• Title/Summary/Keyword: 발생액

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Determination of brightener concentrations in Watt-type Ni Electroplating bath using dilution titration-cyclic voltammetry stripping (DT-CVS) (희석 적정-순환전류전압법을 이용한 와트욕 내부 광택제 농도 모니터링)

  • Choe, Seung-Hoe;Gwon, Yeong-Hwan;Lee, Ju-Yeol;Kim, Man;Park, Yeong-Bae;Lee, Gyu-Hwan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.30-30
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    • 2018
  • 스마트 도금공장을 구축하기 위해서는 도금액 내부의 화학 물질 농도 변화를 측정할 수 있는 화학 센서 기술이 필수적으로 요구된다. 와트욕은 대표적인 고속 니켈 도금액 중 하나로 기본적으로 황산니켈, 염화니켈, 보릭산의 염과 함께 케리어(type-1 광택제), 광택제(type 2-광택제), 응력 제어제 등의 유기 첨가제로 구성되어 있다. 이러한 유기 첨가제는 전차된 니켈층의 두께 균일도, 조도, 미세 구조, 내부 응력 등 다양한 특성을 제어하며, 정밀한 농도 관리가 필수적으로 요구되나, 분석 기술의 부재로 인하여 지금까지도 대부분의 액관리는 할셀법이나 작업자의 경험에 의존하고 있다. Cyclic voltammetry stripping(CVS) 방법은 전기화학 분석 과정에서 나타나는 첨가제의 가속, 감속 특성 등과 여기에 수반되는 stripping peak의 변화를 이용하여 개별 첨가제의 농도를 측정하는 방법이며, 지금까지 인쇄회로기판의 비아필 공정, 전해 동박 제조, 반도체 배선 등 구리도금 산업 전반에 걸쳐 첨가제 관리에 효과적으로 적용되고 있다. 그러나 수소 발생으로 인한 stripping 효율 문제로 인하여 니켈, 주석, 아연 등 표준 환원 전위가 높은 금속 도금액 내부 첨가제 농도 측정은 아직 어려운 상황이다. 본 연구에서는 이 문제를 극복하기 위해 염소를 과량 첨가한 구리 도금액을 CVS 분석의 base 용액으로 이용하여 니켈 도금액 내부 여러 광택제 (polyetylene glycol(PEG) 계열, thiourea 계열, 2-butyne-1,4-diol 등) 농도를 측정하는 법을 제시하였다. 제시된 방법은 CVS 분석 과정에서 구리-염소 사이의 상호 작용으로 인해 생성되는 3가지 stripping peak의 상대적인 크기 변화가 첨가제 농도에 따라 영향을 받는다는 사실에 기반하였다. 본 연구에서는 여기에 관한 원인에 대해 고찰하였으며, 제시된 방법을 통해 광택제 계열 첨가제 농도 측정을 선택적으로 할 수 있다는 것을 증명하였다.

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Biological Activity of Tumor Necrosis Factor-α Secreted from Smooth Muscle Cell Overexpressing FADD (FADD 과발현 평활근세포에서 분비하는 Turner Necrosis Factor-α의 작용)

  • Kim, Sun-Mi;Lee, Kyeong-Ah;Kim, Koan-Hoi
    • Journal of Life Science
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    • v.17 no.1 s.81
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    • pp.45-50
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    • 2007
  • This study investigated biological activity of tumor necrosis factor $(TNF)-\alpha$ secreted from smooth muscle cell (SMC) destined for death by expressing Fas associated death domain containing protein (FADD) (FADD-SMC) when the cells are grown without tetracycline in culture medium. In the absence of tetracycline the FADD-SMC secreted approximately 1000 pg/ml $TNF-\alpha$, whereas hardly detectable amount of the cytokine existed in the presence of tetracycline. The culture medium collected from the FADD-SMC grown in the absence of tetracycline increased phosphorylated form of p38 MAPK and up-regulated nuclear factor kappa B (NF-kB). The medium collected without tetracycline also caused death of L929 cells. Depletion of $TNF-\alpha$ with the soluble TNF receptor (sTNFR) inhibited the phosphorylation of p38 MAPK, the up-regulation of NF-kB activity and the death activity of the medium collected from FADD-SMC in the absence of tetracycline. These results indicate that $TNF-\alpha$ secreted from SMC undergoing death is biologically active and can affect cellular function.

