• Title/Summary/Keyword: 발포성 폴리스티렌

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Setting Behavior of Polystyrene Mortars with Elapsed Curing Time (폴리스티렌 모르타르의 양생재령에 따른 경화거동)

  • Choi Nak-Woon;Kim Han-Sang
    • Journal of the Korea Concrete Institute
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    • v.16 no.1 s.79
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    • pp.54-60
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    • 2004
  • This study deals with the setting behavior of polystyrene mortars using waste expanded polystyrene(EPS) solution-based binders. The binders for polystyrene mortars are made by mixing crosslinking agent with EPS solutions prepared by dissolving EPS in styrene. Polystyrene mortars are prepared with various EPS concentrations of EPS solutions and crosslinking agent contents, subjected to a dry curing, and tested for working life, peak exotherm temperature and 10h-length change. From the test results, He working lives of polystyrene mortars are shortened with raising EPS concentration of EPS solution and crosslinking agent content. Low-shrinkage or non-shrinkage polystyrene mortars could be obtained by adjusting EPS concentration of EPS solution and crosslinking agent content.

Design of Lightweight Fill Method on Soft Ground using Expanded Polystyrene (연약지반상 스치로폴 경량성토공법의 설계)

  • 유기송
    • Journal of the Korean Professional Engineers Association
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    • v.27 no.5
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    • pp.39-45
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    • 1994
  • 스치로폴은 발포폴리스티렌(EPS : Expanded Poly-Styrene)을 말하며, 이것은 스티렌모노머(Stone Monomer)를 중합하여 만든 플리스티렌과 여기에 첨가한 발포제가 주원료로 되어 있다. 폴리스티렌은 1930년대에 미국과 독일에서 공업화되었고 스치로폴은 1943년 초에 미국에서 공업화가 이루어져 건물의 단열재, 물품포장재 등으로 이용되어 왔다. 1972년에는 노르웨이에서 연약지반상 교량의 접속도로 보수공사에 처음 스치로폴 성토공법이 이용되어 교대의 측방유동 방지대책으로 성공을 거둠에 따라 연약지반상의 경량성 토재 및 토압을 받는 옹벽, 교대 등 구조물의 경량 뒷채움재로서 각광을 받게 되었다. 한편 우리나라에서는 1994. 6월에 한국지반 공학회 주최로 개최된 "발포폴리스티렌(EPS) 이용 성토공법 국제심포지엄"에서 양산-구포간 고속도로성토(L=70m) 및 서해안고속도로의 교대 뒷채움에 스치로폴 경량성토재가 이용된 문헌이 발표된 바 있으며, 시중에서 단열재용으로 판매되고 있는 스티로폴 평판의 규격은 표 1과 같다. 스치로폴은 그 가격이 비싼 편이지만 단위중량(20-40kgf/m$^3$)이 흑의 50/1-100/1 밖에 안되는 초경량재로서 강도, 내구성 및 시공성이 우수한 성토용 신재료이기 때문에 연약지반상에서 구조물 시공시 지반의 과대한 침하, 측방유동 및 사면활동 등이 생길 경우 도로성 토재 또는 교대, 옹벽 등 구조물의 뒷채움재로서 스치로폴을 사용하면 이를 방지할 수 있으므로 매우 효과적인 토목자재라 할 수 있다. 따라서 본고에서는 지금까지의 연구결과, 시험시공 및 시공실적 등을 토대로 발표된 참고문헌을 중심으로 연약지반상 스치로폴 성토공법의 설계방법에 대하여 간단히 소개하고자 한다. 소개하고자 한다.

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Preparation, Morphology and Electrical Conductivity of Polystyrene/Polydopamine- Carbon Nanotube Microcellular Foams via High Internal Phase Emulsion Polymerization (고내상 에멀젼 중합에 의한 폴리스티렌/폴리도파민-탄소나노튜브 미세기공 발포체의 제조, 모폴로지 및 전기 전도도)

  • Kim, Haseung;Na, Hyo Yeol;Lee, Jong Heon;Lee, Seong Jae
    • Polymer(Korea)
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    • v.39 no.2
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    • pp.293-299
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    • 2015
  • Conductive microcellular foams consisted of polystrene (PS) and polydopamine-coated carbon nanotube (PDA-CNT) were prepared via high internal phase emulsion (HIPE) polymerization and their morphology and electrical conductivity were investigated. CNT as a conductive nanofiller was modified to PDA-CNT by coating with hydrophilic PDA on the surface of CNT to increase aqueous phase dispersion and emulsion stability. It was possible to prepare the HIPEs having higher PDA-CNT content and the resultant foams having improved conductivity due to its good dispersion. The foams showed the morphology of interconnected cell structure. As PDA-CNT content increased, yield stress and storage modulus increased and cell size reduced. The PDA-CNT content showing electrical percolation threshold was ca. 0.58 wt% and the conductivity at PDA-CNT content of 5 wt% was increased to $10^{-3}S/m$.

