• Journal of the Korean Data and Information Science Society
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• v.24 no.1
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• pp.33-39
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• 2013

In the transformation of response variable in partial linear models outliers can cause a bad effect on estimating the transformation parameter, just as in the linear models. To solve this problem the processes of estimating transformation parameter and detecting outliers are needed, but have difficulties to be performed due to the arbitrariness of the nonparametric function included in the partial linear model. In this study, through the estimation of nonparametric function and outlier detection methods such as a sequential test and a maximum trimmed likelihood estimation, processes for transforming response variable robust to outliers in partial linear models are suggested. The proposed methods are verified and compared their effectiveness by simulation study and examples.

• Journal of the Mineralogical Society of Korea
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• v.23 no.2
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• pp.161-170
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• 2010

Many microbes, including both bacteria and fungi, produce manganese (Mn) oxides by oxidizing soluble Mn(II) to form insoluble Mn(IV) oxide minerals, a kinetically much faster process than abiotic oxidation. These biogenic Mn oxides drive the Mn cycle, coupling it with diverse biogeochemical cycles and determining the bioavailability of environmental contaminants, mainly through strong adsorption and redox reactions. This mini review introduces recent findings based on quantum mechanical density functional theory that reveal the detailed mechanisms of toxic metal adsorption at Mn oxide surfaces and the remarkable role of Mn vacancies in the photochemistry of these minerals.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.11a
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• pp.415-418
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• 2011

It is critical to assess the characteristics of flame response to pressure perturbations for the understanding of nonlinear combustion instabilities. Previous studies can be grouped into flame response upon perturbed, fresh air and fuel mixture, and flame response directly perturbed from longitudinal waves. The present study presents experimental methodology for the understanding of the flame response exposed to transverse acoustic waves generated by loud speakers.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2010.04a
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• pp.624-627
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• 2010

최근 자동차 업계서는 차량의 온실가스 배출량을 줄이고 연비를 개선시킬 수 있는 방법 중의 하나로 경량화 소재를 사용하여 차체의 중량을 줄이는 연구가 활발히 진행 중에 있다. 특히 알루미늄 합금의 경우 기존 강재에 비해 비중이 낮아 가볍고 부식에 대한 저항성이 높아 많이 사용되어지고 있는 추세이다. 본 연구에서는 먼저, 저입열 용접공정을 적용하여 용접 변수와 토치의 각도에 따른 인장강도 특성을 비교하여 적정 용접 범위를 산정하였으며, 인장강도와 비드형상의 관계를 다중 회귀 분석을 이용하여 비드 예측 회귀 모델을 제시하였다. 또한 호감도 함수를 적용한 반응표면분석법을 이용하여 자동차 생산 현장에서 겹치기 용접 이음부의 강건한 용접 품질을 가질 수 있는 최적용접 공정 조건을 도출할 수 있는 효과적인 방법을 제안하고자 한다.

• Proceeding of EDISON Challenge
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• 2016.03a
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• pp.1-7
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• 2016

Triphenylsulfonium 양이온(TPS)은 잘 알려진 광산 생성자(photoacid generator, PAG)중 하나로 양이온성 중합반응(cationic polymerization)의 개시제로 널리 사용됐으며, 유기발광다이오드의 활성층, 폴리머 발광다이오드의 전자주입층을 구성하는 재료로도 사용되고 있다. TPS는 200nm 주변의 빛을 흡수하면 탄소-황 결합이 끊어져 페닐 라디칼과 diphenylsulfonium 양이온 라디칼로 분해되는 것이 알려져 있다. 본 연구에서는 밀도범함수이론과 시간의존 밀도범함수이론을 이용 triphenylsulfonium 이온의 광학적 특성을 조사하였다. 가장 안정한 구조를 기준으로 자외선 흡광 스펙트럼을 계산하였고, 실험값에 잘 맞는 것을 확인하였다. TPS의 빛에 의한 해리 과정을 알아보기 위해 페닐-황 결합 길이를 변화시키며 TPS의 흡광 스펙트럼을 계산, 여기상태 포텐셜 에너지 곡선을 구할 수 있었다. 결합의 분해에 이용되는 상태들은 주로 점유 분자 오비탈에서 최저준위 비점유 분자 오비탈(LUMO)로 들뜨는 성분을 가지고 있었는데, 이는 LUMO가 반결합성 오비탈이기 때문이다.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.5
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• pp.242-248
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• 2016

