• Title/Summary/Keyword: 물리ㆍ화학적 특성

Search Result 49, Processing Time 0.022 seconds

A Study on Characteristics of Jointed Rock Masses and Thermo-hydro-mechanical Behavior of Rock Mass under High Temperature (방사성 폐기물 저장을 위한 불연속 암반의 특성 및 고온하에서의 암반의 수리열역학적 상호작용에 관한 연구)

  • 이희근;김영근;이희석
    • Tunnel and Underground Space
    • /
    • v.8 no.3
    • /
    • pp.184-193
    • /
    • 1998
  • In order to dispose radioactive wastes safely, it is needed to understand the mechanical, thermal, fluid behavior of rockmass and physico-chemical interactions between rockmass and water. Also, the knowledge about mechanical and hydraulic properties of rocks is required to predict and to model many conditions of geological structure, underground in-situ stress, folding, hot water interaction, intrusion of magma, plate tectonics etc. This study is based on researches about rock mechanics issues associated with a waste disposal in deep rockmass. This paper includes the mechanical and hydraulic behavior of rocks in varying temperature conditions, thermo-hydro-mechanical coupling analysis in rock mass and deformation behavior of discontinuous rocks. The mechanical properties were measured with Interaken rock mechanics testing systems and hydraulic properties were measured with transient pulse permeability measuring systems. In all results, rock properties were sensitive to temperature variation.

  • PDF

Biodegradation of Recalcitrant Chlorinated Aromatic Compounds via Microbial Dechlorination (미생물의 탈염소화 작용에 의한 난분해성 염화방향족 오염물질의 분해)

  • 채종찬;김치경
    • Korean Journal of Environmental Biology
    • /
    • v.17 no.2
    • /
    • pp.129-138
    • /
    • 1999
  • Chlorinated aromatic compounds are one of the largest groups of environmental pollutants as a result of world-wide distribution by using them as herbicides, insecticides, fungicides, solvents, hydraulic and heat transfer fluids, plasticizers, and intermediates for chemical synthesis. Because of their toxicity, persistence, and bioaccumulation, the compounds contaminated ubiquitously in the biosphere has attracted public concerns in terms of serious influences to wild lives and a human being, such as carcinogenicity, mutagenicity, and disturbance in endocrine systems. The biological recalcitrance of the compounds is caused by the number, type, and position of the chlorine substituents as well as by their aromatic structures. In general, the carbon-halogen bonds increase the recalcitrance by increasing electronegativity of the substituent, so that the dechlorination of the compounds is focused as an important mechanism for biodegradation of chlorinated aromatics, along with the cleavage of aromatic rings. The removal of the chlorine substituents has been known as a key step for degradation of chlorinated aromatic compounds under aerobic condition. This can occur as an initial step via oxygenolytic, reductive, and hydrolytic mechanisms. The studies on the biochemistry and genetics about microbial dechlorination give us the potential informations for microbial degradation of xenobiotics contaminated in natural microcosms. Such investigations might provide biotechnological approaches to solve the environmental contamination, such as designing effective bioremediation systems using genetically engineered microorganisms.

  • PDF

Effect of Feeding Dietary Oils on Physico-Chemical Changes of Pork during Storage (오일 급여가 돈육의 저장 중 물리ㆍ화학적 변화에 미치는 영향)

