• Title/Summary/Keyword: 반응속도모델

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Effect of Sodium ion on the Anaerobic Degradation of Food Waste : Quantitative Evaluation, Inhibition Model (주방폐기물의 혐기성분해에 대한 나트륨이온의 영향: 저해 특성평가, 저해모델)

  • Shin, Hang-Sik;Song, Young-Chae;Paik, Byeong-Cheon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.2 no.2
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    • pp.3-17
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    • 1994
  • The inhibitory effect of sodium ion on the anaerobic degradation of food waste was studied by an anaerobic batch toxicity assay and inhibition model. The anaerobic degradation activity of food waste spiked with over $2g\;Na^+/L$ of sodium ion was severely inhibited at the initial stage of the exposure. The inhibition response of anaerobic microorganisms on the sodium ion estimated from the methane production was differed according to the concentration of sodium ion. The relative acclimation time(RAT) and methanation rate(RMR), defined as the ratios of initial lag time and maximum methane production rate of the sample spiked with sodium ion to the control. respectively, were used to evaluate the acclimation and inhibitory effects quantitatively on the anaerobic microorganisms. When sodium ion was increased from $2g\;Na^+/L$ to $20g\;Na^+/L$, the RAT was exponentially increased from 18.9 to 90. but the RMR was linearly decreased from 0.97 to 0.02. The effects of sodium ion for the maximum methanation rate, first order kinetic constant and ultimate methane production were well evaluated by a generalized nonlinear expression model. it could be described by the uncompetitive inhibition mode. The sodium ion concentration causing 50% inhibition of methanation activity was about $11g\;Na^+/L$, and the critical sodium ion beyond to compelete inhibition was 20 to $21g\;Na^+/L$. The presented results could be used to obtain the design or operation parameters of the anaerobic process treating food waste of high salt.

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Development and Validation of Urea- SCR Control-Oriented Model for NOX and NH3 Slip Reduction (NOX 및 NH3 Slip 저감을 위한 Urea-SCR 제어기반 모델 개발 및 검증)

  • Lee, Seung Geun;Lee, Seang Wock;Kang, Yeonsik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.1
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    • pp.1-9
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    • 2015
  • To satisfy stricter $NO_X$ emission regulations for light- and heavy-duty diesel vehicles, a control algorithm needs to be developed based on a selective catalytic reaction (SCR) dynamics model for chemical reactions. This paper presents the development and validation of a SCR dynamics model through test rig experiments and MATLAB simulations. A nonlinear state space model is proposed based on the mass conservation law of chemical reactions in the SCR dynamics model. Experiments were performed on a test rig to evaluate the effects of the $NO_X$ and $NH_3$ concentrations, gas temperature, and space velocity on the $NO_X$ conversion efficiency for the urea-SCR system. The parameter values of the proposed SCR model were identified using the experimental datasets. Finally, a control-oriented model for an SCR system was developed and validated from the experimental data in a MATLAB simulation. The results of this study should contribute toward developing a closed-loop control strategy for $NO_X$ and $NH_3$ slip reduction in the urea-SCR system for an actual engine test bench.

Modeling of Visual Attention Probability for Stereoscopic Videos and 3D Effect Estimation Based on Visual Attention (3차원 동영상의 시각 주의 확률 모델 도출 및 시각 주의 기반 입체감 추정)

  • Kim, Boeun;Song, Wonseok;Kim, Taejeong
    • Journal of KIISE
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    • v.42 no.5
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    • pp.609-620
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    • 2015
  • Viewers of videos are likely to absorb more information from the part of the screen that attracts visual attention. This fact has led to the visual attention models that are being used in producing and evaluating videos. In this paper, we investigate the factors that are significant to visual attention and the mathematical form of the visual attention model. We then estimated the visual attention probability using the statistical design of experiments. The analysis of variance (ANOVA) verifies that the motion velocity, distance from the screen, and amount of defocus blur affect human visual attention significantly. Using the response surface modeling (RSM), we created a visual attention score model that concerns the three factors, from which we calculate the visual attention probabilities (VAPs) of image pixels. The VAPs are directly applied to existing gradient based 3D effect perception measurement. By giving weights according to our VAPs, our algorithm achieves more accurate measurement than the existing method. The performance of the proposed measurement is assessed by comparing them with subjective evaluation as well as with existing methods. The comparison verifies that the proposed measurement outperforms the existing ones.