The overall reaction rate of fuel cell is governed by oxygen reduction reaction (ORR) in the cathode due to its slowest reaction compared to the oxidation of hydrogen in the anode. The ORR efficiency can be readily evaluated by examining the adsorption strength of atomic oxygen on the surface of catalysts (i.e., known as a descriptor) and the adsorption energy can be controlled by transforming the surface geometry of catalysts. In the current study, the effect of the surface geometry of catalysts (i.e., strain effect) on the adsorption strength of atomic oxygen on platinum catalysts was analyzed by using density functional theory (DFT). The optimized lattice constant of Pt ($3.977{\AA}$) was increased and decreased by 1% to apply tensile and compressive strain to the Pt surface. Then the oxygen adsorption strengths on the modified Pt surfaces were compared and the electron charge density of the O-adsorbed Pt surfaces was analyzed. As the interatomic distance increased, the oxygen adsorption strength became stronger and the d-band center of the Pt surface atoms was shifted toward the Fermi level, implying that anti-bonding orbitals were shifted to the conduction band from the valence band (i.e., the anti-bonding between O and Pt was less likely formed). Consequently, enhanced ORR efficiency may be expected if the surface Pt-Pt distance can be reduced by approximately 2~4% compared to the pure Pt owing to the moderately controlled oxygen binding strength for improved ORR.

• Communications for Statistical Applications and Methods
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• v.5 no.3
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• pp.777-792
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• 1998

병원의 임상연구실험에서 종종 환자들의 치료에 따른 병세의 호전상태를 여러단계로 분류하여 상이한 치료방법에 대한 치료효과간의 차이론 알고자 하는 경우가 있다. 이와 같이 다중상태의 생존자료를 분석하기 위해서 본 논문에서는 semi-Markov 모형에 Cox 회귀모형을 적용하여 회귀계수와 기저생존함수를 추정하고 이를 바탕으로 반응확률함수를 추정하였다. 그리고 본 논문의 결과를 실제 임상실험에서 얻어진 자료에 적용하여 분석하였다.

• School Mathematics
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• v.18 no.3
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• pp.457-478
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• 2016

The purpose of this study is to investigate middle school students' understanding and development of function graphs. We collected the data from the teaching experiment with two middle school students who had not yet received instruction on linear function in school. The students participated in a 15-day teaching experiment(Steffe, & Thompson, 2000). Each teaching episode lasted one or two hours. The students initially focused on numerical values rather than the overall relationship between the variables in functional situations. This study described meaning, role of and students' responses for the given tasks, which revealed the students' understanding and development of function graphs. Especially we analyzed students' responses based on their methods to solve the tasks, reasoning that derived from those methods, and their solutions. The results indicate that their continuous reasoning played a significant role in their understanding of function graphs.

• Journal of Energy Engineering
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• v.3 no.1
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• pp.18-27
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• 1994

석탄액화반응에서 촉매 세공구조가 촉매 불활성화에 미치는 영향을 조사하기 위하여 간단한 모델을 전개하였다. 촉매의 세공수 분포에 근거하여 두 개의 Dirac delta 함수분포를 갖는 다공질 촉매구조를 제안하였으며 촉매 세공구조와 반응속도상수와의 관계를 유도하기 위하여 단순화된 반응계를 가정하였다. 균일 코드피복 가정에서 본 모델을 촉매 불활성화 예측에 적용하였으며 계산과정에서 세공율, 세공 크기 등의 촉매 특성치에 대해서는 실제값을 이용하였다. 본 모델연구에 의하면 unimodal 촉매에 비해 bimodal 촉매가 촉매 불활성화에 덜 민감하였다.

• The Korean Journal of Applied Statistics
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• v.29 no.5
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• pp.773-786
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• 2016

Multiple quantile regression that simultaneously estimate several conditional quantiles of response given covariates can provide a comprehensive information about the relationship between the response and covariates. Some quantile estimates can cross if conditional quantiles are separately estimated; however, this violates the definition of the quantile. To tackle this issue, multiple quantile regression with non-crossing constraints have been developed. In this paper, we carry out a comparison study on several popular methods for non-crossing multiple linear quantile regression to provide practical guidance on its application.