Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Solvent Extraction of Uranium with Acetylacetone and Tri-n-Butyl Phosphate in n-Dodecane

아세틸아세톤과 트리부틸인산의 도데칸용액에 의한 우라늄의 용매추출

  • Published : 1980.06.30
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Abstract

Uranium (Ⅵ) was extracted from dilute aqueous solutions of uranyl nitrate with acetylacetone and tri-n-butyl phosphate in n-dodecane. Synergistic effect was observed with the mixed reagents above pH 1. The species extracted are the 1:2:1 and the 1:2:2 uranyl-AA-TBP complexes. The extraction constants for these reactions have been determined.

도데칸에 녹인 아세틸아세톤과 트리부틸인산으로 묽은 질산우라닐수용액에서 우라늄(Ⅵ)을 추출했다. pH 1 이상에서 이 혼합추출제의 상승적 효과가 관측되었다. 추출되는 화학종은 1:2:1 및 1:2:2 우라닐-아세틸 아세톤-트리부틸 인산착물이다. 이들 반응의 추출정수들을 측정하였다.

Keywords

References

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