• Title/Summary/Keyword: 묽은 산

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A Study on the Efficient Use of Fused Phosphate for the Improvement of Upland Soil Productivity (토양(土壤)의 생산력증진을 위(爲)한 용성인비(鎔成燐肥)의 효과적인 시용법에(施用法) 관(關)하여)

  • Oh, Wang Keon;Han, Dong Uk;Lee, Jung Jai
    • Korean Journal of Soil Science and Fertilizer
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    • v.5 no.2
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    • pp.53-57
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    • 1972
  • In order to obtain some informations on the improvement of fertility of poor red yellow soils widely distributed in hilly lands of Korean peninsula, a pot culture study was made with a hill land soil in comparison with a fertile soil commonly used for vegetables. The results are as follows; 1. In addition to the normal application of phosphate, the mixing of a large dose of fused phosphate with whole soil increased the yeild of chinese cabbage remarkably, having the promotion particulary of the available phosphate level in the acidic low fertility soil. At the sometime the mixing seemed to short down the period of soil maturing to fertile for good crop. It is, however, considered that such effect of fused phosphate must also be evaluated economically through a long term experiment. 2. A relatively close relationship between the soil phosphate soluble in dilute acid and chinese cabbage growth was observed.

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Nitration of Chlorobenzenes with NO2-O3 (이산화질소-오존을 이용한 클로로벤젠들의 니트로화 반응)

  • Lee, Bon-Su;Chung, Kyoo-Hyun;Lee, Won-Heui;Kim, Young-Su;Kim, Tae-Hyoung
    • Applied Chemistry for Engineering
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    • v.7 no.3
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    • pp.530-535
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    • 1996
  • Nitrochlorobenezenes are used as intermediates for dyes, pharmaceuticals and perfumes. By far the most common industrial nitration process employs a mixture of nitric acid and sulfuric acid. Due to water formed in the reaction, the mixed acid nitration requires subsequent separation of spent acid, mainly dilute sulfuric acid. In the stream of ozone, nitrogen dioxide can be used as a nitrating agent for the nitration of chlorobenzene. With 6eq of $NO_2$ and 1.0eq/hr of ozone flow, the mononitration of chlorobenzene ended within 3hr at $0^{\circ}C$ while the dinitration of chlorobenzene did in 12hr. This method can be employed for the nitration of some aromatic compounds to reduce pollutants from the present mixed-acid process.

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Controlling of Molecular Weight and Degree of Deacetylation of Chitosan and Its Characteristics in Film Formation (키토산 분자량과 탈아세틸화도 조절 및 이에 따른 필름 특성)

  • Hwang, Kwon-T.;Park, Hyun-J.;Jung, Soon-T.;Ham, Kyung-S.;Yoo, Yong-K.;Cho, Gun-S.
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.5 no.1
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    • pp.47-55
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    • 1999
  • Applications of chitosan are related to molecular weight and degree of deacetylation(DOD) of chitosan completely. The molecular weight and DOD were greatly affected by the concentration of solution time and temperature. The degree of demineralization was not significantly different at $50^{\circ}C\;and\;70^{\circ}C$ after 30 minutes. Deproteinization decreased as process time increased. The nitrogen content was reached to 6.92% after 90 minute at $80^{\circ}C$, which is similar to theoretical nitrogen content of chitin. The DOD was 82.84% after 2 hours reaction and increased as the reaction time increased in the process. Viscosity and molecular weight are increased as recycling number of concentrated NaOH solution increased. Chemical, biological and physical properties of chitosan depend on the DOD and molecular size of the molecule. Tensile strength of the films from acetic acid solutions was between $28.9{\sim}33.6$ MPa and was generally higher than that of the films from lactic acid. Elongation of the films from lactic acid was between $97.0{\sim}109.7%$ and was generally higher than that of the films from the acetic acid. Water vapor permeability of the films prepared from lcetic acid solutions was between $1.9{\sim}2.3ng{\cdot}m/m^2{\cdot}s{\cdot}Pa$ and was generally higher than that of the films from the acetic acid.

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Blood-Anticoagulant Activity of Fucoidans from Sporophylls of Undaria pinnatifida, Laminaria religiosa, Hizikia fusiforme and Sargassum fulvellum in Korea (국내산 미역포자엽, 다시마, 톳, 모자반 fucoidan의 항혈액응고 특성)

