• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2001.11a
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• pp.22-22
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• 2001

전통적으로 초경합금은 무라까미 용액에서 에칭하거나 묽은 염산에 넣고 끓이는 방법에 의해 그 밋구조를 관찰하였다. 그러나 carbide 입자가 suvmicron 크기인 초경합금에서는 전통적인 에칭 방법으 에칭 후에도 입자/기지상, 입자/입자 입계를 동시에 구분시킬 수 있는 SEM 사진을 얻을 수 없다. 본 연구에서는 submicron 크기 초경합금의 고배율 SEM 사진을 얻을 수있는 90H2O2 - 10HNO3 (vol%)의 새로운 에칭 용액을 개발하였다. 경명의 submicron 크기 WC-Co 시편을 샐운 에칭 용액인 90H2O2 - 10HNO3 (vol%)에 넣고 약 6$0^{\circ}C$에서 약 12분 동안 에칭하였다. 에칭에 의해 Co 기지상은 빠르게 제기(dissolution)되었고, 동시에 표면의 WC 입자들은 각각의 결정학적 방향에 따라 천천히(slowly) 다른 속도로 부식(sissolution)되었다. 고배율 SEM을 관찰한 결과 WC/기지상 계면과 WC/WC 입계가 명화갛게 관찰되었다. WC 입자의 성장을 억제시키는입자성장 억제제(Cr3C2, TaC,VC)가 첨가된 WC Co 초경합금을 새로운 에칭 용액인 90H2O2 - 10HNO3 (vol%)에 넣고 약 6$0^{\circ}C$에서 약 12분동안 에칭하였다. 매우 작은 입자를 갖는 미세구조임에도 불구하고 고배율 SEM에서 WC/기지상 계면과 WC/WC 입계가 명확하게 관찰되었다. 90H2O2 - 10HNO3 (vol%)에서 Co 기지상이 빠르게 제거되는 것은 산 (acid)인 HNO3)에서 금속인 Co가 쉽게 녹기 때문이다. 동시에 WC 입자들이 각각 다른 속도로 에칭 된 것은 강력한 산화제인 H2O2가 각각의 WC입자 표면에 얇은 텅스텐 산화물 층을 형성시켰고 이들이 산인 HNO3에서 녹았기 때문이다. 본 연구에서 개발된 새로운 에칭 용액인 90H2O2 - 10HNO3 (vol%)의 에칭 원리가 똑같이 적용 가능한 다른 종류의 초경 합금에서도 사용이 가능할 것으로 판단된다.로 판단된다.

• Journal of the Korean Chemical Society
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• v.19 no.2
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• pp.92-97
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• 1975

The molecular and electronic structures of $TiCl(OC_6H_5)_3{\cdot}C_6H_5OH\;and\;Ti(OC_6H_5)_4{\cdot}C_6H_5OH$ have been studied by employing cryoscopic and electronic spectroscopic methods. The cryoscopic data have shown that the dimeric tetraphenoxytitanium(Ⅳ) phenolate in solid undergoes complete dissociation into monomer in solution and also the chlorocomplex starts dissociation around the concentration of 8 m mole/l. Therefore, these two Ti-complexes are pentacoordinated in dilute solution and the local symmetry of the titanium ion in these complexes seems to be trigonalbipyramid. The electronic spectra of $TiCl(OC_6H_5)_3{\cdot}C_6H_5OH$ and $Ti(OC_6H_5)_4{\cdot}C_6H_5OH$ each show two band, systems, one vibration-structural band characteristic of the aromatic ring in the near UV and another visible band at 26.8 kK, 29.6 kK, respectively, which are assigned as a ligand to metal charge transfer band corresponding to $^1A_1''{\to}^1E'\;or\;^1E''$ transition.

• Journal of the Korean Chemical Society
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• v.36 no.5
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• pp.674-678
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• 1992

An instrument is described that can obtain directly the whole capacitance vs. potential curve and accurately even in dilute solutions using positive feedback for IR correction. Applying a small (7∼10 mV) triangular signal, controlled rectification of the resulting square wave using sample-and-hold circuit allows one to plot the corrected double layer capacitance over a wide potential range. Several illustrations involving the improved performance characteristics of its applicability are given and its limitations discussed.

• Journal of the Korean Chemical Society
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• v.20 no.5
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• pp.374-379
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• 1976

Apparent molal volumes of urea, 1,3-dimethylurea (DMU), and 1,1,3,3-tetramethylurea(TMU) in dimethylsulfoxide(DMSO) and in methanol have been measured at low concentration by the density measurements at $25^{\circ}C$. It is confirmed that urea molecules in the dilute DMSO solution self-associate to a greater extent than in the concentrated solution, while DMU and TMU molecules in DMSO solutions interact with the solvent molecules. In addition, the molecules of the three solutes also interact predominatingly with methanol molecules.

