• Title/Summary/Keyword: 방사성 불소

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Calculation of Shielding Rate and Dose Distribution of Space of L-Block-Type Protective Equipment for Radioactive Fluorine using the Monte Carlo Method (몬테칼로 방법을 이용한 방사성 불소에 대한 L-블럭형 방호장비의 차폐율 및 공간의 선량분포 계산)

  • Han, Dong-Hyun
    • Journal of the Korean Society of Radiology
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    • v.15 no.6
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    • pp.813-819
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    • 2021
  • In this study, the shielding rate of L-block-type shielding equipment used for radiation protection when radioactive fluorine is injected into the human body and the dose distribution of the space in the injection room were calculated using the Monte Carlo method. The shielding rate of the body and window parts of the L-block-type shielding equipment was 99.99%. The dose distribution calculated at a distance of 1 m was relatively high at 135°, 45°, 225°, 315°, and 180° of the XZ plane, and was calculated to be very low at 0°, 90°, and 270°. In the YZ plane, it was relatively high at 135°, 180°, and 225°, and was calculated very low at the remaining angles. The AZ and BZ planes also showed similar results to the YZ plane. In addition, it was confirmed that the shielding rate was the best in the range of 225° to 315° through the dose distribution in the horizontal direction of the source and the 45° direction above the source. These results can be used as basic data necessary for radiation protection of radiation workers.

Influence of Fluorinated Illite on Thermal, Antibiotic and Far-infrared Emission Properties of Polypropylene Non-woven Fibers (폴리프로필렌 부직포 섬유의 열, 항균 및 원적외선 방사 특성에 미치는 불소화 일라이트 첨가의 영향)

  • Kim, Jinhoon;Im, Ji Sun;Seo, Kyeong-Won;Lee, Young-Seak
    • Polymer(Korea)
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    • v.37 no.1
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    • pp.86-93
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    • 2013
  • In this work, the thermal, antibiotic properties and far-infrared emissivity of fluorinated illite embedded polypropylene non-woven fibers (f-illite/PP fibers) were investigated in the presence of 0, 1, 3, 5 and 7 wt% illite powders. The thermal properties of f-illite/PP fibers were studied by thermogravimetric analysis (TGA). Their antibiotic properties were examined by Staphylococcus aureus and Klebsiella pneumoniae test. Their far-infrared emissivity was also investigated by Fourier transform infrared spectroscopy. From the experimental results, thermal, antibiotic properties and far-infrared emissivity of f-illite/PP fibers were improved by increasing fluorinated illite contents and the property values of 5 wt% f-illite/PP fibers were increased remarkably by about 10.3, 41.2 and 9.8% respectively in comparison with PP non-woven fibers having no fluorinated illite additive. This result was interpreted as the development of interfacial adhesion force between the polymer chains due to the fluorination of illite power.

Fluoro-illite/polypropylene Composite Fiber Formation and Their Thermal and Mechanical Properties (불소화 일라이트/폴리프로필렌 복합섬유 형성 및 열 및 기계적 특성)

  • Jeong, Euigyung;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.22 no.5
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    • pp.467-472
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    • 2011
  • This study investigated illite/polypropylene (PP) composite filament formation via melt-spinning and evaluated their physical properties to prepare functional fibers using natural materials. When composite filaments were formed, the composite filaments exhibited smaller fiber diameters compared to that of neat PP filament because of the lubricant effect of illite induced by its layered structure. Moreover, fluorination effect increased interfacial affinity and dispersion in the polymer, resulting in smaller diameter of fluorinated illite/PP composite filament, which was 2/3 of the neat PP filament diameter. Addition of raw and fluorinated illite improved thermal stability of illite/PP composite filament. Raw illite/PP composite filament cannot be used for a practical application, because it broke during drawing process, whereas the fluorinated illite/PP composite filament can be used for a practical application, because it exhibited similar tensile strength of the neat PP filament and 50% increased modulus. Even with improved illite/PP interfacial affinity and illite dispersion in the polymer, illite/PP composite filament formed microcomposite, because non-expandable illite had strongly bound layers, resulting in only a little illite exfoliation and PP intercalation into illite.