  • KOO Jae-Geun;CHOI Yong-Seok;KWAK Jung-Ki
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.5
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    • pp.515-520
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    • 2001
  • The anticoagulant activities of fucoidan fractions extracted from Sporophylls of Undaria pinnatifida, Laminaria religiosa, Hizikia fusiforme and Sargassum fulvellum were studied to assess the relationship between chemical characteristics and the activities. Crude fucoidans extracted with diluted HCl solution (pH 2.0) at $65^{\circ}C$ were precipitated with cetylpyridinum chloride and then fractionated by dissolving the precipitated complex with increasing $CaCl_2$, concentrations (1.0 M, 1.5 M, 3.0 M). The anticoagulant activities of the fractions with respect to activated partial thromboplastin (APTT) increased with increase in their sulfate content and Undaria finnatifida Fr-3.0 fraction, prepared by dissolving with 3.0 M $CaCl_2$ solution, exhibited the highest activity. The Undaria finnatifida Fr-3.0 fraction was further modified with pronase and laminase. The pronase and laminase treatment decreased protein and glucose content and the APTT activity was higher than that or parent Undaria finnatifida Fr-3.0 fraction. The pronase and laminase modified Undaria finnatifida Fr-3.0 was composed of fucose, galactose, mannose, sulfate, uronic acid in the approximately molar ratio of 1.00 : 1.30: 0.03 : 2.70 : 0.08.

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Ion Exchange of Copper from Sulphate Effluent using DOWEX G-26 (황산용액(黃酸溶液)으로부터 DOWEX G-26에 의한 구리의 회수(回收))

  • Nguyen, Nghiem Van;Lee, Jae-Chun;Jha, Manis Kumar;Kim, Min-Seuk;Jeong, Jin-Ki;Hwang, Taek-Sung
    • Resources Recycling
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    • v.17 no.4
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    • pp.37-46
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    • 2008
  • In view of the increasing importance of the waste recycling to meet the strict environmental regulations, the present investigation reports an adsorption process using cationic exchanger DOWEX G-26 for the recovery of copper from the synthetic sulphate solutions containing copper 0.3 to 0.5 mg/ml, similar to the CMP waste effluent of electronic industry. Various process parameters viz. contact time, solution pH, resin dose, and A/R ratio for elution were investigated to recover copper from the effluents. Complete adsorption of copper from the solution was achieved at equilibrium pH 2.5 and aqueous I resin (A/R) ratio of 100 ml/g in 14 minutes contact time. The adsorption of copper on DOWEX G-26 resin was found to follow the Langmuir isotherm and second order reaction. The copper was eluted from loaded resin with dilute sulphuric acid to produce copper-enriched solution.

Study on the Elution Behaviors of Uranium and Vanadium in the Various Acids by Anion Exchange Chromatography (음이온 교환크로마토그래피법에 의한 여러가지 산에서 우라늄과 바나듐의 용리현상에 관한연구)

  • Ki-Won Cha;Jong-Hun Kim
    • Journal of the Korean Chemical Society
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    • v.28 no.5
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    • pp.309-314
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    • 1984
  • The species and equilibria of uranium and vanadium have been investigated in the various concentration of perchloric, hydrochloric and sulfuric acid by anion exchange chromatography. In the concentration range of $0.01\;{\sim}\;0.5M$ hydrochloric and $0.01\;{\sim}\;0.5M$ perchloric acid, uranium seems to be $UO_2^{2+}$species and in higher concentration than 0.5M hydrochloric acid $UO_2^{2+}$seems to form the chloride complex ion as $UO_2Cl^+$, $UO_2Cl_2$, $UO_2Cl_3^-$ and $UO_2Cl_4^{2-}$ according to the increase of the hydrochloric acid concentration. In the dilute(0.01N) sulfuric acid the adsorbability of uranium on anion exchange resin is strong and then decreases with increasing the sulfuric acid concentration. From this result we conclude that $UO_26{2+}$ formed the complex ion as $UO_2(SO_4)_2^{2-}$. In the perchloric acid of $0.01\;{\sim}\;0.5N$ concentration the existing equilibrium of vanadium and its constant calculated at $20^{\circ}C$ is $1.9{\times}108$ for $H_2V_{10}O_{28}^{4-}$ + $14H^+$ = $10VO_2^+ + 8H_2O$. The elution behaviors of vanadium in the hydrochloric and sulfuric acid are smiliar to those in perchloric acid.

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Storage and Acceptability of a Smoked Sebastes schlegeli Product (훈연처리에 의한 조피볼락의 저장성 및 기호도)

  • Lee, In-Sung;Kim, In-Cheol;Chae, Myoung-Hee;Chang, Hae-Choon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.36 no.11
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    • pp.1458-1464
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    • 2007
  • This study was conducted to develope a new type of ready-to-eat smoked Sebastes schlegeli product with high acceptability and extended shelf-life. A Sebastes schlegeli was salted at 4% salt concentration for 6 hr at $4^{\circ}C$. The cold smoking conditions for the salted Sebastes schlegeli consisted of drying for 2 hr at $22{\sim}24^{\circ}C$ followed by smoking for 2 hr at $22{\sim}24^{\circ}C$. The warm smoking conditions for the salted Sebastes schlegeli consisted of drying for 2 hr at $22{\sim}24^{\circ}C$, smoking for 2 hr at $22{\sim}24^{\circ}C$, and smoking again for 30 min at $47{\sim}50^{\circ}C$. The rancidity of the smoked Sebastes schlegeli did not change after 1 year storage at $-20^{\circ}C$ by monitoring the iodine value, peroxide value, and acid value. The number of viable cells in the cold and warm smoked samples were counted as $7.4{\times}10^5$ and $6.2{times}10^5$ CFU/g, respectively. Viable cells were not detected after 1 year of storage at $-20^{\circ}C$. The sensory evaluations of the processed Sebastes schlegeli showed that elastic texture increased with smoking as compared to with salting. There were no significant differences between cold and warm smoking in terms of sweetness, elastic texture, color, and smoke flavor. However, for overall acceptability, preference were in the oder of cold smoked, warm smoked, and salted.

