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Oil Gelling Agents made from Polyurethane by One-Shot Method (One-Shot법을 이용한 폴리우레탄계 유겔화제의 특성)

  • Kim, Dongsung;Kim, Wonho
    • Journal of Adhesion and Interface
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    • v.3 no.2
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    • pp.1-8
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    • 2002
  • Polyurethane NCO prepolymers were synthesized with the polyols such as PTMG, GP and the isocyanate such as TDI at $40^{\circ}C$ for 8.5 minutes. As average molecular weights (${\bar{M_n}}$: 1000, 2000, 3000, 4000) of PTMG, and GP were decreased from 4000 to 1000, ratio of oil gelation increased from 298%, to 440%, for Bunker B. When oil and water were emulsified, the ratio of gelation was increased approximately two times. Ratio of gelation for emulsive Bunker B was increased from 402% to 910%, for PTMG1000 and increased from 440%, W 958% for GPI1000. Ratio of oil gelation for emulsive Bunk C which has higher viscosity than Bunker B was measured w 923% for PTMG1000 made with chain extender, i.e. EG, and measured to 1098% for GP1000. The gel made from GP which has three functional group showed soft and strong characteristic, as a result, it can be removed easily from oil spilled ocean.

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Resonance Characteristics of a Metallic Enclosure Having Sub-Cavity with Lossy Dielectric Materials (부공동에 손실 유전체를 충진한 함체 케이스의 공진 특성)

  • Lim, Sung-Min;Jung, Sung-Woo;Kim, Ki-Chai
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.9
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    • pp.936-942
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    • 2009
  • This paper presents the delivered power and reflection coefficient in metallic shielding enclosure with a sub-cavity, which are evaluated with the method of moments, sad describes a method for controlling the resonance characteristics of the metallic cavity by putting lossy dielectric material in the sub-cavity. In this paper we introduce carbon polystyrene-foam as lossy dielectric material and observe it's effects of reduction when the dimensions of the sub-cavity and permittivity of lossy dielectric material are changed. The results show that the reduction of the electromagnetic radiation can be achieved by controlling the amount of carbon in lossy dielectric material and the dimensions of the sub-cavity. The theoretical analysis is verified by the measured delivered power.

Fabrication and Evaluations of Hydrogenation Properties of TiH2/TiH2-Al agents on Aluminum Foam Alloy (알루미늄 발포용 TiH2/TiH2-Al의 제조와 수소화 특성 평가)

  • Hong, T.-W.;Cho, G.-W.;Kweon, S.-Y.;Kim, I.-H.;Lee, J.-I.;Ur, S.-C.;Lee, Y.-G.;Ryu, S.-L.
    • Journal of Hydrogen and New Energy
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    • v.15 no.3
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    • pp.235-243
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    • 2004
  • A number of potential applications of aluminum foams are being identified and renewed interest in these engineering materials is also reflected by several current research projects. One of the key issues for industrial exploitation of aluminum foams is the development of cost-effective manufacturing strategies facilitating, preferably, net shape production of foams with controlled porosity and cell size, and minimized structural imperfection. Especially, melt route to aluminum foam production based on the foaming agents offer attraction of low cost and the potential for good microstructure. The present paper is focused mainly on foaming agents of melt-foam aluminum such as $TiH_2$ or $TiH_2-Al$ mixture. For the purpose of economical manufacturing, we are proposed to hydrogen induced mechanical alloying (HIMA) process. Thermo-physical properties of particles synthesized are compared with conventional methods. Specimens synthesized are characterized by scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS), thermo- gravimetry-differential scanning calorymetry (TG-DSC), pressure-composition-isotherm. (PCI).

Fabrication of BCP/Silica Scaffolds with Dual-Pore by Combining Fused Deposition Modeling and the Particle Leaching Method (압출 적층 조형법과 입자 추출법을 결합한 이중 공극 BCP/Silica 인공지지체의 제작)

  • Sa, Min-Woo;Kim, Jong Young
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.10
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    • pp.865-871
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    • 2016
  • In recent years, traditional scaffold fabrication techniques such as gas foaming, salt leaching, sponge replica, and freeze casting in tissue engineering have significantly limited sufficient mechanical property and cell interaction effect due to only random pores. Fused deposition modeling is the most apposite technology for fabricating the 3D scaffolds using the polymeric materials in tissue engineering application. In this study, 3D slurry mould was fabricated with a blended biphasic calcium phosphate (BCP)/Silica/Alginic acid sodium salt slurry in PCL mould and heated for two hours at $100^{\circ}C$ to harden the blended slurry. 3D dual-pore BCP/Silica scaffold, composed of macro pores interconnected with micro pores, was successfully fabricated by sintering at furnace of $1100^{\circ}C$. Surface morphology and 3D shape of dual-pore BCP/Silica scaffold from scanning electron microscopy were observed. Also, the mechanical properties of 3D BCP/Silica scaffold, according to blending ratio of alginic acid sodium salt, were evaluated through compression test.

