• Composites Research
• /
• v.35 no.2
• /
• pp.93-97
• /
• 2022

The application of infrared heating in the hot press forming of the thermoplastic composites is conducive to productivity with high-speed heating. However, high energy, high forming temperature, and high-speed heating derived from infrared heating can cause material degradation and deteriorate properties such as re-melting performance. Therefore, this study was conducted to optimize the process conditions of the hot press forming suitable for carbon fiber reinforced polyetherketoneketone(CF/PEKK) composites that are actively researched and developed as high-performance aviation materials. Specifically, the degradation mechanisms and properties that may occur in infrared high-speed heating were evaluated through morphological and thermal characteristics analysis and mechanical performance tests. The degradation mechanism was analyzed through morphological investigation of the crystal structure of PEKK. As a result, the size of the spherulite decreased as the degradation progressed, and finally, the spherulite disappeared. In thermal characteristics, the melting temperature, crystallization temperature and heat of crystallization tend to decrease as degradation progresses, and the crystal structure disappeared under long-term exposure at 460℃. In addition, the low bonding strength was observed on the degraded surface, and the bonding surfaces of PEKK did not melt intermittently. In conclusion, it was confirmed that the CF/PEKK composite material degraded at 420℃ in the infrared high-speed heating. Furthermore, the spherulite experienced morphological changes and the re-melting properties of thermoplastic materials were degraded.

• Resources Recycling
• /
• v.31 no.1
• /
• pp.29-36
• /
• 2022

The hydrogen reduction behavior of molybdenum oxides was studied using a horizontal-tube reactor. Reduction was carried out in two stages: MoO₃ → MoO₂ and MoO₂ → Mo. In the first stage, a mixed gas composed of 30 vol% H₂ and 70 vol% Ar was selected for the MoO₃ reduction because of its highly exothermic reaction. The temperature ranged from 550 to 600 ℃, and the residence time ranged from 30 to 150 min. In the second step, pure H₂ gas was used for the MoO₂ reduction, and the temperature and residence time ranges were 700-750 ℃ and 30-150 min, respectively. The hydrogen reduction behavior of molybdenum oxides was found to be somewhat different between the two stages. For the first stage, a temperature dependence of the reaction rate was observed, and the best curve fittings were obtained with a surface reaction control mechanism, despite the presence of intermediate oxides under the conditions of this study. Based on this mechanism, the activation energy and pre-exponential were calculated as 85.0 kJ/mol and 9.18 × 10⁷, respectively. In addition, the pore size within a particle increases with the temperature and residence time. In the second stage, a temperature dependence of the reaction rate was also observed; however, the surface reaction control mechanism fit only the early part, which can be ascribed to the degradation of the oxide crystals by a volume change as the MoO₂ → Mo phase transformation proceeded in the later part.

• Fire Science and Engineering
• /
• v.24 no.5
• /
• pp.136-141
• /
• 2010

The purpose of this study is to examine the structure and heat generation mechanism of low voltage switches used to turn on or off the power supply to an indoor lighting system and investigate how the fixtures and movable contacts of the switches are damaged depending on the types of energy sources in order to secure the judgment base for expected PL disputes. Based on the Korean Standard (KS) testing method for incombustibility, this study applied a general flame to the switch. In addition, current was supplied to the switch using the PCITS (Primary Current Injection Test System). The ambient temperature and humidity were maintained at $22{\pm}2^{\circ}C$ and 40~60% respectively while performing the test. It is thought that the switch generated heat due to a defective connection of the wire and clip, insulation deterioration and defective contact of the movable contact, etc. The surface of the switch damaged by the general flame was uniformly carbonized. When the flame source was removed, the fire on the switch was extinguished naturally. From the result obtained by disassembling the switch carbonized by the general flame, it could be seen that fixtures and movable contacts remained in comparatively good shape but the enclosure, clip support, movable contact, indicating lamp, etc. showed carbonization and discoloration. In the case of the switch damaged by overcurrent, the clip connecting the wires, clip support, etc. showed almost no trace of damage, but the fixtures, movable contact, indicating lamp, etc. were severely carbonized. That is, the sections with high contact resistance were intensively damaged and showed a damage pattern indicating that carbonization progressed from the inside to the outside. Therefore, it is possible to judge the initial energy source by analyzing the characteristics of the carbonization pattern and the metal fixtures of damaged switches.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.20 no.7
• /
• pp.291-298
• /
• 2019

We describe the improvement of insulation performance and the prevention of electrolyte leakage in a single cell in order to prevent the fuming phenomenon caused by leakage of electrolyte in a lithium secondary battery in a submerged weapon (torpedo) operated in Korea. A torpedo using lithium secondary battery as a main power source (propulsion battery) can induce the heat and fuming phenomenon, which makes it inconvenient for naval equipment operation in Korea. In the simulation test, the electrolyte of some battery cells leaked in the battery pack unit, leading to a short circuit between the main power circuit and the terminal tab of the high voltage part. We analyzed the characteristics and mechanism of the lithium secondary battery during this heat generation and fuming phenomenon. In order to prevent leakage of the electrolyte in the lithium secondary battery, the design was improved via fundamental (terminal tap enhancement) and complementary (insulation block selection and installation) measures. Comparison of the performance test before and after the improvement showed that the tensile strength of the tap terminal was improved about 2 times and the withstand voltage characteristic was improved. The application of quality improvement measures resulted in no fuming even after more than 3 years of field operation. This result is expected to improve the operation and storage stability of the torpedo propulsion cell.