  • 진상근;김일석;송영민;정기화;이성대;김희윤;남기윤;하경희;강양수
    • Food Science of Animal Resources
    • /
    • v.23 no.3
    • /
    • pp.227-235
    • /
    • 2003
  • The results were obtained from pigs which had been fed finishing pig diets containing 5% beef tallow(C) as control and 2% perilla seed oil(Tl), 3% beef tallow and 2% squid viscera oil(T2), 3% beef tallow and 2% CLA(conjugated linoleic acid, T3). All porks were stored at 1$^{\circ}C$ for 28 days. pH value of control group was higher than other treatments. Water holding capacity(WHC) did not show any significant difference among treatments, however, WHC of C and T3 was increased as storage days increased. Protein solubility of T3 was higher than the other treatments, but that of all groups increased up to 14 days of storage and then decreased. The a* value of C was higher than the others, but b* value was low on 28 days of storage. Volatile base nitrogen(VBN) value of T3 showed the highest level, but that of Tl was the lowest. Thiobarbituric acid reactive substances(TBARS) of T2 and T3 were' higher than those of C and Tl. In sensory analysis, meat color and overall acceptability of C were higher than those of the other treatments in raw meat, and meat appearance was higher than level in Tl.

A Study of Engineering Properties of Rock Mass Weathered by Sea water (해수에 의한 암반 풍화의 공학적 특성 연구)

  • Choi Kang-Il;Kang Coo-Won;Go Chin-Surk
    • Explosives and Blasting
    • /
    • v.23 no.1
    • /
    • pp.9-17
    • /
    • 2005
  • This study is to clarify the comparative relationship and mechanical anisotropy of granite distributed in the Nam-weon on the subject of weathered rock mass sea water surroundings. Artificial weathering test is defined as a test, which controls the weathering rate and agents by controlling the weathering rate and agents by artificial environmental of salt water. Increased weathering degree is large indicated by weathering salt water, such as apparent specific gravity, absorption, porosity, uniaxial compression strength, P-wave velocity, slake durability, shore hardness, indirect tensile strength(brazilian test) and cohesion were measured. As the Weathering salt water proceeds, cracks develope increasingly. A number the cracks affect the rock deformation. Therefore, stress-strain curve of weathered salt water rock in one confined state are quite differ from weathered fresh water rock those. A reason of their deformation type is the formation of micro-cracks and potential porosity caused by artificial weathering test.

Effects of Evaporation on the Weathering Rate and Chemical Composition of Iranian Heavy Crude Oil (이란산 원유의 증발에 따른 풍화율 및 화학적 성상 변화)

  • Kim, Beom;Kim, Gi-Beum;Sim, Won-Joon;Yim, Un-Hyuk
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.15 no.3
    • /
    • pp.238-246
    • /
    • 2012
  • Once oil is spilled into marine environment, it experiences various weathering processes among which evaporation is the most dominant process in the initial stage of weathering. This study aimed to elucidate the effects of evaporation on the physicochemical properties of spilled oil using standardized laboratory experiments. Laboratory evaporation process was successfully reproduced using controlled rotary evaporation method. In case of Iranian Heavy crude (IHC), evaporation rate after 48 hours was $29.3{\pm}0.4%$ (n=40, p<0.001). Evaporation was simulated using ADIOS2 weathering model and the result was in agreement with laboratory experiment. Chemical composition changes of petroleum hydrocarbons including alkanes, polycyclic aromatic hydrocarbons (PAHs) and biomarkers by evaporation rate were also analyzed. As oil evaporated, low molecular weight alkanes and PAHs decreased, while biomakers showed conservative characteristics. Among biomarkers, $17{\alpha}(H)$, $21{\beta}(H)$-hopane was used for calculation of weathering rates, which matched with evaporative mass losses. Weathering rate calculation using hopane showed that stranded oils of weathering stage I (28.9%) and mesocosm oil weathering experiment till 5 days (26.5%) were mainly affected by evaporation process.

