at a Diplomatic Conference of the IMO in October 2001. It was a key issue that there should be a global prohibition on the presence of organo-tin compounds in ships by 1 Jan. 2008. TBT Paint Waste from ship happens by vast quantity since 2003. This paper suggests a method to design Treatment System for TBT Paint Waste from Ship. The result of measurement in pyrolysis system were removal rate on 99%. at hight temperature in 1000$^{\circ}C$ and reaction time 1hr. TBT removal was more that 99%.

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