• Analytical Science and Technology
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• v.22 no.2
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• pp.136-140
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• 2009

To improve the carbon recovery yield of chemical pretreatment in soil and sediment for $^{14}C$ age dating using AMS (Accelerator Mass Spectrometry), we have developed ultrasonic method in chemical pretreatment to replace with stirring method which has been generally used in each step of humic acid extraction for soil and sediment samples. Extraction conditions such as ultrasonic power, temperature and reaction time have been optimized. Six times higher carbon recovery yield could be obtained from low carbon content samples using ultrasonic method. We also compared the dating results by AMS obtained using ultrasonic method with the ages of samples treated by the stirring method. It was found that this new method could be applied to the pretreatment process of low carbon content samples for AMS age dating without effects on the dated ages, and with highly improved carbon recovery yields.

• Journal of Conservation Science
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• v.18 s.18
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• pp.97-104
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• 2006

Absolute ages for three pieces of organic materials such as wood and shell were determined with radio-carbon concentrations and two potsherds with thermoluminescence measurements. Radiocarbon contents of each sample were compared with those of modern standard oxalate(NBS SRM4990C) and calculated radiocarbon ages of them. Quartz grains with diameter of $90\sim150{\mu}m$ were extracted from potsherds and used for measuring the archaeodose. Annual dose were calculated with measuring the alpha count rates and water contents and analysing $K_2O$ concentration of both potsherds and soils. Radiocarbon ages of organic materials were in the ranges of $4\sim2C$ BC and Quartz grain techniques for thermoluminescence dating showed 170 BC ud 210 BC respectively. It was found that the results of radiocarbon dating and TL dating were accorded with each other. But the deviations of TL dating have shown 13% and 20% respectively. It need to reduce the deviations.

• The Science & Technology
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• v.6 no.9 s.52
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• pp.16-17
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• 1973

오늘날 전세계가 직면하고 있는 에너지 위기를 해결할 수 있는 열쇠로서 원자력발전은 크게 각광을 받고 있다. 뿐만아니라 불치의 병으로 알려져 있는 암의 조기발견 및 치료, 농작물의 품종개량, 미장합판의 표면처리, 플라스틱 및 섬유류의 품질개선등 각 분야에 걸쳐 원자력의 이용범위는 확대되어 가고 있다. 심지어는 최근 사학계의 지대한 관심을 모으고 있는 경주 155호 고분의 연대측정시에도 원자력방사성 탄소에 의한 연대측정법이 활용되었음은 특기할 만한 사실이 아닐 수 없다. 그렇다면 과연 우리나라에 있어서 원자력의 산업적 이용은 어느 단계에까지 와있는 것일까? 이에 본지에서는 공학, 농학, 의학등에 활용되고 있는 방사선의 산업적 이용을 살펴봄과 동시에 원자력 발전의 국내실정과 전망을 전문지식인들에게 알아보았다.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2004.06a
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• pp.223-224
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• 2004

고준위폐기물 혹은 사용후 핵연료의 처분용기 재질은 각 국의 처분개념과 처분공의 주위 환경에 따라 달라질 수 있다. 용기의 후보재질로는 탄소강, 스텐레스 강, 구리, 니켈, 티탄 혹은 이들의 합금이 주로 고려되고 있으나, 국내에서는 아직 선정되지 않았다. 국내 처분환경에서 이들 재질의 부식특성을 조사하고자 모의 화강암 지하수를 가해 만든 겔 상태의 경주 벤토나이트에 탄소강, 스텐레스 강, 구리 시편을 넣고, $70^{\circ}C$, 아르곤 분위기에서 530일 경과한 후 시편의 표면 변화 (그림 1) 및 무게 감소를 측정하였다. 철 부식시편은 검정색의 철 화합물 층으로 덮여 있었으며, 구리표면에는 노란색의 부식층이 형성되었는데, 이를 XRD로 분석한 결과 $Cu_2O$로 판명되었다. 그러나 $700^{\circ}C$에서 각각 0, 24, 96시간동안 예민화시킨 스텐레스 강 시편들은 모두 초기상태 그대로 광택을 유지하고 있었으며, XRD에서 다른 화합물의 형성을 발견할 수 없었다 (그림 2). 시편의 무게 감소가 균일부식에 기인한 것으로 가정하여 환산한 결과, 구리와 스텐레스 강 모두 0.3~0.4 $\mu\textrm{m}/yr$의 부식속도를 나타내었다. 그러나 구리는 부식생성물이 표면에 부착되어 있기 때문에 실제 부식두께는 이 값보다 더 클 것으로 생각된다. 용기가 초기 530일간과 같은 속도로 처분용기의 부식이 진행된다면 한국에서 기준처분 개념으로 삼고 있는 50mm 두께의 내부식성 외벽 금속용기는 적어도 만년이상 견딜 수 있을 것으로 추정된다. 한편, 검정색 부식층을 제거한 무게감소로부터 계산한 철의 부식속도는 구리의 약 30배에 해당하였다. 금속 재질의 정확한 부식 거동을 파악하기 위해서는 보다 장기간의 실험이 요구된다. 시험법 선정에 각계(규제기관, 학계, 발전소 현장 및 산업계 등) 전문가로부터 기술자문회의를 통하여 자문 의견을 받기로 하였다. 특히 현재 폐기물 인수 기술기준치가 설정된 국가의 시험법을 심층 있게 검토하기로 하였다.검토하기로 하였다. 혹은 수성주변 환경이 지배하는 산악이나 구릉지에서 흔히 나타나는 침엽수-낙엽활엽수의 혼합림 식생상태를 잘 대변해 주고 있는 것으로 판단된다. 끝으로, 의림지 호저 퇴적층 중에서 인위적인 교란흔적이 없는 암회색 유기질 니층에 대한 탄소연대측정 결과, 제1호공 12번 시료에서 950$\pm$40 years B.P을 얻었으며, 제3-1호공에서도 아래로 내려가면서 8, 10, 11번 시료에 대하여 500$\pm$30 years B.P, 650$\pm$30 years B.P, 800$\pm$40 years B.P의 연대측정 결과를 획득하였다. 이상과 같은 의림지 호저 퇴적층의 형성환경과 형성시기 연구를 통하여 의림지의 제방축조의 최초시기를 해석해 보면, 의림지의 제방은 적어도 과거 약 827년 전에서 866년 전에는 이미 축조되어 있었음을 알 수 있다. 과거 제천 일대에 살았던 옛사람들이 의림지 하류의 곡지중앙과 고기 충적선상지에 대한 관계용 용수조달의 필요성에 부응하여 상류부 곡지하천의 자연입지 환경을 최대한 이용하여 축조한 것으로 판단된다..준비하였다.전류를 구성하는 주요 입자의 에너지 영역(75~l13keV)에서 가장 높은(0.80) 상관계수를 기록했다. 넷째, 회복기 중에 일어나는 입자들의 유입은 자기폭풍의 지속시간을 연장시키는 경향을 보이며 큰 자기폭풍일수록 현저했다. 주상에서 관측된 이러한 특성은 서브스톰 확장기 활동이 자기폭풍의 발달과 밀접한 관계가 있음을 시사한다.se that were all low