Development of a Nutriculture System for Fruit Vegetables Using Perlite and Its Mixtures with Other Substrates II. Effects of Substrates on the Growth and Fruit Quality of Hydroponically Grown Tomato (Perlite 단용 및 혼용처리를 이용한 과채류 양액재배 기술 개발 II. 배지의 종류가 양액재배 토마토의 생장과 과실품질에 미치는 영향)

  • 정순주;서범석;이범선;이정현
    • Journal of Bio-Environment Control
    • /
    • v.5 no.1
    • /
    • pp.7-14
    • /
    • 1996
  • This experiment was carried out to investigate the growth and yield responses of hydroponically grown tomato as affected by the different substrates using perlite and mixtures with perlite. Substrates used in this experiment were perlite (fine and coarse granule), peatmoss, rice hull and carbonized rice hull. The results obtained were as follows ; The best results in terms of total fruit yield and average fruit weight obtained in the single treatment of perlite, followed by perlite mixture with rice hull and carbonized rice hull. Leaf area was also higher in the plots of perlite mixture and optimum mixing ratio of perlite, peatmoss and carbonized rice hull was determined as 5:3:2 by volume. The more the rice hull was added to the mixed substrates, the less in fruit production was observed. However, adding perlite to other substrates brought higher fruit yield. Single treatment of rice hull showed the lowest fruit yield but enhanced in soluble solids contents over 6.0 $^{\circ}$Brix at each cluster.

  • PDF

Studies on the Patterning of Polyimide LB Film and Its Application for Bioelectronic Device (폴리이미드 LB 필름을 이용한 패터닝 및 생물전자 소자로의 응용에 관한 연구)

  • 오세용;박준규;정찬문;최정우
    • Polymer(Korea)
    • /
    • v.26 no.5
    • /
    • pp.634-643
    • /
    • 2002
  • Ultrathin film of polyamic acid having benzene and sulfonyloxyimide moieties was prepared using the Langmuir-Blodgett (LB) technique, and then photosensitive polyimide LB film was obtained by the thermal treatment of precursor polyamic acid multilayers at 200$\^{C}$ for 1 hr. The polyamic acid was synthesized by condensation polymerization under THF and pyridine cosolvent. All monomers and polymers were identified through elemental analysis, FT-IR and $^1$H-NMR spectroscopic measurements. The microarray patterning of photosensitive polyimide LB film on a gold substrate was generated with a deep UV lithography technique. The well-characterized monolayer of cytochrome c was immobilized on the microarray patterns using two different self-assembly processes. Physical and electrochemical properties of the self-assembled cytochrome c monolayer were investigated based on cyclic voltammetry and atomic force microscopy (AFM). Also, its application in bioelectronic device was examined.

A Study on the Marine Biological and Chemical Environments in Yeosu Expo Site, Korea (여수 엑스포 해역의 생물.화학적 해양환경 특성)

  • Noh, Il-Hyeon;Oh, Seok-Jin;Park, Jong-Sick;An, Yeong-Kyu;Yoon, Yang-Ho
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.13 no.1
    • /
    • pp.1-11
    • /
    • 2010
  • In order to understand the biological environmental characteristics with temporal variations of the physico-chemical factors in 2012 Yeosu Expo site of Korea, we investigated at one station, once per week, from April 2006 to December 2007. The surface water temperature ranged from 6.8 to $27.8^{\circ}C$ and the bottom water temperature ranged from 6.3 to 25.9 $25.9^{\circ}C$. The salinity varied from 12.8 to 33.0 psu in the surface water and from 25.2 to 33.6 psu in the bottom water. A strong halocline was observed between the surface and bottom layers in the summer when a rapid decrease of salinity coincided with heavy rainfall. The DIN concentration ranged from 1.36 to $82.7{\mu}M$ in the surface water and from 0.82 to $25.2{\mu}M$ in the bottom water. Phosphate concentration varied from 0.06 to $2.13{\mu}M$ in the surface water and from 0.07 to $1.38{\mu}M$ in the bottom water. Silicate was $1.68-52.0{\mu}M$ in the surface water and $1.37-30.7{\mu}M$ in the bottom water. The nutrient concentrations were generally high during heavy rainfalls and low water temperature periods, and considerably decreased in spring and autumn. The N/P ratio ranged from 4.43 to 325 in the surface water and from 3.8 to 321 in the bottom water. It increased rapidly during the heavy rainfall season and remained at a value of approximately 16 in other periods. The chlorophyll a concentration ranged from 0.46 to $65.0{\mu}g$ $L^{-1}$ in the surface water and from 0.71 to $15.0{\mu}g$ $L^{-1}$ in the bottom water. $Chl-{\alpha}$ concentration remained low in periods of low water temperature, however rapidly increased in periods of high water temperature. From the results of principal component analysis (PCA) and multiple regression analysis (MRA), we conclude that temporal variations of physico-chemical and biological factors were greatly affected by the influx of fresh water, and that nutrients were well controlled by their uptake and assimilation by phytoplankton. Also, during the low water temperature periods, environmental structure in this study site was affected by recycled nutrients through nutrient cycling and mineralization.