• Fire Science and Engineering
• /
• v.27 no.2
• /
• pp.40-45
• /
• 2013

In recent years, many electrical fires have occurred due to complex causes. Therefore, products are required to make with scientific design considering electrical, thermal, mechanical and environmental influences. Disasters can cause losses of life and property with fall in confidence of countries and companies. And demands for safe product have been increased by reason of recent deregulation followed by limitless competition. It is necessary to design safe product in order to improve corporate image and strengthen international competitive power. This paper addresses electrical fire case of air conditioner. The use of air conditioner have recently increased as a result of global warming. The aim of this study is to provide safety design and fire prevention measures of air conditioner through cause analysis and reappearance experiments.

• Journal of Advanced Marine Engineering and Technology
• /
• v.36 no.8
• /
• pp.1097-1103
• /
• 2012

There are many fish farms being cultivated in the southwestern cost of South Korea. Because the farms cultivating use the basic method that inflow and circulate sea-water, slight negligence and bad design cause major negative impact on fish deaths. Also, the optimal temperature for each specie of fishes has already been proven to differ on each specie. Maintaining this environment, regardless of seasons, is very difficult and that requires research to develop. In this paper, basic characteristics of heat and mechanism of heat transfer are studied. Based on this, Open-end water vessel is designed and constructed using sandwich-insulation panels and simulated to store the heat in certain isolated space. This study confirmed that it is possible to keep constant temperature by this method, in large areas of water where it is insulated by heat insulator. and equipped with heater in Open-end water vessel where the other part is heated. The AC power controller maintains the constant temperature required and the temperature controller detects and displays the temperature by using the micro-processor.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2008.11a
• /
• pp.557-560
• /
• 2008

This was done by analyzing the sandwich panels that are now widely used in construction work. Sandwich panels are used for diverse purposes in construction work worldwide. In Korea, polystyrene panels that have organic materials as their core material are used. These panels are thus very vulnerable to fire, with risks of core melting, sheet deformation, and hazardous gases. Accordingly, sandwich panels' fire-resistant or non-flammable properties must be secured. To solve these problems, the optimal mixing proportion of lightweight foamed concrete for the sandwich panel core was determined. A new method of doing this was introduced that is completely different from the existing method, wherein a foaming agent is added to realize lightweight concrete. For lightweight concrete, the foaming mechanisms via diverse chemical reactions were identified, H$_2$O$_2$ was added for heating in the reaction, and the concrete foaming was maximized. Through diverse experiments to determine the optimal mixing proportion of lightweight foamed concrete and to examine the filling characteristic of lightweight foamed concrete for sandwich panel cores using waste materials, the physical and mechanical properties of lightweight foamed concrete were examined.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.30 no.10
• /
• pp.631-636
• /
• 2017

The degradation mechanism of $Mo_xW_{1-x}Si_2$ ultrahigh-temperature heating elements fabricated by self-propagating high-temperature synthesiswas investigated. The $Mo_xW_{1-x}Si_2$ specimens (with and without post-annealing) were subjected to ADTs (accelerated degradation tests) at temperatures up to $1,700^{\circ}C$ at heating rates of 3, 4, 5, 7, and $14^{\circ}C/min$. The surface loads of all the specimen heaters were increased with the increase in the target temperature. For the $Mo_xW_{1-x}Si_2$ specimens without annealing, many pores and secondary-phase particles were observed in the microstructure; the surface load increased to $23.9W/cm^2$ at $1,700^{\circ}C$, while the bending strength drastically reduced to 242 MPa. In contrast, the $Mo_xW_{1-x}Si_2$ specimens after post-annealing retained $single-Mo_xW_{1-x}Si_2$ phases and showed superior durability after the ADT. Consequently, it is thought that the formation of microcracks and coarse secondary phases during the ADT are the main causes for the degraded performance of the $Mo_xW_{1-x}Si_2$ heating elements without post-annealing.

• Applied Chemistry for Engineering
• /
• v.34 no.3
• /
• pp.279-284
• /
• 2023

Isothermal titration calorimetry (ITC) is a useful technique to obtain thermodynamic binding properties such as enthalpy, Gibbs free energy, entropy, and stoichiometry of the chelation reaction. A single independent binding site model was used to evaluate the thermodynamic binding properties in BaCl₂ and ethylenediaminetetraacetic acid (EDTA) in Trince and HEPES buffers. ITC enables us to elucidate the binding mechanism and find an optimal chelation condition for BaCl₂ and EDTA in the pH range of 7~11. Chelation of BaCl₂ and EDTA is a spontaneous endothermic reaction. As pH increased, entropic contributions dominated. The optimal pH range is narrow around pH 9.0, where 1:1 binding between BaCl₂ and EDTA occurs.

• Journal of the Korean Institute of Gas
• /
• v.28 no.1
• /
• pp.59-64
• /
• 2024

In this study, we conducted research on a miniaturized transmission system suitable for ultra-compact electric vehicles, such as electric arts or small electric cars. While conventional electric vehicles eliminate multi-gear transmissions and control motor output or secure initial driving force through reducers, in vehicles like electric karts or compact electric cars, which have relatively small battery capacities, the driving range can be reduced or the motor can be stressed epending on the loading state. Therefore, in this study, we developed a low stage ratio 0.625 and high stage ratio 1.6 a two-stage transmission system that can change gears as needed, considering factors such as slope conditions and loading status, by applying the continuously variable transmission (CVT) mechanism. Based on the selected gear ratios, we designed the transmission and created a test rig to verify the power transmission efficiency of the developed transmission. Using the test rig, we varied the rotational speed and load of the transmission to confirm its power transmission characteristics and also examined the heat generation characteristics during shifting and operation. As a result, developed a two-stage transmission with a CVT structure.