Study on Optimum Condition of Water-Repellent Finishing For PPS Fabrics (PPS 원단의 발수가공을 위한 최적의 가공조건 고찰)

  • Lee, In-Yeol;Jeong, Go-Eun;Lee, Stephen
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.47-47
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    • 2011
  • 국내의 기능성 난연성 섬유 제조기술은 원사 자체에 난연제가 포함된 상태인 난연 PET 원사나, 일반 PET 원단에 후방염 처리한 원단이 사용되기에 난연 방염성능이 만족스럽지 못하고 친환경적이지 못한 실정이다. 오늘날 세계 난연섬유 시장 규모는 10조원에 이르고 있으며 국내에서도 화재에 대한 경각심이 높아지는 추세이므로 기능성을 갖춘 고부가가치 난연소재의 개발이 시급하다. 폴리페닐렌술피드(PPS)는 내열성 및 내화학약품성이 뛰어난 열가소성 고분자로 용융방사가 가능하다. 난연성이 높은 양모섬유 또는 아크릴계 난연섬유, 아라미드 섬유 등은 비용 문제로 범용화에 한계가 있으므로 비교적 저렴한 PPS 섬유가 개발될 경우 범용화를 기대할 수 있다. 현재는 PPS 섬유가 특수한 용도에 주로 사용되고 있으나 우수한 난연 특성을 이용하여 일반 용도로의 사용 및 수요가 급격히 늘어날 것으로 예상되며 우선적으로 인테리어용 원단, 특히 커튼이나 소파용 원단으로 용도 전개가 가능할 것으로 판단하였다. 본 연구에서는 소파용 PPS 원단의 후가공 조건의 선정 및 불소계 발수방오가공을 위한 최적의 조건을 선정하고자 하였다. Padding(wet pick up율 $80{\pm}3%$)-Drying($105^{\circ}C$, 2.5min)-Curing은 시간은 1분으로 고정시킨 후, 온도를 150, 160, 170, 180, 190, $200^{\circ}C$에서 처리하여 Yellowness값을 측정한 결과, 온도가 높아질수록 Yellowness값이 커지는 것으로 미루어 보아 PPS원단은 높은 열에 영향을 받아 황변 현상이 일어나는 것으로 사료된다. 특히 $180^{\circ}C$를 기점으로 값에 큰 변화를 보였으므로 최적의 열처리 온도는 $170^{\circ}C$로 선정하여 이후의 실험을 진행하였다. 또한 큐어링 시간이 황변에 미치는 영향을 분석한 결과 온도에 의한 영향에 비해 적은 편으로 사료되었으나, 1.5min을 기점으로 Yellowess값이 높아졌으므로 최적의 열처리 시간을 1분으로 선정하였다. 최종 가공조건인 $170^{\circ}C$, 1분에서 처리한 시험포는 처리전 원단과 비교하였을 때, ${\Delta}$Yellowness가 2.84 정도로 나타났다. 그 후, PPS 원단에 불소가공제 (TG-991N, 동인텍스켐)의 적정 농도를 선정하기 위해 1~7%까지 농도를 높이며 처리한 결과, 불소가공제의 농도가 높아짐에 따라 황변현상이 나타남을 알 수 있었다. 농도가 높아짐에 따라 Yellowness값은 증가하다가 4% 이후 완만해지는 것을 알 수 있었으므로 IPA/Water Drop test와 발수도시험 (KS K 0590;2008)을 통해 적정 농도를 선정하였다. PPS 원단은 불소가공제의 농도가 높아짐에 따라 발수도가 우수해졌으며, 가공제 농도 3% 처리만으로도 우수한 발수도를 나타내었으나 100% 발수를 위해서는 가공제 농도가 5% 이상 처리되어야 하는 것을 확인할 수 있었다.

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Production of $[^{18}F]F_2$ Gas for Electrophilic Substitution Reaction (친전자성 치환반응을 위한 $[^{18}F]F_2$ Gas의 생산 연구)

