• Journal of the Korean Applied Science and Technology
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• v.29 no.1
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• pp.116-121
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• 2012

In this paper, yellow coupler was prepared by the reaction of ${\alpha}$-pivaloyl- 2-chloro-5-aminoacetaniline hydrogen chloride with 1-hexadecane sulfonyl chloride in the presence of pyridine. The product was identified by using various analytical tools such as melting poin elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, mass spectrometer. The reaction of yellow coupler with CD-3(color development agent) was shown yellow color.

• Korean Journal of Crystallography
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• v.9 no.2
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• pp.159-167
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• 1998

천연에서 발견되는 유색수정은 자수정, 연수정, 황수정, 청수정, 녹수정, 장미수정 등 그 색의 종류에 따라 크게 6가지로 분류되며 발색 기구에 따라 색중심(color center), 전이금속 불순물(transition metal impurity), 산란(scattering), 전하이동(charge transfer) 등 4가지로 분류된다. 이들은 천연에서 고온고압의 열수가 냉각되면서 그 안아 녹아있던 광물질이 재결정하여 생성된 것이다. 이러한 유색수정은 실험실에서도 합성되며 그 방법은 천연 수정의 생성 과정과 유사하다. 그러나 천연수정 중의 일부는 실험실에서 성장하기가 거의 불가능하기 때문에 다른 방법을 이용하여 유사한 색을 가지게 한다. 본 논문에서는 불순물 원소의 종류 및 수정 격자내의 위치, 최외각 전자의 상태에 따라 색이 달라지는 것을 고찰하고 이러한 유색수정을 합성하는 원리에 대하여 논하고자 한다.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.16 no.1
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• pp.25-31
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• 2006

Many amethysts of different origins such as South America, Aftrica, and Asia were compared. According to ICP-AES analysis, the colorizing elements were Fe, Cr, Cu, and Co. Amethysts from South America showed higher concentrations of the elements. UV- VIS analysis showed that both natural and synthetic amethysts were characterized by the higher absorption at 350 nm and 550 nm wavelength. The natural amethysts had lower permeability than that of the synthetic amethysts. According to FT-IR analysis, the synthetic amethysts were distinguished from the natural amethysts in that they had a typical absorption band of $3543cm^{-1}$. The amethyst from South America showed strong absorption bands of $3584cm^{-1}\;and\;3435cm^{-1}$, and African amethyst had absorption bands of $3299cm^{-1}\;and\;3196cm^{-1}$. $3381cm^{-1}$ absorption band was shown strongly for Asian origins.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.8 no.1
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• pp.160-168
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• 1998

In order to investigate the color variation and the solubility limit in wagnerites by metal ion substitution, wagnerite ($A_2XO_4Z$) was synthesized and then, substituted by coloring metal ions, especially $CO^{2+},Ni^{2+}$ and $Cu^{2+}$ ions. When calcium was replaced with Mg, Co, Ni and Cu divalent ions, solid solutions were formed with a limited solubility. Single phase wagnerites were synthesized by the substitution of Ca with Mg and Co, and their colors were white and purple, respectively. Substitutions with $Li^+$ were succeeded in the specific composition and the substitution of vanadium for $X^{5+}$ were attempted, resulting in the wagnerites of dark purple, dark gold and light yellow colors. The substitution of chlorine was, also, attmepted for the fluorine site.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.3 no.2
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• pp.93-98
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• 1993

In the ternary system of $CaF_2-CaO-P_2O_5$. Apatite$(Ca_{10}(PO_4)_6F_2)$ single crystal having a congruent point was grown by FZ process. The atmospheric condition was kept by oxygen blowing. Adjusting the growth parameters of rotation rate, growth rate and gas amount, we tried to find the optimum growth condition. By partly substituting Ca as Co element, the absorption of infrared is increased and the color effect was observed. Using the Laue back reflection, XRD and FTIR analysis, the characterization of the crystal was carried out.

• Journal of Conservation Science
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• v.32 no.3
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• pp.425-436
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• 2016

The Yakhyeon catholic church (Historic Site No. 252 in Korea) that was constructed in 1892 has been the first western brick structure to ever have existed and one of the most important historical materials in the Korean modern architecture. After a fire had broken out at the catholic church in 1998, the stained glass on the back wall, the slab glass (dalle de verre) introduced by Lee Nam Guy in 1974, was repaired in 1999 because of singe scorch and water leakage. An analysis of the coloration elements showed that yellow, red and green included Zn, K and Cd, respectively. The glass of red contained Se, dark green contained Mn and Cr, and blue contained Pb and S. According to material analysis, the masonry joint was identified dolomite ($CaMg(CO_3)_2$) and calcite ($CaCO_3$), which was observed plate, columnar, rhombic and square of crystalline particles. Meanwhile, ultrasonic velocity in the stained glass recorded low speed in the middle and lower right of the window (an average of 4,130 m/s). And the joint was measured the lowest physical properties of the top left and middle of the window (an average of 2,053 m/s). This study have showed that extensive physical damage was founded to the left and middle rather than the right side. In this respect, more research in needed to conserve the correlation between color and physical properties.