Effect of Human Hydrosalpingeal Fluid on the Development of Mouse Embryo (난관수종액이 생쥐 배아발달에 미치는 영향)

  • Park, Joon-Cheol;Kim, Jeong-A;Kim, Dong-Ja;Bae, Jin-Gon;Kim, Jong-In;Rhee, Jeong-Ho
    • Clinical and Experimental Reproductive Medicine
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    • v.37 no.2
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    • pp.125-134
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    • 2010
  • Objective: The aim of this study was to measure the concentrations of cytokines contained in the hydrosalpingeal fluid and to evaluate the effect on the mouse embryo development with the different cytokine concentration. Methods: The hydrosalpingeal fluids (HSF) were collected during the surgery for hydrosalpinx which was confirmed by hysterosalphingogram. The cytokines in HSF including interleukin (IL)-$1{\alpha}$, IL-$1{\beta}$, IL-2, IL-4, IL-6, IL-8, IL-10, TNF-$\alpha$, Interferon-$\gamma$ (IFN-$\gamma$), vascular endothelial growth factor (VEGF), epidermal growth factor (EGF), monocyte chemotactic protein-1 (MCP-1) were measured by ELISA method. HSF were added up to culture media with 5%, 10%, and 30% concentrations. The blastulation rates were compared. Results: IL-$\alpha$, IL-$1{\beta}$, IL-2, IL-4, IL-6, IL-8, IL-10, TNF-$\alpha$, IFN-$\bamma$, VEGF, EGF, and MCP-1 were detected, but the concentrations were different from each sample. IL-6 and IL-10 were increased in HSF-1 group, and IFN-$\gamma$, MCP-1, VEGF were increased in HSF-2 compared with normal serum range. The Th1/Th2 ratio of HSF-2 (IFN-$\gamma$:IL10) was highly elevated to 61.64, compared with that of HSF-1 (3.69). The blastulation rate was significantly decreased in HSF-2 group (27.7%) compared those of the HSF-1 group (74%) and control group (76.7%). It showed the trend that the blastulation rate was decreased depending on the concentration HSF of culture media in HSF-2 group, but it was not statistically significant. Conclusion: The composition and concentration of cytokines in each HSF were different, and increased proinflammatory cytokines in HSF might be associated with poor embryonic development. Further study will be needed about the effect of each cytokines in HSF.

기업가치 평가모형과 세후 가중평균자본비용 추정모형에 관한 연구 - 법인세, 도산확률, 이익조정 하에서의 모형도출 -

  • Lee, Won-Heum
    • The Korean Journal of Financial Studies
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    • v.12 no.1
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    • pp.63-88
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    • 2006
  • 본 연구는 기업가치를 측정하기 위해서 활용될 수 있는 두 가지의 새로운 모형을 개발하였다. 두 가지 모형은 모두 자산가치와 수익가치의 가중평균으로 기업의 본질가치를 표현할 수 있다는데 공통적인 특징이 있다. 첫째 모형은 도산확률 하의 세후 기업가치 가중평균모형이다. 현금흐름할인법으로 알려진 전체기업가치 평가방법론(entity approach)에 기초한 기업가치 평가모형인 이원흠 최수미(2002)의 지식자산가치 평가모형 및 이원흠 최수미(2004)의 가중평균 가치평가모형으로부터 도산확률 하의 세후 가중평균 기업가치 평가모형을 도출하였다. 이 모형은 기업가치는 수익가치 및 실물자산의 가치와 지급이자의 절세효과, 예상도산비용 등 4부분으로 구성된다는 것을 보여 주고 있다. 둘째 모형은 이익조정에 의한 비정상발생액을 감안한 기업가치 가중평균모형이다. 회계학 분야에 주로 발전한 발생액을 고려한 이익의 질(quality of earnings)을 기업가치 측면에서 평가할 수 있는 새로운 모형이다. 이익의 질을 고려한 기업가치 평가모형도 첫째 모형의 도출논리에 의거하여 세후 혹은 도산확률 하의 세후 기업가치 평가모형으로 확장할 수 있다. 새로이 개발된 가중평균 가치평가모형을 통해 추정한 수익가치와 자산가치의 가중치, 가중평균자본비용 등의 정보는 상장주식의 목표가격 평가, 투자등급 판정 등에 활용될 수 있을 뿐만 아니라, 신규상장주식의 공모가, 비상장기업의 합병가액산정, 지주회사의 가치평가 등 비상장기업의 가치평가 분야에 광범위하게 응용될 수 있을 것이다.