• Journal of the Korean Chemical Society
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• v.44 no.1
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• pp.10-16
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• 2000

In general, acid rain is unbuffered solution with low ionic strength and high resistance. Therefore during the pH measurement of acid rain, error can be occurred due to the liquid junction potential difference between the sample and the standard solution. Actually the average conductivity of rain in Taeduk Science Town during 1998 is 12.8 ${\mu}S/cm$, while that of pH standmd solutions is about 5,980 ${\mu}S/cm$. There is a large difference in ionic strength. To compensate the bias due to residual liquid junction potentials, a quality control standard(QCS) of dilute sulfuric acid, which has the conductivity and pH values simikw to rain, was prepared. The pH of QCS solution was determined using the hydrogen electrode system without liquid junction, and compensation has been made for the bias terms by performing the pH measurements with glass electrode. On the basis of this compensation method, the pH vaiues of rain in Taeduk Science Town during 1998 were measured.

• Polymer(Korea)
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• v.26 no.2
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• pp.227-236
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• 2002

The structure of pregel state in thermoreversible poly(vinylidene fluoride)(PVDF) /propylene carbonate(PC) system was investigated by laser light scattering. It was found that the PVDF chain did not exist as a separate chain even in a very dilute concentration(i.e. 100 times more dilute than the gel formation concentration) but as a large spherical aggregate with the radius of gyration $R_G$, of 232 nm and the effective hydrodynamic radius $R_H$= of 407 nm at $40^{\circ}C$. Based upon experimental results such as $R_H/R_G$=ratio of 1.75 and the pattern of scattering intensity with a minimum, a core-shell type sphere model was suggested as a structure of the aggregate. According to this model, the radius of core part was estimated as 215 nm, the shell thickness as 192 nm, and the ratio of monomer density of the shell part to that of the core part as about 0.075.

• Journal of the Korean Chemical Society
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• v.24 no.3
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• pp.245-249
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• 1980

Uranium (Ⅵ) was extracted from dilute aqueous solutions of uranyl nitrate with acetylacetone and tri-n-butyl phosphate in n-dodecane. Synergistic effect was observed with the mixed reagents above pH 1. The species extracted are the 1:2:1 and the 1:2:2 uranyl-AA-TBP complexes. The extraction constants for these reactions have been determined.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.11b
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• pp.565-570
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• 1996

$^{32}$P는 순수한 $\beta$$^{-}$ 방출핵종(방출에너지 ＝ 1.71 MeV, 반감기 ＝ 14.3일)이며 의료용, 표지화합물 합성용, 유전공학 실험용 등으로 널리 사용되므로 고품질의 $^{32}$P의 수요에 부응하기 위해 감압증류법을 개발하였는 바 그 방법과 결과는 다음과 같다. 연구로 2호에서 중성자 조사된 황 표적을 감압 증류용기내에서 5~10 mmHg의 감압하에 200~30$0^{\circ}C$로 가열하여 황을 증류해 낸 다음 묽은 염산을 역류시켜 넣고 $^{32}$P 를 울궈냈다. 이 용액을 이온교환 수지로 정제하여 약 60 mCi/batch의 정제 $^{32}$P를 얻었다. 이온교환수지에 흡착되는 $^{32}$P의 방사능은 전체의 3% 미만이었고 여기에 흡착되는 불순 핵종은 $^{131}$ Ba, $^{85}$ Sr, $^{59}$ Fe, $^{65}$ Zn, $^{60}$Co이었다. 이 방법으로 얻은 $^{32}$P 최종제품은 핵종순도 >99%, 방사화학적 순도 >98%, 고형성분 함량 <1.2 mg/mL 이어서 그 품질이 우수함을 알 수 있었다.

• Resources Recycling
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• v.17 no.4
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• pp.37-46
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• 2008

In view of the increasing importance of the waste recycling to meet the strict environmental regulations, the present investigation reports an adsorption process using cationic exchanger DOWEX G-26 for the recovery of copper from the synthetic sulphate solutions containing copper 0.3 to 0.5 mg/ml, similar to the CMP waste effluent of electronic industry. Various process parameters viz. contact time, solution pH, resin dose, and A/R ratio for elution were investigated to recover copper from the effluents. Complete adsorption of copper from the solution was achieved at equilibrium pH 2.5 and aqueous I resin (A/R) ratio of 100 ml/g in 14 minutes contact time. The adsorption of copper on DOWEX G-26 resin was found to follow the Langmuir isotherm and second order reaction. The copper was eluted from loaded resin with dilute sulphuric acid to produce copper-enriched solution.

• Polymer(Korea)
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• v.36 no.5
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• pp.628-636
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• 2012

The polymer concentration dependence of depletion layer was investigated by means of dynamic light scattering after the very small amount of polystyrene spherical latex particles was added into the matrix solution of poly(vinyl alcohol)(PVA)/dimethyl sulfoxide. At the dilute regime, the magnitude of depletion layer kept constant at the level of $63{\pm}3%$ of the radius of gyration of the corresponding PVA chain. Next, at the early semi-dilute regime of $1.5{\leq}C[{\eta}]{\leq}3$, polymer concentration dependence of the layer thickness ${\delta}$ was obtained as ${\delta}{\sim}C^{-0.8}$, and this experimental value was very close to theoretical one of -0.75. However it was observed above $C[{\eta}]$ >3 that its thickness decreased abruptly, and this was ascribed to aggregation effect of latex particles which was driven by Oosawa type attractive interaction.