The Effect of Additives on Sound Absorption Coefficient of Polyurethane Foam (폴리우레탄폼의 흡음율에 대한 첨가제의 영향)

  • Park, Nam-Cook;Kim, Young-Chul;Park, Chong-Rai
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.197-203
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    • 1997
  • The effect of additives on the mechanical properties of polyurethane foam were investigated. The resin used in this study was prepared by adding catalyst, surfactant and cross-linker to both KONIX FA-703 polyether polyol(80%) and KONIX FA-733 polyether polyol(20%). The polyurethane was foamed by adding equivalent amount of isocyanate(TDI-80, prepolymer M-200, pure MDI) to the resin and was used in property measurements after 72 hours hardening. The physical properties of polyurethane foam were investigated in terms of density, tensile strength, tear strength, elongation, sound absorption coefficient and gel profile measurements. The effects of surfactant on the cell size was investigated by scanning electron microscopy(SEM). The sound absorption coefficient was directly related to the cell size. The physical properties were improved with increasing amount of surfactant(L-5309) until 1.0 part per hundred polyol(1.0pphp).

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Development of the Novel Cosmetics Impregnation Material and Study on Makeup W/O Emulsions using It (새로운 화장료 함침재의 개발과 이를 활용한 메이크업 유중수형 에멀전에 관한 연구)

  • Kang, Sungsoo;Kim, Hyeon Jeong;Oh, Se Woong;Park, Sang Wook;Kim, Kyung Seob
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.43 no.1
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    • pp.27-33
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    • 2017
  • Up to now, better convenience and portability were important factors in the development of the cosmetics and achieved by immersing low viscosity makeup water-in-oil (W/O) emulsion into the impregnation material. Conventionally, polyurethane sponges having porous network structures and hard textures have been dominantly used. It has an advantage of easy to manufacture because of its good impregnation property due to its structural characteristics. However, it releases emulsion too much at first use, and shows unexpected dramatic decline during the period of usage. In this study, we studied on makeup W/O emulsion with various features and developed the new foaming sponge, which showed excellent formability and proper absorption and discharge ability of cosmetic composition through the combination of natural rubber (NR) and styrene butadiene rubber (SBR). This impregnation material is characterized by the softness of elasticity like a rubber, high elongation and uniform output. We confirmed that this material can be used to develop makeup products using various oils depending on polarity and controlling the viscosity of the makeup W/O emulsion. Thus, it is concluded that these results provide valuable information in developing new cosmetics impregnation materials.

A Study on Clean Agents for Halon Replacement in the Portable Extinguisher with CO2 as an Expellant Gas (이산화탄소를 가압원으로 하는 할론대체 소화기용 청정소화약제에 대한 연구)

  • Jeong, Keesin
    • Fire Science and Engineering
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    • v.33 no.3
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    • pp.51-55
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    • 2019
  • To prevent ozone depletion caused by CFCs, the replacement of Halon with clean agents has been developed in the fire protection field along with refrigerants, detergents, and foaming agents. The alternatives for Halon 1211 have been developed in the portable fire extinguisher area and HCFC-123 is used widely as a clean fire extinguishing agent. The type of expellant gas is important because their own vapor pressure is low. In this study, HCFC-123, HCFC-124, HFC-125, and Novec-1230 were selected as fire extinguishing agents and CO2, which is expected to improve the fire extinguishing ability, was chosen as the expellant gas. For each agent, experiments changing the agent and CO2 amount were carried out and HCFC-123 showed a good result, as expected. The extinguisher, HCFC-123 of 1.5 kg, showed the same ability to suppress a class A and B fire as the extinguisher, HCFC-123 of 2.5 kg, which is currently sold on the market. According to this result, the expellant gas has a subsidiary fire extinguish effect. This can reduce the amount of HCFC fire extinguishing agent, which is categorized in the phase-out alternatives, and is a more eco-friendly and economical fire extinguisher than the previous one. This study can also help solve the problems of CO2 fire extinguishers for class B and C fires, and can be used to extinguish electric and electron facilities fire, which contains large amounts of class A fire combustibles.

Effect of Hairy Vetch Green Manure on Corn Growth and Yield Cropping System of Corn-Oats/Hairy Vetch (옥수수-연맥 헤어리벳치 작부체계에서 옥수수에 대한 헤어리벳치 녹비효과)