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Performance Test of Wet Type Decontamination Device (습식 제염장치의 성능시험)

  • 이은표;김은가;민덕기;전용범;이형권;서항석;권형문;홍권표
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.105-108
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    • 2003
  • The intervention area located at rear hot cell can be contaminated by hot cell maintenance work. For effective decontamination of the intervention floor a wet type decontamination device was developed. The device was assembled with a brush rotating part, a washing liquid supplying part, an intake part for recovering contaminated liquid and a device moving cart part. The device was made of stainless steel for easy decontamination and corrosion resistance. The function test carried out at intervention area of the PIE facility showed good performance.

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Storage of Rabbit Ova in 199 Media at 5℃ (조직배양액(組織培養液) 199배지(培地)에 의(依)한 가토난자(家兎卵子)의 저온(低溫)(5℃) 보존(保存))

  • Jeon, C.G.;Isijima, Yosiro
    • Korean Journal of Agricultural Science
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    • v.1 no.1
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    • pp.41-46
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    • 1974
  • Fertilized rabbit ova at 16-cell stage kept in TC 199, TC $199_+{^+}$ rabbitserum(4:1, 3:2, 2:3 and 1:4), rabbit serum, saline and serum+saline(1:1) were stored at $5^{\circ}C$ for 48 hours. They were than cultured at 37 C for 48 hours to determine their viability. The percentage of ova survived in each storage media was 31, 87, 100, 80, 100, 75 and 83%, respectively.

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기술가치평가를 적용한 R&D 평가관리체계의 효율성 제고 : ICT분야 기술의 경제적 가치와 매출발생 효과 비교분석

  • Seong, Taek-Eung;Lee, Heon-Hwi;Kim, Hyo-Eun;Park, Hyeon-U
    • Proceedings of the Korea Technology Innovation Society Conference
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    • 2017.11a
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    • pp.689-696
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    • 2017
  • 4차 산업혁명의 도래와 더불어 ICT 기계, ICT 금융, ICT 의료, ICT 나노 등과 같이 기술분야별 영역의 장벽이 허물어지고, 학제간 연구(Interdisplinary Research)가 일상화됨에 따라 국가 R&D 과제도 융합기술의 형태로 진화, 발전하고 있다. 부처별 R&D 과제의 결과물에 대한 성과평가는 현 시점에서 정성 평가지표에 대한 전문가의견법 결과를 참조하고 있으며, 일부 과제에 있어서 특허의 상태적 우위도(등급화) 결과를 반영하는데 머물러 있다. 본 연구에서는 과거 3~5년전 기술가치평가가 수행된 정부 R&D 과제에 대해, 가치평가 결과를 매출발생 시점 이후의 매출액 증감분과 비교 분석하여 시사점을 얻고자 한다. 특히 ICT 분야 R&D 과제로부터 산출된 기술적 성과(특허 10건 선정)에 대해, 해당 기술을 사업화한 주체(기업)의 매출액 실적을 비교하여 상호 관련성을 파악하고, 공공 R&D 과제의 평가관리 체계에 포함할 수 있는 실질적 개선 방안을 제시한다. 본 연구에서 제안된 기술가치평가 모형 및 참조정보 활용방안은 R&D 평가년도의 성과물에 대한 경제적 가치 수준 파악을 할 수 있는 평가툴이 되는 동시에, 차년도 국가 R&D 과제에 지원한 우수 기술 보유 기관의 미래 수익성을 파악하여 과제선정의 객관성을 높일 수 있는 정보지원툴로 활용할 수 있을 것으로 기대된다.