A Theoretical Study for Estimation of Oxygen Effect in Radiation Therapy (방사선 조사시 산소가 세포에 미치는 영향의 이론적 분석)

  • Rena J. Lee;HyunSuk Suh
    • Progress in Medical Physics
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    • v.11 no.2
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    • pp.157-165
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    • 2000
  • Purpose: For estimation of yields of l)NA damages induced by radiation and enhanced by oxygen, a mathematical model was used and tested. Materials and Methods: Reactions of the products of water radiolysis were modeled as an ordinary time dependant equations. These reactions include formation of radicals, DNA damage, damage repair, restitution, and damage fixation by oxygen and H-radical. Several rate constants were obtained from literature while others were calculated by fitting an experimental data. Sensitivity studies were performed changing the chemical rate constant at a constant oxygen number density and varying the oxygen concentration. The effects of oxygen concentration as well as the damage fixation mechanism by oxygen were investigated. Oxygen enhancement ratio(OER) was calculated to compare the simulated data with experimental data. Results: Sensitivity studies with oxygen showed that DNA survival was a function of both oxygen concentration and the magnitude of chemical rate constants. There were no change in survival fraction as a function of dose while the oxygen concentration change from 0 to 1.0 x 10$^{7}$ . When the oxygen concentration change from 1.0 $\times$ 107 to 1.0 $\times$ 101o, there was significant decrease in cell survival. The OER values obtained from the simulation study were 2.32 at 10% cell survival level and 1.9 at 45% cell survival level. Conclusion: Sensitivity studies with oxygen demonstrated that the experimental data were reproduced with the effects being enhanced for the cases where the oxygen rate constants are largest and the oxygen concentration is increased. OER values obtained from the simulation study showed good agreement for a low level of cell survival. This indicated that the use of the semi-empirical model could predict the effect of oxygen in cell killing.

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Combustion and NOx Emission Characteristics of the Gas Turbine Combustor Burning Medium-Btu Gas as Alternative Fuel (중발열량 가스 대체 시 가스터빈 연소기의 연소 및 NOx 배출 특성)

  • Lee, Chan;Seo, Je-Young
    • Journal of Energy Engineering
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    • v.12 no.4
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    • pp.320-327
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    • 2003
  • A CFD (Computational fluid Dynamics) research is conducted for the investigation of the fuel alteration of MBTU (medium-Btu) gas in IGCC gas turbine combustor. The computational analysis method of the gas turbine combustor is constructed by incorporating MBTU gas reaction and fuel NOx models into commercial CFD code. With the use of the present analysis method, comparisons are made on the flow velocity, the chemical species and the temperature distributions, and on the flame shape and behavior of gas turbine combustor firing natural gas and MBTU gases (coal gas, heavy residue oil gas). Furthermore, the NOx formation characteristics and the turbine matching condition of the combustor are analyzed. Based on the computed analysis results, the present study provides the directions for the redesign and the design modification of IGCC gas turbine combustor firing MBTU gas as alternative fuel.

Operability of Composting Facilities by Modeling (모델링에 의한 퇴비화 시설의 운전성에 관한 연구)

  • Yoo, Yeong Seok;Kim, I Tae;Gee, Chai Sung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.3 no.2
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    • pp.59-68
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    • 1995
  • Composting facilities are operated with air and moisture control. Composting effects on two operating factors was analysed changing aeration rate with and without water addition to maintain the optimun moisture level. Though the composting facilties are provided with appropriate surroundings for compositing, operating temperature is set for decomposition rate. Accordingly control of decomposition phases was analysed by modeling the process of high and low decomposition phases with various operating temperature. A composting model of "The Library of Compost Engineering Software" developed by Roger T. Haug Inc. in U.S.A. was applied in modeling. As result of this study, operation with optimum moisture has more sensitive temperature to aeration fluctuation and lead to higher reaction rate with lower aeration than operation with poor moisture. Decomposition rate in composting facilities depend on slow decomposition phase because high rate decomposing substances already have been decomposed before entire process is not completed. In order to enhance decomposition rate of organics, effective decomposition in slow decomposition phase needs to be focused.