Morphology and Electrical Conductivity of Polystyrene/Carbon Nanotube Microcellular Foams Polymerized by High Internal Phase Emulsions (고내상 에멀젼 중합법으로 제조한 폴리스티렌/탄소나노튜브 미세기공 발포체의 모폴로지 및 전기 전도도)

  • Noh, Won-Jin;Kang, Myung-Hwan;Lee, Seong-Jae
    • Polymer(Korea)
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    • v.36 no.5
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    • pp.579-585
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    • 2012
  • Polystyrene/carbon nanotube (CNT) microcellular foams were prepared to have electrically conductive properties via high internal phase emulsion polymerization. In this study, we have investigated the effects of surface modification of CNT, surfactant content and dispersion time to improve the stability of emulsion and the electrical conductivity of foam. Acid treatment and a surfactant were used to effectively disperse CNTs in the aqueous phase. In the organic phase, CNTs were used after a surface modification with organic functional groups. The degree of dispersion of CNTs was estimated by the electrical conductivity of resultant microcellular foams. With raw CNTs dispersed with the surfactant in the aqueous phase, substantial conductivity increase was observed but the foams were slightly shrunk. The foams prepared with organically modified CNTs dispersed in the organic phase showed stable cell morphology without shrinkage, but displayed limitation to improve the conductivity.

Migration of Low Molecular Weight Substances from Expanded Polystyrene Cup to Aqueous Food Simulant (발포 폴리스티렌 용기로부터 증류수로의 저분자물질 이행)

  • 이동선;송봉수;최진옥;박우포
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.6
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    • pp.1056-1062
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    • 2004
  • Migration of low molecular weight components from expanded polystyrene (ESP) to distilled water was measured at different temperature conditions. Overall migration and specific monomer migration were measured. Diffusion model based on Fick's law was used to determine the apparent diffusion coefficients at various experimental conditions. The overall and specific migration levels were estimated to give some practical implications for regulatory guideline development and safe package design. Diffusion coefficients for overall migration in KMnO$_4$ oxidizable extractives and specific migration of styrene monomer from ESP at 6$0^{\circ}C$ were 0.030 and 6.8${\times}$10$^{-5}$ $\textrm{mm}^2$/h, respectively. Their temperature dependence could be explained by Arrhenius equation with respective activation energies of 80.5 and 98.6 kJ/㏖. Experimental conditions ensuring desired migration level were suggested for reliable examination of migration from the packaging material. Some explanatory estimations of migrations were given for some typical conditions of potential usages.

Ignition of ceiling insulation depending on working condition of Sprinkler head in underground parking lot fire (지하주차장 화재 시 스프링클러헤드 작동 여부에 따른 천장 위 단열재의 발화 여부)

  • Kim, Seo-Young;Kong, Ha-Sung
    • The Journal of the Convergence on Culture Technology
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    • v.8 no.1
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    • pp.461-468
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    • 2022
  • This study is focused on the ignition of ceiling insulation depending on working condition of Sprinkler head in underground parking lot fire. When temperature changes of same point were measured depending on sprinkler's working condition, in Scenario 1, inner temperature at border of spray applied material(SP-2) of ceiling part near the fire and ceiling insulation(blowing polystyrene) was 658.27℃ and its which inner maximum temperature is higher than 427℃ which is the ignition point of ceiling insulation(blowing polistyrene), so it was observed that flame is ignited on the ceiling insulation and spread fire. In scenario 2, Inner fire temperature at border of spray applied material(SP-2) and ceiling insulation(blowing polystyrene) near the fire was 53.10℃ and it was lower than ignition point so it was observed that flame was not ignated on the ceiling insulation. As a result, it was foreseen that possibility of ignition on the ceiling insulation depending on working condition of sprinkler.

수산물표준규격 고시-상품성 향상, 유통효율 제고, 공정한 거래 실현 위해

  • Korea Foam-Styrene Recycling Association
    • 환경사랑
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    • s.48
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    • pp.7-7
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    • 2007
  • 국립수산물품질검사원은 수산물의 상품성 향상과 유통효율 제고 및 공정한 거래 실현을 위한 수산물표준규격을 지난 1월 22일 고시한 바 있다. 고시는 어종의 표준거래단위, 수산물의 포장치수, 포장재료 및 포장재료의 시험방법 등을 규정하고 있다. 고시에 따르면 포장재료는 식품위생법에 따른 용기.포장의 제조방법에 관한 기준과 그 원재료에 관한 규격에 적합하여야 한다. 고시 된 표준포장규격과 포장재료 중 P.S.대(폴리스티렌대)의 규격은 아래와 같다

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