A Correlation between the Fractionation of Heavy Metals in the Paddy Soil of the Mangyeong River Basin and their Uptake by Rice Plants Grown on it (만경강 유역 논 토양 중 중금속 형태분류와 수도체의 흡수량과의 관계)

  • Kim, Seong-Jo;Baek, Seung-Hwa;Moon, Kwang-Hyun
    • Korean Journal of Environmental Agriculture
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    • v.15 no.3
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    • pp.372-382
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    • 1996
  • In order to elucidate the relationship between the mobility of heavy metals in soil and their uptake by plants, the soil samples collected from the Mangyeong River area were analyzed for the contents and existing forms of the heavy metals and the correlation between the contents of heavy metals in the soil and those in various parts of rice plants therefrom. The soil samples were collectes from ten sites in the paddy fields in 1982 and 1990, respectively, and the analysis on heavy metals including Cd, Zn, Cu and Pb was performed. The results are as follows: Total contents of heavy metals in the samples of 1990 were higher than those of 1982. The extent of increase was that Cd, Zn, Cu and Pb were 3, 29, 59 and 8% in top soil and 8, 50, 91 and 8% in sub-soil, respectively. The order of increasing ratio was Cu > Zn > Pb > Cd and the variation of Cd content by sequentially different extraction was organically bound > dilute acid-extractable=Fe-Mn oxide bound > exchangeable > residual fractions and the content of Cd with organically bound was $46.62{\sim}48.08$ and $41.18{\sim}50.18%$ of total Cd in top and sub-soil, respectively. The ratios of immobile heavy metals, Cd, Pb, Cu and Zn, bound within an oxide or silicate matrix of Fe-Mn oxide in top-soil were 21.25, 35.98, 74.18 and 82.12%, respectively, and consequently their mobile ratios of exchangeable, dilute acid-extractable and organically bound were more than 17.88%. Those of mobile Cd, Pb, Cu and Zn were 78.25, 64.02, 25.82 and 17.88%, respectively. Except for Pb a correlation between the contents of Cd, Zn, and Cu of exchangeable and dilute acid-extractable in top-soil and those in leaf blade, stem and panicle axis was significant, but was not significant in sub-soil.

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Nutritional quality evaluation of complementary baby food products in Korea according to food composition (국내 시판 간편 이유식의 식품 구성에 따른 영양적 질 평가)

  • Eun-Ju Lee;Jee-Young Yeon;Mi-Hyun Kim
    • Journal of Nutrition and Health
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    • v.56 no.5
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    • pp.537-553
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    • 2023
  • Purpose: The purpose of this study was to evaluate the nutritional quality of complementary baby food products sold in Korea according to the baby food stages and food composition. Methods: A total of 1,587 complementary food products sold online and offline between March and December 2021 were investigated. They ranged from liquid meals to solid rice for babies aged 5 to 36 months. Results: The number of intakes per packaged volume was 2.8 in Stage 1, 1.9 in Stage 2, 1.4 in Stage 3, and 1.1 in Stage 4 (p < 0.0001). The dietary variety scores (DVS) of the complementary baby food products were 3.4 in Stage 1, 5.5 in Stage 2, 7.1 in Stage 3, and 9.7 in Stage 4 (p < 0.0001) and showed a significant increase in the later stages. The Korean dietary diversity score (KDDS) significantly increased from 2.3 in Stage 1, to 2.8 in Stage 2, 3.0 in Stage 3, and 3.4 in Stage 4 (p < 0.0001). The higher the baby food stage, the higher the proportion of grains/meat/vegetable ingredients. The ratio of protein intake to Adequate Intake (AI) or Recommended Nutrition Intake (RNI) was higher in products with a KDDS of 3 points or more, or in products with 2 points or fewer in Stages 1 and 2 (p < 0.0001, respectively). The ratio of protein intake to RNI increased as the KDDS score increased in Stages 3 and 4 (p < 0.0001, respectively). For all stages of baby foods, the ratio of protein intake to AI or RNI was high in products that included the meat group (beans, nuts, meat, eggs, fish, and shellfish) (p < 0.0001, respectively). Conclusion: Continuous research and nutritional evaluation are required for establishing nutrient content standards for commercially available baby foods, considering breast milk intake.