• Journal of The Geomorphological Association of Korea
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• v.26 no.2
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• pp.39-54
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• 2019

In this paper, based on evidence of coastal sediment, we show that erosion and sedimentation environments are very sensitive to sea level changes during the Medieval Warm Period (MWP) and the Little Ice Age (LIA). We identified four sedimentary units(4.57-3.07m), which formed in the Dark Age Cool Period (DACP), MWP and LIA were classified based on the lithostratigraphy, grain size distribution, magnetic susceptibility and geochemistry of a drilling core taken from the west coast of Hwaseong City. The unconformity surfaces as boundaries of the units were also identified by the lithostratigraphy shown on the drilling core. We propoese that sedimentation was dominant in the area during the periods of sea level rise, whereas erosion prevailed during the periods of sea level fall. Particularly, extreme events, such as floods and typhoons are believed to have accelerated these processes, and we found the associated evidence in sediments of two units. This study provides an example of estimating the relative sea level variation using coastal sediments and may be useful for studying past sea level changes around the Korean Peninsula.

• The Journal of Engineering Geology
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• v.32 no.4
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• pp.611-625
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• 2022

One of the applications of geomagnetic paleo-secular variation (PSV) is the age dating of archeological remains (i.e., the archeomagnetic dating technique). This application requires the local model of PSV that reflects non-dipole fields with regional differences. Until now, the tentative Korean paleosecular variation (t-KPSV) calculated based on JPSV (SW Japanese PSV) has been applied as a reference curve for individual archeomagnetic directions in Korea. However, it is less reliable due to regional differences in the non-dipole magnetic field. Here, we present PSV curves for AD 1 to 600, corresponding to the Korean Three Kingdoms (including the Proto Three Kingdoms) Period, using the results of archeomagnetic studies in the Korean Peninsula and published research data. Then we compare our PSV with the global geomagnetic prediction model and t-KPSV. A total of 49 reliable archeomagnetic directional data from 16 regions were compiled for our PSV. In detail, each data showed statistical consistency (N > 6, 𝛼₉₅ < 7.8°, and k > 57.8) and had radiocarbon or archeological ages in the range of AD 1 to 600 years with less than ±200 years error range. The compiled PSV for the initial six centuries (KPSV0.6k) showed declination and inclination in the range of 341.7° to 20.1° and 43.5° to 60.3°, respectively. Compared to the t-KPSV, our curve revealed different variation patterns both in declination and inclination. On the other hand, KPSV0.6k and global geomagnetic prediction models (ARCH3K.1, CALS3K.4, and SED3K.1) revealed consistent variation trends during the first six centennials. In particular, the ARCH3K.1 showed the best fitting with our KPSV0.6k. These results indicate that contribution of the non-dipole field to Korea and Japan is quite different, despite their geographical proximity. Moreover, the compilation of archeomagnetic data from the Korea territory is essential to build a reliable PSV curve for an age dating tool. Lastly, we double-check the reliability of our KPSV0.6k by showing a good fitting of newly acquired age-controlled archeomagnetic data on our curve.