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Application of Numerical Model for the Effective Design of Large Scale Fire Calorimeter (화재발열량계의 효율적 설계를 위한 수치해석 모델의 적용)

  • Kim, Sung-Chan
    • Fire Science and Engineering
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    • v.24 no.6
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    • pp.28-33
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    • 2010
  • The present study develops a numerical model based on the computational fluid dynamics technique to analyse the thermal flow characteristics of large scale fire calorimeter and examine the characteristics of primary parameters affecting on the uncertainty of heat release rate measurement. ANSYS CFX version 12.1 which is a commercial CFD package is used to solve the governing equations of the thermal flow field and the eddy dissipation combustion model and P-1 radiation model are applied to simulate the fire driven flow. The numerical results shows that the horizontal duct system with $90^{\circ}$ bend duct was shown relatively high deviated asymmetric flow profiles at the sampling location and the deviation of the velocity field was higher than that of the temperature and species quantities. The present study shows that the computational model can be applicable to optimize the design process and operating condition of the large scale fire calorimeter based on the understanding of the detail flow field.

Study on HRV Analysis in Sleep Stage Using Wavelet Transform (웨이브렛 변환을 이용한 수면상태의 HRV 분석에 관한 연구)

  • 최혜진;정기삼;이병채;김용규;안인석;주관식
    • Progress in Medical Physics
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    • v.10 no.3
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    • pp.141-149
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    • 1999
  • This research analyzed the HRV signals by using wavelet transform to observe the activities of autonomous nervous system in a sleep state. This research also restructured the HRV signals from electrocardiogram and by using coefficient which was obtained through wavelet transform, analyzed the signals by frequency bandwidth. Then compared the analyzed results with existing frequency analyzing method using AR model techniques. The suggested wavelet coefficient from power spectrum component in the study shows a similar tendency with the results from FFT or AR model technique. Therefore, it can be found that power spectrum analyzing method by wavelet coefficient is a useful as a tool for analyzing autonomous nervous system activities using HRV signals. Since the suggested method able to clearly depict the progression of change in time zone, which was once impossible with the existing methods, it is presumed that it will be useful in other physiological signals.

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Adsorption Characteristics of Non-degradable Eosin Y Dye by Carbon Nano Tubes (Carbon Nano Tubes에 의한 난분해성 염료 Eosin Y의 흡착 특성)

  • Lee, Min-Gyu;Yun, Jong-Won;Suh, Jung-Ho
    • Korean Chemical Engineering Research
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    • v.55 no.6
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    • pp.771-777
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    • 2017
  • Adsorption characteristics of Eosin Y dye by carbon nano tubes (CNTs) were examined through batch experiments. CNTs used in the study had specific surface area of $106.9m^2/g$, porosity volume of $1.806cm^3/g$, and porosity diameter of $163.2{\AA}$, respectively. Adsorption experiments were carried out as function of contact time, initial solution pH (2~10), dye concentration (100, 150 and 200 mg/L), adsorbent dose (0.05~1.0 g) and temperature (293, 313 and 333 K). The adsorption was favoured at lower pHs and temperatures. Adsorption data were well described by the Langmuir model. The adsorption process followed the pseudo-second order kinetic model. The adsorption capacity decreased with increase in temperature. The results of the intraparticle diffusion model suggested that film diffusion and particle diffusion were simultaneously occured during the adsorption process. Thermodynamic studies suggested the spontaneous and endothermic nature of adsorption of Eosin Y dye onto CNTs.

Estimation of Compressive Strength of Concrete Incorporating Fine Particle Cement Considering Blaine Fineness (분말도 변화를 고려한 미분시멘트 사용 콘크리트의 압축강도증진 해석)

  • Han, Min-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.9 no.4
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    • pp.139-145
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    • 2009
  • This study presents an estimation of the strength development of concrete considering the equivalent age using fine particle cement (FC), which is manufactured according to the classification process. Contents and W/B were considered as experimental parameters. The strength considering the equivalent age is gradually increased, and the deviation of the strength according to W/C is increased with decrease of W/C in accordance with the replacement of the fine particle cement. For estimating the apparent activation energy (Ea) considering setting time and blame fineness of cement, Ea of the FC based on setting time is calculated with $27.6{\sim}28.9$ KJ/mol, which is somewhat similar to that of OPC, while by applying Ea based on blame fineness, Ea is increased with increase of FC contents, and is calculated with $40{\sim}56$ KJ/mol. Good agreement is obtained by applying Ea based on setting time, while there was remarkable variation between calculated value and measured value when Ea based on blame fineness. Therefore, it is necessary to add influencing factors in existing Ea to enhance the accuracy of the estimation.