• Journal of the Korean Institute of Intelligent Systems
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• v.14 no.7
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• pp.847-851
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• 2004

In the original mixture density network(MDN), which was introduced by Bishop and Nabney, the parameters of the conditional probability density function are represented by the output vector of a single multi-layer perceptron. Among the recent modification of the MDNs, there is the so-called modified mixture density network, in which each of the priors, conditional means, and covariances is represented via an independent multi-layer perceptron. In this paper, we consider a further simplification of the modified MDN, in which the conditional means are linear with respect to the input variable together with the development of the MATLAB program for the simplification. In this paper, we first briefly review the original mixture density network, then we also review the modified mixture density network in which independent multi-layer perceptrons play an important role in the learning for the parameters of the conditional probability, and finally present a further modification so that the conditional means are linear in the input. The applicability of the presented method is shown via an illustrative simulation example.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.5
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• pp.242-248
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• 2016

The overall reaction rate of fuel cell is governed by oxygen reduction reaction (ORR) in the cathode due to its slowest reaction compared to the oxidation of hydrogen in the anode. The ORR efficiency can be readily evaluated by examining the adsorption strength of atomic oxygen on the surface of catalysts (i.e., known as a descriptor) and the adsorption energy can be controlled by transforming the surface geometry of catalysts. In the current study, the effect of the surface geometry of catalysts (i.e., strain effect) on the adsorption strength of atomic oxygen on platinum catalysts was analyzed by using density functional theory (DFT). The optimized lattice constant of Pt ($3.977{\AA}$) was increased and decreased by 1% to apply tensile and compressive strain to the Pt surface. Then the oxygen adsorption strengths on the modified Pt surfaces were compared and the electron charge density of the O-adsorbed Pt surfaces was analyzed. As the interatomic distance increased, the oxygen adsorption strength became stronger and the d-band center of the Pt surface atoms was shifted toward the Fermi level, implying that anti-bonding orbitals were shifted to the conduction band from the valence band (i.e., the anti-bonding between O and Pt was less likely formed). Consequently, enhanced ORR efficiency may be expected if the surface Pt-Pt distance can be reduced by approximately 2~4% compared to the pure Pt owing to the moderately controlled oxygen binding strength for improved ORR.

• Applied Chemistry for Engineering
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• v.9 no.4
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• pp.561-564
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• 1998

The radial distribution functions of a linear spheroidal type gas molecule $C_2H_4$ were calculated by using the Stockmayer molecular molel, which assumed the $C_2H_4$ molecule as simple quadrupolar molecule. To examine the validity of the calculated radial distribution of $C_2H_4$ gas, the density dependent pressures of $C_2H_4$ gas at several temperatures were calculated and compared with literarily known experimental pressure data of $C_2H_4$ gas. The temperatures examined was 50, 100 and $150^{\circ}C$ and the densities were up to $0.02/{\AA}^3$ (maximum pressure = 1500 atm). The radial distribution function expression used was derived by Yoon, Hacura, and Baglin (YHB) with Baker and Henderson's perturbation theory. The calculated results by a computer showed that the $C_2H_4$ pressures calculated agreed well with the experimental values within ${\pm}5%$ of error range. This indicated that the YHB radial distribution function expression is good enough to obtain various physical quantities sensitive to density such as pressure with resonable accuracy.

• Journal of the Korean Chemical Society
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• v.53 no.6
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• pp.671-676
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• 2009

Described here for the first time is an investigation on geometrical and electronic molecular structure of metol (N-methyl-p-aminophenol sulphate) as corrosion inhibitor of steel using density functional theory (DFT) calculations. Quantum chemical parameters such as highest occupied molecular orbital energy (EHOMO), lowest unoccupied molecular orbital energy (ELUMO), energy gap ((${\Delta}E$), Mulliken charges (($q_M$) and natural atomic (($q_n$) charge have been calculated both for gas and aqueous phases by using B3LYP/6-31G+(d,p) basis set. The relation between the inhibition efficiency and quantum chemical parameters have been discussed in order to elucidate the inhibition mechanism of the title compound.