  • Moon, Byung-Seok;Kim, Jae-Hong;Lee, Kyo-Chul;An, Gwang-Il;Cheon, Gi-Jeong;Chun, Kwon-Soo
    • Nuclear Medicine and Molecular Imaging
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    • v.40 no.4
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    • pp.228-232
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    • 2006
  • Purpose: electrophilic $^{18}F(T_{1/2}=110\;min)$ radionuclide in the form of $[^{18}F]F_2$ gas is of great significance for labeling radiopharmaceuticals for positron omission tomography (PET). However, its production In high yield and with high specific radioactivity is still a challenge to overcome several problems on targetry. The aim of the present study was to develop a method suitable for the routine production of $[^{18}F]F_2$ for the electrophilic substitution reaction. Materials and Methods: The target was designed water-cooled aluminum target chamber system with a conical bore shape. Production of the elemental fluorine was carried out via the $^{18}O(p,n)^{18}F$ reaction using a two-step irradiation protocol. In the first irradiation, the target filled with highly enriched $^{18}O_2$ was irradiated with protons for $^{18}F$ production, which were adsorbed on the inner surface of target body. In the second irradiation, the mixed gas ($1%[^{19}F]F_2/Ar$) was leaded into the target chamber, fellowing a short irradiation of proton for isotopic exchange between the carrier-fluorine and the radiofluorine absorbed in the target chamber. Optimization of production was performed as the function of irradiation time, the beam current and $^{18}O_2$ loading pressure. Results: Production runs was performed under the following optimum conditions: The 1st irradiation for the nuclear reaction (15.0 bar of 97% enriched $^{18}O_2$, 13.2 MeV protons, 30 ${\mu}A$, 60-90 min irradiation), the recovery of enriched oxygen via cryogenic pumping; The 2nd irradiation for the recovery of absorbed radiofluorine (12.0 bar of 1% $[^{19}F]fluorine/argon$ gas, 13.2 MeV protons, 30 ${\mu}A$, 20-30 min irradiation) the recovery of $[^{18}F]fluorine$ for synthesis. The yield of $[^{18}F]fluorine$ at EOB (end of bombardment) was achieved around $34{\pm}6.0$ GBq (n>10). Conclusion: The production of $^{18}F$ electrophilic agent via $^{18}O(p,n)^{18}F$ reaction was much under investigation. Especially, an aluminum gas target was very advantageous for routine production of $[^{18}F]fluorine$. These results suggest the possibility to use $[^{18}F]F_2$ gas as a electrophilic substitution agent.

A STUDY ON THE TRANSFER OF RADIOACTIVE FLUORINE (18F) TO DENTAL HARD TISSUE (방사성(放射性) 불소(弗素)(18F)의 치아경조직내(齒牙硬組織內) 침투(浸透)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Oh, An-Min
    • Restorative Dentistry and Endodontics
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    • v.2 no.1
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    • pp.15-19
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    • 1976
  • The author studied on the transfer of radioactive fluorine ($^{18}F$) to dental hard tissue through animal experiments which was divided into two groups. First group of rats were sacrified 1, 2, 5, 10 and 20 minutes after intraperitoneal injection. Second group were sacrified 1 and 3 minutes after topical application on anterior teeth. The teeth were removed and sectioned by means of abrasive wheel and polished on india stone as thick as about 50 microns. Autoradiograph picture was made by close contact of high-speed dental X-ray film on prepared specimen for 2 hours. The results of this study were as follows; 1) There was no evidence of transfer of $^{18}F$ on dental hard tissue on the cases of 1, 2 and 5 minutes survival after intraperitoneal injection. 2) Radioactive sodium fluorine incorporated to dental hard tissue was slight and diffuse at 10 minutes cases and significant incorporated picture was noticed at 20 minutes cases in intraperitoneal injection. 3) On topical application groups incorporated $^{18}F$ to enamel was traced clearly only on enamel surface at 1 minute cases and significant transfer into whole enamel was found at 3 minutes cases.

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Electromagnetic Indirect Induction Fluid Heating System using Series Resonant PWM Inverter and Its Performance Evaluations (직렬공진 PWM인버터를 이용한 전자간절유도가열 열유체 에너지시스템과 그 성능평가)

  • 김용주;김기환;신대철
    • The Transactions of the Korean Institute of Power Electronics
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    • v.7 no.1
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    • pp.48-54
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    • 2002
  • This paper is described the indirect induction heated boiler and induction heated hot air producer using the voltage-fed series resonant high-frequency inverter which can operate in the frequency range from 20 kHz to 50 kHz. A specially designed induction heater is composed of laminated stainless plates, which have many tiny holes and are interconnected by spot welding. This heater is inserted into the ceramic type vessel with external working coil. This working coil is connected to the inverter and turbulence fluid through this induction heater to moving fluid generates in the vessel. The operating performances of this unique appliance in next generation and its effectiveness are evaluated and discussed from a practical point of view.