• Journal of the Korean Chemical Society
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• v.33 no.3
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• pp.304-308
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• 1989

The spectrophotometric determination of $Lu^{3+},\;Eu^{3+}$ and some other rare earths have been investigated using Methyl Thymol Blue(MTB) as spectrophotometric reagent. Rare earth elements form a stable complex with MTB abount pH 6.5 and the ratio of its complex is 1 to 1. MTB has a absorption maxima at 440nm and rare earth MTB complex has absorption maxima 610nm at pH 6.5, respectively. The absorbance of the rare earth MTB complex is stable in 7 hours after color developing and obey the Beer law in the range of $0{\sim}110{\mu}g/50ml$. The ligand such as phosphate, citrate and EDTA decrease the absorbance of its complex considerably, and this method has a poor selectivity of each rare earth element and the molar absorptivity is $1.2{\sim}2.0{\times}10^4mol^{-1}{\cdot}l{\cdot}cm^{-1}$. In methyl alcohol, ethyl alcohol and acetone medium we did not find out any absorption change of the rare earth MTB complex.

• Journal of Conservation Science
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• v.27 no.1
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• pp.31-40
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• 2011

Copper-red (Dongwha, Jinsa) is Korean traditional inorganic pigment used for red-coloring on the porcelain surface during Goryeo and Joseon Periods. Trace amounts of copper-red porcelains are handed down because of the technical difficulty of making and coloring of the pigment. It is known that copper ore sources were extensively distributed in Korea according to old literatures and some of them are still producing copper ore at this present. Main types of copper-bearing mineral in Korea are chalcopyrite ($CuFeS_2$) and malachite ($Cu_2CO_3(OH)_2$), and they are easily collected from the ground surface. This means Korea had geographical and economic geological advantages for supplying raw material of the pigment. These two minerals showed good red-coloring in color test for porcelain pigment. As a coloring element, copper showed micro size less than $5{\mu}m$ in diameter in glaze matrix. The dispersion of copper particle is the most decisive factor for red chromaticity of copper-red porcelain, as well as copper content of the pigment.

• Journal of Conservation Science
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• v.27 no.3
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• pp.323-332
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• 2011

Microtexture and components of 7 glass bead fragments excavated from Andong tumulus in Gildu-ri, Goheung have been analyzed to determine the characteristics of their weathered condition as well as chemical compositions. Firstly, status of microtexture shows that there is a large quantity of pollutants which were presumably transferred from the buried environment into the surface and the gap of the cracks. The examination has displayed that there are less amount of alkali metal components such as sodium (Na) and potasium (K) in the gap of the cracks than on the surface. The chemical compositions analysis has confirmed that two samples belongs to potash glass group ($K_2O-SiO_2$), four to soda glass group ($Na_2O-SiO_2$), and one to the mixed alkali glass group. Chromophoric elements of the glass varies by different colours: blue and navy are cobalt (Co); greenish blue is copper (Cu) and iron (Fe); and light brown is Fe respectively. Such kind of scientific analysis of the excavated glass beads will contribute to the understanding of interchange between various local cultures and arts within the southwest region of Korean Peninsula during the 4th and the 5th centuries.

• Analytical Science and Technology
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• v.6 no.1
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• pp.121-129
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• 1993

UV/VIS spectrophotometer interfaced with HPIC(High Performance Ion Chromatography) has been applied to the determination of lanthanide elements. The separation of lanthanide elements with HPIC helped to avoid erroneous analytical results due to interferences. Individual lanthanide elements at ppm level were separated on a HPIC CS5 column using pyromellitic acid and oxalic acid. The individual lanthanide elements were detected at 520nm following post-column reaction with PAR. Sm, Eu, Gd, Y, Tb, Dy, Ho, Er, Tm, Tb, and Lu were separated by pyromellitic acid. La, Ce, Pr and Nd were separated by oxalic acid. Appropriate pH of pyromellitic acid for separation was at pH 2.99.