• Journal of the Korean association of regional geographers
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• v.22 no.2
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• pp.439-449
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• 2016

Understanding the variability of the monsoon system requires information about the changes in the past. We revealed the Mid- and Late-Holocene paleo-climate changes and Asian monsoon variations in Korea by the speleothem records from Pyeongchang. To this, we used thicknesses of growth laminae, stable-isotope analysis (carbon, oxygen), and radio-carbon age dating. The speleothem grew between ~4580 yr BP to ~660 yr BP and we identified several weak AM(Asian monsoon) events, such as Middle Bronze Age Cold Epoch, Iron Age Cold Epoch, and Dark Age Cold Period. These events might have occurred relatively early compared to those of other studies.

• The Journal of the Petrological Society of Korea
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• v.25 no.4
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• pp.373-388
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• 2016

To understand human activity in the past, the information about past environmental change including geomorphological and climatic conditions is essential and this can be traced by using age dating and geochemical analysis of sediments from the prehistoric sites. The sedimentary sequence of Seokgwan-dong Paleolithic Site located in Seoul was 5m long unconsolidated sediments and consists of lower part bedrock weathering sediments, slope deposits and upper-part fluvial deposits. In this study, upper part sediments were used to reconstruct past environmental change through age dating and various physical and chemical analyses including grain size, magnetic susceptibility and mineral and elements. The fluvial sediments can be divided into 4 units including three organic layers. Grain size analysis results showed that the sediments were very poorly sorted with fining upward features. Magnetic susceptibility was relatively high in the organic layers, indicating environmental changes causing mineral composition change at that times. The mineral and major element composition are similar to Jurassic biotite granite which mainly consists of quartz, K-feldspar, biotite and muscovite. The radiocarbon age of $14,240{\pm}80yr$ BP was obtained from the lower most organic layer of Unit III(O), suggesting that the fluvial sediments formed at least from the early stage of deglacial period after the end of Last Glacial Maximum. Subsequent wet and warm climates and resultant fluvial process including slope sedimentation during the Holocene may have been responsible for the sedimentary sequence in Seokgwan-dong paleolithic site and surrounding area. The observed organic layers suggests frequent wetland occurrence combined with natural levee changes in this area.

• Journal of Ecology and Environment
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• v.29 no.3
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• pp.287-293
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• 2006

We carried out pollen analysis and radiocarbon dating from sediments of Wangdeungjae moor (960 m a.s.l.) to clarify vegetation history of temperate broad-leaved deciduous forest zone of Mt. Jiri. Three local pollen zones and two sub-zones were recognized on the basis of variation in the palynofloral assemblage: I. Quercus zone (150-114 cm), II. Quercus-Pinus zone (114-43 cm): IIa. Quercus-Pinus subzone (114-83 cm), IIb. Quercus-Pinus-Herbs subzone (83-43 cm), III. Pinus-Quercus zone (43-27 cm). Radiocarbon date from sediment depth 111-116 cm was estimated $1,160{\pm}40yr$ B.P. From these results, overall vegetation around of Wangdeungjae moor and Mt. Jiri have changed from Q. mongolica dominant to steady decrease of Q. mongolica whereas steady increase of P. densiflora, finally abrupt increase of P. densiflora. 'Medieval Warm Period (MWP)' and 'Little Ice Age (LIA)' have not had an effect on change of vegetation around, at least, Mt. Jiri. But at maximum period of LIA, extension of grassland and steady increase of Pinus were recognized around the moor. After then, an abrupt increase of Pinus is supposed that vegetation change is reflected in human impact surging around foothills.

• Korean Journal of Heritage: History & Science
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• v.57 no.3
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• pp.56-67
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• 2024

This study aims to characterize the material of the finishing materials used in the No.1 stone chamber tomb of the Baekje-era tumuli in Songjeri, Naju with mineralogical, chemical, and physical analyses. The finishing material is a mixture of white lumps and fragments, presumed to be shells, that remain on the surface and between the gaps of the stone walls inside the tomb. The analysis results revealed that the main constituent mineral of the finishing material is calcite. Infrared spectroscopy showed peaks due to calcium carbonate, and thermal reaction decarbonation in the 700~800℃ range, high calcium content, and loss on ignition were confirmed. Therefore, the main material of the finishing materials was determined to be lime, and since no aggregates such as sand or gravel were found, it was identified as lime paste. The shell fragments mixed into the lime paste appear dark blue or grayish-white in color, with no original shape remaining. The surface has a layered structure, and microscopic observations revealed prismatic layers with a columnar structure and nacreous layers with a consistent orientation, suggesting that the shells are from bivalve mollusks. Additionally, X-ray imaging of the shell fragments showed holes and tunnels caused by boring marine organisms both on the surface and inside, and radiocarbon dating results confirmed that the dating of the shells was consistent with the construction period of the tomb. It is concluded that the finishing material used in Tomb No. 1 in Songje-ri, Naju, was lime paste mixed with shell fragments, and the lime was made using the shells of bivalve mollusks as the raw material.