  • 서종호;이호진;허일봉
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.46 no.3
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    • pp.189-194
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    • 2001
  • It is possible to use hairy vetch as green manure for corn not only in corn single cropping but also in double cropping system of corn and fall oats. Fall oats and hairy vetch were mixed-sown after corn harvest and harvested as forage in the early of November, and then hairy vetch stubble was over-wintered and incorporated into soil at corn planting as green manure without N fertilizer (FO+HV-GM). Other treatments were fall oats without N fertilizer on corn (FO-0N) and with N fertilizer 200kg/ha on corn (FO-200N), hairy vetch green manure without N fertilizer on corn (HV-GM), and fell winter follow without N fertilizer on corn (WF-0N). Soil nitrate content, corn growth and nitrogen uptakes, and yield of corn were measured and compared during 2-year experimental seasons. Dry matter and N amount of hairy vetch at the plot of FO+HV-GM were 60% less than those at the plot of HV-GM. The N effect of hairy vetch green manure on corn at the plot of HV-GM was similar to that at FO-200N plot for two years. Soil nitrate at the plot of FO+HV-GM was below the half of those at plots of HV-GM and FO-200N at 6-leaf stage of corn. N uptake of corn at the plot of FO+HV-GM at silking stage was 30% less than those at plot of HV-GM and FO-200N. However, soil nitrate at 6-leaf stage of corn and the amount of nitrogen uptake of corn at silking stage increased two times and 30-40 kg/ha, respectively, compared with those at the plot of FO-0N. Corn yield at FO+HV-GM decreased about 2 ton/ha due to the decrease of corn grain weight in the first year compared with plot of HV-GM and FO-200N, but its difference was not shown in succeeding second year. Corn N uptake at FO+HV-GM decreased 60 kg/ha and 20 kg/ha in 1999 and 2000, compared with plot of HV-GM and FO-200N, respectively, but increased 30kg/ha and 45kg/ha compared with the plot of FO-0N in 1999, 2000, respectively. Therefore, it is estimated that hairy vetch green manure in fall oats-corn double cropping system can reduce nitrogen chemical fertilizer on corn as much as 50-100 kg/ha although its N effect is much lower than the N effect of hairy vetch green manure in corn single cropping of which N effect is over 200 kg/ha.

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Evaluation of Filtration and Backwash Efficiency of Non-point Source Pollution Reduction Facility (장치형 비점오염원 저감시설의 여과 및 역세 효율 평가)

  • Yun, Sangleen;Lee, Yong-Jae;Ahn, Jae-Hwan;Choi, Won-Suk;Lee, Jungwoo;Oh, Hye-Cheol;Kim, Seog-Ku
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.12
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    • pp.664-671
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    • 2017
  • Non-point source pollution is the emission source that unspecifically releases pollutants to water system from unspecific places such as cities, agricultural lands, mountains, and construction sites and its discharge path is not easily identified. Also, it is difficult to design and manage the reduction facilities for the emission quantity is primarily affected from weather conditions like rainfall. Since 2006, the significance of non-point source pollution reduction has been grown in Republic of Korea and this reinforces needs for the installation of reduction facilities. However, because the standards for the installation details and reduction efficiency are not clarified by law, people are preferring technologies that do not require particular maintenance and high expenses. The purpose of this study is to examine and maintain the efficiency of non-point source pollutants reduction facility which uses expended polypropylene as a media. The higher the depth of the media, the less range of variations in the reduction efficiency was observed and the final efficiency was also increased. When the media depth was 60 cm, the average reduction efficiency was 94% and 90% where linear velocities were 10 m/hr and 20 m/hr respectively. The results from 180 minutes operation in 10 m/hr and 20 m/hr of linear velocities were slightly different in head loss changes which were caused by media depth variations. The backwash experiments which were conducted in triplicate showed the reduction efficiency decreased as the time went on because of the media clogging. However, it was found that after the backwashing the reduction efficiency was increased as effective as the efficiency of the initial filtration.

Manufacturing of geopolymers for replacing autoclaved lightweight concrete panels (ALC 패널 대체용 지오폴리머의 제조)

  • Kim, Minjeong;Kim, Yootaek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.1
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    • pp.33-39
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    • 2020
  • Lightweight geopolymers were fabricated by using fused slag from integrated gasification combined cycle as a law material and Si sludge from silicon wafer process as a bloating material for the purpose of replacing autoclaved lightweight concrete (ALC). Density and compressive strength of geopolymers were measured and compared with the properties of ALC according to the variation of mol concentration of alkaline activator, W/S ratio, addition of fibers, and addition of polystyrene and the possibility of replacing ALC panel was estimated through the comparisons. Although the geopolymer satisfying the standard of ALC panel was not made by controlling mol concentration and W/S ratio, addition of inserts such as fibers and polystyrene insert was tried to overcome the obstacle of enhancing properties. Geopolymers cannot satisfying the standard of ALC panel by adding carbon or glass fibers; however, adding fibers can be suggested as one of the methods enhancing compressive strength because the compressive strength of the specimen containing 0.3 wt.% glass fibers was increased by 3 times. The maximum addition of polystyrene insert was turned out to be 50 vol.% and the properties of geopolymers varied by the method of insertion. When using single polystyrene insert, compressive strength was 17.8 MPa and density was 0.996 g/㎤ which were similar values to the standard of ALC panel. If the difficulties of reproductivity of production and insertion method of inserts were overcome through the future research, the geopolymers containing polystyrene inserts could possibly replace ALC panel.