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Economic Analysis of Korean-type Mobile Carbonization Apparatus for the Field Utilization of Logging Residues (산지폐잔재의 현지 활용을 위한 한국형 조립식 탄화장치의 경제성분석)

  • Chang, Cheol-Su
    • Journal of Forest and Environmental Science
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    • v.23 no.1
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    • pp.11-19
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    • 2007
  • This study was designed to analyze the economic efficiency that is needed to develop and make practical application of a mobile carbonization apparatus, which are able to make wood charcoals and pyroligneous liquid at the logging field with debris. B/C ratio was employed to make an economic analysis, and sensitivity analysis with respect to change in price and interest rates also was made. Cylindrical type is the proper type for the mobile carbonization apparatus, when important factors such as handling capacity, a carbonization time, quality of products and assembling ability were considered. It weighs 400 kg, and a three-step fold-up equipment. The size of 2 (diameter) by 2.4 m (height) carbonization equipment required 1,500 kg wood debris per batch. A forty-eight to fifty-two carbonization time produced 300 kg of wood charcoal and $45{\ell}$ of pyroligneous liquid. The average life span of the apparatus was 5 years. If the private enterprise operated 100 batch, 80 batch, and 70 batch with one apparatus, the B/C ratio of them was greater than 1, indicating that the production is economically feasible. The period to achieve a break-even point required to be 4 years in case of 100 and 80 batches to 5 years in case of 70 batch. But the private enterprises should operate at least two apparatus for the profits. Also, if the production was to be profitable, the prices of wood charcoals and pyroligneous liquid should be at least 750 won per kg and 700 won per liter.

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Effect of Relative Humidity on Calcium Uptake of Tomato Plant (상대(相對) 습도(濕度)가 토마토의 Ca흡수(吸收)에 미치는 영향(影響))

  • Cho, Ill-Hwan
    • Korean Journal of Soil Science and Fertilizer
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    • v.30 no.2
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    • pp.178-183
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    • 1997
  • The effect of different relative humidity(RH) of atmosphere on the uptake of calcium by tomato plant was investigated through an experiment in the protected cultivation system. The RH regime was imposed by humidifiying by humidifier in one plot, and by mulching the ridge to cut down the evaporation of water to lower the RH, in another plot. During the course of plant growth, RH in the humidified plot, at noon, was about 70%, while in non-humidufied plot, RH was about 50%. The humidification also resulted in the lowering of temperature significantly(by about, $3.1^{\circ}C$). This higher RH of atmosphere under humidifying treatment, resulted in the increase in the water efflux rate of root significantly(greater by 0.24g/g dry root/h than that under mulching treatment). Relatively severe occurrence of blossom end rot(23%) was observed in the humidifying treatment, while no such symptom occurred in mulching plot. The efflux rates of Ca, K and Mg were found to be higher in the humidifying plot. It was also observed that the concentrations of Ca, Mg and K in the xylem solution was 2-4 times higher than that of gydroponic solution. This suggested that the occurrence of blossom end rot, under high RH of atmosphere, would not be due to the decrease in the uptake of Ca per se, by tomato plant, but due to anomalies in the distribution of it within the plant.

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Process Optimization for Reduction of Waste Acids of Electropolishing Solution using Round Bus Bar (구형 부스바를 이용한 전해연마액의 폐산 폐기물 감소를 위한 공정 최적화)

  • Kim, Soo Han;Cho, Jaehoon;Park, Chulhwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.8
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    • pp.722-727
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    • 2016
  • In this study, we attempted to reduce the generation of waste acids in the electropolishing process by improving the current efficiency. The optimum conditions of the electropolishing process when using the round bus bar were determined by the Taguchi method. The current density, polishing time, electrolyte temperature and flow rate were selected as the control factors for the current efficiency in the electropolishing process. An orthogonal array was created by considering three levels for each factor and experiments were carried out. The larger-the-better SN ratios were calculated by the Taguchi method. The current density was the most important factor affecting the current efficiency and the polishing time was the least important one. The optimum conditions to minimize the generation of waste acids were a current density of $45A/dm^2$, polishing time of 4 min, electrolyte temperature of $65^{\circ}C$ and flow rate of 7 L/min. The results of the ANOVA confirmed that the effects of the current density, electrolyte temperature and flow rate are significant at the 95% confidence level. The increase in the contact area and contact force afforded by using the round bus bar improved the current efficiency which, in turn, reduced the amount of waste acids generated. Further research is planned to investigate the effect of the type of bus bar on the current efficiency.