• Journal of Korean Society of Disaster and Security
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• v.10 no.2
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• pp.21-28
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• 2017

Wind turbulence data is required for engineering calculations of gust speeds, mean and fluctuating loading. Spectral densities are required as input data for methods used in assessing dynamic response. This study is concerned with the estimation of daily instantaneous maximum wind velocity in the meteorological major cities (selected each 6 points) during the yearly 1987-2016.12.1. The purpose of this paper is to present the power spectral densities of the daily instantaneous maximum wind velocity. In the processes of analysis, used observations data obtained at Korea Meteorological Adminstration(KMA), it is assumed as a random processes. From the analysis results, in the paper estimated power spectral densities function(Blunt model) shows a very closed with von Karman and Solari's spectrum models.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.32 no.3
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• pp.147-160
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• 2020

A stochastic probabilistic model for harbor structures such as rubble-mound breakwater has been formulated by using the generalized Wiener process considering the nonlinearity of damage drift and its nonlinear uncertainty, by which the damage path with real-time can be tracked, the residual useful lifetime at some age can also be analyzed properly. The formulated stochastic model can easily calculate the probability of failure with the passage of time through the probability density function of cumulative damage. In particular, the probability density functions of residual useful lifetime of the existing harbor structures can be derived, which can take into account the current age, its present damage state and the future damage process to be occurred. By using the maximum likelihood method and the least square method together, the involved parameters in the stochastic model can be estimated. In the calibration of the stochastic model presented in this paper, the present results are very well similar with the results of MCS about tracking of the damage paths as well as evaluating of the density functions of the cumulative damage and the residual useful lifetime. MTTF and MRL are also evaluated exactly. Meanwhile, the stochastic probabilistic model has been applied to the rubble-mound breakwater. The related parameters can be estimated by using the experimental data of the cumulative damages of armor units measured as a function of time. The theoretical results about the probability density function of cumulative damage and the probability of failure are very well agreed with MCS results such that the density functions of the cumulative damage tend to move to rightward and the amounts of its uncertainty are increased as the elapsed time goes on. Thus, the probabilities of failure with the elapsed time are also increased sharply. Finally, the behaviors of residual useful lifetime have been investigated with the elapsed age. It is concluded for rubble-mound breakwaters that the probability density functions of residual useful lifetime tends to have a longer tail in the right side rather than the left side because of the gradual increases of cumulative damage of armor units. Therefore, its MRLs are sharply decreased after some age. In this paper, the special attentions are paid to the relationship of MTTF and MRL and the elapsed age of the existing structure. In spite of that the sum of the elapsed age and MRL must be equal to MTTF deterministically, the large difference has been shown as the elapsed age is increased which is due to the uncertainty of cumulative damage to be occurred in the future.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.1
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• pp.343-347
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• 2012

Non-linear equalization techniques using decision feedback structure are highly demanded for cancellation of intersymbol interferences occurred in severe channel environments. In this paper decision feedback structure is applied to the linear blind equalizer algorithm that is based on information theoretic learning and a randomly generated symbol set. At the decision feedback equalizer (DFE) the random symbols are generated to have the same probability density function (PDF) as that of the transmitted symbols. By minimizing difference between the PDF of blind DFE output and that of randomly generated symbols, the proposed DFE algorithm produces equalized output signal. From the simulation results, the proposed method has shown enhanced convergence and error performance compared to its linear counterpart.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.38A no.7
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• pp.552-559
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• 2013

In this paper, the multiple-input multiple-output (MIMO) system with a precoder is considered in the transmit-correlated Rayleigh channels. We specifically target the MIMO system employing the minimum mean square error receivers. Based on random matrix theory, we first present a direct and generalized formulation for deriving a probability density function (PDF) of the signal-to-interference-plus-noise ratio (SINR). Then, we derive the accurate closed-form SINR PDFs for a small number of transmit and receive antennas. Based on the SINR PDFs, tight closed-form approximations of the symbol error rate (SER) are derived. Our analysis suggests that the SER approximations can be used to accurately estimate the error probabilities or as a useful tool for the system design.

• Nuclear Engineering and Technology
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• v.5 no.2
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• pp.77-82
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• 1973

A method of obtaining the partition function for a system of electrons is developed by defining a new density matrix, in which the Fermi statistics is explicitly incorporated. The corresponding Bloch equation is formulated and a practical method of solving the equation is obtained for weak potential. This theory is applied to structurally disordered ststems which might be reasonable models for liquid metals.

• Journal of the Korean Chemical Society
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• v.64 no.6
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• pp.334-344
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• 2020

The adsorption of various atmospheric harmful gases (COx, NOx, SOx) on graphene-like Germanene 2D sheet was theoretically investigated using density functional theory(DFT) method. The structures were fully optimized at the B3LYP/cc-pvDZ and CAM-B3LYP/cc-pvDZ levels of theory and confirmed to be a local minimum by the calculation of the harmonic vibrational frequencies. The adsorptions of gases on the Germanene sheet were predicted to be a physisorption process for CO, CO2, NO, and SO2 gases but to be a chemisorption process for NO2, SO, and SO2 gases.