Distribution of rhysico-chemical Characteristics on the Development of Marine Ranching Program in the Chagwi-Do Coastal Waters, Jeju Island (제주도 바다목장화개발 해역인 차귀도 연안해역의 이화학적특성)

  • Choi, Young-Chan;Kim, Jin-Seok
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.11 no.2
    • /
    • pp.105-112
    • /
    • 2008
  • The surface and bottom water were sampling in ten stations of the coastal area of Chagwi-Do, Jeju Island, which was repeated 6 times in several different months(September, November, 2004 and March, May, August, and November 2005) in order to examine the physico-chemical characteristics of water. The temperature varied by approximately $16^{\circ}C$, ranging somewhere between 1$12.2^{\circ}C$ and $28.9^{\circ}C$. Specifically, the temperature of bottom water was $13^{\circ}C$, implying the emergence of low temperature water. The salinity ranged from 30.2 to 34.9%o, and the lowest salinity in August may be attributable to the effect of land-based water. N/P ratio, the growth factor of phytoplankton, ranged from 5 to 76, which varied depending on the season and station. The ratio, however, was over 22 on the average, suggesting that phosphate phosphorus is an factor that restricts the growth of phytoplankton. TOC in the concentration of organic carbon ranged between $92.5{\mu}M$ and $438.3{\mu}M$, and the mean was $217{\mu}M$. DOC ranged from $82.5{\mu}M$ to $299.2{\mu}M$, and the mean was $130{\mu}M$. The ratio of DOC/POC was 60% with abundant dissolved organic carbon.

  • PDF

A Study on the Optimum Environmental Conditions for the Creation and Restoration of Artificial Tidal Flat (인공간석지 창출과 복원을 위한 최적환경조건 선정에 관한 연구)

  • Lee Jeoung-Gyu;Okada Mitsumasa
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.2 no.1
    • /
    • pp.102-112
    • /
    • 1999
  • The purpose of this study is to evaluate the effects of design criteria and environmental conditions of the site of created tidal flats on the structure and function of man-made ecosystem. Seven constructed tidal flats and three natural tidal flats were studied taking the difference in the location (wave height and tidal current), inflow of river water, slope of tidal flat and age after the construction completed into consideration. Parameters studied were physico-chemical and biological characteristics of soils and rate of respiration. The natural tidal flats had higher contents of silt, nitrogen and organic matter compared with the constructed ones. The natural ones had reductive zone below 2cm, whereas the constructed ones had aerobic zone from the surface to below 20cm. The bacterial population in the soil of the constructed tidal flats was one to two orders of magnitude lower than that in the natural ones. Both biomass of macrobenthos and microbial respiration rate, however, were not different significantly between the natural and the constructed tidal flats. There was an exceptional constructed tidal flat with similar physico-chemical and biological characteristics to the natural ones. It is most probable that sufficient conditions to have similar tidal flats to natural ones are the location in enclosed bay or calm coastal area. Thus, to make man-made tidal flats with the same characteristics as those in natural ones, man-made tidal flats should be designed and/or located to enhance the accumulation of silt on tidal flat. It is important to select a place having low water motion for construction of tidal flat.

  • PDF